The present study focuses on the synthesis and characterization of lanthanum(La^(3+))-doped calcium nanoferrites(CaLa_(x)Fe_(2-x)O_(4):x=0.025,0.050,0.075 and 0.100)using the sonochemical *** techniques were employed ...
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The present study focuses on the synthesis and characterization of lanthanum(La^(3+))-doped calcium nanoferrites(CaLa_(x)Fe_(2-x)O_(4):x=0.025,0.050,0.075 and 0.100)using the sonochemical *** techniques were employed to analyze the effect of La^(3+)infusion,Raman spectroscopy confirms the presence of active A_(1g),T_(2g)and E_g modes in the CaLa_(x)Fe_(2-x)O_(4)nanoferrite,indicating the formation of an active ferrite *** introduction of La^(3+)doping results in a significant increase in the band gap energy,rendering the nanoferrites insulating(3.23-3,57 eV).At higher frequencies,the impedance studies reveal minimal losses and better AC conductivity,pointing to improved dielectric *** higher frequencies,the Q-factor of La-doped calcium nanoferrites shows lower electromagnetic *** M-H curve exhibits ferromagnetic behavior,with La^(3+)-doped calcium nano ferrites displaying a saturation magnetization ranging from 12.72 to 18.10 emu/*** incorporation of La^(3+)also induces enhanced electrical polarization,leading to notable dielectric loss and increased absorption of electromagnetic ***,these CaLa_(x)Fe_(2-x)O_(4)nanoferrites demonstrate potential as effective microwave absorbers across a wide frequency range,with significant shielding absorption observed at 8.8-9.1 GHz.
Margination, a fundamental process in which leukocytes migrate from the flowing blood to the vessel wall, is well-documented in physiology. However, it is still an open question on how the differences in cell size and...
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Margination, a fundamental process in which leukocytes migrate from the flowing blood to the vessel wall, is well-documented in physiology. However, it is still an open question on how the differences in cell size and stiffness of white and red cells contribute to this phenomenon. To investigate the specific influence of cell stiffness, we conduct experimental and numerical studies on the segregation of a binary mixture of artificially stiffened red blood cells within a suspension of healthy cells. The resulting distribution of stiffened cells within the channel is found to depend on the channel geometry, as demonstrated with slit, rectangular, and cylindrical cross sections. Notably, an unexpected central peak in the distribution of stiffened red blood cells, accompanied by fourfold peaks at the corners, emerges in agreement with simulations. Our results unveil a nonmonotonic variation in segregation/margination concerning hematocrit and flow rate, challenging the prevailing belief that higher flow rates lead to enhanced margination.
In 2023,pivotal advancements in artificial intelligence(AI)have significantly *** that in mind,traditional methodologies,notably the p-y approach,have struggled to accurately model the complex,nonlinear soil-structure...
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In 2023,pivotal advancements in artificial intelligence(AI)have significantly *** that in mind,traditional methodologies,notably the p-y approach,have struggled to accurately model the complex,nonlinear soil-structure interactions of laterally loaded large-diameter drilled *** study undertakes a rigorous evaluation of machine learning(ML)and deep learning(DL)techniques,offering a comprehensive review of their application in addressing this geotechnical challenge.A thorough review and comparative analysis have been carried out to investigate various AI models such as artificial neural networks(ANNs),relevance vector machines(RVMs),and least squares support vector machines(LSSVMs).It was found that despite ML approaches outperforming classic methods in predicting the lateral behavior of piles,their‘black box'nature and reliance only on a data-driven approach made their results showcase statistical robustness rather than clear geotechnical insights,a fact underscored by the mathematical equations derived from these ***,the research identified a gap in the availability of drilled shaft datasets,limiting the extendibility of current findings to large-diameter *** extensive dataset,compiled from a series of lateral loading tests on free-head drilled shaft with varying properties and geometries,was introduced to bridge this *** paper concluded with a direction for future research,proposes the integration of physics-informed neural networks(PINNs),combining data-driven models with fundamental geotechnical principles to improve both the interpretability and predictive accuracy of AI applications in geotechnical engineering,marking a novel contribution to the field.
Linear defects such as dislocations and disclinations in ordered materials attract foreign particles since they replace strong elastic distortions at the defect cores. In this work, we explore the behavior of isotropi...
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Linear defects such as dislocations and disclinations in ordered materials attract foreign particles since they replace strong elastic distortions at the defect cores. In this work, we explore the behavior of isotropic droplets nucleating at singular disclinations in a nematic liquid crystal, predesigned by surface photopatterning. Experiments show that in the biphasic nematic-isotropic region, although the droplets are attracted to the disclination cores, their centers of mass shift away from the core centers as the temperature increases. The shift is not random, being deterministically defined by the surrounding director field. The effect is explained by the balance of interfacial anchoring and bulk elasticity. An agreement with the experiment can be achieved only if the model accounts for the disparity of the nematic elastic constants; the so-called one-constant approximation, often used in the theoretical analysis of liquid crystals, produces qualitatively wrong predictions. In particular, the experimentally observed shift towards the bend region around a +1/2 disclination core can be explained only when the bend constant is larger than the splay constant. The described dependence of the precise location of a foreign inclusion at defect cores on the elastic and surface anchoring properties can be used in rational design of microscale architectures.
The passivation of hydrogen atoms and the conformation of textured surfaces under oil-lubricated conditions are effective strategies to obtain amorphous carbon(a-C)films with extremely low *** is critical to understan...
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The passivation of hydrogen atoms and the conformation of textured surfaces under oil-lubricated conditions are effective strategies to obtain amorphous carbon(a-C)films with extremely low *** is critical to understanding the influence mechanism of selective surface hydrogenation on the tribological behaviors of textured a-C film under oil-lubricated *** particular,the interactions of hydrogen atoms and lubricants are confusing,which is enslaved to the in situ characterization *** reactive molecular dynamics(RMD)simulations were conducted to analyze the friction response of textured a-C films with selective hydrogenation surfaces under oil-lubricated *** results indicate that the existence of hydrogen atoms on specific bump sites significantly decreases the friction coefficient(μ)of textured a-C film,which is highly dependent on the surface hydrogen *** repulsion between hydrogen atoms and lubricant molecules prompts the formation of a dense lubricant film on the surface of the mating ***,with the enhancement of the surface hydrogen content,the passivation of the friction interface and the repulsion between hydrogen atoms and lubricants play dominant roles in reducing the friction coefficient instead of hydrodynamic lubrication.
Discovering new superconductors via traditional trial-and-error experimental approaches is apparently a time-consuming process,and the correlations between the critical temperature(Tc) and material features are still ...
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Discovering new superconductors via traditional trial-and-error experimental approaches is apparently a time-consuming process,and the correlations between the critical temperature(Tc) and material features are still *** rise of machine learning(ML) technology provides new opportunities to speed up inefficient exploration processes,and could potentially uncover new hints on the unclear *** this work,we utilize open-source materials data,ML models,and data mining methods to explore the correlation between the chemical features and Tcvalues of superconducting *** further improve the prediction accuracy,a new model is created by integrating three basic algorithms,showing an enhanced accuracy with the coefficient of determination(R2) score of 95.9 % and root mean square error(RMSE) of 6.3 *** average marginal contributions of material features towards Tcvalues are estimated to determine the importance of various features during prediction *** results suggest that the range thermal conductivity plays a critical role in Tcprediction among all element ***,the integrated ML model is utilized to screen out potential twenty superconducting materials with Tcvalues beyond 50.0 *** study provides insights towards Tcprediction to accelerate the exploration of potential high-Tcsuperconductors.
Inorganic perovskitenanostructures have attracted considerable attention for their tunable band gaps and excellent optoelectronic *** is inevitable that phase segregation of halide perovskite usually occurs in mixed-h...
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Inorganic perovskitenanostructures have attracted considerable attention for their tunable band gaps and excellent optoelectronic *** is inevitable that phase segregation of halide perovskite usually occurs in mixed-halide perovskites under a focused laser llumination,which caused by photo-induced halide-ion ***,we reported an uniform perovskite alloy nanowires via a chemical vapor deposition(CvD)*** characterization reveals that these perovskite nanowires have independent linear morphology_with high-quality ***-photoluminescence(PL)spectra exhibit that these nanowire structures show a dual-wavelength emissions at 690 and 570 nm,***,time-dependent PL intensity of the emission peak at 690 nm increased by the decrease of the emission peak at 570 nm under a focused laser llumination,indicating the formation of phase segregation at the excited ***,based on these as-grown halide perovskite CsPbBr2.52lo.48 nanowires,a reasonably optical switch is designed and *** optical switch may have potential applications in timed blasting system and time-delay circuit in the future.
We explore the deuteron under strong magnetic fields in Skyrme *** effects of the derivative dependent sextic term in the Skyrme Lagrangian are investigated,and the rational map approximation is used to de-scribe the ...
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We explore the deuteron under strong magnetic fields in Skyrme *** effects of the derivative dependent sextic term in the Skyrme Lagrangian are investigated,and the rational map approximation is used to de-scribe the *** influences of strong magnetic fields on the electric charge distribution and mass of the deu-teron arediscussed.
Lithium-ion batteries(LIBs)with extreme fast charging(XFC)capability are considered an effective way to alleviate range anxiety for electric vehicle(EV)*** to the high ionic and electronic conductivity of LiNi_(x)Co_(...
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Lithium-ion batteries(LIBs)with extreme fast charging(XFC)capability are considered an effective way to alleviate range anxiety for electric vehicle(EV)*** to the high ionic and electronic conductivity of LiNi_(x)Co_(y)Mn_zO_(2)(x+y+z=1,NCM)cathodes,the inevitable Li plating of graphite in NCM|graphite cell is usually identified as a key bottleneck for XFC ***,the capacity decay mechanism of cathode materials under XFC has not been fully *** this work,three typical NCM cathode materials with different Ni fractions were chosen and their electrochemical performances under XFC associated with structural evolution were investigated.A faster capacity decay of NCMs under XFC conditions is observed,especially for Ni-rich ***-situ X-ray diffraction(XRD)reveals that the multiple caxis parameters appear at the high-voltage regions in Nirich NCMs,which is probably triggered by the larger obstruction of Li(de)***,NCMs with moderate Ni fraction also present a similar trend under XFC *** phenomenon is more detrimental to the structural and morphological stability,resulting in a faster capacity decay than that under low current *** work provides new insight into the degradation mechanism of NCMs under XFC conditions,which can promote the development of NCM cathode materials with XFC capability.
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