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Aqueous tape casting of LZSA glass ceramics

6th Pacific Rim Conference on Ceramic and Glass Technology, PacRim6

作者： Gomes, C.M. Biscaia, F.N. Quinaud, J.T. Montedo, O.R.K. Oliveira, A.P.N. Hotza, D. Graduate Program in Materials Science and Engineering - PGMAT Chemical Engineering Department - EQA Federal University of Santa Catarina Florianópolis SC 88040-900 Brazil

ISBN: (纸本)0470080507

The effect of sodium alginate, as binder, and polyethyleneglicol, as plasticizer, on rheological and mechanical properties of suspensions used in water-based tape casting of LZSA glass ceramics was studied. The investigation was carried out using a statistical design approach. An aqueous suspension of a parent glass from the LZSA (Li2O-ZrO2SiO 2-Al2O3) system was used. Viscosity, thixotropy and yield stress behavior were measured for the aqueous suspensions as a function of additive composition. Tensile strength of cast tapes was also measured. The experiments were shown to be statistically significant.

关键词： Glass ceramics

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Solid waste management in the paper industry 5

Solid waste management in the paper industry

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5th International Conference on Energy, Environmental and Information System, ICENIS 2020

作者： Devichi Wibowo, Isabella Purwanto, P. Suherman, S. Master Program of Environmental Science Post-Graduate Studies Universitas Diponegoro Semarang Indonesia Department of Chemical Engineering Faculty of Engineering Universitas Diponegoro Semarang Indonesia

The industry developed rapidly since the Industrial Revolution in the 18th century. The side effect of industrial development was a large amount of non-hazardous waste and hazardous waste. All of this waste must be managed properly so that environmental sustainability is maintained and does not cause harm or problems to the community. A review will be conducted from various research journals in various countries and the types of waste also vary, namely plastic, pulp and paper industry waste, and other solid waste. A comparison of solid waste management will be carried on to reduce the generation of waste in the environment. © The Authors, published by EDP Sciences, 2020.

关键词： Solid wastes

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Solid State Fermentation of Rice Straw Pulp with a Local Trichoderma reesei for Single Cell Protein Production: Effects of Temperature, Initial Medium pH and Fermentation Time

Solid State Fermentation of Rice Straw Pulp with a Local Tri...

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International Conference on Science and Innovated engineering 2018, i-COSINE 2018

作者： Novita, E. Zaki, M. Said, S.D. Post-Graduate Study Program Chemical Engineering Department Faculty of Engineering Syiah Kuala University Darussalam-Banda Aceh23111 Indonesia Chemical Engineering Department Faculty of Engineering Syiah Kuala University Darussalam-Banda Aceh23111 Indonesia

Indonesia is one among countries that produce abundant of rice straw every year generated as post-harvesting residue from paddy field all over country. This abundant amount residue is highly potential to be utilized as carbon source in producing single cell protein (SCP) in solid state fermentation system. SCP is a microbial protein that can be used as alternative protein for substitution of available conventional protein sources such as;fish meal, soy bean, and corn Stover for animal feed production. This research was conducted to evaluating the effects of initial medium pH of substrate (mixed rice straw pulp-urea), fermentation time and fermentation temperature on SCP production by Trichoderma reesei in solid state fermentation (SSF). The results showed that the highest SCP yield (19.71%) was produced at the initial medium pH of 5 and temperature of 30 °C at SSF conditions of C/N ratio 20:1 for 12 days of fermentation time. © Published under licence by IOP Publishing Ltd.

关键词： Urea

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Development of Pd-Loaded Hf-Based Metal-Organic Framework as a Dual-Modal Contrast Agent for Photoacoustic Imaging and Computed Tomography

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ACS Biomaterials Science and engineering 2025年 2025 May 6页

作者： Chen, Yen-Chang Yu, Yu-Sheng Wang, Yu-Kang Rakesh Kumar, R.K. Lee, Cho-Yin Chuang, Cheng-Hsin Liao, Lun-De Wu, Kevin C.-W. Department of Chemical Engineering National Taiwan University Taipei10617 Taiwan Institute of Biomedical Engineering and Nanomedicine National Health Research Institutes Miaoli350401 Taiwan International Graduate Program of Molecular Science and Technology Taiwan International Graduate Program Academia Sinica Taipei115201 Taiwan National Taiwan University Taipei10617 Taiwan Department of Biomedical Engineering National Yang Ming Chiao Tung University Taipei30010 Taiwan Department of Radiation Oncology Taoyuan General Hospital Ministry of Health and Welfare Taoyuan330215 Taiwan Institute of Medical Science and Technology National Sun Yat-sen University Kaohsiung804201 Taiwan Department of Chemical Engineering and Materials Science Yuan Ze University Taoyuan32003 Taiwan

Noninvasive cancer imaging significantly improves diagnostics by providing comprehensive structural and functional information about tumors. Herein, we explored palladium nanoparticles loaded hafnium-based metal-organic framework (MOF) (Hf-EDB), i.e., Pd@Hf-EDB as an efficient dual modal contrast agent for computed tomography (CT) and photoacoustic imaging (PAI). The synergistic collaborations between (i) high-Z element Hf-based MOF with superior X-rays absorbing capabilities, (ii) H2EDB linkers with special π-donation and π-acceptor characteristics capable of strongly anchoring noble metals, and (iii) Pd nanoparticles with broad absorption in the UV to near-infrared (NIR) regions due to strong interband transition are ideal for implementation in CT and PAI. The successful synthesis of Pd@Hf-EDB nanoparticles was confirmed through morphology, crystallinity, and compositional characterizations using X-ray diffraction, SEM, TEM, DLS, and EDS. Soft X-ray tomography verified cellular uptake via phagocytosis of Pd@Hf-EDB by BxPC-3 tumor cells. In-vitro experiments revealed superior CT imaging performance of Pd@Hf-EDB over traditional molecular contrast agents like Iohexol. Broad absorption range in the UV-vis/NIR regions and superior PAI capabilities of Pd@Hf-EDB relative to gold nanorods are reported. Furthermore, the in vivo xenograft model demonstrated significant contrast enhancements near the tumor, highlighting the excellent PAI and CT capabilities of the synthesized Pd@Hf-EDB. © 2025 The Authors. Published by American chemical Society.

关键词： Nanorods

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Effects of Ultraviolet-Enhanced Ozonation on Degradation of Ammonia and Urea in Fertilizer Plant Wastewater

Effects of Ultraviolet-Enhanced Ozonation on Degradation of ...

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International Conference on Science and Innovated engineering 2018, i-COSINE 2018

作者： Muhammad Yusuf, A.R. Mulana, Farid Said, Syahiddin Dahlan Post-Graduate Study Program Chemical Engineering Department Syiah Kuala University Darussalam-Banda Aceh23111 Indonesia Chemical Engineering Department Syiah Kuala University Darussalam-Banda Aceh23111 Indonesia

Ammonia and urea contained in fertilizer plant wastewater are pollutants to the environment. High concentration of ammonium and urea in wastewater can affects algae blooms in ecosystem which will generate various diseases in aquatic biota. It is known that there are many methods for degradation of ammonium and urea contained in fertilizer plant wastewater. One of potential method is ultraviolet-enhanced ozonation. Ozonation is oxidation with O3 that generates hydroxyl radicals which subsequently react with organic contaminants, while UV irradiation can break down O3 molecules and produce radical ions OH. The objectives of this study were to examine the effects of the utilization of the ultraviolet-enhanced ozonation method in degradation of various initial ammonium (100-300 ppm) and urea concentration (100-300 ppm) in inlet feed of ozonation-UV irradiation combination system. Some important variables such as contact time (0-120 minutes) and ozone feed rate of 0.2, 0.6, and 1.21 g/h were evaluated. Degradation process was carried out in two steps;ozonation and UV irradiation. Ozonation process was carried out in a contacting tank at constant feed flow rate of 1.5 l/min and at room temperature, while UV irradiation process was conducted in pipeline equipped with UV lamp at various contact time. The ultraviolet-enhanced ozonation could degraded ammonium and urea nitrogen up to 83.6% and 63.8%, respectively, at ozone feed rate 1,21 g/h, contacting time 60 and 120 min, initial feed concentration of ammonia (100 ppm) and urea (40 ppm). © Published under licence by IOP Publishing Ltd.

关键词： Ozonization

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Effects of ultraviolet-enhanced ozonation on the degradation of ammonia and urea in fertilizer plant wastewater

Effects of ultraviolet-enhanced ozonation on the degradation...

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International Conference on Science and Innovated engineering 2018, i-COSINE 2018

Ammonia and urea contained in fertilizer plant wastewater are pollutants to the environment. High concentration of ammonium and urea in wastewater can affects algae blooms in the ecosystem which will generate various diseases in aquatic biota. It is known that there are many methods for degradation of ammonium and urea contained in fertilizer plant wastewater. One of the potential method is ultraviolet-enhanced ozonation. Ozonation is oxidation with O3 that generates hydroxyl radicals which subsequently react with organic contaminants, while UV irradiation can break down O3 molecules and produce radical ions OH. The objectives of this study were to examine the effects of the utilization of the ultraviolet-enhanced ozonation method in degradation of various initial ammonium (100-300 ppm) and urea concentration (100-300 ppm) in inlet feed of ozonation-UV irradiation combination system. Some important variables such as contact time (0-120 minutes) and ozone feed rate of 0.2, 0.6, and 1.21 g/h were evaluated. Degradation process was carried out in two steps;ozonation and UV irradiation. Ozonation process was carried out in a contacting tank at a constant feed flow rate of 1.5 l/min and at room temperature, while UV irradiation process was conducted in pipeline equipped with a UV lamp at various contact time. The ultraviolet-enhanced ozonation could degrade ammonium and urea nitrogen up to 83.6% and 63.8%, respectively, at ozone feed rate 1,21 g/h, contacting time 60 and 120 min, initial feed concentration of ammonia (100 ppm) and urea (40 ppm). © Published under licence by IOP Publishing Ltd.

关键词： Urea

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One dimensional pea-shaped NiSe_(2) nanoparticles encapsulated in N-doped graphitic carbon fibers to boost redox reversibility in sodium-ion batteries

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Journal of Materials Science & Technology 2024年第1期168卷 215-226页

作者： Hyunjeong Gim Achmad Yanuar Maulana Jiwon Choi Jungwook Song Boram Yun Yuri Jeong Nahyun An Myeongkee Park Cybelle M.Futalan Jongsik Kim Department of Chemical Engineering(BK21 FOUR Graduate Program) Dong-A UniversityBusan 49315Korea(the Republic of) Department of Chemistry Dong-A UniversityBusan 49315Korea(the Republic of) Department of Chemistry Pukyong National UniversityBusan 48513Korea(the Republic of) Institute of Civil Engineering University of the PhilippinesDiliman 1127Philippines

In recent years,sodium-ion batteries(SIBs)have emerged as a promising technology for energy storage systems(ESSs)because of the abundance and affordability of ***,metal selenides have been studied as promising high-performance conversion-type anode materials in *** them,nickel se-lenide(NiSe_(2))has received considerable attention due to its high theoretical capacity of 495 mAh g^(-1)and ***,it still suffers from poor cycling stability because of the low electrochemical reactivity,large volume expansion,and structural instability during *** address these challenges,NiSe_(2)nanoparticles encapsulated in N-doped graphitic carbon fibers(NiSe_(2)@NGCF)were synthesized by using ZIF-8 as a ***_(2)@NGCF showed a high discharge capacity of 558.3 mAh g^(-1)with a fading rate of 0.14%per cycle after 200 cycles at 0.5 A g^(-1)in 0.01-3.0 *** a very high current density of 5 A g^(-1),the capacity still displayed excellent long-term cycle life with a discharge capacity of 406.1 mAh g^(-1)with a fading rate of 0.016%per cycle after 3000 *** mechanism of the excellent electrochem-ical performance of NiSe_(2)@NGCF was thoroughly investigated by ex-situ XRD,TEM,and SEM ***,NiSe_(2)@NGCF//Na_(3)V_(2)(PO_(4))_(3)full-cell also delivered an excellent reversible capacity of 378.7 mAh g^(−1)at 0.1 A g^(−1)after 50 cycles,demonstrating its potential for practical application in SIBs.

关键词： Sodium-ion batteries Anode materials Nickel selenide N-doped graphitic carbon fibers One-dimensional electrode

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Physically crosslinked polyurethane hydrogels for tissue engineering applications

Physically crosslinked polyurethane hydrogels for tissue eng...

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8th World Biomaterials Congress 2008, WBC 2008

作者： Patel, Alpesh Mequanint, Kibret Department of Chemical and Biochemical Engineering Canada Graduate Program in Biomedical Engineering University of Western Ontario London ON N6A 5B9 Canada

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Lignin-based polyurethane composites enhanced with hydroxyapatite for controlled drug delivery and potential cellular scaffold applications

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Polymer Composites 2024年第16期45卷 15159-15172页

作者： Nugroho, Roshid Adi Saputra, Ozi Adi Pradita, Agung Lucky Fajar, Al Bukhori Nur Wibowo, Fajar Rakhman Department of Chemistry Faculty of Mathematics and Natural Sciences Universitas Sebelas Maret Central Java Surakarta Indonesia Sustainable Chemical Science and Technology Taiwan International Graduate Program Academia Sinica Taipei Taiwan Institute of Chemistry Academia Sinica Taipei Taiwan Department of Chemical Engineering Collage of Engineering National Taiwan University Taipei Taiwan

Polymer technology has rapidly advanced across diverse domains, particularly in biomedical applications. Among various polymers, polyurethane (PU) hold great potential in developing biomaterials such as biomedical scaffold and drug delivery. In this study, we have innovatively engineered eco-friendly polyurethane using lignin, a sustainable bio-polyol derived from oil palm empty fruit bunches. To enhance the physicochemical properties of the PU, we have incorporated hydroxyapatite (HA) into the composites. The inclusion of HA has led to notable improvements in crucial properties such as density, porosity, and water absorption, making these composites ideal candidates for tissue regeneration scaffolds. Furthermore, to assess their biomedical applicability in drug delivery and cell scaffolding, we have employed the quercetin drug model. The results revealed a sustained kinetic release behavior within the polyurethane/hydroxyapatite (PU/HA) composites, showcasing their potential for controlled drug delivery applications. Moreover, cytotoxicity assays conducted using neuro-2a cell models demonstrated the non-cytotoxic nature of both PU and PU/HA composites. This finding holds significant implications for biomedical applications, indicating that these composites offer biocompatible platforms for tissue engineering and regenerative medicine endeavors. The ability of these composites to support cell viability underscores their potential for a wide range of biomedical applications, including neural tissue engineering and drug delivery systems targeting brain diseases. These findings pave the way for the development of innovative and sustainable biomaterials with diverse biomedical applications. Highlights: An eco-friendly polyurethane has been engineered by harnessing liginin-derived oil palm empty fruit bunches. Incorporation of hydroxyapaptite enhance the physical properties of polyurethane. Controlled kinetic drug release is one of polyurethane/hydroxyapatite (PU/HA) com

关键词： Fruits

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Low-Temperature Methanolysis of Polycarbonate over Solid Base Sodium Aluminate

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Langmuir 2024年第10期40卷 5338-5347页

作者： Krisbiantoro, Philip Anggo Sato, Miyu Lin, Tzu-Ming Chang, Yu-Chia Peng, Tzu-Yun Wu, Yun-Chih Liao, Weisheng Kamiya, Yuichi Otomo, Ryoichi Wu, Kevin C.-W. Molecular Science and Technology Program Taiwan International Graduate Program Academia Sinica Taipei11529 Taiwan International Graduate Program of Molecular Science and Technology National Taiwan University Taipei10617 Taiwan Department of Chemical Engineering College of Engineering National Taiwan University Taipei10617 Taiwan Graduate School of Environmental Science Hokkaido University Nishi 5 Kita 10 Sapporo060-0810 Japan Faculty of Environmental Earth Science Hokkaido University Nishi 5 Kita 10 Sapporo060-0810 Japan Center of Atomic Initiative for New Materials National Taiwan University Taipei10617 Taiwan Department of Chemical Engineering and Materials Science Yuan Ze University Taoyuan320 Taiwan

Herein, a low-cost and readily available sodium aluminate (NaAlO2) was used as a solid base catalyst for the depolymerization of polycarbonate (PC) via methanolysis in the presence of tetrahydrofuran (THF) as a solvent. NaAlO2 was highly active for the reaction, and the performance was comparable to that of soluble strong base SrO and much higher than those of MgO and CaO. By the reaction over the catalyst, a highly pure and crystalline bisphenol A (BPA) was obtained. Among tested organic solvents, THF was the best in aiding PC methanolysis over NaAlO2 due to the polarity similar to PC according to Hansen solubility parameters (HSPs). At 60 °C, 98.1% PC conversion and 96.8% BPA yield were achieved within just 2 h. NaAlO2 was reusable without any severe catalyst deactivation in at least four runs. The mechanistic study revealed that the reaction proceeded via the methoxide pathway, with THF aiding the dissolution of PC. The reaction over NaAlO2 possessed a low apparent activation energy (Ea) of 75.1 kJ mol-1, which is the lowest ever reported so far for the reaction over solid catalysts. © 2024 The Authors. Published by American chemical Society.

关键词： Sodium Aluminate

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