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Reuse of sodium–doped iridium oxide nanoparticles as a bio–stimulating electrode by a chemical and electrochemical recovery process

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Ceramics International 2024年第4期50卷 6220-6228页

作者： Tso, Kuang-Chih Chen, Chieh-Hsuan Chen, Po-Chun Li, Shao-Sian Chen, Jeng-Lung Ohta, Jun Wu, Pu-Wei Division of Materials Science Graduate School of Science and Technology Nara Institute of Science and Technology Nara630-0192 Japan Graduate Degree Program of Science and Technology of Accelerator Light Source National Yang Ming Chiao Tung University Hsinchu300 Taiwan Department of Materials Science and Engineering National Yang Ming Chiao Tung University Hsinchu300 Taiwan Institute of Materials Science and Engineering National Taipei University of Technology Taipei106 Taiwan National Synchrotron Radiation Research Center Hsinchu300 Taiwan

A sequential chlorination and electrochemical reduction process is demonstrated to convert Na–doped iridium oxide nanoparticles into useful IrIIICl63−(aq) serving as the precursor for the fabrication of bio–stimulating electrode. The Na–doped iridium oxide nanoparticles are treated in 35 wt% hydrochloric acid at 70 °C for 18 h to form IrIVCl62−(aq) with pH of 0.3, so the latter could be readily reduced to IrIIICl63−(aq) at a potentiostatic mode of 0.6 V (vs. SCE). The oxidation state and the nature of complexing ligands for the regenerated IrIIICl63− and IrIVCl62−, as well as commercially available IrIIICl63− are validated by X–ray Absorption Spectroscopy. UV–Vis profiles of regenerated IrIVCl62−(aq) are recorded and the absorbance at 487 nm signal is benchmarked against that of standard IrIVCl62−(aq) to obtain the effective regeneration ratio of 68.6%. X–ray diffraction patterns of Na–doped iridium oxide nanoparticles before and after the annealing treatment indicate the amorphous structure facilitates the chlorination step. The regenerated IrIIICl63− is reused to synthesize Na–doped iridium oxide thin film serving as a bio–stimulating electrode for implantable bio–electronics. The regenerated Na–doped iridium oxide thin film reveals a charge-storage capacity of 0.32 mC/cm2-nm and impressive stability that are comparable to those of fresh Na–doped iridium oxide thin film derived from commercially available IrIIICl63−. © 2023 Elsevier Ltd and Techna Group S.r.l.

关键词： Transition metal oxides

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180 °-twisted bilayer ReSe2 as an artificial noncentrosymmetric semiconductor

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Physical Review Research 2024年第2期6卷 L022048-L022048页

作者： S. Akatsuka M. Sakano T. Yamamoto T. Nomoto R. Arita R. Murata T. Sasagawa K. Watanabe T. Taniguchi N. Mitsuishi M. Kitamura K. Horiba K. Sugawara S. Souma T. Sato H. Kumigashira K. Shinokita H. Wang K. Matsuda S. Masubuchi T. Machida K. Ishizaka Quantum-Phase Electronics Center and Department of Applied Physics Research Center for Advanced Science and Technology (CEMS) Wako Saitama 351-0198 Japan Materials and Structures Laboratory Research Center for Electronic and Optical Materials Research Center for Materials Nanoarchitectonics Photon Factory Institute of Materials Structure Science Institute for Advanced Synchrotron Light Source Department of Physics Graduate School of Science and Advanced Institute for Materials Research (WPI-AIMR) Precursory Research for Embryonic Science and Technology (PRESTO) Institute of Multidisciplinary Research for Advanced Materials (IMRAM) Institute of Advanced Energy Institute of Industrial Science

We have fabricated a 180 °-twisted bilayer ReSe2 by stacking two centrosymmetric monolayer ReSe2 flakes in opposite directions, which is expected to cause the loss of spatial inversion symmetry. We successfully observed spatial inversion-symmetry breaking, in contrast to the monolayer and natural bilayer ReSe2 by the second harmonic generation. ARPES measurements further revealed emergent band dispersions in the 180 °-twisted bilayer ReSe2, distinct from those of the monolayer ReSe2 used in its fabrication. The band calculation shows the finite lifting of spin degeneracy (∼50 meV) distinct from natural monolayer and bilayer ReSe2, which demonstrates that the spin-momentum locked state leading to Berry curvature related phenomena can be realized even with the stacking of centrosymmetric monolayers.

关键词： Electronic structure First-principles calculations Spin-orbit coupling 2-dimensional systems Nanotechnology Transition metal dichalcogenides High-harmonic generation Photoemission spectroscopy

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Influence of Ru-substitution on the performance of pyrochlore catalysts in oxidative steam reforming of ethanol

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Sustainable Energy and Fuels 2024年第9期8卷 2104-2114页

作者： Huang, Yu-Hsuan Hsieh, Ho-Chen Wang, Yun-Hsin Weng, Sheng-Feng Lee, Chi-Shen Department of Applied Chemistry National Yang Ming Chiao Tung University 1001 University Rd Hsinchu 30010 Taiwan Graduate Degree Program of Science and Technology of Accelerator Light Source National Yang Ming Chiao Tung University Hsinchu 30010 Taiwan Center for Emergent Functional Matter Science National Chiao-Tung University Hsinchu 30010 Taiwan

This study introduces a series of Ru-substituted pyrochlore catalysts, achieved by using La2Zr2−xRuxO7−δ (LZRO-00-04, x = 0.0-0.4) during the oxidative steam reforming of ethanol reaction (OSRE). The samples were cha...

This study introduces a series of Ru-substituted pyrochlore catalysts, achieved by using La₂Zr_2−xRu_xO_7−δ (LZRO-00-04, x = 0.0-0.4) during the oxidative steam reforming of ethanol reaction (OSRE). The samples were characterized using X-ray diffraction (XRD), temperature programmed reduction (TPR), and X-ray photoelectron spectroscopy (XPS). The reduction behavior and catalytic performance correlate directly with the Ru content. The 5 wt% LZRO02 catalytic system outperforms the supported Ru-based catalyst (5 wt% RuO₂/LZO), boasting lower Ru concentrations (2.66 wt%). The enhancement is attributed to the uniform dispersion of Ru ≥ 4+ ions embedded within the pyrochlore structure, as convincingly supported by the XPS result. This underscores notable distinctions between the internal and external structures of the two systems. On the other hand, our extensive long-term testing of LZRO02 across γ-Al₂O₃ and lab-made LZO carriers, coupled with meticulous mapping and Raman analysis, revealed a significant observation: the catalyst exhibits notably reduced aggregation tendencies and enhanced activity when utilized on the LZO carrier. The La₂Zr_1.8Ru_0.2O_7−δ catalyst supported on LZO demonstrated selectivity of hydrogen S_H = 86.4(1)%;Y_H = 2.55(3) (mol/mol EtOH) for long-term stability tests at T = 400 °C, C/O = 0.6, and O₂/C₂H₅OH = 1.5. This discovery underscores the catalyst's remarkable stability and activity, making it a promising candidate for catalytic applications. © 2024 The Royal Society of Chemistry.

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Unravelling the strong interplay for interfacial magnetic switching in metal-organic-based spintronics

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Journal of Materials Chemistry C 2024年第11期12卷 3931-3942页

作者： Chen, Wan-Ting Yu, Li-Chung Lin, Jiu-Hua Cheng, Su Ling Shiu, Hung Wei Lai, Yu-Ling Chu, Ying-Hao Chin, Yi-Ying Wang, Jeng-Han Hsu, Yao-Jane National Synchrotron Radiation Research Center Hsinchu30076 Taiwan Graduate Program for Science and Technology of Accelerator Light Sources National Yang Ming Chiao Tung University Hsinchu30076 Taiwan Department of Materials Science and Engineering National Tsing Hua University Hsinchu30013 Taiwan Department of Chemistry National Taiwan Normal University Taipei11677 Taiwan Department of Photonics National Cheng Kung University Tainan70101 Taiwan Department of Physics National Chung Cheng University Chiayi62102 Taiwan

Organic semiconductors are promising building blocks for multifunctional spintronics. The spinterface plays a key role in affecting the magnetic properties of the performance of spin-based devices. Herein, we reveal the strong interfacial interplay affecting the magnetic switching at the interface of the synthetic paramagnetic tris(8-hydroxyquinoline)iron(iii) (Feq3) layer on the ferromagnetic surface. In combination with synchrotron-based analysis and density functional theory (DFT) calculations, we observed that the robust magnetic interactions of the Co/Feq3 system were strongly influenced by the interfacial reaction between Co and Feq3. As the charge transferred from the contacted Co to Feq3, the central iron was reduced from Fe(iii) to Fe(ii) and hybridized with the 8-hydroxyquinoline, causing spin polarization at the interface. The reduced central Fe(ii) exhibited apparent ferromagnetic ordering after contact with the ferromagnetic Co substrate. With increasing the Feq3 layer thickness, the central Fe reverted to its original Fe(iii) state, resulting in the disappearance of ferromagnetic ordering. The thickness dependence of the Feq3 layer on the magnetic response could be used to tune the spinterface properties and thus the interfacial magnetic interplay. These findings reveal the effect of the strong interfacial redox on the spinterface and open up a promising approach for the use of metal-organic materials in oragnic spintronic devices. © 2024 The Royal Society of Chemistry.

关键词： Organometallics

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Spectral phase interferometry for direct electric-field reconstruction of XUV synchrotron light

Spectral phase interferometry for direct electric-field reco...

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2023 Conference on Lasers and Electro-Optics Europe and European Quantum Electronics Conference, CLEO/Europe-EQEC 2023

作者： Fuji, Takao Kaneyasu, Tatsuo Fujimoto, Masaki Okano, Yasuaki Salehi, Elham Hosaka, Masahito Takashima, Yoshifumi Mano, Atsushi Hikosaka, Yasumasa Wada, Shin-Ichi Katoh, Masahiro Laser Science Laboratory Toyota Technological Institute Nagoya468-8511 Japan SAGA Light Source Tosu841-0005 Japan Institute for Molecular Science Okazaki444-8585 Japan Synchrotron Radiation Research Center Nagoya University Nagoya464-0814 Japan National Synchrotron Radiation Laboratory University of Science and Technology of China Hefei230029 China Institute of Liberal Arts and Sciences University of Toyama Toyama930-0194 Japan Graduate School of Advanced Science and Engineering Hiroshima University Higashi-Hiroshima739-8526 Japan Hiroshima Synchrotron Radiation Center Hiroshima University Higashi-Hiroshima739-0046 Japan

ISBN: (纸本)9798350345995

An undulator is a device which is widely used in the modern synchrotron light sources to produce quasi-monochromatic light. The waveform of the electric-field produced by an relativistic electron in the undulator is basically defined by the number of magnets and the gap between the magnets in the undulator. The square shaped waveform is predicted by a simple electro-magnetic theory, however, it has never been measured because no method has been suggested. It is important to characterize the electric-field produced in the undulator for the development of synchrotron sources. © 2023 IEEE.

关键词： Wigglers

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Waveform characterization of synchrotron light using spectral phase interferometry for direct electric-field reconstruction

Waveform characterization of synchrotron light using spectra...

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2023 Ultrafast Optics, UFO 2023

Ultraviolet and extreme ultraviolet electric-fields generated from a synchrotron light source are characterized by using spectral phase interferometry for direct electric-field reconstruction. The reconstructed 10-cycle square envelope electric-field corresponds to the radiation from an electron accelerated with the undulator which consists of 10 periods of permanent magnets. © 2023 The Author(s).

关键词： synchrotrons

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A robust bendable IrO_x thin film via mild alkaline solution process for neuron stimulating electrodes

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Surfaces and Interfaces 2024年 44卷

作者： Tso, Kuang-Chih Chan, Tzu-Ying Yu, Tsung-Chun Tao, Yu-Jen Chu, Chao-Yi Chen, San-Yuan Lee, Jyh-Fu Ohta, Jun Chen, Po-Chun Wu, Pu-Wei Graduate Program of Accelerator Light Source National Yang Ming Chiao Tung University Hsinchu 300 Taiwan Division of Materials Science Graduate School of Science and Technology Nara Institute of Science Technology Nara Ikoma Takayama 8916-5 Japan Department of Materials Science and Engineering National Yang Ming Chiao Tung University Hsinchu 300 Taiwan Institute of Materials Science and Engineering National Taipei University of Technology Taipei 106 Taiwan National Synchrotron Radiation Research Center Hsinchu 300 Taiwan

We demonstrate a unique chemical formula to deposit hydrous iridium oxide thin film on a platinum-coated polyimide substrate. In a mild alkaline solution, the iridium (III) precursor undergoes the ligand exchange and hydrolysis reaction to become the iridium (III) dimers that are physically adsorbed on the substrate for subsequent heterogeneous condensation and growth of amorphous hydrous iridium oxide thin film. Both UV–Vis and X-ray absorption spectroscopy (XAS) are employed to determine the reaction steps involved. The chemical nature and crystallinity of the hydrous iridium oxide thin film are investigated by XAS, X-ray photon spectroscopy, and X-ray diffraction. The hydrous iridium oxide thin film reveals an impressive normalized charge storage capacity (CSC) of 0.3 mC/cm²-nm and a low impedance (80.5 Ω) at 1k Hz. In addition, in bending test of 3,000 cycles, the hydrous iridium oxide thin film retains 91.2 % of its initial normalized CSC without any physical crack and delamination. The cell viability test suggests negligible bio-toxicity. Our results provide a solid evidence of fabricating a robust flexible electrode for neural interfaces for potential use in implantable electronic devices. © 2023 Elsevier B.V.

关键词： Bio-electrode Flexible substrate Implantable electronic devices Iridium dimers Iridium oxide Polyimide

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A Robust Bendable Irox Thin Film Via Mild Alkaline Solution Process for Neuron Stimulating Electrodes

SSRN

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SSRN 2023年

作者： Tso, Kuang-Chih Chan, Tzu-Ying Yu, Tsung-Chun Pan, Shih-Chin Chu, Chao-Yi Chen, San-Yuan Lee, Jyh-Fu Ohta, Jun Wu, Pu-Wei Chen, Po-Chun Graduate Program of Accelerator Light Source National Yang Ming Chiao Tung University Hsinchu300 Taiwan Division of Materials Science Graduate School of Science and Technology Nara Institute of Science Technology Takayama Ikoma Nara8916-5 Japan Department of Materials Science and Engineering National Yang Ming Chiao Tung University Hsinchu300 Taiwan Institute of Materials Science and Engineering National Taipei University of Technology Taipei106 Taiwan National Synchrotron Radiation Research Center Hsinchu300 Taiwan

We demonstrate a unique chemical formula to deposit hydrous iridium oxide thin film on a platinum-coated polyimide substrate. In a mild alkaline solution, the iridium (III) precursor undergoes the ligand exchange and hydrolysis reaction to become the iridium (III) dimers that are physically adsorbed on the substrate for subsequent heterogeneous condensation and growth of amorphous hydrous iridium oxide thin film. Both UV-Vis and X-ray absorption spectroscopy (XAS) are employed to determine the reaction steps involved. The chemical nature and crystallinity of the hydrous iridium oxide thin film are investigated by XAS, X-ray photon spectroscopy, and X-ray diffraction. The hydrous iridium oxide thin film reveals an impressive normalized charge storage capacity (CSC) of 0.3 mC/cm2-nm and a low impedance (80.5 Ω) at 1k Hz. In addition, in bending test of 3,000 cycles, the hydrous iridium oxide thin film retains 91.2% of its initial normalized CSC without any physical crack and delamination. The cell viability test suggests negligible bio-toxicity. Our results provide a solid evidence of fabricating a robust flexible electrode for neural interfaces for potential use in implantable electronic devices. © 2023, The Authors. All rights reserved.

关键词： Iridium compounds

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Spectral Phase Interferometry for Direct Electric-Field Reconstruction of XUV synchrotron light

Spectral Phase Interferometry for Direct Electric-Field Reco...

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Conference on Lasers and Electro-Optics Europe (CLEO EUROPE)

作者： Takao Fuji Tatsuo Kaneyasu Masaki Fujimoto Yasuaki Okano Elham Salehi Masahito Hosaka Yoshifumi Takashima Atsushi Mano Yasumasa Hikosaka Shin-ichi Wada Masahiro Katoh Laser Science Laboratory Toyota Technological Institute Nagoya Japan SAGA Light Source Tosu Japan Institute for Molecular Science Okazaki Japan Synchrotron Radiation Research Center Nagoya University Nagoya Japan National Synchrotron Radiation Laboratory University of Science and Technology of China Hefei China Institute of Liberal Arts and Sciences University of Toyama Toyama Japan Graduate School of Advanced Science and Engineering Hiroshima University Higashi-Hiroshima Japan Hiroshima Synchrotron Radiation Center Hiroshima University Higashi-Hiroshima Japan

ISBN: (纸本)9798350345995

关键词： Femtosecond pulses Interferometry light sources Phase Phase retrieval Photon counting

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Coherent X-ray Spectroscopy Elucidates Nanoscale Dynamics of Plasma-Enhanced Thin-Film Growth

arXiv

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arXiv 2023年

作者： Myint, Peco Woodward, Jeffrey M. Wang, Chenyu Zhang, Xiaozhi Wiegart, Lutz Fluerasu, Andrei Headrick, Randall L. Eddy, Charles R. Ludwig, Karl F. Department of Physics Division of Materials Science and Engineering Boston University BostonMA United States Electronics Science and Technology Division U.S. Naval Research Laboratory WashingtonDC United States Department of Physics and Materials Science Program University of Vermont Burlington United States National Synchrotron Light Source II Brookhaven National Laboratory Upton United States

Sophisticated thin film growth techniques increasingly rely on the addition of a plasma component to open or widen a processing window, particularly at low temperatures. However, the addition of the plasma into the growth environment also complicates the surface dynamical evolution. Taking advantage of continued increases in accelerator-based X-ray source brilliance, this real-time study uses X-ray Photon Correlation Spectroscopy (XPCS) to elucidate the nanoscale surface dynamics during Plasma-Enhanced Atomic Layer Deposition (PE-ALD) of an epitaxial indium nitride film. XPCS examines the evolution of the coherent X-ray scattering speckle pattern, which is a fingerprint of the unique sample microstructure at each moment in time. In PE-ALD, ultrathin films are synthesized from repeated cycles of alternating self-limited surface reactions induced by temporally-separated pulses of material precursor and plasma reactant, allowing the influence of each on the evolving morphology to be examined. During the heteroepitaxial 3D growth examined here, sudden changes in surface structure during initial film growth, consistent with numerous overlapping stress-relief events, are observed. When the film becomes continuous, the nanoscale surface morphology abruptly becomes long-lived with correlation time spanning the period of the experiment. Throughout the growth experiment, there is a consistent repeating pattern of correlations associated with the cyclic growth process, which is modeled as transitions between different surface states. The plasma exposure does not simply freeze in a structure that is then built upon in subsequent cycles, but rather there is considerable surface evolution during all phases of the growth cycle. © 2023, CC BY.

关键词： Ultrathin films

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