检索结果-内蒙古大学图书馆

Force-Trainable Liquid Crystal Elastomer Enabled by Mechanophore-Induced Radical Polymerization

Angewandte Chemie 2025年

作者： Yiyi Xu Yinliang Huang Jinyu Wang Dr. Shuai Huang Prof. Hong Yang Prof. Quan Li Institute of Advanced Materials and School of Chemistry and Chemical Engineering Southeast University Nanjing 211189 China Materials Science Graduate Program Kent State University Kent OH 44242 USA

In nature, organisms adapt to environmental changes through training to learn new abilities, offering valuable insights for developing intelligent materials. However, replicating this “adaptive learning” in synthetic materials presents a significant challenge. This study introduces a feasible approach to train liquid crystal elastomers (LCEs) by integrating a mechanophore tetraarylsuccinonitrile into their main chain, addressing the challenge of enabling synthetic materials to exchange substances with their environment. Inspired by biological training, the LCEs can self-strengthen and acquire new functionalities through mechanical stress-induced radical polymerization. The research not only enhances the mechanical performance of LCEs, but also endows them with the ability to learn properties such as flexibility, light responsiveness, and fluorescence. These advancements are crucial for overcoming the limitations of current materials, paving the way for the creation of advanced intelligent soft materials with autonomous self-improvement, akin to the adaptive skills of living organisms.

关键词： force-induced chemical reaction mechanical stress-induced radical polymerization liquid crystal elastomer soft actuator smart material

来源：评论

学校读者我要写书评

暂无评论

Pulsed Terahertz Time Domain Spectroscopy for Evaluating Treatment Efficacy: Initial Validation in Monitoring Pancreatic Ductal Adenocarcinoma

Pulsed Terahertz Time Domain Spectroscopy for Evaluating Tre...

引用

International Conference on Infrared and Millimeter Waves

作者： Debamitra Chakraborty Bradley N. Mills Jing Cheng Ivan Komissarov Scott A. Gerber Roman Sobolewski Materials Science Graduate Program University of Rochester Rochester New York USA Laboratory for Laser Energetics University of Rochester Rochester New York USA Department of Surgery University of Rochester Medical Center Rochester New York USA Department of Electrical and Computer Engineering University of Rochester Rochester New York USA

Pancreatic Ductal Adenocarcinoma (PDAC) is a highly invasive malignancy with limited curative effectiveness. Here, we report the viability of using pulsed Terahertz (THz) time domain spectroscopy (THz TDS) to monitor the efficacy of Stereotactic Body Radiation Therapy (SBRT) in treating PDAC in murine models. Our study shows that THz imaging can provide reliable and reproducible results to differentiate the changes in untreated and SBRT-treated PDAC tissue using THz refractive index and absorption coefficient as mapping parameters with statistical significance. Hence the study highlights that pulsed THz-TDS can be used as a technique to monitor tumor responses to immunotherapy, providing a comprehensive assessment of the tumor’s reaction to the treatment.

关键词：

来源：评论

学校读者我要写书评

暂无评论

Nernst-Ettingshausen effect in thin Pt and W films at low temperatures

arXiv

引用

arXiv 2023年

作者： Luo, Renjie Legvold, Tanner J. Chen, Liyang Natelson, Douglas Department of Physics and Astronomy Rice University HoustonTX77005 United States Applied Physics Graduate Program Smalley-Curl Institute Rice University HoustonTX77005 United States Department of Electrical and Computer Engineering Department of Materials Science and NanoEngineering Rice University HoustonTX77005 United States

As spin caloritronic measurements become increasingly common techniques for characterizing material properties, it is important to quantify potentially confounding effects. We report measurements of the Nernst-Ettingshausen response from room temperature to 5 K in thin film wires of Pt and W, metals commonly used as inverse spin Hall detectors in spin Seebeck characterization. Johnson-Nyquist noise thermometry is used to assess the temperature change of the metals with heater power at low temperatures, and the thermal path is analyzed via finite-element modeling. The Nernst-Ettingshausen response of W is found to be approximately temperature-independent, while the response of Pt increases at low temperatures. These results are discussed in the context of theoretical expectations and the possible role of magnetic impurities in Pt. Copyright © 2023, The Authors. All rights reserved.

关键词： Inverse problems

来源：评论

学校读者我要写书评

暂无评论

High Spatial Resolution Terahertz Time-Domain Imaging of Murine Pancreatic Ductal Adenocarcinoma Tissues

High Spatial Resolution Terahertz Time-Domain Imaging of Mur...

引用

Conference on Lasers and Electro-Optics (CLEO)

作者： Debamitra Chakraborty Bradley N. Mills Jing Cheng Ivan Komissarov Scott Gerber Roman Sobolewski Materials Science Graduate Program University of Rochester Rochester New York USA Laboratory for Laser Energetics University of Rochester Rochester New York USA Department of Surgery University of Rochester Medical Center Rochester New York USA Department of Electrical and Computer Engineering University of Rochester Rochester New York USA

We developed a terahertz time-domain spectroscopy system to generate high-resolution 2-dimensional images of paraffin-embedded murine pancreatic ductal adenocarcinoma tissues using the refractive index and absorption ... 详细信息

ISBN: (纸本)9781957171258

关键词： Absorption coefficient Biological imaging Refractive index Spatial resolution Terahertz spectroscopy Tissue

来源：评论

学校读者我要写书评

暂无评论

Chemical Structures and Stability of Amine Plasma Polymers Deposited on Porous Hydroxyapatite Artificial Bone with Bipolar Pulsed Discharges

SSRN

引用

SSRN 2024年

作者： Harumningtyas, Anjar Anggraini Ito, Tomoko Michlíček, Miroslav Kodama, Joe Nečas, David Kita, Hidekazu Kaito, Takashi Zajíčková, Lenka Hamaguchi, Satoshi International Priority Graduate Program on Applied and Engineering Physics Division of Precision Engineering and Applied Physics Osaka University 2-1 Yamadaoka Suita Osaka565-0871 Japan Division of Materials and Manufacturing Science Graduate School of Engineering Osaka University 2-1 Yamadaoka Suita Osaka565-0871 Japan Jalan Babarsari Kotak Pos 6101 ykbb Yogyakarta55281 Indonesia Department of Condensed Matter Physics Faculty of Science Masaryk University Kotlarska 2 Brno61137 Czech Republic Department of Orthopaedic Surgery Osaka University Graduate School of Medicine Osaka565-0871 Japan CEITEC Central European Institute of Technology Brno University of Technology Purkyňova 123 Brno61200 Czech Republic

A recent in vivo study by Kodama et al. shows that porous artificial bones coated with aminecontaining polymers deposited in a plasma-enhanced chemical vapour deposition (PECVD) process with high-voltage, low-frequency bipolar pulsed discharges significantly enhanced bone regeneration. This article reports the chemical and physical properties of amine plasma polymers (PPs) formed under the same deposition conditions, including the film stability for up to two months, the effects of sterilization on the chemical compositions of the films, and the penetration of amine PPs into the inner surfaces of interconnected microscopic pores of the amine-PP-coated porous artificial bone. It was found that, immediately after the plasma polymerization process, approximately 15% of nitrogen atoms on the surface of the deposited amine PP formed primary amines but the number decreased to approximately 5% over one month if the sample was exposed to ambient air or sterilized by autoclaving or ethylene oxide gas. Nitriles ( –CN) were also detected in the deposited amine PPs. Molecular dynamics simulations of simplified deposition processes suggest that the observed nitriles were likely to be formed by the incorporation of gas-phase cyano radicals that were also observed in the experiments of this study. © 2024, The Authors. All rights reserved.

关键词： Hydroxyapatite

来源：评论

学校读者我要写书评

暂无评论

Theoretical insights into the chemical bonding, electronic structure, and spectroscopic properties of the lanarkite Pb2SO5 structure

arXiv

引用

arXiv 2023年

作者： Fabris, Guilherme S.L. Ferrer, Mateus M. Sambrano, Julio R. Almeida, Cláudio R.R. Paskocimas, Carlos A. La Porta, Felipe A. Graduate Program in Materials Science and Engineering Technological Development Center Universidade Federal de Pelotas RS Pelotas96010-610 Brazil Modeling and Molecular Simulation Group São Paulo State University Bauru São Paulo17033-360 Brazil Department of Materials Engineering Federal University of Rio Grande do Norte RN Natal59078-970 Brazil Postgraduate Program in Science and Engineering of Materials Federal University of Rio Grande do Norte RN Natal59078-970 Brazil Federal University of Technology - Paraná Nanotechnology and Computational Chemistry Laboratory Avenida dos Pioneiros 3131 CEP PR Londrina86036-370 Brazil State University of Londrina Post-Graduation Program in Chemistry Rodovia Celso Garcia Cid 445 km 380 CEP PR Londrina86057-970 Brazil

Lanarkite is a mineral formed by a combination of lead, sulphur, and oxygen atoms arranged in the general chemical formula Pb2SO5 (PSO) that crystallises with monoclinic symmetry (belonging to the C2/m space group, No. 12). This mineral was first discovered in Lanarkshire, Scotland and was named after its location. PSO has a unique structure comprising alternating penta-coordinated lead [PbO5] and tetra-coordinated sulphur [SO4] clusters. This lanarkite-type structure has recently attracted significant scientific interest and has been the focus of the superconducting material research community. However, its chemistry needs to be explored further. This article presents a comprehensive investigation on the chemical bonding, electronic structure, and spectroscopic properties of the lanarkite-type PSO structure from a computational perspective. Thus, different functionals in the DFT (e.g., PBE, PBE0, PBESOL, PBESOL0, BLYP, WC1LYP37, and B3LYP) were assessed to accurately predict their fundamental properties. All the DFT calculations were performed using a triple-zeta valence plus polarisation basis set. Among all the DFT functionals tested in this study, PBE showed the best agreement with the experimental data available in the literature. Our results also reveal that the [PbO5] clusters are formed with three Pb–O bond lengths, with values of about 2.32, 2.59, and 2.84 Å, respectively, while the [SO4] clusters have the same S–O bond length of 1.57 Å. We performed a complete topological analysis of this system to comprehend these structural differences. Additionally, the PSO structure has an indirect band gap energy of 2.9 eV and an effective mass ratio (mℎ∗ /me∗) of about 0.415 (using PBE calculations) which may, in principle, indicate a low recombination of electron-hole pairs in the lanarkite structure. Therefore, we believe that a detailed understanding of their electronic structures, spectroscopic properties as well as their chemical bonding is critically important

关键词： Lead compounds

来源：评论

学校读者我要写书评

暂无评论

Mo-Terminated Edges in Mos2 for Site-Specific Hydrolysis and DNA Cleavage

SSRN

引用

SSRN 2024年

作者： Wang, Cong Wu, Menghan Li, Muqing Zhao, Yingcan Zhao, Mingchuang Zhang, Yunhao Bai, Yichao Gao, Jianxiang Wang, Xiaoxia Tian, Xilin Zhang, Han Chang, Liang Zou, Xiaolong Liu, Bilu Kang, Feiyu Terrones, Mauricio Lei, Yu Institute of Materials Research Shenzhen Key Laboratory of Advanced Layered Materials for Value-added Applications Guangdong Provincial Key Laboratory of Thermal Management Engineering and Materials Center of Double Helix Tsinghua Shenzhen International Graduate School Tsinghua University Shenzhen518055 China Institute of Materials Research Shenzhen Geim Graphene Center Shenzhen Key Laboratory of Advanced Layered Materials for Value-added Applications Tsinghua-Berkeley Shenzhen Institute Tsinghua Shenzhen International Graduate School Tsinghua University Shenzhen518055 China Environmental Science Program Department of Life Sciences Beijing Normal University-Hong Kong Baptist University United International College Guangdong 519087 China Tsinghua Shenzhen International Graduate School Tsinghua University Shenzhen518055 China Department of Physics Department of Chemistry Department of Materials Sciences Center for 2-Dimensional and Layered Materials The Pennsylvania State University University Park PA16802 United States International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology Ministry of Education Institute of Microscale Optoelectronics Shenzhen University Shenzhen518060 China Key Laboratory of Optoelectronic Devices and Systems China

The hydrolysis of DNA serves as the foundational principle for gene engineering that enable precise gene cleavage at the molecular level. This process typically occurs in biological nucleases, which exhibit nucleobase-selective and catalytic hydrolysis capabilities rarely replicated in abiotic nanomaterials. Here, we demonstrate that molybdenum-terminated (Mo-terminated) edges of molybdenum disulfide (MoS2) possess the unique ability to abstract a proton (H+) from water molecules, thereby facilitating catalytic hydrolysis reactions that cleave the phosphodiester bonds in DNA through the action of hydroxide ions. The enhanced proton absorption at Mo-terminated edges of MoS2 significantly reduces the activation energy required for the DNA hydrolysis reaction. Furthermore, the favorable interaction between the Mo-terminated edges and thymine nucleobases promotes both charge transfer and P-O bond cleavage, enabling targeted DNA hydrolysis at 'TTTTTTT' sequences under dark conditions. This discovery underscores the potential of MoS2 as a stable, efficient nanosystem for precise genetic editing, heralding advanced applications in the field of gene engineering. © 2024, The Authors. All rights reserved.

关键词： DNA sequences

来源：评论

学校读者我要写书评

暂无评论

Braiding fractional quantum Hall quasiholes on a superconducting quantum processor

引用

Physical Review B 2023年第6期108卷 064303-064303页

作者： Ammar Kirmani Derek S. Wang Pouyan Ghaemi Armin Rahmani Physics Department City College of the City University of New York New York 10031 USA IBM Quantum IBM T.J. Watson Research Center Yorktown Heights 10598 USA Physics Program Graduate Center of City University of New York New York 10031 USA Department of Physics and Astronomy and Advanced Materials Science and Engineering Center Western Washington University Bellingham Washington 98225 USA

Direct experimental detection of anyonic exchange statistics in fractional quantum Hall systems by braiding the excitations and measuring the wave-function phase is an enormous challenge. Here, we use a small, noisy quantum computer to emulate direct braiding within the framework of a simplified model applicable to a thin cylinder geometry and measure the topological phase. Our algorithm first prepares the ground state with two quasiholes. It then applies a unitary operation controlled by an ancilla, corresponding to a sequence of adiabatic evolutions that take one quasihole around the other. We finally extract the phase of the wave function from measuring the ancilla with a compound error mitigation strategy. Our results point out an avenue for studying braiding statistics in fractional Hall states.

关键词： Anyons Fractional quantum Hall effect Quantum algorithms Superconducting devices

来源：评论

学校读者我要写书评

暂无评论

Far-Field Subwavelength Acoustic Computational Imaging with a Single Detector

引用

Physical Review Applied 2022年第1期18卷 014046-014046页

作者： Yuan Tian Hao Ge Xiu-Juan Zhang Xiang-Yuan Xu Ming-Hui Lu Yun Jing Yan-Feng Chen National Laboratory of Solid State Microstructures and Department of Materials Science and Engineering Nanjing University Nanjing 210093 China The Institute of Acoustics of the Chinese Academy of Sciences Beijing 100190 China Collaborative Innovation Center of Advanced Microstructures Nanjing 210093 China Graduate Program in Acoustics The Pennsylvania State University University Park Pennsylvania 16802 USA

Acoustic imaging techniques suffer from the diffraction limit due to the loss of evanescent waves that carry subwavelength information of objects. To overcome the diffraction limit, the evanescent components have to be collected and measured. Most of the existing methods targeting this task rely on expensive detector arrays and inefficient near-field point-by-point scanning. Here, we propose and experimentally demonstrate the realization of a far-field acoustic subwavelength imaging method based on a single stationary detector. Specifically, we utilize a series of masks to structure the detected field, so that the evanescent wave information is encoded into the propagating waves due to spatial frequency convolution between the object and masks. Our study shows that, by combining the principles of computational imaging and metalens, high-quality images of a subwavelength object can be reconstructed in the far field, even in the presence of unwanted scatterers. Our work provides a robust method for far-field acoustic subwavelength imaging, which could bring possibilities for acoustic microscopy and could further be applied to medical ultrasonography, underwater sonar, and ultrasonic nondestructive evaluation.

关键词： Acoustic metamaterials Acoustic modeling Acoustics Ghost imaging

来源：评论

学校读者我要写书评

暂无评论

Rapid Electronic Transport Channel of Co-P with Mo in a Heterostructure Embedded with P, N Dual Doped Porous Carbon for Electrocatalytic Oxygen and Hydrogen Evolution

引用

ChemNanoMat 2024年第7期10卷

作者： Dey, Tapan Rajput, Anubha Jhaa, Gaurav Matsagar, Babasahab M. Chen, Norman C.-R Kumar, Nitish Salunkhe, Rahul Wu, Kevin C.-W. Chakraborty, Biswarup Dutta, Saikat Electrochemical Energy & Sensor Research Laboratory Amity Institute of Click Chemistry Research & Studies Amity University Noida India Department of Chemistry Indian Institute of Technology Delhi Hauz Khas New Delhi110016 India Chemical Information Sciences Laboratory Department of Chemistry Pondicherry University Kalapet Pondicherry605014 India Department of Chemical Engineering National Taiwan University No. 1 Sec. 4 Roosevelt Road Taipei10617 Taiwan Molecular Science and Technology Program Taiwan International Graduate Program Academia Sinica Taiwan Materials Research Laboratory Department of Physics Indian Institute of Technology Jammu Jammu India Department of Chemical Engineering and Materials Science Yuan Ze University Taoyuan Chung-Li Taiwan Department of Chemical Engineering Chung Yuan Christian University No. 200 Zhongbei Rd. Zhongli Dist. Taoyuan City320 Taiwan

We developed a molybdenum (Mo)-doped cobalt (Co)-heterostructure embedded on a phosphorous (P) and nitrogen (N) dual-doped porous carbon which exhibits an intrinsic electronic transport channel of Co to Mo and P. The P,Mo,O−Co/PNC/NF (NF=Nickel foam) electrode offers 335 mV overpotential at 10 mA cm−2 in OER as compared with PMA-ZIF67-NC/NF and ZIF67-NC/NF electrode with an overpotential of 357 and 373 mV respectively. Linear sweep voltammetry (LSV) of overall water splitting (OWS) supports that the current density gradually increased at a cell potential of 1.6 V with a maximum of 40 mA with a corresponding cell potential of 1.79 V at a current density of 10 mA cm−2. Density functional theory (DFT) calculations for water adsorption on optimized [111] surface of Co, CoMo, and CoMoP2 with adsorbed H2O and corresponding lattice determine the electron density difference of [111] surface with adsorbed H2O for Eads (eV) 4.23 corresponds to adsorption energy for CoMoP2. XANE-EXAFS spectroscopy of P,Mo,O−Co/PNC at Co K edge and Mo K edge suggests the presence of higher valence of both Cox+ and Mox+ without metallic Co and Mo and Co−P and Mo−P bonds as major structural units due to phosphidation as determined by R-space FT-EXAFS spectra. © 2024 Wiley-VCH GmbH.

关键词： Cobalt

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：