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Incommensurate magnetic orders and topological Hall effect in the square-net centrosymmetric EuGa2Al2 system

Physical Review materials 2022年第7期6卷 074201-074201页

作者： Jaime M. Moya Shiming Lei Eleanor M. Clements Caitlin S. Kengle Stella Sun Kevin Allen Qizhi Li Y. Y. Peng Ali A. Husain Matteo Mitrano Matthew J. Krogstad Raymond Osborn Anand B. Puthirath Songxue Chi L. Debeer-Schmitt J. Gaudet P. Abbamonte Jeffrey W. Lynn E. Morosan Applied Physics Graduate Program Smalley-Curl Institute Rice University Houston Texas 77005 USA Department of Physics and Astronomy Rice University Houston Texas 77005 USA NIST Center for Neutron Research National Institute of Standards and Technology Gaithersburg Maryland 20899 USA Department of Physics University of Illinois at Urbana-Champaign Urbana Illinois 61801 USA International Center for Quantum Materials School of Physics Peking University CN-100871 Beijing China Department of Physics and Astronomy and Quantum Matter Institute University of British Columbia Vancouver British Columbia Canada V6T 1Z1 Department of Physics Harvard University Cambridge Massachusetts 02138 USA Materials Science Division Argonne National Laboratory Lemont Illinois 60439 USA Department of Materials Science and NanoEngineering Rice University Houston Texas 77005 USA Neutron Scattering Division Oak Ridge National Laboratory Oak Ridge Tennessee 37831 USA Department of Materials Science and Engineering University of Maryland College Park Maryland 20742-2215 USA

Neutron diffraction on the centrosymmetric square-net magnet EuGa2Al2 reveals multiple incommensurate magnetic states (AFM1, 2, 3) in zero field. In applied field, a new magnetic phase (A) is identified from magnetization and transport measurements, bounded by two of the μ0H=0 incommensurate magnetic phases (AFM1, helical, and AFM3, cycloidal) with different moment orientations. Moreover, magnetotransport measurements indicate the presence of a topological Hall effect, with maximum values centered in the A phase. Together, these results render EuGa2Al2 a material with noncoplanar or topological spin texture in applied field. X-ray diffraction reveals an out-of-plane (OOP) charge density wave (CDW) below TCDW∼50 K while the magnetic propagation vector lies in plane below TN=19.5 K. Together these data point to a new route to realizing in-plane noncollinear spin textures through an OOP CDW. In turn, these noncollinear spin textures may be unstable against the formation of topological spin textures in an applied field.

关键词： Charge density waves Exotic phases of matter Hall effect Magnetic phase transitions Magnetotransport Symmetry protected topological states Topological materials

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Correction: Advancements in additive manufacturing for video laryngoscopes: a comprehensive scoping and technological review

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Systematic reviews 2024年第1期13卷 31页

作者： Ana Cristina Beitia Kraemer Moraes Chiara das Dores do Nascimento Everton Granemann Souza Mauricio Beitia Kraemer Mauricio Moraes Neftali Lenin Villarreal Carreno Evandro Piva Rafael Guerra Lund Pelotas Dental School Graduate Program in Dentistry Federal University of Pelotas Pelotas RS 96010‑560 Brazil. Master's Degree in Electronic and Computer Engineering Center for Social and Technological Sciences Catholic University of Pelotas Pelotas RS 96015‑560 Brazil. Faculty of Medicine São Francisco University Bragança Paulista SP 12916‑900 Brazil. Faculty of Medicine Federal University of Pelotas Pelotas RS 96010‑560 Brazil. Graduate Program in Materials Science and Engineering Technological Development Center Federal University of Pelotas Pelotas RS 96010‑610 Brazil. Pelotas Dental School Graduate Program in Dentistry Federal University of Pelotas Pelotas RS 96010‑560 Brazil. rafael.lund@***. Graduate Program in Materials Science and Engineering Technological Development Center Federal University of Pelotas Pelotas RS 96010‑610 Brazil. rafael.lund@***.

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Giant Second-Order Nonlinearity and Anisotropy of Large-Sized Few-Layer SnS with Ferroelectric Stacking

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Advanced Optical materials 2024年第19期12卷

作者： Moqbel, Redhwan Nanae, Ryo Kitamura, Satsuki Lee, Ming-Hao Lan, Yann-Wen Lee, Chi-Cheng Nagashio, Kosuke Lin, Kung-Hsuan Department of Physics National Taiwan University No. 1 Sec. 4 Roosevelt Rd. Taipei106319 Taiwan Institute of Physics Academia Sinica No. 128 Sec. 2 Academia Rd. Nangang Dist. Taipei115201 Taiwan Nano-Science and Technology Program Taiwan International Graduate Program Academia Sinica No. 128 Sec. 2 Academia Rd. Nangang Dist. Taipei115201 Taiwan Department of Materials Engineering The University of Tokyo 7-3-1 Hongo Tokyo Bunkyo113-8656 Japan Center for Condensed Matter Sciences National Taiwan University Taipei10617 Taiwan The Key Consortium of Electron Microscopy National Taiwan University Taipei10617 Taiwan Department of Physics National Taiwan Normal University Taipei11677 Taiwan Department of Physics Tamkang University New Taipei Tamsui251301 Taiwan

The giant second-order nonlinearity of SnS with ferroelectric stacking is reported. Based on theoretical calculations, the susceptibility of second harmonic generation (SHG) from SnS with ferroelectric stacking is up to 1354 pm V−1, which is three orders of magnitude higher than the values of traditional nonlinear crystals such as BBO and KTP. The SHG from ferroelectric SnS few layers is experimentally measured and its intensity is found to be 131 times larger than that of a MoS2 monolayer under the same experimental conditions, with a photon energy of 1.55 eV. The SHG susceptibility is determined to be on the order of 100 pm V−1. Numerous SnS flakes are systematically investigated using polarization-resolved SHG. Micrometer-sized flakes with a single domain are found, and their SHG anisotropic patterns fit well with the theoretical calculations derived from first-principles methods. The variation in SHG anisotropic patterns, attributed to SHG interference from multiple domains, is investigated both theoretically and experimentally. Additionally, the impact of stacking disorder on the SHG anisotropic pattern is explored. It is demonstrated that polarization-resolved SHG microscopy is a valuable tool for identifying domains in SnS flakes and examining stacking disorder. © 2024 Wiley-VCH GmbH.

关键词： Harmonic generation

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Hexaazatriphenylene-Based Two-Dimensional Conductive Covalent Organic Framework with Anisotropic Charge Transfer

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Angewandte Chemie 2023年第42期135卷

作者： Seong-Wook Kim Hyeonjung Jung Dr. Mahmut Sait Okyay Dr. Hyuk-Jun Noh Sein Chung Young Hyun Kim Jong-Pil Jeon Prof. Dr. Bryan M. Wong Prof. Dr. Kilwon Cho Dr. Jeong-Min Seo Prof. Dr. Jung-Woo Yoo Prof. Dr. Jong-Beom Baek Department of Energy and Chemical Engineering/ Center for Dimension-Controllable Organic Frameworks Ulsan National Institute of Science and Technology (UNIST) Ulsan 44919 Republic of Korea These authors contributed equally to this work School of Materials Science and Engineering Ulsan National Institute of Science and Technology (UNIST) Ulsan 44919 Republic of Korea Materials Science & Engineering Program Department of Chemistry and Department of Physics & Astronomy University of California-Riverside Riverside CA 92521 USA Department of Chemistry Dartmouth College Hanover NH 03755 USA Department of Chemical Engineering Pohang University of Science and Technology Pohang 37673 Republic of Korea School of Materials Science and Engineering/ Graduate School of Semiconductor Materials and Devices Ulsan National Institute of Science and Technology (UNIST) Ulsan 44919 Republic of Korea

The development of covalent organic frameworks (COFs) with efficient charge transport is of immense interest for applications in optoelectronic devices. To enhance COF charge transport properties, electroactive building blocks and dopants can be used to induce extended conduction channels. However, understanding their intricate interplay remains challenging. We designed and synthesized a tailor-made COF structure with electroactive hexaazatriphenylene (HAT) core units and planar dioxin (D) linkages, denoted as HD-COF. With the support of theoretical calculations, we found that the HAT units in the HD-COF induce strong, eclipsed π–π stacking. The unique stacking of HAT units and the weak in-plane conjugation of dioxin linkages leads to efficient anisotropic charge transport. We fabricated HD-COF films to minimize the grain boundary effect of bulk COFs, which resulted in enhanced conductivity. As a result, the HD-COF films showed an electrical conductivity as high as 1.25 S cm −1 after doping with tris(4-bromophenyl)ammoniumyl hexachloroantimonate.

关键词： Anisotropic Charge Transfer Conductivity Covalent Organic Frameworks Doping

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Recycling of PE/PA/EVOH Multilayer Flexible Packaging Films via Reactive Compatibilization

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Journal of Applied Polymer science 2025年

作者： Barbosa, Felipe D. Staffa, Lucas H. Costa, Lidiane C. Graduate Program in Materials Science and Engineering Federal University of Sao Carlos São Carlos Brazil Packaging & Specialty Plastics Dow Brasil S.A. São Paulo Brazil São Carlos Brazil Federal University of São Carlos São Carlos Brazil

The recycling of a 7-layer co-extruded blown flexible film composed of polyethylene (LLDPE/LDPE blend), polyamide-6/6.6 (PA), and random copolymer of ethylene vinyl alcohol (EVOH) was assessed via reactive compatibilization using a maleic anhydride grafted polyethylene. Flat monolayer films were obtained from mechanical recycling of the multilayer film using a co-corotating twin screw extruder, with and without the compatibilizer. After that, they were characterized for their morphological, rheological, thermal, and mechanical properties. According to Harkin's spreading coefficient concept, the Relative Interfacial Energy (RIE) approach, and SEM images, a core-shell morphology was revealed, with the dispersed phase consisting of a thin EVOH layer and a PA6/6.6 copolymer core embedded within a continuous LLDPE/LDPE matrix. Adding up to 10 phr of the compatibilizer induced significant changes in the size and distribution of the dispersed phase. Moreover, compatibilized monolayer films exhibited enhanced mechanical properties, such as tensile, puncture, tear propagation strength, and dart drop impact resistance, compared to the uncompatibilized blend. Nonetheless, the compatibilizer presence negatively impacted the film's optical properties, although its clarity remained suitable for flexible packaging applications. © 2025 The Author(s). Journal of Applied Polymer science published by Wiley Periodicals LLC.

关键词： Tensile strength

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Unraveling the Cr 2 N Precipitation and Its Negative Effect on the Corrosion Resistance of Friction Stir Welded UNS S32760 Super Duplex Stainless Steel

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Surfaces and Interfaces 2025年 71卷

作者： G.S. Vacchi W.S. de Carvalho C.P. Meinhardt L.A. Bergmann S.T. Amancio-Filho C.A.D. Rovere Munir Rachid Corrosion Laboratory Department of Materials Engineering Federal University of São Carlos Rodovia Washington Luis Km 235 São Carlos SP 13565-905 Brazil Graduate Program in Materials Science and Engineering Federal University of São Carlos Brazil Institute of Materials Science Joining and Forming BMK Endowed Professorship for Aviation Graz University of Technology – TU Graz Kopernikusgasse 24/1 Graz 8010 Austria Department of Mechanical Engineering Federal University of Pampa Avenida Tiarajú 810 Alegrete RS Brazil Helmholtz-Zentrum Hereon Institute of Materials Mechanics Solid State Materials Processing Max-Planck-Straße 1 Geesthacht Germany

The root surface of a friction stir welded super duplex stainless steel (UNS S32760) was thoroughly characterized in this study. The findings revealed a refined grain structure and a conspicuous increase of 50 HV 0.3 in the Root’s hardness. Interestingly, the volume fraction of the ferrite phase remained largely unchanged. Rapid cooling in the welding process led to the Cr 2 N precipitation at the ferrite/ferrite grain boundaries in the root area, significantly increasing sensitization, reducing localized corrosion resistance under high electrode potentials in a neutral pH saline environment, and adversely affecting root passivity in a hydrochloric acid environment compared to the base metal.

关键词： Friction stir welding Localized corrosion Polarization Sensitization Super duplex stainless steel

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Correction: A review of Gum Metal: Developments over the years and new perspectives

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Journal of materials Research 2023年第1期38卷 265-265页

作者： da Silva, Murillo Romero Plaine, Athos Henrique Pinotti, Vitor Eduardo Mazzer, Eric Marchezini Bolfarini, Claudemiro School of Metallurgical Industrial Engineering of Volta Redonda Federal Fluminense University Volta Redonda Brazil Department of Mechanical Engineering State University of Santa Catarina - UDESC Joinville Brazil Graduate Program in Materials Science and Engineering Federal University of São Carlos São Carlos Brazil Department of Metallurgical and Materials Engineering Federal University of Minas Gerais Belo Horizonte Brazil Department of Materials Engineering Federal University of São Carlos São Carlos Brazil

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Diversification of the Carbodicarbene Class by Embedding an Anionic Component in its Scaffold

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Chemistry - A European Journal 2023年第71期29卷 e202302886页

作者： Yu, Cheng-Han Au-Yeung, Ka-Chun Liu, Ruiqin Lee, Chao-Hsien Jiang, Dandan Semagne Aweke, Bamlaku Wu, Chia-Hung Wang, Yu-Jou Wang, Ting-Hsuan Voon Kong, Kien Yap, Glenn P. A. Chen, Wen-Ching Frenking, Gernot Zhao, Lili Ong, Tiow-Gan Institute of chemistry Academia Sinica Taipei115201 Taiwan School of Chemistry and Molecular Engineering State Key Laboratory of Materials-Oriented Chemical Engineering Nanjing Tech University Nanjing China Fachbereich Chemie Philipps-Universität Marburg Hans-Meerwein-Strasse MarburgD-35043 Germany Department of Chemistry and Biochemistry University of Delaware NewarkDE United States Department of Chemistry National Taiwan University Taipei Taiwan Department of Applied Chemistry National Yang Ming Chiao Tung University Hsinchu Taiwan Sustainable Chemical Science and Technology Taiwan International Graduate Program Academia Sinica Taipei Taiwan Corporate R&D Center LCY Chemical Corporation Kaohsiung Taiwan Department of Medicinal and Applied Chemistry Kaohsiung Medical University Kaohsiung Taiwan

Carbodicarbene (CDC) has become an emerging ligand in many fields due to its strong σ-donating ability. 2- moiety within the framework to leverage the electronic feature of carbon carbone. The elucidation of X-ray crystal structures, ligand competition as well as transmetallation experiments suggest that the anionic moiety has enhanced the overall donor strength of the traditional neutral CDC. Importantly, this anionic scaffold exhibits a facile second coordination toward Au(I), Ag(I) and Pd(II) without any external ligand assistance, whereas previously reported neutral pincer CDC complexes do not possess a two-fold donor capacity. The analysis of the bonding situation via theoretical methods shows that the description of the anionic CDC moieties in terms of dative bonding is preferred over the model of delocalized positive charge, as it accounts for the two-fold donor ability of the divalent carbon atom, preserving a characteristic feature of a carbone. © 2023 Wiley-VCH GmbH.

关键词： Scaffolds

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Bispropylurea bridged polysilsesquioxane: A microporous MOF-like material for molecular recognition

arXiv

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arXiv 2021年

作者： Doustkhah, Esmail Tahawy, Rafat Simon, Ulla Tsunoji, Nao Ide, Yusuke Hanaor, Dorian A.H. Hussein N. Assadi, M. 1-1 Namiki Tsukuba Ibaraki305-0044 Japan Fachgebiet Keramische Werkstoffe Technische Universität Berlin Berlin10623 Germany Graduate School of Advanced Science and Engineering Applied Chemistry Program Hiroshima University 1-4-1 Kagamiyama Higashi-Hiroshima739-8527 Japan School of Materials Science and Engineering The University of New South Wales SydneyNSW2052 Australia

Microporous organosilicas assembled from polysilsesquioxane (POSS) building blocks are promising materials that are yet to be explored in-depth. Here, we investigate the processing and molecular structure of bispropylurea bridged POSS (POSS-urea), synthesised through the acidic condensation of 1,3-bis(3-(triethoxysilyl)propyl)urea (BTPU). Experimentally, we show that POSS-urea has excellent functionality for molecular recognition toward acetonitrile with an adsorption level of 74 mmol/g, which compares favourably to MOFs and zeolites, with applications in volatile organic compounds (VOC). The acetonitrile adsorption capacity was 132-fold higher relative to adsorption capacity for toluene, which shows the pores are highly selective towards acetonitrile adsorption due to their size and arrangement. Theoretically, our tight-binding density functional and molecular dynamics calculations demonstrated that this BTPU based POSS is microporous with an irregular placement of the pores. Structural studies confirm maximal pore sizes of ~ 1 nm, with POSS cages possessing an approximate edge length of ~ 3.16 Å. © 2021, CC BY.

关键词： Urea

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Identifying topologically associating domains using differential kernels

arXiv

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arXiv 2023年

作者： Maisuradze, Luka King, Megan C. Surovtsev, Ivan V. Mochrie, Simon G.J. Shattuck, Mark D. O’Hern, Corey S. Department of Molecular Biophysics and Biochemistry Yale University New HavenCT United States Department of Cell Biology Yale School of Medicine New HavenCT United States Department of Physics Yale University New HavenCT United States Benjamin Levich Institute Physics Department The City College of New York New YorkNY United States Department of Mechanical Engineering and Materials Science Yale University New HavenCT United States Graduate Program in Computational Biology and Bioinformatics Yale University New HavenCT United States

Chromatin is a polymer complex of DNA and proteins that regulates gene expression. The three-dimensional (3D) structure and organization of chromatin controls DNA transcription and replication. High-throughput chromatin conformation capture techniques generate Hi-C maps that can provide insight into the 3D structure of chromatin. Hi-C maps can be represented as a symmetric matrix Aij, where each element represents the average contact probability or number of contacts between chromatin loci i and j. Previous studies have detected topologically associating domains (TADs), or self-interacting regions in Aij within which the contact probability is greater than that outside the region. Many algorithms have been developed to identify TADs within Hi-C maps. However, most TAD identification algorithms are unable to identify nested or overlapping TADs and for a given Hi-C map there is significant variation in the location and number of TADs identified by different methods. We develop a novel method to identify TADs, KerTAD, using a kernel-based technique from computer vision and image processing that is able to accurately identify nested and overlapping TADs. We benchmark this method against state-of-the-art TAD identification methods on both synthetic and experimental data sets. We find that the new method consistently has higher true positive rates (TPR) and lower false discovery rates (FDR) than all tested methods for both synthetic and manually annotated experimental Hi-C maps. The TPR for KerTAD is also largely insensitive to increasing noise and sparsity, in contrast to the other methods. We also find that KerTAD is consistent in the number and size of TADs identified across replicate experimental Hi-C maps for several organisms. Thus, KerTAD will improve automated TAD identification and enable researchers to better correlate changes in TADs to biological phenomena, such as enhancer-promoter interactions and disease states. © 2023, CC BY.

关键词： Topology

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