The pronounced variation of the optical reflectance R of nanometer thin VO2 films with temperature T at the phase transition recently has triggered interest in the development of compact thermo-optical sensors that ut...
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Proton‐coupled electron‐transfer oxidation of a Ru II −OH 2 complex, having an N‐heterocyclic carbene ligand, gives a Ru III −O . species, which has an electronically equivalent structure of the Ru IV =O species, i...
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Proton‐coupled electron‐transfer oxidation of a Ru II −OH 2 complex, having an N‐heterocyclic carbene ligand, gives a Ru III −O . species, which has an electronically equivalent structure of the Ru IV =O species, in an acidic aqueous solution. The Ru III −O . complex was characterized by spectroscopic methods and DFT calculations. The oxidation state of the Ru center was shown to be close to +3; the Ru−O bond showed a lower‐energy Raman scattering at 732 cm −1 and the Ru−O bond length was estimated to be 1.77(1) Å. The Ru III −O . complex exhibits high reactivity in substrate oxidation under catalytic conditions; particularly, benzaldehyde and the derivatives are oxidized to the corresponding benzoic acid through C−H abstraction from the formyl group by the Ru III −O . complex bearing a strong radical character as the active species.
This study performed a salt water spray test using zinc-coated steel sheet specimens, which are coated with S-700 solution and LR-0317. Test specimens were treated in the drying oven at 170∼210 °C for 5 minutes ...
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Ca3Co4O9 is one of the most promising thermoelectric oxide materials at high temperature. Its structure consists of two misfit layers: the CaO-CoO-CaO rocksalt-type (RS) layer and the CdI 2-type CoO2 layer. In this pa...
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Nanocrystalline CoFe films were fabricated by electrodeposition process for an investigation of the relationship between the alloys' characteristics and their magnetic properties. The study shows that coating thic...
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Nanocrystalline CoFe films were fabricated by electrodeposition process for an investigation of the relationship between the alloys' characteristics and their magnetic properties. The study shows that coating thickness promotes softer magnetic properties of the films, and induces changes of film roughness, preferred orientation and domain pattern. The preferred orientation of the μm films(thin films) is(110) plane, whereas that of the μm films(thick films) are(110) and(200) planes. The magnetic domain of the thin films exhibit a stripe-liked pattern, whereas a bubble-liked pattern appears in the thick films. Iron content significantly affects the magnetic properties of the thick films. In this study, the 57.3wt.%Fe thick film has the highest saturation magnetization, and the 80.0wt.%Fe thick film shows the lowest coercivity.
Ultrasonic velocity profiler method is now an accepted tool in modern experimental fluid mechanics and fluid engineering. As a relative new technology, different applications and improvements of the technique are bein...
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ISBN:
(纸本)9781467363846
Ultrasonic velocity profiler method is now an accepted tool in modern experimental fluid mechanics and fluid engineering. As a relative new technology, different applications and improvements of the technique are being researched over the last years. This paper presents an environment to develop new algorithms to improve the ultrasonic velocity estimation technique. The system uses the LabVIEW modular platform integrated with mathematical script language used in many signal-processing software. The phase-shift algorithm was implemented and tested using the proposed system. The results are validated with standard velocity measurements generated by a rotating cylinder.
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