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Antioxidant system alterations and oxidative stress caused by polyfluoroalkyl substances (PFAS) in exposed biota: a review

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science of the Total Environment 2025年 977卷 179395页

作者： Soares, Lorena Oliveira Souza de Araujo, Gabriel Farias Gomes, Thais Braga Júnior, Sidney Fernandes Sales Cuprys, Agnieszka Katarzyna Soares, Raquel Moraes Saggioro, Enrico Mendes Laboratory of Environmental Health Assessment and Promotion Oswaldo Cruz Institute Oswaldo Cruz Foundation Av. Brasil 4365 RJ Rio de Janeiro21045-900 Brazil Post-Graduate Program in Public Health and Environment Sergio Arouca National School of Public Health Oswaldo Cruz Foundation Av. Leopoldo Bulhões 1480 RJ Rio de Janeiro21041-210 Brazil Faculty of Science and Technology Norwegian University of Life Sciences P.O. Box 5003 Ås1432 Norway Post-Graduate Program in Environmental Technology and Water Resources Department of Civil and Environmental Engineering – FT University of Brasília Darcy Ribeiro Campus Via L3 Norte DF Brasília70910-900 Brazil

Contamination of aquatic and terrestrial organisms by Perfluoroalkyl substances (PFAS), emerging contaminants, is widespread, as these compounds are present in water, soil, air, and food, owing to their environmental persistence. PFAS exposure induces biochemical process alterations associated with the disruption of the antioxidant defense system in several species. This review aims to discuss how PFAS-induced antioxidant system alterations lead to changes in biochemical processes in different organisms exposed to these pollutants. This disruption, then leads to an imbalance in antioxidant defense systems, contributing to the formation of reactive oxidative species (ROS), which, in turn, can be exacerbate oxidative stress, induce cellular damage, enhance lipid peroxidation, destabilize lysosomal membranes, and cause genotoxic effects, ultimately compromising DNA integrity. In acute tests, PFAS have led to mortality, growth inhibition, diminished behavioral and locomotor abilities, and reproductive impairment. PFAS-induced effects differ with varying species or types of substances, and further bioaccumulation through food chains exacerbates environmental contamination, carrying considerable risks. These findings demonstrate the complex and enduring impact of PFAS on environmental health, emphasizing the importance of this review in corroborating studies on sub-lethal toxicity in exposed organisms and how these effects reflect on the environment. © 2025 Elsevier B.V.

关键词： Biotic

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Determinant of importance-performance and willingness to participate in Komodo adaptive conservation programs

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Journal for Nature Conservation 2024年 81卷

作者： Sianipar, Imelda Masni Juniaty Lee, Chun-Hung Wang, Hurng-Jyuhn Kim, Doo-Chul Suryawan, I Wayan Koko PhD Student in Asia-Pacific Regional Studies College of Humanities and Social Sciences National Dong Hwa University Department of International Relations Faculty of Social Science and Political Science Universitas Kristen Indonesia Department of Natural Resources and Environmental Studies College of Environmental Studies and Oceanography National Dong Hwa University Program in Asia-Pacific Regional Studies College of Humanities and Social Sciences National Dong Hwa University Department of Rural Environment Management Graduate School of Environmental and Life Science Okayama University Ph.D Program in Asia-Pacific Regional Studies College of Humanities and Social Sciences National Dong Hwa University Department of Environmental Engineering Faculty of Infrastructure Planning Universitas Pertamina Jalan Sinabung II Terusan Simprug

This study delves into the evaluation of the Komodo dragons Adaptive Conservation program (KACP) at Komodo National Park in Indonesia through Importance-Performance Analysis (IPA). It aims to understand how the programs components align with community priorities and assess its effectiveness. Utilizing a mixed-methods approach, this research analyzes community perceptions of KACP's critical elements, spanning eco-tourism initiatives to environmental protection strategies. The community is categorized into local advocates, eco-tourism enthusiasts, and eco-community harmonizers, identifying how each group perceives and interacts with various facets of KACP. The findings reveal significant differences in perceptions of importance and performance among these groups, providing insights into areas of strength and those needing improvement. Additionally, the study includes an analysis of demographic influences on these perceptions through Logit and Probit models, aiming to understand the impacts across different community segments. The results highlight the necessity for an adaptive and responsive design in conservation efforts, considering community expectations and ecological impacts. Despite offering comprehensive insights, the study acknowledges limitations in the demographic scope and suggests future research directions, such as longitudinal studies and an expanded analysis of variables. These findings offer critical guidance for policymakers and conservation practitioners to enhance conservation programs’ effectiveness and community alignment, emphasizing the need to adapt to the challenges and changes introduced by KACP. © 2024 Elsevier GmbH

关键词： Adaptive capacity Community perception Conservation strategy evaluation Importance-performance analysis Protected areas

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Ciwars: A Web Server for Antibiotic Resistance Surveillance Using Longitudinal Metagenomic Data

SSRN

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SSRN 2024年

作者： Emon, Muhit Islam Cheung, Yat Fei Stoll, James Rumi, Monjura Afrin Brown, Connor Choi, Joung Min Moumi, Nazifa Ahmed Ahmed, Shafayat Song, Haoqiu Sein, Justin Yao, Shunyu Khan, Ahmad Gupta, Suraj Kulkarni, Rutwik Butt, Ali Vikesland, Peter Pruden, Amy Zhang, Liqing Department of Computer Science Virginia Tech BlacksburgVA24060 United States Fralin Life Science Institute Virginia Tech BlacksburgVA24060 United States Department of Civil and Environmental Engineering Virginia Tech BlacksburgVA24060 United States The Interdisciplinary PhD Program in Genetics Bioinformatics and Computational Biology Virginia Tech BlacksburgVA24060 United States

The rise of antibiotic resistance (AR) poses substantial threats to human and animal health, food security, and economic stability. Wastewater-based surveillance (WBS) has emerged as a powerful strategy for population-level AR monitoring, providing valuable data to guide public health and policy decisions. Metagenomic sequencing is especially promising, as it can yield comprehensive profiles of antibiotic resistance genes (ARGs) and other genes relevant to AR in a single run. However, online analytical platforms to facilitate continuous AR monitoring through longitudinal metagenomic data are lacking. To address this, we introduce Cyberinfrastructure for Waterborne Antibiotic Resistance Surveillance (CIWARS), a web server configured for characterizing key AR trends from longitudinal metagenomic WBS data. CIWARS offers comprehensive ARG and taxonomic profiling, along with detection of anomalous AR indicators over time, aiding in identifying potential events of concern, such as the emergence of resistant strains or outbreaks. Through interactive temporal data visualization, CIWARS enables AR monitoring and demonstrates its potential for informing effective and timely interventions to mitigate the spread and transmission of AR. CIWARS is broadly applicable to longitudinal metagenomic data from any environment and thus could be a valuable tool to support global efforts to combat the evolution and spread of AR, while also guiding agricultural and public health efforts aimed at optimizing antibiotic use when it is needed. The web server is freely available at https://***/. © 2024, The Authors. All rights reserved.

关键词： Gene encoding

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Mercury transformation processes in nature: Critical knowledge gaps and perspectives for moving forward

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Journal of environmental sciences 2022年第9期34卷 152-165页

作者： Zhiyuan Gao Wang Zheng Yanbin Li Yurong Liu Mengjie Wu Shouying Li Ping Li Guangliang Liu Xuewu Fu Shuxiao Wang Feiyue Wang Yong Cai Xinbin Feng Baohua Gu Huan Zhong Yongguang Yin Centre for Earth Observation Science and Department of Environment and GeographyUniversity of ManitobaWinnipegMB R3T 2N2Canada Institute of Surface-Earth System Science Tianjin UniversityTianjin 300192China Key Laboratory of Marine Chemistry Theory and Technology Ministry of Education and College of Chemistry and Chemical EngineeringOcean University of ChinaQingdao 266100China State Key Laboratory of Agricultural Microbiology Huazhong Agricultural UniversityWuhan 430070China School of the Environment Nanjing UniversityState Key Laboratory of Pollution Control and Resource ReuseNanjing 210023China State Key Laboratory of Environmental Geochemistry Institute of GeochemistryChinese Academy of SciencesGuiyang 550081China Department of Chemistry and Biochemistry Florida International UniversityMiamiFL 33199USA School of Environment and State Key Joint Laboratory of Environment Simulation and Pollution Control Tsinghua UniversityBeijing 100084China Environmental Sciences Division Oak Ridge National LaboratoryOak RidgeTennessee 37831USA Environmental and Life Sciences Program(EnLS) Trent UniversityPeterboroughOntario K9L 0G2Canada Research Center for Eco-Environmental Sciences Chinese Academy of SciencesBeijing 100085China

The transformation of mercury(Hg) in the environment plays a vital role in the cycling of Hg and its risk to the ecosystem and human health. Of particular importance are Hg oxidation/reduction and methylation/demethylation processes driven or mediated by the dynamics of light, microorganisms, and organic carbon, among others. Advances in understanding those Hg transformation processes determine our capacity of projecting and mitigating Hg risk. Here, we provide a critical analysis of major knowledge gaps in our understanding of Hg transformation in nature, with perspectives on approaches moving forward. Our analysis focuses on Hg transformation processes in the environment, as well as emerging methodology in exploring these processes. Future avenues for improving the understanding of Hg transformation processes to protect ecosystem and human health are also explored.

关键词： Mercury oxidation reduction methylation demethylation isotope fractionation

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Harnessing machine learning for transmembrane pressure prediction in MBR systems during textile wastewater treatment

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Desalination and Water Treatment 2025年 322卷

作者： Zahoor, Onaira Khan, Sher Jamal Usama, Muhammad Tanudjaja, Henry J. Ghaffour, Noreddine Nawaz, Muhammad Saqib Institute of Environmental Sciences and Engineering (IESE) School of Civil and Environmental Engineering (SCEE) National University of Sciences and Technology (NUST) Sector H-12 Islamabad Pakistan Department of Civil and Environmental Engineering Northeastern University Boston 02115 MA United States Environmental Science and Engineering Program Division of Biological and Environmental Science and Engineering (BESE) King Abdullah University of Science and Technology (KAUST) Thuwal 23955-6900 Saudi Arabia

Membrane Bioreactors (MBRs) are preferred for treating high-strength industrial wastewater due to their exceptional treatment efficiency and compact design. However, membrane fouling remains a significant challenge that limits their broader application. Since transmembrane pressure (TMP) is closely associated with membrane fouling mechanisms, its accurate prediction is essential for anticipating fouling events. This study focuses on predicting TMP in a bench-scale MBR by employing advanced regression models such as Lasso, support vector machines, and random forest. The bioreactor is operated using synthetic textile wastewater, with a primary focus on critical sludge parameters. A total of 60 datasets were compiled for training and testing of the models. The random forest model attained an R² of 0.95 and 0.86 and root mean square error values of 1.75 kPa and 3.3 kPa for the training and test datasets, respectively, demonstrating the best predictive accuracy. Extra polymeric substances were the most influential parameter, while particle size distribution was the least. The random forest and lasso regression models predicted high values more accurately, while the support vector regression model was inclined towards making more conservative predictions for extreme values. The effectiveness of the proposed models showcases the significance of utilizing machine learning in advancing MBR technology for wastewater treatment. Accurate TMP predictions through machine learning can help in maintaining key parameters within optimal ranges, thereby reducing the likelihood of membrane fouling and enhancing system efficiency. © 2025 The Authors

关键词： Extra polymeric substances Machine learning models Membrane bioreactor Textile wastewater treatment Transmembrane pressure

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Enhancing Sustainable Development Goals Through Future Vapor Pressure Deficit Analysis In The Nile River Basin

Enhancing Sustainable Development Goals Through Future Vapor...

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IEEE International Symposium on Geoscience and Remote Sensing (IGARSS)

作者： Surendra Maharjan Wenzhao Li Shahryar Fazli Hani Sewilam Hesham El-Askary Computational and Data Sciences Graduate Program Schmid College of Science and Technology Chapman University Orange CA USA Earth Systems Science and Data Solutions Lab Chapman University Orange CA USA The Center for Applied Research on the Environment and Sustainability The American University in Cairo Cairo Egypt Department of Engineering Hydrology RWTH Aachen University Aachen Germany Department of Environmental Sciences Faculty of Science Alexandria University Alexandria Egypt

ISBN: (数字)9798350360325

ISBN: (纸本)9798350360332

Vapor Pressure Deficit (VPD) is crucial in meteorology and agriculture for understanding plant-environment interactions. Its application as an indicator in agricultural practices notably advances Sustainable Development Goals such as Zero Hunger (SDG 2) and Climate Action (SDG 13). This research focuses on the impact of climate change on agricultural productivity and food security in the Nile River Basin (NRB), emphasizing the role of VPD, temperature, and precipitation. Utilizing Coupled Model Intercomparison Project Phase 6 (CMIP6) datasets from NEX-GDDP-CMIP6, the study analyzes key climatic variables that influence agricultural conditions. The study applies the Mann-Kendall test to evaluate VPD trends from 2000 to 2060 under two Shared Socioeconomic Pathways (SSPs), SSP2-4.5 and SSP5-8.5. The study's findings on the implications of rising VPD levels in the Nile River Basin (NRB), particularly under the SSP 5-8.5 scenario, highlight a critical challenge for the region's agricultural productivity and food security. The increased VPD, indicative of drier conditions, leads to a moisture deficit for crops, potentially reducing agricultural yields. This scenario poses a significant threat to food security, as lower crop yields can result in food shortages and higher food prices, adversely affecting vulnerable populations. The study underscores the necessity of integrating VPD insights into agricultural and water resource management strategies to uphold food security against climatic variations in support of the SDGs.

关键词： Productivity Climate change Precipitation Food security Agriculture Rivers Sustainable development

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Plugging Effect of Fine Pore Water in Opc and LC3 Paste During Accelerated Carbonation Monitored Via Single-Sided Nuclear Magnetic Resonance Spectroscopy

SSRN

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SSRN 2024年

作者： Cheng, Luge Kurihara, Ryo Ohkubo, Takahiro Kitagaki, Ryoma Suda, Yuya Teramoto, Atsushi Maruyama, Ippei Department of Architecture Graduate School of Engineering The University of Tokyo Tokyo113-8656 Japan Department of Applied Chemistry and Biotechnology Graduate School of Engineering Chiba University Chiba263-8522 Japan Division of Human Environmental Systems Graduate School of Engineering Hokkaido University Sapporo060-8628 Japan Department of Architecture Graduate School of Advanced Science and Engineering Hiroshima University Hiroshima739-8527 Japan Civil Engineering Program Faculty of Engineering University of the Ryukyus Okinawa903-0213 Japan Nagoya University Japan

This study focuses on the investigation of the influence of CO2 concentration on the carbonation process in cementitious paste using ordinary Portlandite cement and limestone-calcined clay cement, specifically on the water content distribution. Employing single-sided nuclear magnetic resonance spectroscopy for water profiling, we revealed that the water content of fine pores (interlayer space and gel pores) was consistent at the carbonation front under accelerated carbonation processes with CO2 concentrations of 5% and 1%, demonstrating the plugging effect where fine pore water governs the carbonation progress. This effect was absent under natural carbonation conditions because of the carbonation process was slower than drying. It was confirmed that the rate-determining mechanisms of natural and accelerated carbonation with CO2 concentrations greater than 1% were different. © 2024, The Authors. All rights reserved.

关键词： Carbonation

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Sesquiterpenes from the Saudi Arabian Red Sea sponge Lamellodysidea herbacea

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Phytochemistry Letters 2025年 67卷

作者： Tammam, Mohamed A. Tziveleka, Leto-Aikaterini Duarte, Carlos M. Ioannou, Efstathia Roussis, Vassilios Section of Pharmacognosy and Chemistry of Natural Products Department of Pharmacy National and Kapodistrian University of Athens Panepistimiopolis Zografou Athens 15771 Greece Department of Biochemistry Faculty of Agriculture Fayoum University Fayoum 63514 Egypt Marine Science Program Division of Biological and Environmental Sciences and Engineering King Abdullah University of Science and Technology Thuwal 23955-6900 Saudi Arabia

Eleven sesquiterpenes (1–11), with the majority of them decorated with either a furan or a γ-lactone moiety in their carbocycle, were isolated from an organic extract of the marine sponge Lamellodysidea herbacea collected from the coral reefs in the vicinity of Thuwal in Saudi Arabia. Two of the isolated metabolites (1 and 2) are not previously described, whereas the linear furanosesquiterpene 11 is reported for the first time from a natural source. The structures and the relative configurations of the isolated metabolites have been determined through extensive analysis of their NMR and MS data. Compounds 1–11 were evaluated for their antibacterial and antioxidant activity but did not display any noteworthy activity. © 2025 Phytochemical Society of Europe

关键词： Dysideidae Lamellodysidea herbacea Red Sea Saudi Arabia Sesquiterpenes Sponge

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The effect of thermal pre-Treatment on cassava rhizome properties for utilizing as green fuel in gasification 5

The effect of thermal pre-Treatment on cassava rhizome prope...

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2020 5th International Conference on Sustainable and Renewable Energy engineering, ICSREE 2020

作者： Sirinwaranon, Punchaluck Atong, Duangduen Sricharoenchaikul, Viboon Interdisciplinary Program in Environmental Science Graduate School Chulalongkorn University Bangkok10330 Thailand National Science and Technology Development Agency [NSTDA Thailand Science Park Pathum Thani12120 Thailand Department of Environmental Engineering Faculty of Engineering Chulalongkorn University Bangkok10330 Thailand

Cassava rhizome (CR) was torrefied to provide superior solid fuel quality for further gasification process. The torrefaction was carried out in the absence of oxygen at 220, 240, 260, and 280°C with a fixed residence time. Solid fuel after torrefaction has a higher calorific value from that of reduced volatile matters. The optimum energy yield of torrefied CR is 88.16% at 260°C. The heating value of 20.86 MJ/kg for a torrefied product can be achieved compared to 15.37 MJ/kg for untreated CR. The subsequent gasification of torrefied CR at temperature of 800°C yielded the highest gas product of 65 wt.%. The carbon and hydrogen conversions into CO and H2 were 14.28% and 29.95%, respectively. Synthesis gas (syngas) from the conversion maintained the H2/CO ratio of around 2-2.50, which is suitable for the Fischer-Tropsch process or can be used as the feedstock for petrochemical industry. © The Authors, published by EDP sciences, 2020.

关键词： Gasification

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Unleashing the Power of Nature: Eco-Friendly Mussel-Byssus-Inspired Pbs/Pbat Fishing Gear for Biodegradation by Marine Microbes

SSRN

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SSRN 2023年

作者： Hong, Yuri Yang, Ho-Sung Lee, Min Hee Kim, Sinyang Park, Sung Bae Hwang, Sung Yeon Park, Jeyoung Koo, Jun Mo Oh, Dongyeop Hwang, Dong Soo Gyeongsangbuk-do Pohang37673 Korea Republic of Ulsan44429 Korea Republic of Department of Plant & Environmental New Resources Graduate School of Biotechnology Kyung Hee University Gyeonggi-do 17104 Korea Republic of Department of Chemical and Biomolecular Engineering Sogang University Seoul04107 Korea Republic of Department of Organic Materials Engineering Chungnam National University Daejeon34134 Korea Republic of Department of Polymer Science and Engineering and Program in Environmental and Polymer Engineering Inha University Incheon22212 Korea Republic of

Abstract Abandoned, lost, and discarded fishing gear (ALDFG) poses global challenges for marine ecosystems as they destroy algal forests, the largest oceanic carbon dioxide sinks. Biodegradable polybutylene succinate (PBS), which has a tensile toughness similar to that of nylon, has been suggested as a potential fishing-gear material. However, its slow degradation in the marine environment and limited draping characteristics need to be addressed before it can be used in environmentally friendly fishing gear. Inspired by the mussel byssus, a mussel-thread-like holdfast known for its stiff yet extensible mechanical properties, we developed fishing gear using a mussel-byssus-mimetic fiber (artificial byssus, AB) structure. The AB was composed of poly(butylene adipate-co-butylene terephthalate) (PBAT) fibers with favorable draping characteristics coated with mechanically resilient and PBS, which demonstrated sufficient toughness and draping properties for use in fishing gear. The AB may serve as fishing-gear material capable of mitigating ALDFG issues, given its marine degradability by microbial strains that degrade PBS and PBAT. Furthermore, it could serve as a substrate for ocean afforestation, given the improved settlement and growth of seaweed spores (Pyropia yezoensis) on AB. Overall, AB-based fishing gear is expected to enhance macroalgal forest conservation and expansion, and facilitate marine carbon capture through marine afforestation. © 2023, The Authors. All rights reserved.

关键词： Butenes

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