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Isolation of 24-homoscalarane sesterterpenoids from a sponge of the genus Lendenfeldia

Phytochemistry Letters 2024年 61卷 177-181页

作者： Zheng, Li-Guo Chen, You-Yan Liaw, Chia-Ching Lin, Yu-Chi Chien, Su-Ying Lo, Yi-Hao Tsai, Yu-Chi Hu, Hao-Chun Chen, You-Ying Hwang, Tsong-Long Ou, Tzu-Ming Sung, Ping-Jyun Doctoral Degree Program in Marine Biotechnology National Sun Yat-sen University Kaohsiung 804201 Taiwan National Museum of Marine Biology and Aquarium Pingtung 944401 Taiwan School of Traditional Chinese Medicine College of Medicine Chang Gung University Taoyuan 333323 Taiwan Division of Chinese Materia Medica Development National Research Institute of Chinese Medicine Ministry of Health and Welfare Taipei 112304 Taiwan Department of Biochemical Science and Technology National Chiayi University Chiayi 600355 Taiwan Instrumentation Center National Taiwan University Taipei 106319 Taiwan Department of Family Medicine Zuoying Armed Forces General Hospital Kaohsiung 813204 Taiwan Shu-Zen Junior College of Medicine and Management Kaohsiung 821004 Taiwan Institute of Medical Science and Technology National Sun Yat-sen University Kaohsiung 804201 Taiwan School of Chinese Medicine College of Chinese Medicine China Medical University Taichung 404333 Taiwan Graduate Institute of Natural Products College of Medicine Chang Gung University Taoyuan 333323 Taiwan Research Center for Chinese Herbal Medicine College of Human Ecology Chang Gung University of Science and Technology Taoyuan 333324 Taiwan Graduate Institute of Health Industry Technology College of Human Ecology Chang Gung University of Science and Technology Taoyuan 333324 Taiwan Department of Anesthesiology Chang Gung Memorial Hospital Taoyuan 333423 Taiwan Department of Chemical Engineering Ming Chi University of Technology New Taipei City 243303 Taiwan Division of Gastroenterology Department of Internal Medicine Kaohsiung Armed Forces General Hospital Kaohsiung 802301 Taiwan Department of Marine Biotechnology and Resources National Sun Yat-sen University Kaohsiung 804201 Taiwan Chinese Medicine Research and Development Center China Medical University Hospital Taichung 404394 Taiwan Graduate Institute of Natural Products Kaohsiung Medical University Kaohsiung 807378 Taiwan Program in Ph

The chemical screening of an algae-containing marine sponge identified as Lendenfeldia species has isolated two 24-homoscalarane sesterterpenoids, including a known compound, felixin A (1) and a new analogue, lendenfeldarane V (2). The structure of 1, obtained in a previous study, was cited for the first time in this study via single-crystal X-ray diffraction analysis. The structure of 2 was ascertained via 2D NMR experiments and a literature review. The absolute configurations of 1 and 2 were delineated with DP4+ computation and specific optical rotation. Homoscalarane 1 exhibited cytotoxicity towards MG63 human osteosarcoma cells. © 2024 Phytochemical Society of Europe

关键词： Felixin Homoscalarane Lendenfeldarane Lendenfeldia MG63

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Altitudinal Migration of Species of Fir (Abies spp.) in Adaptation to Climate Change

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Water, Air, and Soil Pollution 2022年第9期233卷 385-385页

作者： Tekin, Oktay Cetin, Mehmet Varol, Tugrul Ozel, Halil Baris Sevik, Hakan Zeren Cetin, Ilknur Institute of Science and Engineering Department of Sustainable Agriculture and Natural Plant Resources Kastamonu University Kastamonu Turkey Faculty of Architecture Department of City and Regional Planning Ondokuz Mayis University Samsun Turkey Faculty of Forestry Department of Forest Engineering Bartin Turkey Faculty of Forestry Department of Forest Engineering Bartin University Bartin Turkey Faculty of Engineering and Architecture Department of Environmental Engineering Kastamonu University Kuzeykent Campus Kastamonu37150 Turkey YOK 100/2000 Scholarship Program of Sustainable Forestry Institute of Graduate School Department of Forest Engineering Bartin University Bartin Turkey Department of Park and Garden Plants Program of Landscape and Ornamental Plants Cultivation Samsun Vocational School Ondokuz Mayis University Samsun Turkey

Global climate change is considered an irreversible problem, which might directly or indirectly affect all the organisms and ecosystems on the earth and the world has to struggle with. Plants having no effective movement mechanism are the group that global climate change will affect the most. In order to minimize the species and population losses, it is important to estimate the changes in the available distribution areas of species and to ensure the migration mechanism, which the species will need, by the hand of humans. The present study aims to reveal how potential distribution areas of fir, which is among the significant tree species of Turkey and significant portion of global distribution of which is in Turkey, will change from an altitudinal aspect because of the climate change. The results achieved showed that, because of the effects of global climate change, the suitable distribution areas of Abies nordmanniana subsp. nordmanniana will significantly decrease especially at high altitudes and that suitable distribution areas of Abies nordmanniana subsp. equi-trojani will reduce at altitudes higher than 1400 m but increase generally at the altitudes between 200 and 600 m. Moreover, suitable distribution areas of Abies cilicica will shift towards higher altitudes. © 2022, The Author(s), under exclusive licence to Springer Nature Switzerland AG.

关键词： Climate change

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Occurrence and fate of pharmaceutical pollutants in wastewater: Insights on ecotoxicity, health risk, and state–of–the-art removal

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Chemosphere 2024年 354卷 141678页

作者： Nguyen, Minh-Ky Lin, Chitsan Bui, Xuan-Thanh Rakib, Md. Refat Jahan Nguyen, Hoang-Lam Truong, Quoc-Minh Hoang, Hong-Giang Tran, Huu-Tuan Malafaia, Guilherme Idris, Abubakr M. Faculty of Environment and Natural Resources Nong Lam University Hamlet 6 Linh Trung Ward Thu Duc City Ho Chi Minh City700000 Viet Nam Ph.D. Program in Maritime Science and Technology National Kaohsiung University of Science and Technology Kaohsiung81157 Taiwan Department of Marine Environmental Engineering National Kaohsiung University of Science and Technology Kaohsiung81157 Taiwan Linh Trung Ward Thu Duc City Ho Chi Minh City700000 Viet Nam Ho Chi Minh City700000 Viet Nam Department of Environmental Science and Management North South University Dhaka Bashundhara1229 Bangladesh Department of Civil Engineering McGill University Montreal Canada Faculty of Management Science Thu Dau Mot University Binh Duong 75000 Viet Nam Faculty of Medicine Dong Nai Technology University Dong Nai Bien Hoa76100 Viet Nam Laboratory of Ecology and Environmental Management Science and Technology Advanced Institute Van Lang University Ho Chi Minh City700000 Viet Nam Faculty of Applied Technology School of Engineering and Technology Van Lang University Ho Chi Minh City700000 Viet Nam Post-Graduation Program in Ecology Conservation and Biodiversity Federal University of Uberlândia MG Uberlândia Brazil Post-Graduation Program in Biotechnology and Biodiversity Federal University of Goiás GO Goiânia Brazil Post-Graduation Program in Conservation of Cerrado Natural Resources Goiano Federal Institute GO Urutaí Brazil Department of Chemistry College of Science King Khalid University Abha62529 Saudi Arabia King Khalid University Abha62529 Saudi Arabia

Pharmaceutical active compound (PhAC) residues are considered an emerging micropollutant that enters the aquatic environment and causes harmful ecotoxicity. The significant sources of PhACs in the environment include the pharmaceutical industry, hospital streams, and agricultural wastes (animal husbandry). Recent investigations demonstrated that wastewater treatment plants (WWTPs) are an important source of PhACs discharging ecosystems. Several commonly reported that PhACs are detected in a range level from ng L−1 to μg L−1 concentration in WWTP effluents. These compounds can have acute and chronic adverse impacts on natural wildlife, including flora and fauna. The approaches for PhAC removals in WWTPs include bioremediation, adsorption (e.g., biochar, chitosan, and graphene), and advanced oxidation processes (AOPs). Overall, adsorption and AOPs can effectively remove PhACs from wastewater aided by oxidizing radicals. Heterogeneous photocatalysis has also proved to be a sustainable solution. Bioremediation approaches such as membrane bioreactors (MBRs), constructed wetlands (CWs), and microalgal-based systems were applied to minimize pharmaceutical pollution. Noteworthy, applying MBRs has illustrated high removal efficiencies of up to 99%, promising prospective future. However, WWTPs should be combined with advanced solutions, e.g., AOPs/photodegradation, microalgae–bacteria consortia, etc., to treat and minimize their accumulation. More effective and novel technologies (e.g., new generation bioremediation) for PhAC degradation must be investigated and specially designed for a low-cost and full-scale. Investigating green and eco-friendly PhACs with advantages, e.g., low persistence, no bioaccumulation, less or non-toxicity, and environmentally friendly, is also necessary. © 2024 Elsevier Ltd

关键词： Microalgae

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DPSIR analysis of water resource quality concerning land use in Bantul Regency, Province of Yogyakarta, Indonesia

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AIP Conference Proceedings 2024年第1期3019卷

作者： Aditya Pandu Wicaksono Mohammad Abdul Khafid Department of Environmental Engineering Faculty of Mineral Technology UPN Veteran Yogyakarta Special Region of Yogyakarta Indonesia Study Progam of Natural Resources and Environmental Management Science Graduate School IPB University Bogor West Java Indonesia

The increase in population will impact the need for land, and the use of aquatic resources will increase along with the increase in anthropogenic activities. The DPSIR approach model is used to identify that population dynamics, land use, and hydrogeological characteristics are important driving factors for quality and water. Conditions of pressure on waters with domestic waste inputs, excess water utilization, and leachate water pollution entering the water system. Groundwater and river water quality has decreased, especially in industrial areas and the Piyungan landfill area. Impact on disrupted public health and weak water resource resilience. The response from the local government issued Bantul Regency Regional Regulation Number 05 of 2011 concerning Building Buildings which was then strengthened again by the existence of Bantul Regency Regional Regulation Number 6 of 2019 concerning Housing Implementation. Surveillance and enforcement measures against violators of environmental policies formed a special team. Guidance and mentoring activities for local communities in preserving environmental functions and forest rehabilitation are also carried out, considering the community as the leading actor and is more aware of environmental problems.

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Preparation of tungsten trioxide/graphene oxide/ hydroxyapatite (WO₃/GO/HAp) for photocatalytic removal of methylene blue under visible light

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Case Studies in Chemical and Environmental engineering 2024年 10卷

作者： Mizar, Khalid Mulyati, Sri Aprilia, Sri Aulia, Muhammad Prayogie Arahman, Nasrul Postgraduate School of Engineering Studies Universitas Syiah Kuala Banda Aceh 23111 Indonesia Graduate School of Environmental Management Universitas Syiah Kuala Jl. Tgk. Chik Pante Kulu No. 5 Darussalam Banda Aceh 23111 Indonesia Graduate School of Science and Engineering Kobe University Rokkodai Cho Nada Ku Hyogo Kobe Japan Atsiri Research Center PUI Universitas Syiah Kuala Jl. Syeh A Rauf No. 5 Darussalam Banda Aceh 23111 Indonesia Research Center for Environmental and Natural Resources Universitas Syiah Kuala Jl. Hamzah Fansuri No. 4 Darussalam Banda Aceh 23111 Indonesia

The textile industry is one of the leading contributors of liquid waste in the form of synthetic dyes, which significantly contaminate water sources. Heterogeneous photocatalysts employ semiconductors that trigger photocatalytic processes with the assistance of UV or visible light to degrade waste. Tungsten trioxide (WO₃) is a potential semiconductor with a small band gap (2.8 eV) that absorbs visible light. WO₃ was combined with graphene oxide (GO) and hydroxyapatite (HAp) to exploit the ultrasonication method to degrade methylene blue (MB) dye. The results of the SEM-EDX characterization confirm the constituent elements of the WO₃/GO/HAp material. The chemical elements were confirmed by energy-dispersive X-ray spectroscopy. The ability of the original and modified WO₃ photocatalysts (WO₃/HAp, WO₃/GO and WO₃/GO/HAp) to degrade 15 ppm of 50 ml of MB solution at concentrations of 10, 15, and 20 mg for 4 h under visible light was investigated. The breakdown of the methylene blue dye demonstrated that the reaction speed followed a first-order pattern. Meanwhile the adsorption isotherm better fit Langmuir for WO₃/GO and WO₃/GO/HAp. The highest pollutant degradation was achieved using 20 mg WO₃/GO and WO₃/GO/HAp photocatalysts, which achieved efficiencies of 99.1 % and 98.3 %. These results confirm that the WO₃/HAp;WO₃/GO, and WO₃/GO/HAp hybrid photocatalysts exhibit better degradation performance than unmodified WO₃ photocatalysts. Additionally, these photocatalysts can be reused up to three times without experiencing substantial loss in effectiveness. © 2024 The Authors

关键词： Antifouling Photocatalytic degradation Wastewater treatment

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Determinant of importance-performance and willingness to participate in Komodo adaptive conservation programs

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Journal for Nature Conservation 2024年 81卷

作者： Sianipar, Imelda Masni Juniaty Lee, Chun-Hung Wang, Hurng-Jyuhn Kim, Doo-Chul Suryawan, I Wayan Koko PhD Student in Asia-Pacific Regional Studies College of Humanities and Social Sciences National Dong Hwa University Department of International Relations Faculty of Social Science and Political Science Universitas Kristen Indonesia Department of Natural Resources and Environmental Studies College of Environmental Studies and Oceanography National Dong Hwa University Program in Asia-Pacific Regional Studies College of Humanities and Social Sciences National Dong Hwa University Department of Rural Environment Management Graduate School of Environmental and Life Science Okayama University Ph.D Program in Asia-Pacific Regional Studies College of Humanities and Social Sciences National Dong Hwa University Department of Environmental Engineering Faculty of Infrastructure Planning Universitas Pertamina Jalan Sinabung II Terusan Simprug

This study delves into the evaluation of the Komodo dragons Adaptive Conservation program (KACP) at Komodo National Park in Indonesia through Importance-Performance Analysis (IPA). It aims to understand how the programs components align with community priorities and assess its effectiveness. Utilizing a mixed-methods approach, this research analyzes community perceptions of KACP's critical elements, spanning eco-tourism initiatives to environmental protection strategies. The community is categorized into local advocates, eco-tourism enthusiasts, and eco-community harmonizers, identifying how each group perceives and interacts with various facets of KACP. The findings reveal significant differences in perceptions of importance and performance among these groups, providing insights into areas of strength and those needing improvement. Additionally, the study includes an analysis of demographic influences on these perceptions through Logit and Probit models, aiming to understand the impacts across different community segments. The results highlight the necessity for an adaptive and responsive design in conservation efforts, considering community expectations and ecological impacts. Despite offering comprehensive insights, the study acknowledges limitations in the demographic scope and suggests future research directions, such as longitudinal studies and an expanded analysis of variables. These findings offer critical guidance for policymakers and conservation practitioners to enhance conservation programs’ effectiveness and community alignment, emphasizing the need to adapt to the challenges and changes introduced by KACP. © 2024 Elsevier GmbH

关键词： Adaptive capacity Community perception Conservation strategy evaluation Importance-performance analysis Protected areas

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Sea Surface Wind Structure in the Outer Region of Tropical Cyclones Observed by Wave Gliders

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Journal of Geophysical Research: Atmospheres 2023年第3期128卷 e2022JD037235-e2022JD037235页

作者： Tian, Di Zhang, Han Wang, Shuai Zhang, Wenyan Sun, Xiujun Zhou, Ying Zheng, Gang Jiang, Han Yang, Shili Zhou, Feng State Key Laboratory of Satellite Ocean Environment Dynamics Second Institute of Oceanography Ministry of Natural Resources Hangzhou China Observation and Research Station of Yangtze River Delta Marine Ecosystems Ministry of Natural Resources Zhoushan China Key Laboratory of Ocean Space Resource Management Technology Ministry of Damage the Coastal Ecosystem Natural Resources Marine Academy of Zhejiang Province Hangzhou China Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai) Zhuhai China Program in Atmospheric and Oceanic Sciences Princeton University Princeton NJ United States Institute of Coastal Systems - Analysis and Modeling Helmholtz-Zentrum Hereon Geesthacht Germany Physical Oceanography Laboratory Ocean University of China Qingdao China Institute for Advanced Ocean Study Ocean University of China Qingdao China Beijing Meteorological Observation Centre Beijing Meteorological Bureau Beijing China Ocean College Zhejiang University Zhoushan China

Understanding the sea surface wind structure during tropical cyclones (TCs) is the key for study of ocean response and parameterization of air-sea surface in numerical simulation. However, field observations are scarce. In 2019, three wave gliders were deployed in the South China Sea and the adjacent Western Pacific region, which acquired sea surface wind structure of eight TCs. Analysis of the field data suggests that the wave glider-observed surface winds are consistent with most analysis/reanalysis data (i.e., ERA5, Cross-Calibrated Multi-Platform, and National Centers for Environmental Prediction-Global Data Assimilation System) and Soil Moisture Active Passive. Both wave glider observations and analysis/reanalysis data indicate that TC wind fields induce an obvious increase in speed toward the sea surface together with a sharp change in direction, showing an asymmetric wind structure which is sensitive to TC translation speed and intensity. Larger mean values of wind speed and inflow angle are located on the right side along TC tracks. The inflow angle shows a highly dynamic dependence on the radial distance from the TC center, the TC intensity, as well as the TC-relative azimuth. Comparisons between field observations and theoretical models indicate that the most widely used, ideal TC wind profile models can largely represent the observed sea surface wind structure, but generally underestimate the wind speed due to lack of consideration of background wind. Moreover, simple ideal models (e.g., the modified Rankine vortex model) may outperform complex models when accurate information of TCs is limited. Wave glider observations have potential for better understanding of air-sea exchanges and for improvements of the corresponding parameterization schemes. © 2023. American Geophysical Union. All Rights Reserved.

关键词： ideal wind model inflow angle sea surface wind tropical cyclone wave glider

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Riparian Areas and Fine-Scale Forest Cover and Structure Drive Occupancy Patterns of Sympatric Mustelids

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Ecology and Evolution 2025年第5期15卷 e71370页

作者： Wheelhouse, Lauren Bryan, Heather Crowley, Shannon Johnson, Chris Hodder, Dexter John Prince Research Forest University of Northern British Columbia Prince George BC Canada Natural Resources and Environmental Studies Graduate Program University of Northern British Columbia Prince George BC Canada Department of Ecosystem Science and Management University of Northern British Columbia Prince George BC Canada

Boreal and subboreal forests of western North America support diverse mesocarnivore populations with overlapping spatial, temporal, and dietary niches. However, interactions among these species and the factors influencing their co-occurrence—such as population cycles, landscape changes, harvest mortality, and resource availability—are not well documented. We used 5 years (2015, 2016, 2020, 2021, and 2022) of data from remote cameras and fine-scale habitat data from Light Detection and Ranging to assess patterns in the spatial co-occurrence of short-tailed weasel (Mustela erminea), American mink (Neogale vison), American marten (Martes americana), and fisher (Pekannia pennanti) in central British Columbia, Canada. We used multispecies occupancy models to test hypotheses about the relationships between mesocarnivore co-occurrence and habitat. Mesocarnivores were more likely to co-occur at sites closer to riparian zones and at sites with greater complexity of vertical forest structure. Short-tailed weasel, however, did not co-occur with other mustelids in riparian zones. Importantly, we found that habitat covariates associated with co-occurrence were relatively similar over time despite changes in the abundance of predators and prey. Our findings highlight the importance of retaining riparian habitats and forest complexity as part of forest harvesting practices to promote species co-occurrence. © 2025 The Author(s). Ecology and Evolution published by British Ecological Society and John Wiley & Sons Ltd.

关键词： ecology habitat mesocarnivores occupancy riparian

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Worrying about Climate Change

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Atmospheric and Climate Sciences 2022年第2期12卷 441-461页

作者： Naser W. Alnaser Roger Flanagan Lawrence Kazmerski Ali A. Sayigh Munir H. Nayfeh Waheeb E. Alnaser Department of Architecture and Interior Design College of Engineering University of Bahrain Isa Town Kingdom of Bah-rain School of Construction Management and Engineering University of Reading Reading UK National Renewable Energy Laboratory (NREL) Renewable and Sustainable Energy Institute (RASEI) University of Colora-do Boulder Boulder USA World Renewable Energy Congress & World Renewable Energy Network Reading UK Department of Physics University of Illinois at Urbana-Champaign Urbana USA Department of Natural Resources and Environment College of Graduate Studies Arabian Gulf University Manama Kingdom of Bahrain

It is becoming clear that Climate Change is getting severe. It was reported that the improved ocean heat measurements have a rate of warming upwards from 4 to 5 Hiroshima bombs liberated heat per second or 388,800 per day. It was reported also that our climate has accumulated the equivalent of a total of more than 2.8 billion Hiroshima bombs’ worth of heat since 1998. Despite this global concern about the effect of global change on environment, it is believed that the problem is much more severe and with greater impact on all facets of life. The effect of Climate Change, especially with a 1℃increase in global temperature (from 14℃to 15℃) is equivalent to the heat liberated from explosion of about 300 million Hiroshima of atomic bomb. This is why this CoP 26 becomes more serious and had targeted year 2060 as a year of zero CO₂ emission. This paper discusses the impact of climate change on ten sectors;water, water desalination, energy, renewable energy supply, health, society, agriculture, economy, industry, and built environment.

关键词： Global Warming Impact of Climate Change Major Impact of Climate Change Physics of Climate Change

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Social vulnerability: A driving force in amplifying the overall vulnerability of protected areas to natural hazards

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Heliyon 2025年第4期11卷 e42617页

作者： Pirasteh, Saied Mafi-Gholami, Davood Li, Huxiong Wang, Tao Zenner, Eric K. Nouri-Kamari, Akram Frazier, Tim G. Ghaffarian, Saman Institute of Artificial Intelligence Shaoxing University 508 West Huancheng Road Yuecheng District Zhejiang Province Shaoxing 312000 China Department of Geotechnics and Geomatics Saveetha School of Engineering Saveetha Institute of Medical and Technical Sciences Tamilnadu Chennai India Department of Forest Sciences Faculty of Natural Resources and Earth Sciences Shahrekord University Shahrekord *** Iran Metrology Research Group Quality Assessment and Management Systems Research Center Standard Research Institute PO Box 31585-163 Alborz Karaj Iran Department of Ecosystem Science and Management The Pennsylvania State University Forest Resources Building University Park 16802 PA United States Department of Geography Education Farhangian University Tehran Iran Emergency and Disaster Management Program School of Continuing Studies (SCS) Georgetown University Washington DC United States Institute for Risk and Disaster Reduction University College London United Kingdom

Incorporating social vulnerability (SoV) into vulnerability assessments for protected areas provides critical insights for enhancing the resilience and adaptability of these regions to environmental hazards. This study aimed to develop and apply an integrated social-ecological vulnerability assessment framework for a forest-protected area, focusing on scales relevant to management decisions. We collected data from 70 villages within the protected area through structured surveys, interviews, and reviews of secondary socio-economic and environmental datasets. A total of 24 socio-economic and environmental indicators were selected, based on expert consultation and literature review, to quantify the indices of exposure, sensitivity, adaptive capacity, and SoV. These indicators were weighted using the Fuzzy Analytical Hierarchy Process (FAHP) to ensure objective and expert-driven prioritization. Subsequently, the SoV index, derived from socio-economic metrics, was incorporated as a key variable in the exposure assessment. This integration involved 18 additional ecological indicators measured across a spatial grid, enabling a fine-scale analysis of the protected area's exposure, sensitivity, adaptive capacity, and overall vulnerability. Integrating social and ecological dimensions allowed for a spatially explicit evaluation of vulnerability at the grid-cell level, providing granular insights for localized management interventions. The results revealed that SoV significantly influenced the levels of exposure and overall vulnerability across the study area. High SoV values corresponded to areas with elevated overall vulnerability, emphasizing the interplay between social conditions and ecological risks. To enhance resilience in the medium and long term, the study recommends shifting investments toward active community engagement in conservation planning, increasing environmental awareness through education programs, and improving the socio-economic well-being of local commu

关键词： Environmental hazard resilience FAHP Integrated social-ecological framework and vulnerability assessment Protected area management Spatial pattern

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