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2023 Conference on Lasers and Electro-Optics, CLEO 2023

作者： Xu, Rui Lin, Tong Luo, Jiaming Chen, Xiaotong Blackert, Elizabeth R. Moon, Alyssa R. JeBailey, Khalil M. Zhu, Hanyu Department of Materials Science and Nano Engineering Rice University Houston United States Applied Physics Graduate Program Rice University Houston United States Program Rice University Houston United States

ISBN: (纸本)9781957171258

We report the experimental demonstration of surface phonon-polaritonic devices in a broad spectral range of 7-13 THz based on SrTiO3. We designed planar ultrafast concentrators that amplifies transient electric field by 6 times and measured an average field of 0.5 GV/m in an optically resolvable area in the far field. © 2023 The Author(s)

关键词： Perovskite

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DAMAGE TOLERANCE OF DOUBLE-DOUBLE LAMINATES 23

DAMAGE TOLERANCE OF DOUBLE-DOUBLE LAMINATES

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23rd International Conference on Composite materials, ICCM 2023

作者： Melo, Jose Daniel D. Cunha, Rayane D. Targino, Talita G. Freire Junior, Raimundo C.S. Ferreira, Evans P.C. Medeiros, Antonio M. Department of Materials Engineering Federal University of Rio Grande do Norte Natal Brazil Graduate Program in Materials Science and Engineering Federal University of Rio Grande do Norte Natal Brazil SENAI Innovation Institute Natal Brazil

Double-double (DD) lay-up is a new configuration strategy for the design of composite laminates, which allows the use of simplified stacking sequences that leads to potential advantages, such as improved manufacturability and design optimization, as compared to traditional quadriaxial laminates (Quad), which are limited to ply angles of 0°, ±45° and 90°. With the double-double concept, through-the-thickness homogenization is facilitated using thinner sub-laminates and, consequently, profile optimization through thickness tapering becomes possible. In this work, damages after impact and after CAI tests of a double-double laminate (+50/0/-50/0)10 and a hard conventional laminate of equivalent in-plane stiffness (03/90/±45/02/±45)2S are compared. According to the data presented, maximum delaminated areas were of the same order of magnitude for the quad and for the DD laminates, under both conditions: after impact and after CAI tests. The results contribute to the understanding of potential benefits of the double-double concept to damage resistance and damage tolerance of composite laminates. © 2023 International Committee on Composite materials. All rights reserved.

关键词： Damage tolerance

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Transforming organic chemistry research paradigms:Moving from manual efforts to the intersection of automation and artificial intelligence

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National science Open 2024年第2期3卷 98-127页

作者： Chengchun Liu Yuntian Chen Fanyang Mo School of Materials Science and Engineering Peking UniversityBeijing 100871China Ningbo Institute of Digital Twin Eastern Institute of TechnologyNingbo 315000China AI for Science(AI4S)-Preferred Program Peking University Shenzhen Graduate SchoolShenzhen 518055China

Organic chemistry is undergoing a major paradigm shift,moving from a labor-intensive approach to a new era dominated by automation and artificial intelligence(AI).This transformative shift is being driven by technological advances,the ever-increasing demand for greater research efficiency and accuracy,and the burgeoning growth of interdisciplinary *** models,supported by computational power and algorithms,are drastically reshaping synthetic planning and introducing groundbreaking ways to tackle complex molecular *** addition,autonomous robotic systems are rapidly accelerating the pace of discovery by performing tedious tasks with unprecedented speed and *** article examines the multiple opportunities and challenges presented by this paradigm shift and explores its far-reaching *** provides valuable insights into the future trajectory of organic chemistry research,which is increasingly defined by the synergistic interaction of automation and AI.

关键词： organic chemistry automation platform artificial intelligence algorithms

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Effect of Cu addition on electrochemical activity of ribbons of Mg-Al-Ca anode materials for magnesium rechargeable batteries manufactured by rapid solidification method

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Keikinzoku/Journal of Japan Institute of Light Metals 2024年第1期74卷 14-17页

作者： Fukui, Shunsaku Tsukeda, Tadayoshi Aida, Tetsuo Tabata, Hironobu Kurihara, Hideki Suzuki, Mayumi Program of Materials Science and Engineering Studies in Science and Engineering Graduate School of Science and Engineering University of Toyama 3190 Gofuku Toyama-shi Toyama930-8555 Japan Faculty of Sustainable Design Academic Assembly University of Toyama Toyama-shi Toyama Japan CHUETSU METAL WORKS CO. LTD. Nakaniikawa-gun Toyama Japan Saitama Industrial Technology Center Kawaguchi Kawaguchi-shi Saitama Japan Department of Mechanical Systems Engineering Faculty of Engineering Toyama Prefectural University Imizu-shi Toyama Japan

The potential for magnesium storage batteries to become the next generation of rechargeable batteries is high. This is largely due to the abundance of magnesium metal resources and their high safety and electric capacity per volume. Our research team has been studying magnesium alloys as anode materials for these batteries. Specifically, we have been investigating the electrochemical activity and mechanism of adding copper to Mg-9mass%Al and Mg-9mass%Al-3mass%Ca. Our findings indicate that the electrochemical activity increased with the addition of 1mass%Cu, but decreased with the addition of 3mass%Cu. In addition, changes in lattice constant and basal orientation were also observed. These changes decreased with 1mass%Cu and increased with 3mass%Cu. SEM observations showed that the cell delimitation was indistinct for the 1%Cu addition. © 2024 The Japan Institute of Light Metals.

关键词： Secondary batteries

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Improvement of corrosion resistance and heat dissipation of Mg-6%Al-4%Ca alloy by the addition of Mn, Mm, and the surface treatment

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Keikinzoku/Journal of Japan Institute of Light Metals 2023年第12期73卷 646-650页

作者： Ito, Mizuki Kondo, Natsuki Kirimoto, Yuichi Tsukeda, Tadayoshi Aida, Tetsuo Tabata, Hironobu Kurihara, Hideki Suzuki, Mayumi Program of Materials Science and Engineering Studies in Science and Engineering Graduate School of Science and Engineering University of Toyama 3190 Gofuku Toyama-shi Toyama930-8555 Japan School of Sustainable Design Materials and Engineering University of Toyama Toyama Toyama-shi Japan Department of Nano and Functional Material Science Graduate School of Science and Engineering for Education University of Toyama Toyama Toyama-shi Japan Faculty of Sustainable Design Academic Assembly University of Toyama Toyama Toyama-shi Japan CHUETSU METAL WORKS CO LTD.. Nakaniikawa-gun Toyama Japan Saitama Industrial Technology Center Kawaguchi-shi Saitama Japan Department of Mechanical Systems Engineering Faculty of Engineering Toyama Prefectural University Toyama Imizu-shi Japan

With the recent digitization, electronic equipment housings are required to be thin-walled and have rigidity, heat dissipation, corrosion resistance, and electromagnetic shielding properties. Magnesium alloys are promising materials that satisfy these requirements. Mg-Al alloys have good castability and high strength, but their thermal conductivity decreases. In general, adding alloying elements to magnesium decreases thermal conductivity the effect of aluminum addition is significant. It was found that adding calcium to Mg-Al alloys to form Mg-Al-Ca (AX) alloys results in higher thermal conductivity than that of Mg-Al alloys. However, AX alloys have poor corrosion resistance and require post-treatment such as surface treatment. In this study, AX64, which has high thermal conductivity among the AX series alloys, was used as the basic composition, and corrosion resistance was improved by adding manganese and misch metal, and an attempt was made to improve corrosion resistance and emissivity through surface treatment. The change in thermal conductivity by heat treatment was also investigated. Experimental results showed that the addition of manganese and misch metal improved corrosion resistance and thermal conductivity. Plasma anodization also improved corrosion resistance and emissivity. Heat treatment of these alloys at 400°C improved the thermal conductivity with longer holding time. © 2023 The Japan Institute of Light Metals.

关键词： Corrosion resistance

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Interface Performance of Untreated Dracaena trifasciata Fibers in Epoxy Composites

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Fibers and Polymers 2025年 1-10页

作者： Minillo, Larissa Queiroz Fabiche, Mariana Natale Fiorelli Ambrosio, Vanessa Carolina Lombardi de Castro Cardoso, Bruno César Ortenzi, Altibano Post-Graduate Program in Materials Science and Engineering Federal University of Paraná Curitiba Brazil Post-Graduate Program in Civil Engineering and Building Technology State University of Maringá Umuarama Brazil Post-Graduate Program in Civil Engineering State University of Londrina Londrina Brazil Post-Graduate Program in Construction Management and Building Technologies University of Western São Paulo Presidente Prudente Brazil

This study evaluates the potential of Dracaena trifasciata (DT) fibers as reinforcement in epoxy composites by analyzing mechanical, thermal, and microstructural properties. Fibers underwent water-retting and drying, and were characterized via SEM and FTIR. Composites were fabricated by vacuum infusion with 55% fiber volume fraction and tested according to ASTM D638. Two epoxy systems were investigated: a rigid matrix (LY5052) and a flexible matrix (AR324). With LY5052, DT fiber incorporation led to a 101% increase in elastic modulus but caused a 26% reduction in tensile strength, attributed to stress concentration at the fiber–matrix interface and brittle matrix behavior. In contrast, composites with AR324 exhibited a 908% increase in stiffness and nearly 1000% improvement in tensile strength, enabled by superior strain compatibility between the flexible matrix and the fiber reinforcement. TGA analysis showed thermal stability above 400 °C and ~ 5% increase in residual mass due to inorganic components in DT fibers. SEM revealed predominant fiber pull-out, 40 µm voids, and resin penetration into the fiber lumen. These findings highlight the importance of matrix selection in maximizing the mechanical potential of natural fibers. DT/epoxy composites are promising for lightweight applications, particularly when paired with ductile matrices that mitigate premature failure mechanisms.

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Low-temperature spin Seebeck effect in nonmagnetic vanadium dioxide

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Physical Review B 2024年第2期110卷 024415-024415页

作者： Renjie Luo Tanner J. Legvold Liyang Chen Henry Navarro Ali C. Basaran Deshun Hong Changjiang Liu Anand Bhattacharya Ivan K. Schuller Douglas Natelson Department of Physics and Astronomy Applied Physics Graduate Program Rice Quantum Institute Department of Physics and Center for Advanced Nanoscience Materials Science Division Department of Electrical and Computer Engineering Department of Materials Science and NanoEngineering

The spin Seebeck effect (SSE) is sensitive to thermally driven magnetic excitations in magnetic insulators. Vanadium dioxide in its insulating low-temperature phase is expected to lack magnetic degrees of freedom, as vanadium atoms are thought to form singlets upon dimerization of the vanadium chains. Instead, we find a paramagnetic SSE response in VO2 films that grows as the temperature decreases below 50 K. The field and temperature-dependent SSE voltage is qualitatively consistent with a general model of paramagnetic SSE response and inconsistent with triplet spin transport. Quantitative estimates find a spin Seebeck coefficient comparable in magnitude to that observed in strongly magnetic materials. The microscopic nature of the magnetic excitations in VO2 requires further examination.

关键词： Spin Seebeck effect Paramagnets Strongly correlated systems

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Self-Attenuating Graphene-Based Antennas Utilizing Polyvinylidene Fluoride (PVDF) Substrates

Self-Attenuating Graphene-Based Antennas Utilizing Polyvinyl...

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Microwave and Antenna Symposium (IMAS), International

作者： Josef Frankhouse Evans Addo-Mensah Uche Wejinya Department of Mechanical Engineering University of Arkansas - Fayetteville Materials Science and Engineering Graduate Program University of Arkansas - Fayetteville

ISBN: (数字)9798350356359

ISBN: (纸本)9798350356366

In this study, a Terahertz (THz) band antenna which can regulate its own resonant frequency without the requirement of manual adjustment is simulated. A polyvinylidene fluoride (PVDF) substrate is applied onto a rectangular graphene patch antenna. With a voltage potential applied onto the PVDF, the patch antenna can attenuate its frequency by physically changing the shape of the antenna, and in turn its resonant frequency. These antennas are within a 0.1 THz band between 1.32 THz to 1.22 THz measured from a radial bend of a flat surface to r = 75 μm, fitting into a return loss (S11) above -30 dB. Although the return loss did not show consistency, the resonating frequency shifted at a linear rate relative to the cylindrical bending.

关键词： Microwave antennas Patch antennas Graphene Resonant frequency Prototypes Bandwidth Bending Loss measurement Substrates Terahertz communications

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Investigation of manufacturing conditions of single roll rapidly solidified ribbon for anode materials of magnesium rechargeable batteries

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Keikinzoku/Journal of Japan Institute of Light Metals 2023年第11期73卷 537-544页

作者： Kirimoto, Yuichi Fuke, Kousuke Tsukeda, Tadayoshi Aida, Tetsuo Nemoto, Yasunori Ikeda, Minoru Tabata, Hironobu Kurihara, Hideki Suzuki, Mayumi Department of Nano and Functional Material Science Graduate School of Science and Engineering for Education University of Toyama 3190 Gofuku Toyama-shi-shiToyama Toyama930-8555 Japan Program of Materials Science and Engineering Studies in Science and Engineering Graduate School of Science and Engineering University of Toyama Toyama-shi-shiToyama Toyama Japan Faculty of Sustainable Design Academic Assembly University of Toyama Toyama-shi Toyama-shi-shiToyama Toyama Japan FLOW Science JAPAN Shizuoka Hamamatsu-shi Japan CHUETSU METAL WORKS CO. LTD Nakaniikawa-gun Toyama Japan Saitama Industrial Technology Center Saitama Kawaguchi-shi Japan Department of Mechanical Systems Engineering Faculty of Engineering Toyama Prefectural University Imizu-shi Toyama Japan

Magnesium rechargeable batteries are attracting attention as next-generation rechargeable batteries because of their resource abundance, cost, safety, and high electrical capacity per volume compared to conventional lithium-ion rechargeable batteries. Our joint research team focused not only on the electrochemically active magnesium composition of ribbon for the negative electrode materials of magnesium rechargeable batteries but also on the production process, focused on the single roll type liquid quenching and rapid solidification method, which can be produced at a lower cost. In this study, the optimal processing conditions were examined by comparing CAE analysis with ribbon actually manufactured, with the aim of further improving manufacturing conditions using the same method, such as length discontinuities, thickness, and surface properties of ribbon. We specifically various process parameters such as injection pressure and roll peripheral speed for evaluation. As a result, several linear cracks were observed on the surface of the ribbon as the peripheral speed increased and as the Gap became wider, and the surface properties tended to deteriorate. Also, It was found that the dominant factor in the length of the ribbon was the peripheral speed. As the peripheral speed increased, the length of the ribbon tended to increase. © 2023 Japan Institute of Light Metals. All rights reserved.

关键词： Surface properties

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Mo-terminated edges in two-dimensional molybdenum disulfide for site-specific hydrolysis and DNA cleavage

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materials Today 2025年 86卷 162-171页

作者： Wang, Cong Wu, Menghan Li, Muqing Zhao, Yingcan Zhao, Mingchuang Zhang, Yunhao Bai, Yichao Gao, Jianxiang Wang, Xiaoxia Tian, Xilin Zhang, Han Chang, Liang Zou, Xiaolong Liu, Bilu Kang, Feiyu Terrones, Mauricio Lei, Yu Institute of Materials Research Shenzhen Key Laboratory of Advanced Layered Materials for Value-added Applications Guangdong Provincial Key Laboratory of Thermal Management Engineering and Materials & Center of Double Helix Tsinghua Shenzhen International Graduate School Tsinghua University Shenzhen518055 China Institute of Materials Research & Shenzhen Geim Graphene Center Shenzhen Key Laboratory of Advanced Layered Materials for Value-added Applications Tsinghua-Berkeley Shenzhen Institute and Tsinghua Shenzhen International Graduate School Tsinghua University Shenzhen518055 China Environmental Science Program Department of Life Sciences Beijing Normal University-Hong Kong Baptist University United International College Guangdong519087 China Tsinghua Shenzhen International Graduate School Tsinghua University Shenzhen518055 China Department of Physics Department of Chemistry Department of Materials Sciences Center for 2-Dimensional and Layered Materials The Pennsylvania State University University ParkPA16802 United States International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education Institute of Microscale Optoelectronics Shenzhen University Shenzhen518060 China

The hydrolysis of DNA serves as the foundational principle for gene engineering that enable precise gene cleavage at the molecular level. This process typically occurs in biological nucleases, which exhibit nucleobase-selective and catalytic hydrolysis capabilities rarely replicated in abiotic nanomaterials. Here, we demonstrate that molybdenum-terminated (Mo-terminated) edges of molybdenum disulfide (MoS2) possess the unique ability to abstract a proton (H+) from water molecules, thereby facilitating catalytic hydrolysis reactions that cleave the phosphodiester bonds in DNA through the action of hydroxide ions. The enhanced proton absorption at Mo-terminated edges of MoS2 significantly reduces the activation energy required for the DNA hydrolysis reaction. Furthermore, the favorable interaction between the Mo-terminated edges and thymine nucleobases promotes both charge transfer and P-O bond cleavage, enabling targeted DNA hydrolysis at 'TTTTTTT' sequences under dark conditions. This discovery underscores the potential of MoS2 as a stable, efficient nanosystem for precise genetic editing, heralding advanced applications in the field of gene engineering. © 2025 The Author(s)

关键词： Activation energy

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