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Self-Fenton Cu-Mn catalysts for efficient ciprofloxacin removal: in-situ H2O2 generation and activation

Journal of Environmental Management 2025年 384卷 125569页

作者： Wu, Yifang Wu, Jianwang Lin, Mei Chen, Zuliang Fujian Key Laboratory of Pollution Control and Resource Reuse School of Environmental Science and Engineering Fujian Normal University Fujian Province Fuzhou350007 China

The Fenton oxidation system is a widely employed advanced oxidation processes (AOPs) in wastewater treatment. However, the traditional Fenton oxidation system suffers from low oxidant utilization efficiency, leading to significant resource wastage. This study presents a novel self-Fenton Cu-Mn bimetallic catalyst (with a Cu:Mn ratio of 10:1), which is capable of simultaneously activating O2 to generate H2O2 in situ and further catalyzing the decomposition of H2O2 to produce reactive oxygen species (ROS). Notably, this self-Fenton system demonstrate high removal efficiency for ciprofloxacin (CIP) across a broad pH range (2−9), achieving up to 92.55 % removal in water. Quenching experiments, electron paramagnetic resonance (EPR) analysis, steady-state concentration measurements, and Galvanic oxidation reactor (GOR) experiments collectively confirmed the generation of multiple ROS species (·OH, ·O2−, and 1O2) and indicated that electron transfer plays a significant role in pollutant degradation. X-ray photoelectron spectroscopy (XPS) analysis revealed that Cu0 exhibited high catalytic activity, enabling simultaneous generation and activation of H2O2. Liquid chromatography-mass spectrometry (LC-MS) and toxicity assessments demonstrated a significant reduction in the toxicity of CIP degradation products. This work elucidates a novel Cu-Mn synergistic mechanism wherein Mn facilitates the generation of H2O2, while Cu effectively activates it into ROS. This synergism effect enables the removal of pollutants through both radical and non-radical pathways, thereby offering an innovative strategy for environmental remediation and AOPs. © 2025 Elsevier Ltd

关键词： Paramagnetic resonance

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Dual-selective silver recovery strategy by simultaneous adsorption-reduction boosted by in-situ magnetic field

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Green Energy & Environment 2025年第2期10卷 433-440页

作者： Jianran Ren Zhiliang Zhu Yanling Qiu Fei Yu Tao Zhou Jie Ma Jianfu Zhao Research Center for Environmental Functional Materials State Key Laboratory of Pollution Control and Resource ReuseCollege of Environmental Science and EngineeringTongji UniversityShanghai200092China School of Civil Engineering Kashi UniversityKashi844000China College of Marine Ecology and Environment Shanghai Ocean UniversityShanghai201306China

The mainstream silver recovery has problems such as resource waste,weak silver selectivity,and complicated ***,self-propelled magnetic enhanced capture hydrogel(magnetic NbFeB/MXene/GO,MNMGH)was prepared by self-crosslinking encapsulation *** achieved high selectivity(K_(d)=23.31 mL/g)in the acidic range,and exhibited ultrahigh silver recovery capacity(1604.8 mg/g),which greatly improved by 66%with the assistance of in-situ magnetic *** recovered silver crystals could be directly physically exfoliated,without acid/base *** selective sieving effect of adsorption,MNMGH preferentially adsorbed Ag(I),and then selectively reduced to Ag(0),realizing dual-selective *** in-situ magnetic field enhanced selective adsorption by enhancing mass transfer,reactivity of oxygen-containing functional ***,density function theory simulations demonstrated that the in-situ magnetic field could lower the silver reduction reaction energy barrier to enhance the selective ***-drive synergy system(reduction drive,adsorption drive and magnetic drive)achieved ultrahigh silver recovery *** study pioneered an in-situ magnetic field assisted enhancement strategy for dual-selective(adsorption/reduction)recovery of precious metal silver,which provided new idea for low-carbon recovery of noble metal from industrial waste liquids.

关键词： In-situ magnetic field Silver recovery Adsorption-reduction Selectivity Physical separation

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Vacuum ammonia stripping from liquid digestate:Effects of pH,alkalinity,temperature,negative pressure and process optimization

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Journal of Environmental Sciences 2025年第3期149卷 638-650页

作者： Qiuhong Chen Donghai Yang Xiang Chen Xiankai Wang Bin Dong Xiaohu Dai State Key Laboratory of Pollution Control and Resource Reuse College of Environmental Science and EngineeringTongji UniversityShanghai 200092China YANGTZE Eco-Environment Engineering Research Center National Engineering Research Center of Eco-environment Protection for Yangtze River Economic BeltChina Three Gorges CorporationWuhan 430010China

High ammonia-nitrogen digestate has become a key bottleneck limiting the anaerobic digestion of organic solid *** ammonia stripping can simultaneously remove and recover ammonia nitrogen,which has attracted a lot of attention in recent *** investigate the parameter effects on the efficiency and mass transfer,five combination conditions(53℃ 15 kPa,60°C 20 kPa,65°C 25 kPa,72°C 35 kPa,and 81°C 50 kPa)were conducted for ammonia stripping of sludge *** results showed that 80%of ammonia nitrogen was stripped in 45 min for all experimental groups,but the ammonia transfer coefficient varied under different conditions,which increased with the rising of boiling point temperature,and reached the maximum value(39.0 mm/hr)at 81°C 50 *** ammonia nitrogen removal efficiency was more than 80%for 30 min vacuum stripping after adjusting the initial pH to above 9.5,and adjustment of the initial alkalinity also affects the pH value of liquid *** was found that pH and alkalinity are the key factors influencing the ammonia nitrogen dissociation and removal efficiency,while temperature and vacuum mainly affect the ammonia nitrogen mass transfer and removal *** terms of the mechanism of vacuum ammonia stripping,it underwent alkalinity destruction,pH enhancement,ammonia nitrogen dissociation,and free ammonia *** this study,two-stage experiments of alkalinity destruction and ammonia removal were also carried out,which showed that the two-stage configuration was beneficial for ammonia *** provides a theoretical basis and practical technology for the vacuum ammonia stripping from liquid digestate of organic solid waste.

关键词： Liquid digestate Vacuum ammonia stripping Alkalinity Mass transfer Process optimization

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High potential in synergizing the reduction of dissolved organic carbon concentration and carbon dioxide emissions for submerged-vegetationcovered river networks

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Journal of Environmental Sciences 2025年第5期151卷 298-309页

作者： Qingqian Li Ruixia Liu Zhangmu Jing Yanjie Wei Shengqiang Tu Huibin Yu Hongjie Gao Peng Yuan State Key Laboratory of Environmental Criteria and Risk Assessment Chinese Research Academy of Environmental ScienceBeijing 100012China State Environmental Protection Key Laboratory of Estuarine and Coastal Environment Chinese Research Academy of Environmental ScienceBeijing 100012China State Key Laboratory of Pollution Control and Resource Reuse College of Environmental Science and EngineeringTongji UniversityShanghai 200092China College of Municipal and Environmental Engineering Shenyang Jianzhu UniversityShenyang 110168China

Various technologies and projects have been explored and developed for the synergetic control of environmental pollution and carbon emissions in aquatic *** submerged vegetation in shallow waters was also expected to achieve this ***,the magnitude and mechanism of carbon dioxide(CO_(2))emission affected by submerged vegetation is not clear enough in complex aquatic *** study investigated the influences of submerged plants on CO_(2)emission,ecosystem metabolism features,and microbial community traits based on observations in river networks on the Changjiang River *** results showed that CO_(2)emission from planted waters accounted for 73%of unplanted ***,planted waters had higher dissolved organic carbon removal capacity in overlying water and higher potential of carbon sequestration in sediment at the same *** distinctions between the two habitats were attributed to(1)improved CO_(2)and bicarbonate consumption in water columns via enhancing photosynthesis and(2)inhibited CO_(2)production by reconstructing the benthic microbial *** eco-advantages were found in planted sediments,such as a high potential of methane oxidation and xenobiotics biodegradation and a low risk of becoming black and *** brief,submerged vegetation is beneficial in promoting pollution removal and carbon retention *** study advances our understanding of the feedback between aquatic metabolism and CO_(2)emission.

关键词： Mitigated CO_(2)emission Submerged vegetation Paired O_(2)-CO_(2)departure Carbon uptake velocity Microbial metabolism pathways The Changjiang River

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Molecular Mechanism Behind the Capture of Fluorinated Gases by Metal–Organic Frameworks

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Nano-Micro Letters 2025年第5期17卷 407-462页

作者： Qian Wang Yong Hu Yifan Gu College of Environmental Science and Engineering State Key Laboratory of Pollution Control and Resource ReuseTongji UniversitySiping Rd 1239Shanghai 200092People’s Republic of China Department of Polymeric Materials School of Materials Science and EngineeringTongji UniversityCaoan Road 4800Shanghai 201804People’s Republic of China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092People’s Republic of China Key Laboratory of Cities’Mitigation and Adaptation to Climate Change China Meteorological Administration(CMA)Tongji UniversityShanghai 200092People’s Republic of China

Fluorinated gases(F-gases)play a vital role in the chemical industry and in the fields of air conditioning,refrigeration,health care,and organic ***,the direct emission of waste gases containing F-gases into the atmosphere contributes to greenhouse effects and generates toxic *** porous materials for the energy-efficient capture,separation,and recovery of F-gases is highly ***,as a highly designable porous adsorbents,metal–organic frameworks(MOFs)exhibit excellent selective sorption performance toward F-gases,especially for the recognition and separation of different F-gases with highly similar properties,showing their great potential in F-gases control and *** this review,we discuss the capture and separation of F-gases and their azeotropic,near-azeotropic,and isomeric mixtures in various application scenarios by MOFs,specifically classify and analyze molecular interaction between F-gases and MOFs,and interpret the mechanisms underlying their high performance regarding both adsorption capacity and selectivity,providing a repertoire for future materials *** faced in the transformation research roadmap of MOFs adsorbent separation technologies toward F-gases are also discussed,and areas for future research endeavors are highlighted.

关键词： Fluorinated gas Metal–organic framework Adsorption Separation Molecular interaction

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Risk management of radionuclide waste from nuclear power plants: Removal techniques and control strategies

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National Science Open 2025年第1期4卷 4-6页

作者： Liang Mao Maofa Ge Fangbai Li State Key Laboratory of Pollution Control and Resource Reuse School of the Environment Chemistry and Biomedicine Innovation CenterNanjing University Institute of Chemistry Chinese Academy of Sciences Institute of Eco-environmental and Soil Sciences Guangdong Academy of Sciences

In modern society, the ceaselessly increasing demand for clean energy has spurred the exploration of novel low-carbon technologies. Nuclear power has proven its effectiveness in resolving the energy crisis. With the rapid expansion of nuclear power facilitating humanity's shift towards a low-carbon energy society, proper management of nuclear waste generated by nuclear plants has become crucial for minimizing environmental impacts and alleviating public concerns.

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Consuming probiotics protects against cadmium exposure from rice consumption while promotes gut health: An assessment based on a mouse model

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Science of the Total Environment 2025年 958卷 177997页

作者： Xi, Jin-Feng Zhou, Lei Zhang, Yao-Sheng Lin, Xin-Ying Chen, Shan Xue, Rong-Yue Zhou, Dongmei Li, Hong-Bo State Key Laboratory of Pollution Control and Resource Reuse Jiangsu Key Laboratory of Vehicle Emissions Control School of Environment Nanjing University Nanjing210023 China

Cadmium (Cd) in rice constitutes a global health risk. It is crucial to develop strategies that not only reduce the bioavailability of Cd in rice but also confer additional health benefits. One potential approach involves the consumption of probiotics, which can bind Cd in the intestines and enhance gut health. The effects of consuming Akkermansia muciniphila, Bifidobacterium pseudolongum, and Psychrobacter sp. on the bioavailability of Cd in rice and gut health were evaluated using in vivo mouse bioassays and in vitro Cd immobilization assays. In mice fed Cd-contaminated rice without dietary calcium (Ca) and iron (Fe) supplementation (i.e., under conditions of mineral deficiency), the intake of these probiotics insignificantly reduced Cd accumulation in the kidneys and livers, although it did promote Cd excretion via feces. This outcome was primarily due to the competition for Ca and Fe between the probiotics and the host, which led to increased intestinal expression of Ca and Fe transporters under mineral-deficient conditions, thereby mitigating the probiotics' ability to reduce Cd bioavailability. Conversely, in mice fed Cd-contaminated rice with adequate dietary Ca and Fe (i.e., under conditions of mineral adequacy), probiotic intake significantly decreased Cd concentrations in the kidneys by 60.0 %–72.0 % compared to the control group exposed to Cd. Additionally, probiotic consumption fostered the growth of beneficial gut bacteria and strengthened intestinal tight junctions, reducing the inflammatory response in the intestines. These findings suggest that combining probiotics with sufficient Ca and Fe intake can effectively reduce dietary Cd exposure and enhance gut health. © 2024 Elsevier B.V.

关键词： Macroinvertebrates

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Model-driven high-throughput zebrafish embryo assay for evaluating whole effluent toxicity variation across 100 full-scale wastewater treatment plants

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Water Research 2025年 281卷

作者： Zhao, Aixia Bai, Hongwei Bao, Xingchen Liao, Kewei Ren, Hongqiang Hu, Haidong State Key Laboratory of Pollution Control and Resource Reuse School of Environment Nanjing University Jiangsu Nanjing210023 China

The zebrafish embryo is a valuable model for evaluating whole effluent toxicity (WET). However, the widely recognized acute toxicity indicator, based on International Organization of Standardization (ISO) methods, requires large numbers of embryos and is often time-consuming due to its complex experimental procedures. In this study, we propose an alternative to the conventional reliance on ISO standards by developing a model-driven high-throughput assay that utilizes actual wastewater, enabling rapid LC10 (the lethal concentration at which 10 % of the test organisms are affected) prediction through machine learning techniques and multidimensional indicators derived from streamlined experimental procedures. We compared three streamlined toxicity assays—developmental toxicity, behavioral toxicity, and vascular toxicity—along with five different models. Among these, the Lasso model based on behavioral toxicity emerged as the most effective, achieving an R2 value of 0.893 while reducing experimental time by 5- to 8-fold. Furthermore, fivefold cross-validation confirmed its robust predictive accuracy. The application of this model-driven high-throughput assay across 100 wastewater treatment plants in China highlights the crucial role of biological treatment, particularly aerobic processes and secondary sedimentation, in reducing toxicity, thereby providing valuable insights into their functions. This high-throughput assay not only surpasses the ISO standard method in efficiency but also substantially decreases embryo usage, facilitating rapid WET assessments of actual wastewater with larger sample sizes. © 2025

关键词： Wastewater treatment

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Research progress of nitrate removal technologies based on photoelectrochemical reduction

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Zhongguo Huanjing Kexue/China Environmental Science 2025年第4期45卷 1878-1888页

作者： Huang, Tian-Rong Wang, Kai-Chong Li, Zi-Bin Li, Dan-Ping Wang, Han Wang, Ya-Yi School of Environmental Science and Engineering Tongji University Shanghai200092 China State Key Laboratory of Pollution Control and Resource Reuse Tongji University Shanghai200092 China

As a common pollutant in water, nitrate has nonnegligible harmful effects on human health and the ecological environment. Faced with an increasingly severe energy crisis, the development of green, clean and sustainable nitrate removal technologies to replace the conventional resource-intensive denitrification process is urgently needed. Photoelectrochemical nitrate reduction powered by sunlight has become a research hotspot at home and abroad. Based on the way photogenerated electrons being transferred from semiconductor to nitrate, this technology can be categorized into photocatalytic reduction, photoelectrocatalytic reduction, and microbial photoelectrotrophic reduction. In this review, the mechanisms of three photoelectrochemical nitrate reduction technologies were discussed. With a focus on improving system performance, the selection and design strategies of photocatalysts, photoelectrodes and microbial photosensitizers were also summarized. Moreover, the technical difficulties of photoelectrochemical nitrate reduction are clarified and the future directions of research are proposed, such as regulating the pathway of microbial absorption and utilization of photogenerated electrons through genetic engineering and other methods. The insights provided will serve as a reference for the development of new nitrate removal and reutilization technologies. © 2025 Chinese Society for Environmental Sciences. All rights reserved.

关键词： Sustainable development

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Optimization of environmental engineering practical teaching system based on cellular mechanics principles and construction of multi-dimensional evaluation model

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MCB Molecular and Cellular Biomechanics 2025年第1期22卷

作者： Meng, Na Jiangsu Key Laboratory of Industrial Pollution Control and Resource Reuse School of Environment Engineering Xuzhou University of Technology Xuzhou221018 China

In the realm of emerging engineering education, the practical teaching of environmental engineering majors cries out for reform and optimization, which can be analogized to the regulatory mechanisms within cellular molecular biomechanics. Cells maintain their functionality and adaptability through a complex network of molecular interactions and signaling pathways. Similarly, an effective practical teaching system must have a well-structured and optimized framework. This study aims to explore the reform of the practical teaching system for environmental engineering majors in the context of emerging engineering education. A multi-dimensional evaluation model was constructed based on the Analytic Hierarchy Process (AHP), and the heuristic algorithm was integrated for weight optimization. The results show that the Improved Genetic Particle Swarm Optimization (IG-PSO) exhibits significant advantages in optimizing the weights of various indicators. After optimization, its Consistency Ratio (CR) decreased to 0.07, representing a 53% and 46% improvement over Particle Swarm Optimization (PSO) and Genetic Algorithm (GA), respectively. Additionally, the fitness value of IG-PSO after 800 iterations reached 0.046, significantly outperforming other comparative algorithms. Furthermore, the assessment of teaching effects in dimensions like experimental performance and innovation ability parallels the overall functionality and responsiveness of a cell. The IG-PSO-optimized evaluation system achieved an excellent score of over 90 in the assessment of actual teaching effectiveness across dimensions such as experimental performance and innovation ability. It shows that the teaching system is a healthy, well-regulated cell that can effectively perform its functions and adapt to different educational needs. Through the analogy with cellular molecular biomechanics, we can gain a deeper understanding of the improvement and optimization of the practical teaching system of environmental engi

关键词： Cell signaling

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