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SSRN 2024年

作者： Rutkoski, C.F. Vergara-Luis, I. Urionabarrenetxea, Erik García-Velasco, Nerea Zaldibar, B. Anza, M. Olivares, Maitane Prieto, Ailett Epelde, L. Garbisu, C. Almeida, E.A. Soto, Manu Environmental Engineering Post-Graduation Program University of Blumenau SC Blumenau Brazil Department of Natural Science University of Blumenau SC Blumenau Brazil Basque Country Leioa Spain Plentzia Basque Country Spain Basque Country Leioa Spain Parque Científico y Tecnológico de Bizkaia P812 Basque Country DerioE-48160 Spain

Soil contamination by antibiotics is a global issue of great concern that contributes to the rise of bacterial antibiotic resistance and can have toxic effects on non-target organisms. This study evaluated the variations of molecular, cellular, and histological parameters in Eisenia fetida earthworms exposed to sulfamethazine (SMZ) and tetracycline (TC), two antibiotics commonly found in agricultural soils. The earthworms were exposed for 14 days to a series of concentrations (0, 10, 100, and 1000 mg/kg) of both antibiotics. Sulfamethazine and TC did not affect the survival of E. fetida, however, other effects at different levels of biological complexity were detected. The two highest concentrations of SMZ reduced the viability of coelomocytes. At the highest TC concentration, there was a noticeable decline in cell viability, acetylcholinesterase activity, and the relative presence of mucopolysaccharides in the epidermis. Glutathione S-transferase activity decreased in all TC treatments and at the highest SMZ concentration. However, levels of malondialdehyde and protein carbonyls did not change, suggesting an absence of oxidative stress. Tetracycline was neurotoxic to E. fetida and changed the integrity of the epidermis. Both antibiotics altered the intestinal microbiota of E. fetida, leading to a reduction in the relative abundance of bacteria from the phyla Proteobacteria and Bacteroidetes, while causing an increase in the phylum Actinobacteroidota. All observed changes indicate that both SMZ and TC can disrupt the earthworms' immune system and gut microbiome, while fostering the growth of bacteria that harbour antibiotic resistance genes. Finally, both antibiotics exerted additional metabolic and physiological effects that increased the vulnerability of E. fetida to pathogens. © 2024, The Authors. All rights reserved.

关键词： Antibiotics

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Diatom biosilica as a supplementary cementitious material

npj Materials Sustainability

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npj Materials Sustainability 2024年第1期2卷 1-9页

作者： Sarah L. Williams Danielle N. Beatty Wil V. Srubar III Materials Science and Engineering Program University of Colorado Boulder Boulder CO USA Department of Civil Environmental and Architectural Engineering University of Colorado Boulder Boulder CO USA

The use of supplementary cementitious materials (SCMs) is a key method used to reduce the embodied carbon of cement-based materials. Uncertainty in traditional SCM markets has led to increased interest in alternative, natural SCM materials. In this work, biosilica derived from freshly cultured diatom frustules (grown byThalassiosira pseudonanaandPhaeodactylum tricornutum) was assessed as an alternative SCM for the first time. The chemical reactivity of each biosilica source was assessed using a small-scale version of ASTM C1897 (the R3 test) previously developed by the authors. The chemical reactivity ofT. pseudonanafrustules was relatively high (i.e., greater than that of blast furnace slag, but lower than that of metakaolin).P. tricornutumfrustules exhibited a lower chemical reactivity, similar to a Class F fly ash. Results demonstrate the potential to grow highly reactive biominerals using diatoms and highlight the potential tunability of diatom biosilica for use as a novel, sustainable SCM.

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Density functional modeling and total scattering analysis of the atomic structure of a quaternary CaO−MgO−Al2O3−SiO2 (CMAS) glass: Uncovering the local environment of calcium and magnesium

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Physical Review Materials 2021年第1期5卷 015603-015603页

作者： Kai Gong V. Ongun Özçelik Kengran Yang Claire E. White Department of Civil and Environmental Engineering Andlinger Center for Energy and the Environment Princeton University Princeton New Jersey 08544 USA Department of Chemistry and Biochemistry Materials Science and Engineering Program University of California San Diego La Jolla California 92093 USA

Quaternary CaO−MgO−Al2O3−SiO2 (CMAS) glasses are important constituents of the Earth's lower crust and mantle, and they also have important industrial applications such as in metallurgical processes, concrete production, and emerging low-CO2 cement technologies. In particular, these applications rely heavily on the composition-structure-reactivity relationships for CMAS glasses, which are not yet well established. In this study, we combined force-field molecular dynamics (MD) simulations and density functional theory (DFT) calculations to generate detailed structural representations for a CMAS glass. The generated structures are not only thermodynamically favorable (according to DFT calculations) but also agree with experiments (including our x-ray and neutron total scattering data as well as literature data). Detailed analysis of the final structure (including partial pair distribution functions, coordination number, and oxygen environment) enabled existing discrepancies in the literature to be reconciled and has revealed important structural information on the CMAS glass, specifically (i) the unambiguous assignment of medium-range atomic ordering, (ii) the preferential role of Ca atoms as charge compensators and Mg atoms as network modifiers, (iii) the proximity of Mg atoms to free oxygen sites, and (iv) clustering of Mg atoms. Electronic property calculations suggest higher reactivity for Ca atoms as compared with Mg atoms, and that the reactivity of oxygen atoms varies considerably depending on their local bonding environment. Overall, this information may enhance our mechanistic understanding on CMAS glass dissolution behavior in the future, including dissolution-related mechanisms occurring during the formation of low-CO2 cements.

关键词： Atomic & molecular structure Composition Density functional theory Scattering of atoms, molecules, clusters & ions Structural properties

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Impact of leachate on irrigation water quality around TPST Piyungan

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AIP Conference Proceedings 2024年第1期3019卷

作者： Farida Afriani Astuti Syafrudin Indah Susilowati Doctoral Program of Environmental Science Graduate School of University Diponegoro Semarang-Indonesia Environmental Engineering UPN Veteran Yogyakarta Yogyakarta-Indonesia Graduate School of University Diponegoro Semarang-Indonesia

Rubbish is becoming a global environmental issue as the amount of waste generated constantly increases due to the continuous growth in the level of consumption. The previous investigation reported that the existence of waste management facility known as TPST such as Piyungan in Bantul Regency as a facility for managing rubbish can have a positive or negative impact on the environment. This is because the leachate from the waste is suspected to pollute the surrounding irrigation water. Therefore, this study aims to determine the impact of leachate on the quality of irrigation water around TPST Piyungan using field surveys and laboratory tests. The water sample was taken in Sitimulyo, one of the villages affected by TPST Piyungan activities, and in Jambidan village as point control. The physical and chemical parameters of the water sample tested include temperature, pH, COD, BOD, TSS, TDS, Zn, Fe, Cr, Cu, and Pb. This was followed by the evaluation of the Index Pollution raw quality Class IV, as stated in the Governor Regulation of the Special Region of Yogyakarta Number 20 of 2008 to determine the quality status. The results showed that the status of the water sample is in category IV, which fulfills raw quality (good condition), where point 1 has a value of 0.22 and 0.13 for points 2 and 3. This indicated that the irrigation water quality is not affected by the leachate generated from the TPST Piyungan.

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Effect of the number of Cyperus rotundus and medium height on the performance of batch-constructed wetland in treating aquaculture effluent

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Chemosphere 2024年 353卷 141595页

作者： Imron, Muhammad Fauzul Hestianingsi, Wa Ode Ayu Putranto, Trisnadi Widyaleksono Catur Citrasari, Nita Abdullah, Siti Rozaimah Sheikh Hasan, Hassimi Abu Kurniawan, Setyo Budi Study Program of Environmental Engineering Department of Biology Faculty of Science and Technology Universitas Airlangga Campus C UNAIR Jalan Mulyorejo Surabaya60115 Indonesia Department of Water Management Faculty of Civil Engineering and Geosciences Delft University of Technology Stevinweg 1 CN Delft 2628 Netherlands Department of Chemical and Process Engineering Faculty of Engineering and Built Environment Universiti Kebangsaan Malaysia UKM Bangi Selangor 43600 Malaysia Faculty of Engineering and Built Environment Universiti Kebangsaan Malaysia UKM Bangi Selangor 43600 Malaysia Laboratory of Algal Biotechnology Centre Algatech Institute of Microbiology of the Czech Academy of Sciences Opatovický mlýn Novohradská 237 Třeboň379 81 Czech Republic

Increasing aquaculture cultivation produces large quantities of wastewater. If not handled properly, it can have negative impacts on the environment. Constructed wetlands (CWs) are one of the phytoremediation methods that can be applied to treat aquaculture effluent. This research was aimed at determining the performance of Cyperus rotundus in removing COD, BOD, TSS, turbidity, ammonia, nitrate, nitrite, and phosphate from the batch CW system. Treatment was carried out for 30 days with variations in the number of plants (10, 15, and 20) and variations in media height (10, 12, and 14 cm). The result showed that aquaculture effluent contains high levels of organic compounds and nutrients, and C. rotundus can grow and thrive in 100% of aquaculture effluent. Besides that, the use of C. rotundus in CWs with the effect of numbers of plants and media height showed performance of COD, BOD, TSS, turbidity, ammonia, nitrate, nitrite, and phosphate with 70, 79, 90, 96, 64, 82, 92, and 48% of removal efficacy, respectively. There was no negative impact observed on C. rotundus growth after exposure to aquaculture effluent, as indicated by the increase in wet weight, dry weight, and growth rate when compared to the control. Thus, adding aquaculture effluent to CWs planted with C. rotundus supports the growth and development of plants while also performing phytoremediation. © 2024 Elsevier Ltd

关键词： Wetlands

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Study of low head turbine propellers axial flow for use of micro-hydropower plant (MHP) in Aceh, Indonesia 9

Study of low head turbine propellers axial flow for use of m...

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9th International Seminar on New Paradigm and Innovation of Natural sciences and Its Application, ISNPINSA 2019

作者： Pribadyo Hadiyanto, H. Jamari, J. Doctoral Program of Environmental Science School of Postgraduate Studies Diponegoro University Semarang Indonesia Department of Mechanical Engineering Faculty of Engineering University Diponegoro Semarang Indonesia Faculty of Engineering Teuku Umar University Meulaboh23615 Indonesia

Low head hydropower has the potential to produce green energy with a minimum on the environment and is one of the best choices for decentralized power plants. Aceh is one of many regions in Indonesia with hilly topography and many river streams. Of the 66 rivers in Aceh that have potential energy sources that can be developed 98.5 percent are low head. Generally, the technique for overcoming altitude problems in low river flows is the use of low head turbines. An important aspect of head power generation techniques is the selection of turbines. The study aimed to study low head propeller turbines for the use of micro hydropower plants. By calculating the main dimensions and main components of the turbine, field experiments were carried out to determine turbine rotation and energy, as well as turbine efficiency at a flow rate of 0.06 m3/sec and a 3.5-meter head. The calculation results obtained by a specific turbine speed of 1.53, runner diameter of 0.30 meters, hub diameter of 0.06 meters, shaft diameter 0.03, runner length 1.08, triangular speed of 30 degrees with the number of blades 4 pieces. From the results of field experiments, the maximum turbine rotation speed is 1828 rpm, the turbine power is 2,530 watts with a voltage between 220 to 240 volts while the maximum efficiency is 57 percent. It can be concluded that propeller-type turbines with the low head are suitable for micro power plants, especially in remote areas. © Published under licence by IOP Publishing Ltd.

关键词： Turbines

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Impacts of vegetation over bedforms on flow characteristics in gravel-bed rivers

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Journal of Hydrodynamics 2019年第5期31卷 986-998页

作者： Hossein Afzalimehr Mohammad Reza Maddahi Jueyi Sui Majid Rahimpour Department of Civil Engineering Iran University of Science and TechnologyTehranIran Department of Water Engineering Shahid Bahonar University of KermanKermanIran Environmental Engineering Program University of Northern British ColumbiaCanada

In the present study,among six gravel-bed river reaches,two natural gravel-bed river reaches with approximately similar bedforms and flow conditions have been found,one river reach with vegetation on bedforms and the other without vegetation on *** on field measurements,the impacts of vegetation over bedforms on flow characteristics have been *** velocity,Reynolds stress and turbulence intensity distributions over bedforms with vegetation have been compared with those over gravel bedforms without *** using the quadrant analysis,the dominant events of turbulent flow structures have been assessed for flows over gravel bedforms with vegetation and without *** show that the effect of vegetation enhances the anisotropy in turbulence and generates strong secondary currents,which lead to the occurrence of dip phenomenon at the stoss section and the crest of vegetated *** change of bed roughness from gravel bed to vegetated bed causes a development of a new boundary *** resulted in the different shape of velocity distributions over bedforms with vegetation from those over bedforms without vegetation,which can affect the lives of aquatic *** shear stress at downstream section of gravel bedform without vegetation is much higher than that of vegetated bedform,which shows that the erosion takes place from downstream of vegetated bedforms,while in the bare beds;the deposition is at downstream of *** is found that the presence of vegetation causes a chaotic distribution pattern of Reynolds shear stress,while it has more orderly pattern at the downstream section of gravel bedform without ***,the distribution of turbulence intensity in the lee side of vegetated bedform has a concave shape and in the stoss section,turbulence is generated in ejections and sweeps near the vegetation *** findings are significant to the practice of river ecological restoration.

关键词： Bedform Reynolds shear stress distribution turbulence intensity vegetation velocity profiles

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Title Biodecolorization of Biogas Power Plant Effluent Derived from Anaerobically Digested Distillery Wastewater by Natural Selected Pseudomonas Putida from Activated Sludge of the Wastewater Treatment Plant

SSRN

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SSRN 2023年

作者： Kumkaew, Ponruedee Suaisom, Pitchaya Mukkata, Kanokwan Koonaphapdeelert, Sirichai Sawatdeenarunat, Chayanon Nitayavardhana, Saoharit Master’s Degree Program in Environmental Engineering Faculty of Engineering Chiang Mai University Chiang Mai50200 Thailand Graduate School Chiang Mai University Chiang Mai50200 Thailand Energy Research and Development Institute – Nakornping Chiang Mai University Chiang Mai50200 Thailand Department of Environmental Engineering Faculty of Engineering Chiang Mai University Chiang Mai50200 Thailand Asian Development College for Community Economy and Technology Chiang Mai Rajabhat University Chiang Mai50300 Thailand Center of Excellence in Materials Science and Technology Chiang Mai University Chiang Mai50200 Thailand

The main aim of this study was to utilize naturally selected Pseudomonas putida strains isolated from activated sludge in a wastewater treatment plant, for the purpose of bioremediation of biogas effluent to remove organic content and color. Biogas effluent from anaerobically digestion of distillery wastewater treated with P. putida at the best evaluated condition (sample concentration of 50% v/v, agitation and aeration rates of 250 rpm and 1.0 vvm for 6 days) showed significant decolorization and organic removal efficacies of 34.29 ± 0.87% and 38.94 ± 0.63%, respectively. Bioremediation efficiency was dependent on bacterial growth which organic content in sample and dissolved oxygen during cultivation were key factors. The natural selected bacterium could tolerate higher organic content and work synergistically with other indigenous microorganisms found in the biogas effluent. Consequently, bioremediation of biogas effluent by natural selected P. putida is feasible to apply in biogas power plant where sterilization is not necessary in the process. © 2023, The Authors. All rights reserved.

关键词： Bioremediation

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Accelerating adoption of species-agnostic plant sensors for precision farming

Nature Reviews Electrical Engineering

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Nature Reviews Electrical engineering 2025年 58-70页

作者： Abdullah Bukhamsin Khaled Nabil Salama Jürgen Kosel Ikram Blilou Bioengineering Program Biological and Environmental Science and Engineering (BESE) Division King Abdullah University of Science and Technology (KAUST) Thuwal Saudi Arabia Center of Excellence — Sustainable Food Security (SFS) King Abdullah University of Science and Technology (KAUST) Thuwal Saudi Arabia Electrical and Computer Engineering Program Computer Electrical and Mathematical Sciences and Engineering (CEMSE) Division King Abdullah University of Science and Technology (KAUST) Thuwal Saudi Arabia Sensor Systems Division Silicon Austria Labs Villach Austria Plant Science Program Biological and Environmental Science and Engineering (BESE) Division King Abdullah University of Science and Technology (KAUST) Thuwal Saudi Arabia

Precision farming is an optimized management farming scheme that seeks to link the real-time needs of crops with the nutrients to be administered. Sensing platforms that can monitor the physiological status of crops in situ are key to enabling timely and localized interventions. However, the underdevelopment of plant sensing strategies limits the potential of precision farming. In this Review, we discuss the challenges and advancements in phyto-monitoring, focusing on strategies that are applicable to a wide range of plant species and suitable for field deployment. We explore species-agnostic sensors, including optical and electrochemical sensors, whose operation is based on principles that are widely applicable to all plant species. These platforms enable real-time monitoring of the physiological state of crops by assessing key biomarkers, such as plant hormones, and metabolites such as salicylic acid and reactive oxygen species. Evaluating these systems, we conclude that an integrative sensing approach is necessary to compensate for the limitations of the individual methods and can provide a holistic view of crop health. Cost-effective species-agnostic sensors are thus needed to provide information that can be used to minimize the resource footprint of farming and meet the growing global demand.

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Monitoring blood pressure through a single hybrid hemodynamic signal with a flexible optoelectronic patch

Device

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Device 2025年

作者： Zhong, Yizhou Zhang, Yongcao Pu, Jing Wustoni, Shofarul Uribe, Johana Lopez-Larrea, Naroa Marks, Adam McCulloch, Iain Mecerreyes, David Baran, Derya Inal, Sahika Organic Bioelectronics Laboratory Biological and Environmental Science and Engineering Division King Abdullah University of Science and Technology (KAUST) Thuwal 23955-6900 Saudi Arabia Materials Science and Engineering Program (MSE) Physical Sciences and Engineering Division (PSE) KAUST Thuwal 23955-6900 Saudi Arabia POLYMAT University of the Basque Country UPV/EHU Avenida Tolosa 72 Guipuzcoa Donostia-San Sebastian 20018 Spain Department of Chemistry University of Oxford Oxford OX1 3TF United Kingdom Andlinger Center for Energy and the Environment and Department of Electrical and Computer Engineering Princeton University Princeton 08544 NJ United States IKERBASQUE Basque Foundation for Science Plaza Euskadi 5 Bilbao 48009 Spain

Hemodynamics, the study of blood flow and circulatory forces, is fundamental for assessing cardiovascular health, disease states, and therapeutic outcomes. Here, we introduce a skin-conformable organic optoelectronic thin-film patch (ePatch) designed to simultaneously capture electrocardiography (ECG) and photoplethysmography (PPG) signals as a single hybrid signal, named the electrocardio-photoplethysmogram (EC-PPG). The ePatch integrates an organic electrochemical transistor (OECT), an organic photodiode, surface-mounted light-emitting diodes, and electrochemical electrodes on a flexible, skin-conforming substrate. By training deep learning models on the hybrid EC-PPG data, we achieved accurate arterial blood pressure estimations, with mean errors of just 1.69 mmHg for systolic and 0.89 mmHg for diastolic blood pressure, outperforming traditional predictions that rely on individual physiological signals as inputs. Our findings underscore the potential of EC-PPG as a compound hemodynamic signal for AI-driven vital sign monitoring and integrated, solution-processable soft electronics for clinical and point-of-care applications. © 2025 The Authors

关键词： DTI-3: Develop electrocardiography electrophysiology flexible electronics OECT OPD organic electrochemical transistor photoplethysmography wearable electronics

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