Bob cuts a pizza into slices of not necessarily equal size and shares it with Alice by alternately taking turns. One slice is taken in each turn. The first turn is Alice's. She may choose any of the slices. In all...
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Along with the recent progress in the development of advanced synthetic methods, the chemical community has witnessed an increasing interest in promising carbon-rich materials. Among them, helicenes are unique 3D arom...
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Along with the recent progress in the development of advanced synthetic methods, the chemical community has witnessed an increasing interest in promising carbon-rich materials. Among them, helicenes are unique 3D aromatic systems that are inherently chiral and attractive for asymmetric catalysis, chiral recognition and material science. However, there have been only limited attempts at synthesizing long helicenes, which represent challenging targets. Here, we report on an organometallic approach to the derivatives of undecacyclic helicene, which is based on intramolecular [2 + 2 + 2] cycloisomerization of aromatic hexaynes under metal catalysis closing 6 new cycles of a helicene backbone in a single operation. The preparation of nonracemic compounds relied on racemate resolution or diastereoselective synthesis supported by quantum chemical (density functional theory) calculations. The fully aromatic [11]helicene was studied in detail including the measurement and theoretical calculation of its racemization barrier and its organization on the InSb (001) surface by STM. This research provides a strategy for the synthesis of long helical aromatics that inherently comprise 2 possible channels for charge transport: Along a ...-conjugated pathway and across an intramolecularly ...-... stacked aromatic scaffold. (ProQuest: ... denotes formulae/symbols omitted.)
In the present work static and spherically symmetric magnetically charged black holes coupled to Euler‐Heisenberg type non‐linear electrodynamics in the scalar‐tensor theories of gravity with massive scalar field a...
In the present work static and spherically symmetric magnetically charged black holes coupled to Euler‐Heisenberg type non‐linear electrodynamics in the scalar‐tensor theories of gravity with massive scalar field are investigated numerically. For the numerical solving of the corresponding boundary‐value problem with free boundary the Continuous Analogue of Newton Method is used. As a result of the numerical experiments some general properties of the solutions were found.
Given an edge coloring F of a graph G, a vertex coloring of G is adapted to F if no color appears at the same time on an edge and on its two endpoints. If for some integer k, a graph G is such that given any list assi...
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In the present, work we find new numerical solutions describing soliton‐like objects coupled to non‐linear electrodynamics in the scalar‐tensor theories of gravity. Approximate solutions have been also obtained and...
In the present, work we find new numerical solutions describing soliton‐like objects coupled to non‐linear electrodynamics in the scalar‐tensor theories of gravity. Approximate solutions have been also obtained and a comparison to the numerical results has been made. The non‐existence of black holes for the specific choice of lagrangian of the nonlinear electrodynamics has been also proved.
The purpose of this work was synthesis of a new copolymer consisting of poly(N-vinylcarbazole) and pyrazoloquinoline based dye, suitable to provide electroluminescence in the wavelength range corresponding to the blue...
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The purpose of this work was synthesis of a new copolymer consisting of poly(N-vinylcarbazole) and pyrazoloquinoline based dye, suitable to provide electroluminescence in the wavelength range corresponding to the blue. The obtained material was tested in a simple, single layer electroluminescent device. It were studied both its electronic and optical performances. It was found that the maximum of electroluminescence spectrum can be tuned within the wavelength of 450 nm and 490 nm (what reads in terms of colours as the blue and the cyan) by simple variation of the dye content.
Phases of scalar‐tensor black holes coupled to non‐linear electrodynamics where recently obtained and thermodynamical analysis of the obtained solutions was performed. Our task is to study numerically the linear sta...
Phases of scalar‐tensor black holes coupled to non‐linear electrodynamics where recently obtained and thermodynamical analysis of the obtained solutions was performed. Our task is to study numerically the linear stability of the solutions which has trivial scalar field. The obtained singular Sturm‐Liouville problem is solved with a modifications of the shooting method. Results are obtained and they are in a good agreement with the predictions of the thermodynamical analysis.
Using X-ray grazing incidence diffraction (GID) it is possible to perform a nondestructive analysis of the heterogeneous stress field for different volumes below the surface of the sample. The stress can be measured a...
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The time evolution of a wave packet injected into a semiconductor quantum ring is investigated in order to obtain the transmission and reflection probabilities. Within the effective-mass approximation, the time-depend...
The time evolution of a wave packet injected into a semiconductor quantum ring is investigated in order to obtain the transmission and reflection probabilities. Within the effective-mass approximation, the time-dependent Schrödinger equation is solved for a system with nonzero width of the ring and leads and finite potential-barrier heights, where we include smooth lead-ring connections. In the absence of a magnetic field, an analysis of the projection of the wave function over the different subband states shows that when the injected wave packet is within a single subband, the junction can scatter this wave packet into different subbands but remarkably at the second junction the wave packet is scattered back into the subband state of the incoming wave packet. If a magnetic field is applied perpendicularly to the ring plane, transmission and reflection probabilities exhibit Aharonov-Bohm (AB) oscillations and the outgoing electrons may end up in different subband states from those of the incoming electrons. Localized impurities, placed in the ring arms, influence the AB oscillation period and amplitude. For a single impurity or potential barrier of sufficiently strong strength, the period of the AB oscillations is halved while for two impurities localized in diametrically opposite points of the ring, the original AB period is recovered. A theoretical investigation of the confined states and time evolution of wave packets in T wires is also made, where a comparison between this system and the lead-ring junction is drawn.
A consequence of Fe/Ni substitution in the intermetallics Dy(Fe 0.7− x Ni x Co 0.3 ) 2 was tested in this paper. Fe 57 Mössbauer effect measurements for the intermetallic system were carried out at 4.2 K. ...
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A consequence of Fe/Ni substitution in the intermetallics Dy(Fe 0.7− x Ni x Co 0.3 ) 2 was tested in this paper. Fe 57 Mössbauer effect measurements for the intermetallic system were carried out at 4.2 K. The obtained hyperfine interaction data are presented. The magnetic hyperfine field as well as the Curie temperature is strongly reduced with a composition parameter x . Band structure calculations using the Full-Potential Linearized Augmented Plane Waves (FLAPW) method were performed. The experimentally determined magnetic hyperfine field correlates linearly with the weighted magnetic moment calculated per transition metal atom and correlates linearly with the average splitting energy between 3d subbands. The Curie temperature changes in an approximate linear fashion with the squared magnetic hyperfine field or with the calculated squared splitting energy between 3d subbands.
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