The epoxy (EP) resin is being intensively applied in electronics packaging, the 5th generation communication technology (5G) and composite tanks for pressurized hydrogen fuel storage. For these applications, to date i...
The epoxy (EP) resin is being intensively applied in electronics packaging, the 5th generation communication technology (5G) and composite tanks for pressurized hydrogen fuel storage. For these applications, to date it has remained a grand challenge for EP to achieve a demanding property portfolio, e.g., the combination of satisfactory fire retardancy, high thermal conductivity (λ) and excellent mechanical properties. Herein, we report an iron phenylphosphinate-functionalized graphene oxide ( [email protected] ) nanohybrid by a facile yet scalable in-situ self-assembly method. Compared to the virgin EP, the EP nanocomposite with 2.0 wt% of [email protected] shows 42.5 % improvement in the limiting oxygen index (LOI), 46.2 % and 23.5 % reductions in the peak heat release rate (PHRR) and total heat release rate (THR), respectively, and a desired UL-94 V-0 rating. In addition, the resultant EP nanocomposite also exhibits improved tensile strength and λ (increased by 32.6 % and 96.0 %, respectively) relative to virgin EP. Such desirable integrated performances outperform those of the previously-reported EP counterparts, because of the multiple synergistic effects between FeHP and GO. This work provides an innovative strategy for the design of multifunctional EP nanocomposites, which holds the great promise for many industrial applications.
Composites based on poly (trimethylene terephthalate) (PTT)/acrylonitrile butadiene styrene (ABS) blend with maleic anhydride grafted PTT (PTT-g-MA) as a compatibilizer and carbon nanotubes (CNTs) as reinforcers were ...
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Aqueous organic contaminants, including dyes, disinfection by-products (DBPs), pharmaceuticals and personal care products (PPCPs), and other emerging contaminants, have been under research lens due to their potential ...
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We report the large-scale synthesis of photoluminescent single-chain nanoparticles (SCNPs) by electrostatic-mediated intramolecular crosslinking in a concentrated solution of 40 mg mL −1 by continuous addition of the ...
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We report the large-scale synthesis of photoluminescent single-chain nanoparticles (SCNPs) by electrostatic-mediated intramolecular crosslinking in a concentrated solution of 40 mg mL −1 by continuous addition of the free radical initiator. Poly(vinyl benzyl chloride) was charged by quaternization with vinyl-imidazolium for the intramolecular crosslinking by using 2,2-dimethoxy-2-phenylacetophenone (DMAP) as the radical initiator. Under the electrostatic repulsion thus interchain isolation, the intrachain crosslinking experiences the transition from coil through pearl-necklace to globular state. The SCNPs demonstrate strong photoluminescence in the visible range when the non-emissive units are confined thereby. Composition and microstructure of the SCNPs are tunable. The photoluminescent tadpole-like Janus SCNP can be used to selectively illuminate interfacial membranes while stabilizing the emulsions.
In this paper,Nafion membrane was firstly modified by copper phthalocyanine tetrasulfonic acid tetrasodium salt(CuTSPc)to prepare the Nafion/CuTSPc-x composite ***,XRD and SEM results revealed the successful incorpora...
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In this paper,Nafion membrane was firstly modified by copper phthalocyanine tetrasulfonic acid tetrasodium salt(CuTSPc)to prepare the Nafion/CuTSPc-x composite ***,XRD and SEM results revealed the successful incorporation of CuTSPc into Nafion and good compatibility between the two *** proton conductivities of the Nafion/CuTSPc-x composite membranes were evidently higher than pure cast Nafion membrane,and increased with CuTSPc *** them,the Nafion/CuTSPc-6%membrane with the highest ion exchange capacity(1.14 mequivg^(-1))exhibited the highest proton conductivity of 0.084 S cm^(-1)at 30℃and 0.131 S cm^(-1)at 80C,*** fabricated of a membrane electrode assembly(MEA),the Nafion/CuTSPc-4.5%membrane displayed an initial fuel cell performance with a power density of 43.3mWcm^(-2)at room temperature,close to that for pure cast Nafion *** from the compact structure,high proton conductivity and outstanding stability,the Nafion/CuTSPc-x composite membranes show promising potentials for fuel cell applications.
Diarylethene-functionalized liquid-crystalline elastomers (DAE-LCEs) containing thiol-anhydride bonds were prepared and shown to undergo reversible, reprogrammable photoinduced actuation. Upon exposure to UV light, a ...
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Diarylethene-functionalized liquid-crystalline elastomers (DAE-LCEs) containing thiol-anhydride bonds were prepared and shown to undergo reversible, reprogrammable photoinduced actuation. Upon exposure to UV light, a monodomain DAE-LCE generated 5.5 % strain. This photogenerated strain was demonstrated to be optically reversible over five cycles of alternating UV/Visible light exposure with minimal photochrome fatigue. The incorporation of thiol-anhydride dynamic bonds allowed for retention of actuated states. Further, re-programming of the nematic director was achieved by heating above the temperature for bond exchange to occur (70 °C) yet below the nematic-to-isotropic transition temperature (100 °C) such that order was maintained between mesogens. The observed thermal stability of each of the diarylethene isomers of over 72 h allowed for decoupling of photo-induced processes and polymer network effects, showing that both polymer relaxation and back-isomerization of the diarylethene contributed to LCE relaxation over a period of 12 hours after actuation unless bond exchange occurred.
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