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SSRN 2024年

作者： Ren, Jie Dowdy, Nicolas D. Acarturk, B. Cansu Srubar, Wil V. Department of Civil Environmental and Architectural Engineering University of Colorado Boulder 1111 Engineering Drive ECOT 441 UCB 428 BoulderCO80309 United States Materials Science and Engineering Program University of Colorado Boulder 4001 Discovery Drive BoulderCO80303 United States College of Civil Engineering

The influence of calcium carbonate (CaCO3) on the alkali-activation kinetics, microstructure, and compressive strength of alkali-activated metakaolin (MK) geopolymer cements was investigated herein. Experimental results showed that replacing 10-50% of MK with ground CaCO3 particles delayed the acceleration stage of alkali-activation regardless of replacement amount. However, 10% CaCO3 replacement increased the overall degree of reaction and yielded pastes with similar 14- and 28-day compressive strengths compared to the experimental control with no CaCO3 addition. In comparison, 50% CaCO3 replacement led to a lower overall degree of reaction and lower compressive strengths through 28 days of curing. Experimental evidence substantiates that N-A-S-H gel forms in samples containing 0% and 10% CaCO3, while N-(C)-A-S-H gel and/or C-(N)-A-S-H are also present in the binding matrix near CaCO3 particles in samples with higher CaCO3 contents (i.e., 30% and 50%). While the CaCO3 particles were primarily composed of calcite, vaterite, a less stable form of CaCO3, was also evident in the samples containing 30% and 50%, suggesting that the CaCO3 particles were moderately reactive during the alkali-activation. © 2024, The Authors. All rights reserved.

关键词： Calcium carbonate

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Simulation of Illipe Butter Purification Originated from West Kalimantan by SuperPro Designer 3

Simulation of Illipe Butter Purification Originated from Wes...

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3rd Borneo International Conference on Applied Mathematics and engineering 2020, BICAME 2020

作者： Ramadhani, Nurul Hikmah Darmawan, Muhammad Arif Perdana Harahap, Andre Fahriz Arya Ramadhan, Muhammad Yusuf Silalahi, Ursula Chriseva Gozan, Misri Bioprocess Engineering Program Department of Chemical Engineering Faculty of Engineering Universitas Indonesia Depok16424 Indonesia School of Environmental Science Universitas Indonesia Jl. Salemba Raya No.4 Jakarta10430 Indonesia

Tengkawang is one of the commodities of non-timber forest products which has been a life of support for people around the forest. Seeds produced by Tengkawang trees are one of the export commodities. However, unfortunately, the process of exporting Tengkawang seeds abroad often requires a long time to reduce the quality of the Tengkawang seeds. Processing of Tengkawang seeds into oil is asolution to the decline in quality of Tengkawang seeds. Like standard crude vegetable oil, Tengkawang oil also contains impurities. Therefore, a purification process to remove these impurities is needed. This research was conducted to produce purified Tengkawang fat optimally. Purification stagesinclude degumming, neutralization and bleaching. This research will focus on the simulation of purified Tengkawang fat production. In this case, the simulation is carried out as an estimator of the feasibility value roughly whether a fat purification plant can be realized or not. © Publishedunder licence by IOP Publishing Ltd.

关键词： Purification

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Influence of conformational change of chain unit on the intrinsic negative thermal expansion of polymers

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Chinese Chemical Letters 2021年第4期32卷 1515-1518页

作者： Qiangsheng Sun Ke Jin Yuhui Huang Jia Guo Thanyada Rungrotmongkol Phornphimon Maitarad Changchun Wang State Key Laboratory of Molecular Engineering of Polymers and Department of Macromolecular Science Fudan UniversityShanghai 200433.China Biocatalyst and Environmental Biotechnology Research Unit Department of BiochemistryFaculty of Science and Program in Bioinformatics and Computational BiologyGraduate SchoolChulalongkom UniversityBangkok 10330Thailand Research Center of Nano Science and Technology Shanghai UniversityShanghai 200444China

Negative thermal expansion(NTE) behavior has roused wide interest for the control of thermomechanical properties of functional *** NTE behaviors have been found in kinds of compounds,it remains challenging for polymers to achieve intrinsic NTE *** this work,we systematically studied the conformational change of dibenzocyclooctadiene(DBCOD) derivatives between chair(C) and twist-boat(TB) forms based on density-functional theo ry(DFT) calculations,and found clear evidence of the relationship between the structure of DBCOD units and the thermal contraction behavior of the related *** order to obtain the polymer with NTE property,two conditions should be met for the thermal contracting DBCOD related units as follows:(i) the TB conformation can turn into C conformation as the temperature increases,and(ii) the volume of C conformation is smaller than that of TB *** rule should offer a guidance to exploration of the new intrinsic NTE polymers in the future.

关键词： Negative thermal expansion Conformational change Polyarylamides Density-functional theory Dibenzocyclooctadiene

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Effects of nanopores and sulfur doping on hierarchically bunched carbon fibers to protect lithium metal anode

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Carbon Energy 2021年第5期3卷 784-794页

作者： Ji In Jung Sunwoo Park Son Ha Se Youn Cho Hyoung-Joon Jin Young Soo Yun Program in Environmental and Polymer Engineering Inha UniversityIncheonSouth Korea KU-KIST Graduate School of Converging Science and Technology Korea UniversitySeoulSouth Korea Carbon Composite Materials Research Center Korea Institute of Science and TechnologyWanju-gunJeollabuk-doSouth Korea Department of Polymer Science and Engineering Inha UniversityIncheonSouth Korea Department of Integrative Energy Engineering Korea UniversitySeoulSouth Korea

Studies on three-dimensional structured carbon templates have focused on how to guide homogeneous lithium metal nucleation and growth for lithium metal anodes(LMAs).However,there is still insufficient evidence for a key factor to achieve their high electrochemical ***,the effects of nanopores and sulfur doping on carbon-based nanoporous host(CNH)electrode materials for LMAs were investigated using natural polymer-derived *** pore-filling behaviors of lithium metal in the nanopores of the CNH electrode materials were first observed by ex situ scanning electron microscopy analysis,where the protective lithium metal nucleation and growth process led to significantly high Coulombic efficiency(CE)of~99.4%and stable 600 *** addition,a comparison study of CNH and sulfurdoped CNH(S-CNH)electrodes,which differ only in the presence or absence of sulfur,revealed that sulfur doping can cause lower electrochemical series resistance,higher CE value,and better cycling stability in a wide range of current densities and number of ***,S-CNH-based LMAs showed high electrochemical performance in full-cell Li-S battery tests using a sulfur copolymer cathode,where a high energy density of 1370Wh kgelectrode−1 and an excellent power density of 4120Wkgelectrode−1 were obtained.

关键词： carbon template Li-S batteries lithium metal anode lithium metal batteries nanoporous carbon sulfur doping

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Prioritization of key indicators for the classification of successional stages in regenerating subtropical Atlantic forest, Southern Brazil: a proposal based on multivariate order statistics

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Environment Systems and Decisions 2023年第2期43卷 232-241页

作者： Bressane, Adriano Siminski, Alexandre Gomes, Isadora Gurjon Melo, Carrie Peres da Rosa, Graziele Coraline Scofano dos Santos Galvão, Amanda Louisi Silva, Mirela Beatriz de Castro Medeiros, Líliam César Negri, Rogério Galante Institute of Science and Technology (ICT) Environmental Engineering Department Campus at São José dos Campos City Rodovia Presidente Dutra Km 1378—Eugênio de Melo12247-004 CEP São José Dos Campos/SP Brazil Agricultural and Natural Ecosystems Graduate Program Federal University of Santa Catarina (UFSC) Campus at Curitibanus City Rod. Ulysses Gaboardi km 3 CEP Curitibanos - SC 89520-000 Brazil Civil and Environmental Engineering Graduate Program São Paulo State University (UNESP) Campus at Bauru City Av. Eng. Luiz Edmundo C. Coube 14-01—Vargem Limpa CEP Bauru—SP/SP 17033-360 Brazil

Statement of problem. Brazilian guidelines establish a set of parameters to classify forest regeneration stages, but there are no criteria or evidence for prioritizing key indicators. Purpose. This study performed a comparative analysis between phytosociological parameters to verify the hypothesis that there is a difference in their explanatory power of the forest regeneration stages. Consequently, it shows the need to prioritize key indicators for classifying forest regeneration stages. Material and methods. The analyzes were carried out using a database of the Floristic Forest Inventory of Santa Catarina, Southern Brazil, composed of 177 sampling units of subtropical Atlantic forest (Mixed Ombrophilous Forest) characterized according to 12 quantitative and qualitative phytosociological parameters. Several statistical tests were performed to analyze the explanatory ability of the phytosociological parameters. Such process includes tests for multivariate ordering, principal component analysis (PCA), discriminant analysis (FDA and QDA), exploratory factor analysis (EFA), and multiple correspondence analysis (MCA). Afterward, is provided a ranking regarding the analyzed indicators based on their usefulness to separate forest regeneration stages, measured in terms of classification accuracy according to the QUEST (Quick Unbiased Efficient Statistical) algorithm. The hypothesis was verified with two-way tests at a significance level (α) equal to 0.05, for a test power (1-β) of 0.8 and a minimum detectable effect of medium size (ρ = 0.3). Results. Statistical significance tests confirmed the research hypothesis. Regarding both the qualitative and quantitative variables, the ranking resulting from the discriminant analysis provided the best accuracy (85.3%). In decreasing priority order, was defined the following parameter order: basal area, number of individuals and species, Shannon diversity index, diameter at breast height, total height, stem height, leaf litter, canop

关键词： Ombrophilous forest Prioritization of indicators Succession stage

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Technology Roadmap for Flexible Sensors

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ACS NANO 2023年第6期17卷 5211-5295页

作者： Luo, Yifei Abidian, Mohammad Reza Ahn, Jong-Hyun Akinwande, Deji Andrews, Anne M. Antonietti, Markus Bao, Zhenan Berggren, Magnus Berkey, Christopher A. Bettinger, Christopher John Chen, Jun Chen, Peng Cheng, Wenlong Cheng, Xu Choi, Seon-Jin Chortos, Alex Dagdeviren, Canan Dauskardt, Reinhold H. Di, Chong-an Dickey, Michael D. Duan, Xiangfeng Facchetti, Antonio Fan, Zhiyong Fang, Yin Feng, Jianyou Feng, Xue Gao, Huajian Gao, Wei Gong, Xiwen Guo, Chuan Fei Guo, Xiaojun Hartel, Martin C. He, Zihan Ho, John S. Hu, Youfan Huang, Qiyao Huang, Yu Huo, Fengwei Hussain, Muhammad M. Javey, Ali Jeong, Unyong Jiang, Chen Jiang, Xingyu Kang, Jiheong Karnaushenko, Daniil Khademhosseini, Ali Kim, Dae-Hyeong Kim, Il-Doo Kireev, Dmitry Kong, Lingxuan Lee, Chengkuo Lee, Nae-Eung Lee, Pooi See Lee, Tae-Woo Li, Fengyu Li, Jinxing Liang, Cuiyuan Lim, Chwee Teck Lin, Yuanjing Lipomi, Darren J. Liu, Jia Liu, Kai Liu, Nan Liu, Ren Liu, Yuxin Liu, Yuxuan Liu, Zhiyuan Liu, Zhuangjian Loh, Xian Jun Lu, Nanshu Lv, Zhisheng Magdassi, Shlomo Malliaras, George G. Matsuhisa, Naoji Nathan, Arokia Niu, Simiao Pan, Jieming Pang, Changhyun Pei, Qibing Peng, Huisheng Qi, Dianpeng Ren, Huaying Rogers, John A. Rowe, Aaron Schmidt, Oliver G. Sekitani, Tsuyoshi Seo, Dae-Gyo Shen, Guozhen Sheng, Xing Shi, Qiongfeng Someya, Takao Song, Yanlin Stavrinidou, Eleni Su, Meng Sun, Xuemei Takei, Kuniharu Tao, Xiao-Ming Tee, Benjamin C. K. Thean, Aaron Voon-Yew Trung, Tran Quang Wan, Changjin Wang, Huiliang Wang, Joseph Wang, Ming Wang, Sihong Wang, Ting Wang, Zhong Lin Weiss, Paul S. Wen, Hanqi Xu, Sheng Xu, Tailin Yan, Hongping Yan, Xuzhou Yang, Hui Yang, Le Yang, Shuaijian Yin, Lan Yu, Cunjiang Yu, Guihua Yu, Jing Yu, Shu-Hong Yu, Xinge Zamburg, Evgeny Zhang, Haixia Zhang, Xiangyu Zhang, Xiaosheng Zhang, Xueji Zhang, Yihui Zhang, Yu Zhao, Siyuan Zhao, Xuanhe Zheng, Yuanjin Zheng, Yu-Qing Zheng, Zijian Zhou, Tao Zhu, Bowen Zhu, Ming Zhu, Rong Zhu, Yangzhi Zhu, Yong Zou, Guijin Chen, Xiaodong Institute of Materials Research and Engineering (IMRE) Agency for Science Technology and Research (A*STAR) 2 Fusionopolis Way #08-03 Innovis Singapore 138634 Republic of Singapore；Innovative Centre for Flexible Devices (iFLEX) School of Materials Science and Engineering Nanyang Technological University Singapore 639798 Singapore Department of Biomedical Engineering University of Houston Houston Texas 77024 United States School of Electrical and Electronic Engineering Yonsei University Seoul 03722 Republic of Korea Department of Electrical and Computer Engineering The University of Texas at Austin Austin Texas 78712 United States；Microelectronics Research Center The University of Texas at Austin Austin Texas 78758 United States Department of Chemistry and Biochemistry California NanoSystems Institute and Department of Psychiatry and Biobehavioral Sciences Semel Institute for Neuroscience and Human Behavior and Hatos Center for Neuropharmacology University of California Los Angeles Los Angeles California 90095 United States Colloid Chemistry Department Max Planck Institute of Colloids and Interfaces 14476 Potsdam Germany Department of Chemical Engineering Stanford University Stanford California 94305 United States Laboratory of Organic Electronics Department of Science and Technology Campus Norrköping Linköping University 83 Linköping Sweden；Wallenberg Initiative Materials Science for Sustainability (WISE) and Wallenberg Wood Science Center (WWSC) SE-100 44 Stockholm Sweden Department of Materials Science and Engineering Stanford University Stanford California 94301 United States Department of Biomedical Engineering and Department of Materials Science and Engineering Carnegie Mellon University Pittsburgh Pennsylvania 15213 United States Department of Bioengineering University of California Los Angeles Los Angeles California 90095 United States School of Chemistry Chemical Engineering and Biotechnology Nanyang Technological University Singapore 637457

Humans rely increasingly on sensors to address grand challenges and to improve quality of life in the era of digitalization and big data. For ubiquitous sensing, flexible sensors are developed to overcome the limitations of conventional rigid counterparts. Despite rapid advancement in bench-side research over the last decade, the market adoption of flexible sensors remains limited. To ease and to expedite their deployment, here, we identify bottlenecks hindering the maturation of flexible sensors and propose promising solutions. We first analyze continued...challenges in achieving satisfactory sensing performance for real-world applications and then summarize issues in compatible sensor-biology interfaces, followed by brief discussions on powering and connecting sensor networks. Issues en route to commercialization and for sustainable growth of the sector are also analyzed, highlighting environmental concerns and emphasizing nontechnical issues such as business, regulatory, and ethical considerations. Additionally, we look at future intelligent flexible sensors. In proposing a comprehensive roadmap, we hope to steer research efforts towards common goals and to guide coordinated development strategies from disparate communities. Through such collaborative

关键词： soft materials mechanics engineering flexible electronics conformable sensors bioelectronics human-machine interfaces body area sensor networks technology translation sustainable electronics

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Anchorene,a carotenoid-derived growth regulator,modulates auxin homeostasis by suppressing GH3-mediated auxin conjugation

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Journal of Integrative Plant Biology 2024年第11期66卷 2490-2504页

作者： Danping Ke Yinpeng Xie Haipeng Li Liqun Hu Yi He Chao Guo Yahui Zhai Jinggong Guo Kun Li Zongyan Chu Junli Zhang Xuebin Zhang Salim Al-Babili Kai Jiang Yuchen Miao Kun-Peng Jia National Key Laboratory of Cotton Bio-breeding and Integrated Utilization State Key Laboratory of Crop Stress Adaptation and ImprovementHenan Joint International Laboratory for Crop Multi-Omics ResearchSchool of Life SciencesHenan UniversityKaifeng 450046China Sanya Institute of Henan University Sanya 572025China State Key Laboratory for Crop Stress Resistance and High-Eﬁciency Production/Shaanxi Key Laboratory of Apple College of HorticultureNorthwest A&F UniversityYangling 712100China Institute of Plant and Food Science Department of BiologySchool of Life SciencesSouthern University of Science and Technology(SUSTech)Shenzhen 518055China The BioActives Lab Center for Desert AgricultureKing Abdullah University of Science and TechnologyThuwal 23955-6900Kingdom of Saudi Arabia Plant Science Program Biological and Environmental Science and Engineering(BESE)DivisionKing Abdullah University of Science and Technology(KAUST)Thuwal 23955-6900Kingdom of Saudi Arabia Laboratory of Cell Metabolism and Diseases State Key Laboratory of Conservation and Utilization of Bio-Resources in YunnanCenter for Life SciencesSchool of Life SciencesYunnan UniversityKunming 650500China

Anchorene,identified as an endogenous bioactive carotenoid-derived dialdehyde and diapocarotenoid,affects root development by modulating auxin ***,the precise interaction between anchorene and auxin,as well as the mechanisms by which anchorene modulates auxin levels,remain largely *** this study,we conducted a comparative analysis of anchorene's bioactivities alongside auxin and observed that anchorene induces multifaceted auxin-like *** genetic and pharmacological examinations,we revealed that anchorene's auxin-like activities depend on the indole-3-pyruvate-dependent auxin biosynthesis pathway,as well as the auxin inactivation pathway mediated by Group II Gretchen Hagen 3(GH3)proteins that mainly facilitate the conjugation of indole-3-acetic acid(IAA)to amino acids,leading to the formation of inactivated storage *** measurements indicated that anchorene treatment elevates IAA levels while reducing the quantities of inactivated IAA–amino acid conjugates and ox *** sequencing further revealed that anchorene triggers the expression of numerous auxin-responsive genes in a manner reliant on Group II ***,our in vitro enzymatic assays and biolayer interferometry(BLI)assay demonstrated anchorene's robust suppression of GH3.17-mediated IAA conjugation with ***,our findings highlight the significant role of carotenoid-derived metabolite anchorene in modulating auxin homeostasis,primarily through the repression of GH3-mediated IAA conjugation and inactivation pathways,offering novel insights into the regulatory mechanisms of plant bioactive apocarotenoids.

关键词： Anchorene auxin conjugation carotenoid-derived bioactive apocarotenoid Gretchen Hagen 3 root development

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Industry 5.0 and sustainability: An overview of emerging trends and challenges for a green future

Innovation and Green Development

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Innovation and Green Development 2024年第4期3卷

作者： Rame, Rame Purwanto, Purwanto Sudarno, Sudarno Doctorate Program in Environmental Science School of Postgraduate Studies Universitas Diponegoro Semarang 50241 Indonesia Center for Standardization and Industrial Pollution Prevention Services Ministry of Industry Indonesia Indonesia Department of Chemical Engineering Faculty of Engineering Universitas Diponegoro Semarang 50275 Indonesia Department of Environmental Engineering Faculty of Engineering Universitas Diponegoro Semarang 50275 Indonesia

In an era of climate change and increasing global environmental challenges, the importance of integrating sustainability principles into the latest industrial revolution, Industry 5.0, is becoming increasingly critical. This revolution marks a turning point from an industrial approach that focuses on efficiency and automation, to a paradigm that prioritizes collaboration between humans and machines, innovation, and harmonization with the environment. This research examines the dynamic intersection between Industry 5.0 and sustainability, emphasizing how this evolution aims to integrate human creativity and expertise with advanced technological capabilities. This report identifies emerging trends and challenges, with a focus on achieving a sustainable future through innovative practices that balance economic growth and environmental management. This article uses a literature review and multidisciplinary analysis to uncover the untapped potential of Industry 5.0 technologies in driving sustainability initiatives. It aims to enrich academic discourse with fresh insights into aligning these technologies with environmental and social goals, thereby offering practical implications for policy makers, industry leaders and sustainability practitioners. © 2024 The Author(s)

关键词： Economic growth environmental stewardship Industry 5.0 Innovation practices Sustainability Technological integration

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New insights into the interactions between Pb(II) and fruit waste biosorbent

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CHEMOSPHERE 2022年第PT 1期303卷 135048页

作者： Wang, Qian Wang, Yunlong Tang, Junjie Yang, Zi Zhang, Li Huang, Xiaowu Department of Physics Chemistry and Pharmacy University of Southern Denmark 5230 Odense M Denmark Key Laboratory of Protected Horticulture Engineering in Northwest Ministry of Agriculture College of Horticulture Northwest A&F University Yangling Shaanxi 712100 China Environmental Science and Engineering Program Guangdong Technion-Israel Institute of Technology 241 Daxue Road Shantou Guangdong 515063 China State Key Laboratory of Crop Stress Biology in Arid Areas College of Life Sciences Northwest A&F University Yangling Shaanxi 712100 China National Engineering Laboratory for Advanced Municipal Wastewater Treatment and Reuse Technology Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery Engineering Beijing University of Technology Beijing 100124 China

Fruit waste is a sustainable biosorbent for heavy metal removal from wastewater. Elucidation of adsorption mechanism is imperative for the process control and development of effective adsorbents. In this study, watermelon rind (WR) exhibited selective and efficient Pb(II) adsorption with a maximum uptake of 230.5 mg/g at pH 5.0. The WR-packed bed column showed high Pb(II) uptake and robust durability over 10 adsorption desorption cycles with long breakthrough time of 8-13 h (89-144 bed volume), and 95% of sequestered Pb (II) was rapidly desorbed in 1-2 h by 0.05 M HCl. Spectroscopic characterization by FTIR and XPS identified hydroxyl, carboxyl, amine, and ether groups as the binding sites for Pb(II) via the binding force of complexation. Physicochemical analysis showed that ion exchange with Mg2+ and Ca2+ accounted for 19% of Pb(II) adsorption by WR;electrostatic attraction and microprecipitation jointly contributed. Quantum chemistry simulation verified the interactions between Pb(II) and binding sites and revealed carboxyl was the preferential functional group. The findings corroborate the applicability of WR in scale-up Pb(II) removal/recovery from wastewater and elaborate the mechanisms of Pb(II) adsorption by the WR biosorbent. This also provides insights into the behavior of heavy metals in other liquid/solid interfaces.

关键词： Fruit waste Heavy metal Adsorption mechanism Column study Circular economy

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Ultrasound for the degradation of endocrine disrupting compounds in aqueous solution: A review on mechanisms, influence of operating parameters and cost estimation

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Chemosphere 2024年 349卷 140864页

作者： Ghosh, Saptarshi Sahu, Manoranjan Aerosol and Nanoparticle Technology Laboratory Environmental Science and Engineering Department Indian Institute of Technology Bombay Mumbai400076 India Inter-Disciplinary Program in Climate Studies Indian Institute of Technology Bombay Mumbai400076 India Centre for Machine Intelligence and Data Science Indian Institute of Technology Bombay Mumbai400076 India

Availability of drinking water is one of the basic humanitarian goals but remains as a grand challenge that the world is facing today. Currently, water bodies are contaminated not only with conventional pollutants but also with numerous recalcitrant pollutants, such as PPCPs, endocrine disrupting compounds, etc. These emerging pollutants require special attention because of their toxicity to living organisms, bio-resistant and can sustain even after primary and secondary treatments of wastewater. Among different treatment technologies, sonolysis is found to be an innovative and promising technique for the treatment of emerging pollutants present in aqueous solution. Sonolysis is the use of ultrasound to enhance or alter chemical reactions by the formation of free radicals and shock waves which ultimately helps in degradation of pollutants. This review summarizes several studies in the sonochemical literature, including mechanisms of sonochemical process, physical and chemical effects of ultrasound, and the influence of several process variables such as ultrasound frequency, power density, temperature and pH of the medium on degradation performance for endocrine disrupting compounds. In addition, this review highlighted techno-economic perspectives focusing on the total cost required for translating the ultrasound-based processes on a large scale. Overall, the objective of this study is to exhibit a critical review of information available in the literature to encourage and promote future research on sonolysis for the degradation of Endocrine Disrupting Compounds (EDCs). © 2023 Elsevier Ltd

关键词： Wastewater treatment

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