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Oxidation Mechanism and Toxicity Evolution of Linalool,a Typical Indoor Volatile Chemical Product

Environment & Health 2024年第7期2卷 486-498页

作者： Zihao Fu Song Guo Ying Yu Hong-Bin Xie Shiyu Li Daqi Lv Putian Zhou Kai Song Zheng Chen Rui Tan Kun Hu Ruizhe Shen Maosheng Yao Min Hu State Key Joint Laboratory of Environmental Simulation and Pollution Control International Joint Laboratory for Regional Pollution ControlMinistry of Education(IJRC)College of Environmental Sciences and EngineeringPeking UniversityBeijing 100871China Collaborative Innovation Center of Atmospheric Environment and Equipment Technology Nanjing University of Information Science&TechnologyNanjing 210044China Key Laboratory of Industrial Ecology and Environmental Engineering(Ministry of Education) School of Environmental Science and TechnologyDalian University of TechnologyDalian 116024China Institute for Atmospheric and Earth System Research/Physics Faculty of ScienceUniversity of HelsinkiP.O.Box 64FIN-00014 HelsinkiFinland

Linalool,a high-reactivity volatile chemical product(VCP)commonly found in cleaning products and disinfectants,is increasingly recognized as an emerging contaminant,especially in indoor *** the gas-phase oxidation mechanism of linalool is crucial for assessing its impact on atmospheric chemistry and human *** quantum chemical calculations and computational toxicology simulations,we investigated the atmospheric transformation and toxicity evolution of linalool under low and high NO/HO_(2)·levels,representing indoor and outdoor *** findings reveal that linalool can undergo the novel mechanisms involving concerted peroxy(RO_(2)·)and alkoxy radical(RO·)modulated autoxidation,particularly emphasizing the importance of cyclization reactions *** expands the widely known RO_(2)·-dominated H-shift-driven autoxidation and proposes a generalized autoxidation mechanism that leads to the formation of low-volatility secondary organic aerosol(SOA)*** analysis shows that over half of transformation products(TPs)exhibited higher carcinogenicity and respiratory toxicity compared to *** also propose time-dependent toxic effects of TPs to assess their long-term *** results indicate that the strong indoor emission coupled with slow consumption rates lead to significant health risks under an indoor *** results highlight complex indoor air chemistry and health concerns regarding persistent toxic products during indoor cleaning,which involves the use of linalool or other VCPs.

关键词： volatile chemical products(VCPs) peroxy radicals(RO_(2)·) atmospheric autoxidation secondary organic aerosol(SOA) computational toxicology

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Secondary organic aerosol formation from straw burning using an oxidation flow reactor

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Journal of environmental Sciences 2022年第4期34卷 249-258页

作者： Hui Wang Song Guo Zhijun Wu Kai Qiao Rongzhi Tang Ying Yu Weizhao Xu Wenfei Zhu Liwu Zeng Xiaofeng Huang Lingyan He Mattias Hallquist State Key Joint Laboratory of Environmental Simulation and Pollution Control International Joint Laboratory for Regional Pollution ControlMinistry of Education(IJRC)College of Environmental Sciences and EngineeringPeking UniversityBeijing 100871China Collaborative Innovation Center of Atmospheric Environment and Equipment Technology Nanjing University of Information Science&TechnologyNanjing 10044China Key Laboratory for Urban Habitat Environmental Science and Technology College of Environment and EnergyPeking University Shenzhen Graduate SchoolShenzhen 518055China Department of Chemistry and Molecular Biology Atmospheric ScienceUniversity of GothenburgSE-41296 GothenburgSweden

Herein,we use an oxidation flow reactor,Gothenburg:Potential Aerosol Mass(Go:PAM)reactor,to investigate the secondary organic aerosol(SOA)formation from wheat straw *** burning emissions are exposed to high concentrations of hydroxyl radicals(OH)to simulate processes equivalent to atmospheric oxidation of 0-2.55 *** volatile organic compounds(VOCs)were investigated,and particles were measured before and after the Go:PAM *** influence of water content(i.e.5%and 11%)in wheat straw was also *** burning stages,the flaming stage,and non-flaming stages,were *** particle emission factors(EFs)at a water content of 11%(~3.89 g/kg-fuel)are significantly higher than those at a water content of 5%(~2.26 g/kg-fuel)during the flaming ***,the water content showed no significant influence at the non-flaming *** of aromatics at a non-flaming stage(321.8±46.2 mg/kg-fuel)are larger than that at a flaming stage(130.9±37.1 mg/kg-fuel).The OA enhancement ratios increased with the increase in OH exposure at first and decreased with the additional increment of OH *** maximum OA enhancement ratio is~12 during the non-flaming stages,which is much higher than~1.7 during the flaming *** mass spectrum of the primary wheat burning organic aerosols closely resembles that of resolved biomass burning organic aerosols(BBOA)based on measurements in ambient *** results show that large gap(0%-90%)still remains to estimate biomass burning SOA if only the oxidation of VOCs were included.

关键词： Gothenburg:Potential Aerosol Mass(Go:PAM)reactor Wheat straw burning Flaming Non-flaming Secondary organic aerosol formation

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Methane and nitrous oxide emissions from municipal wastewater treatment plants in China:A plant-level and technology-specific study

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environmental Science and Ecotechnology 2024年第4期20卷 123-130页

作者： Haiyan Li Liangfang You He Du Bowen Yu Lu Lu Bo Zheng Qiang Zhang Kebin He Nanqi Ren School of Civil and Environmental Engineering Harbin Institute of TechnologyShenzhen518055China Shenzhen Key Laboratory of Ecological Remediation and Carbon Sequestration Institute of Environment and EcologyTsinghua Shenzhen International Graduate SchoolTsinghua UniversityShenzhen518055China Ministry of Education Key Laboratory for Earth System Modeling Department of Earth System ScienceTsinghua UniversityBeijing100084China State Key Joint Laboratory of Environment Simulation and Pollution Control School of EnvironmentTsinghua UniversityBeijing100084China

Wastewater treatment is an important source of greenhouse gases(GHGs).Yet large uncertainties remain in the quantification of GHG emissions from municipal wastewater treatment plants(MWWTPs)in China.A high-resolution and technology-specific emission inventory is still lacking to support mitigation strategies of *** we develop a plant-level and technology-based MWWTP emission inventory for China covering 8703 plants and 19 treatment technology categories by compiling and harmonizing the most up-to-date facility-level ***'s methane(CH_(4))and nitrous oxide(N_(2)O)emissions from MWWTPs in 2020 are estimated to be 150.6 Gg and 22.0 Gg,respectively,with the uncertainty range of-30%to 37%and-30%to 26%at 95%confidence *** find an emission inequality across cities,with the richest cities emitting two times more CH_(4)and N_(2)O per capita from municipal wastewater treatment than the poorest *** emitted CH_(4)and N_(2)O are dominated by Anaerobic/Anoxic/Oxic-,Sequencing Batch Reactor-,Oxidation Ditch-,and Anoxic/Oxic-based MWWTPs of less than 20 years *** the relatively young age structure of China's MWWTPs,the committed emissions highlight the importance of reducing on-site GHG emissions by optimization of operating conditions and innovation *** emission differences among our estimates,previous studies,and the Intergovernmental Panel on Climate Change guidelines are largely attributed to the uncertainties in emission factors,implying the urgent need for more plant-integrated measurements to improve the accuracy of emission accounting.

关键词： Methane Nitrous oxide Emissions Municipal wastewater treatment plants

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Significant increase of assimilable organic carbon(AOC)levels in MBR effluents followed by coagulation,ozonation and combined treatments:Implications for biostability control of reclaimed water

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Frontiers of environmental Science & Engineering 2021年第4期15卷 241-249页

作者： Xiaojie Shi Zhuo Chen Yun Lu Qi Shi Yinhu Wu Hong-Ying Hu Environmental Simulation and Pollution Control State Key Joint Laboratory State Environmental Protection Key Laboratory of Microorganism Application and Risk Control(SMARC)School of EnvironmentTsinghua UniversityBeijing100084China Shenzhen Environmental Science and New Energy Technology Engineering Laboratory Tsinghua-Berkeley Shenzhen InstituteShenzhen518055China

As water reuse development has increased,biological stability issues associated with reclaimed water have gained *** study evaluated assimilable organic carbon(AOC)in effluents from a full-scale membrane biological reactor(MBR)plant and found that they were generally stable over one year(125-216µg/L),with slight increases in warmer *** additional tertiary treatments,the largest increases in absolute and specific AOCs were detected during ozonation,followed by coagulation-ozonation and ***,UV254 absorbance is known to be an effective surrogate to predict the AOC changes during *** coagulation prior to ozonation of MBR effluents for removal of large molecules was found to reduce the AOC formation compared with ozonation treatment ***,the results revealed that attention should be paid to seasonal variations in influent and organic fraction changes during treatment to enable sustainable water reuse.

关键词： Assimilable organic carbon(AOC) MBR effluents Tertiary treatments Coagulation Ozonation

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Chemical characteristics,oxidative potential,and sources of PM_(2.5)in wintertime in Lahore and Peshawar,Pakistan

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Journal of environmental Sciences 2021年第4期33卷 148-158页

作者： Mushtaq Ahmad Qing Yu Jing Chen Siming Cheng Weihua Qin Yuepeng Zhang State Key Joint Laboratory of Environment Simulation and Pollution Control School of EnvironmentBeijing Normal UniversityBeijing 100875China Department of Environmental Sciences University of PeshawarPeshawar 25120Pakistan

The chemical characteristics,oxidative potential,and sources of PM_(2.5)were analyzed at the urban sites of Lahore and Peshawar,Pakistan in February *** species,water soluble ions,and metal elements were measured to investigate the chemical composition and sources of PM_(2.5).The dithiothreitol(DTT)consumption rate was measured to evaluate the oxidative potential of PM_(2.5).Both cities showed a high exposure risk of PM_(2.5)regarding its oxidative potential(DTT v).Carbonaceous and some of the elemental species of PM_(2.5)correlated well with DTT v in both Lahore and ***,the DTT v of PM_(2.5)in Lahore showed significant positive correlation with most of the measured water soluble ions,however,ions were DTT-inactive in *** to the higher proportions of carbonaceous species and metal elements,Peshawar showed higher mass-normalized DTT activity of PM_(2.5)compared to Lahore although the average PM_(2.5)concentration in Peshawar was *** high concentrations of toxic metals also posed serious non-carcinogenic and carcinogenic risks to the residents of both *** component analysis coupled with multiple linear regression was applied to investigate different source contributions to PM_(2.5)and its oxidative *** sources of traffic and road dust resuspension and coal combustion,direct vehicle emission,and biomass burning and formation of secondary aerosol were identified as the major sources of PM_(2.5)in both *** findings of this study provide important data for evaluation of the potential health risks of PM_(2.5)and for formulation of efficient control strategies in major cities of Pakistan.

关键词： Air pollution DTT Health risk Oxidative potential Source apportionment

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Nano-sized alumina supported palladium catalysts for methane combustion with excellent thermal stability

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Journal of environmental Sciences 2023年第4期126卷 333-347页

作者： Wei Shi Guangyan Xu Xuewang Han Yingjie Wang Zhi Liu Sen Xue Nannan Sun Xiaoyan Shi Yunbo Yu Hong He State Key Joint Laboratory of Environment Simulation and Pollution Control Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China University of Chinese Academy of Sciences Beijing 100049China Weichai Power Co. Ltd.Weifang 261061China Center for Excellence in Regional Atmospheric Environment Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China

Pd/Al_(2)O_(3)catalysts supported on Al_(2)O_(3)of different particle sizes were synthesized and applied in methane *** catalysts were systematically characterized by Brunauer-Emmett-Teller (BET),X-ray diffraction (XRD),high resolution-transmission electron microscopy (HR-TEM),high-angle annular dark?eld-scanning transmission electron microscopy (HAADF-STEM),H_(2)-temperature-programmed reduction (H_(2)-TPR),O_(2)-temperature-programmed oxidation (O_(2)-TPO),X-ray photoelectron spectroscopy (XPS),and X-ray absorption?ne structure (XAFS).The characterization results indicated that nanosized Al_(2)O_(3)enabled the uniform dispersion of palladium nanoparticles,thus contributing to the excellent catalytic performance of these nano-sized Pd/Al_(2)O_(3)*** them,Pd/Al_(2)O_(3)-nano-10 (Pd/Al_(2)O_(3)supported by alumina with an average particle size of 10 nm)showed superior catalytic activity and stability for methane oxidation under harsh practical *** maintained excellent catalytic performance for methane oxidation for50 hr and remained stable even after harsh hydrothermal aging in 10 vol.%steam at 800℃ for 16 *** results revealed that the strong metal-support interactions and physical barriers provided by Al_(2)O_(3)-nano-10 suppressed the coalescence ripening of palladium species,and thus contributed to the superior sintering resistance of the Pd/Al_(2)O_(3)-nano-10 catalyst.

关键词： Methane combustion Pd/Al_(2)O_(3) Hydrothermal stability Metal-support interaction Physical barriers

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Recent advances in single-atom catalysts(SACs)for photocatalytic applications

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Materials Reports(Energy) 2024年第3期4卷 1-18页

作者： Tingcha Wei Jing Zhou Xiaoqiang An School of Physics South China Normal UniversityGuangzhou510006China MIIT Key Laboratory of Aerospace Information Materials and Physics College of PhysicsNanjing University of Aeronautics and AstronauticsNanjing211106China Key Laboratory of Songliao Aquatic Environment Ministry of EducationSchool of Municipal and Environmental EngineeringJilin Jianzhu UniversityChangchun130118China Center for Water and Ecology State Key Joint Laboratory of Environment Simulation and Pollution ControlSchool of EnvironmentTsinghua UniversityBeijing100084China

Artificial photocatalysis represents a hopeful avenue for tackling the global crisis of environmental and energy *** crux of industrial application in photocatalysis lies in efficient photocatalysts that can inhibit the recombination of photogenerated charge carriers,thereby boost the efficiency of chemical *** the past decade,single-atom catalysts(SACs)have been growing extremely rapidly and have become the forefront of photocatalysis owing to their superior utilization of metal atoms and outstanding catalytic *** this work,we provide an overview of the latest advancements and challenges in SACs for photocatalysis,focusing on the photocatalytic mechanisms,encompassing the generation,separation,migration,and surface extraction of photogenerated *** also explore the design,synthesis,and characterization of SACs and introduce the progress of SACs for photocatalytic applications,such as water splitting and CO_(2)***,we offer our personal perspectives on the opportunities and challenges of SACs in photocatalysis,aiming to provide insights into the future studies of SACs for photocatalytic applications.

关键词： Single-atom catalysts Artificial photocatalysis Water splitting CO_(2)reduction

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Machine learning for membrane bioreactor research:principles,methods,applications,and a tutorial

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Frontiers of environmental Science & Engineering 2025年第3期19卷 119-144页

作者： Yizhe Lai Kang Xiao Yifan He Xian Liu Jihua Tan Wenchao Xue Aiqian Zhang Xia Huang Beijing Yanshan Earth Critical Zone National Research Station College of Resources and EnvironmentUniversity of Chinese Academy of SciencesBeijing 101408China Key Laboratory of Earth System Numerical Modeling and Application University of Chinese Academy of SciencesBeijing 101408China Environmental Chemistry Faculty College of Resources and EnvironmentUniversity of Chinese Academy of SciencesBeijing 101408China State Key Laboratory of Environmental Chemistry and Ecotoxicology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China Department of Energy Environmentand Climate ChangeSchool of EnvironmentResourcesand DevelopmentAsian Institute of TechnologyP.O.Box 4Klong LuangPathumthani 12120Thailand State Key Joint Laboratory of Environment Simulation and Pollution Control School of EnvironmentTsinghua UniversityBeijing 100084China

Membrane fouling poses a significant challenge to the sustainable development of membrane bioreactor(MBR)technologies for wastewater *** accurate prediction of the membrane filtration process is of great importance for identifying and controlling *** learning methods address the limitations of traditional statistical approaches,such as low accuracy,poor generalization ability,and slow convergence,particularly in predicting complex filtration and fouling processes within the realm of big *** article provides an in-depth exposition of machine learning *** study then reviews advances in MBRs that utilize machine learning methods,including artificial neural networks(ANN),support vector machines(SVM),decision trees,and ensemble *** on current literature,this study summarizes and compares the model input and output characteristics(including foulant characteristics,solution environments,filtration conditions,operating conditions,and time factors),as well as the selection of models and optimization *** modeling procedures of SVM,random forest(RF),back propagation neural network(BPNN),long short-term memory(LSTM),and genetic algorithm-back propagation(GA-BP)methods are elucidated through a tutorial *** simulation results demonstrated that all five methods yielded accurate predictions with R2>***,the existing challenges in the implementation of machine learning models in MBRs were *** is notable that integration of deep learning,automated machine learning(AutoML)and explainable artificial intelligence(XAI)may facilitate the deployment of models in practical engineering *** insights presented here are expected to facilitate the establishment of an intelligent control framework for MBR processes in future endeavors.

关键词： Membrane bioreactor Machine learning Pollutant removal Membrane fouling Model prediction

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超越传统NO_(x)和VOCs控制的臭氧污染防治新思路

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Science Bulletin 2023年第18期68卷 1989-1992页

作者：陆克定周厚华 James Lee Beth Nelson 张远航 State Environmental Protection Key Laboratory of Atmospheric Ozone Pollution Control State Key Joint Laboratory of Environmental Simulation and Pollution ControlCollege of Environmental Sciences and EngineeringPeking UniversityBeijing 100871China National Centre for Atmospheric Science Department of ChemistryUniversity of YorkYork YO105DDUK

Ambient ozone(O3)was first identified as a key harmful air pollutant in the study of photochemical smog during the 1950s in Los *** studies uncovered that surface O3 was not emitted directly,but formed from the reactions of nitrogen oxides(NO_(x))and volatile organic compounds(VOCs)in *** the relationship between O3 and its two main precursors,NOx and VOCs,is considered to be the cornerstone for enabling successful mitigation of *** the past,a central area for the study and practice of O3 pollution control was Los Angeles and the surrounding *** ambient O3 concentrations in the area were successfully and continuously reduced from 400 ppb(1 ppb=109 m^(3)/m^(3))to ca.120 ppb due to the joint mitigation of VOC and NOx emissions from 1960 to 2010[1].Nevertheless,O3 pollution still represents one of the most pervasive and stubborn environmental problems in megacities worldwide,with many populous centres regularly breaching WHO 8-hour Interim Targets-1 levels(160 lg/m^(3)),not to mention the updated air quality guideline value of 100 lg/m^(3).The difficulty of O3 pollution control is due to a number of factors,including its non-linear relationship with NOx[2],the difficulty of anthropogenic VOC control[3]and the contributions of biogenic VOCs.

关键词： pollution difficulty corners

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Improving Fugitive Dust Emission Inventory from Construction Sector Using UAV Images Recognition

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Aerosol and Air Quality Research 2024年第8期24卷 1-18页

作者： He, Yuyao Jang, Jicheng Zhu, Yun Chiang, Pen-Chi Xing, Jia Wang, Shuxiao Zhao, Bin Long, Shicheng Yuan, Yingzhi Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control College of Environment and Energy South China University of Technology Guangzhou Higher Education Mega Center Guangzhou510006 China Graduate Institute of Environmental Engineering Taiwan University Taipei10673 Taiwan Carbon Cycle Research Center National Taiwan University Taipei10672 Taiwan Department of Civil and Environmental Engineering University of Tennessee KnoxvilleTN37996 United States State Key Joint Laboratory of Environment Simulation and Pollution Control School of Environment Tsinghua University Beijing100084 China

Over rapidly developing and urbanizing countries, frequent construction activities are the primary drivers behind the substantial emissions and contributors of fugitive dust. In this study, an innovative method was developed to compile a high-resolution spatiotemporal emission inventory from construction sector, utilizing unmanned aerial vehicle (UAV) images. This methodology offered detailed activity level information by distinguishing various types of construction lands and equipment. Focusing on the Shunde District of Guangdong in China, the new emission inventory derived from this method highlighted that travel, topsoil excavation, and loading collectively contributed up to 90% of particulate matter (PM) emissions during the earthwork phase. Moreover, this new inventory rectified the tendency of traditional methods to underestimate PM10 emissions and overestimate PM2.5 emissions, while revealing the non-linear relationship between PM emissions and construction area. This improved PM emission inventory appeared to precisely identify major emission hotspots and enhanced performance of the Community Multi-scale Air Quality (CMAQ) model, and the correlation coefficient (R-value) is 0.08 ± 0.02 higher than that of the traditional emission inventory. Post integration of monitoring data through the Software for the Modeled Attainment Test-Community Edition (SMAT-CE), the contributions of construction dust to local PM10 and PM2.5 concentrations were estimated at 3.27 ± 0.8 µg m–3 and 1.11 ± 0.27 µg m–3, respectively, with more pronounced impacts observed in the central, northwestern, and south-central zones of the study region. This study provides valuable insight for improving construction dust and PM emission inventories, which should be benefiting the development of air pollution prevention and control strategies over this study area as well as other rapidly growing urban areas. © The Author(s).

关键词： Image enhancement

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