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Spray pyrolysis-derived W-doped MoSe_(2)/rGO paper-like microspheres:optimization of microstructure and mesostructure for enhanced lithium storage

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Rare Metals 2024年第7期43卷 3019-3031页

作者： Wei Wang Jun-Yu Chen Jie Ouyang Hong Yin Ao-Jie Li Liang Chen Jun-Lin Huang Yu-Can Zhu Gang-Yong Li Zhao-Hui Hou Key Laboratory of Hunan Province for Advanced Carbon-based Functional Materials Hunan Institute of Science and TechnologyYueyang 414006China School of Chemistry and Chemical Engineering Hunan Institute of Science and TechnologyYueyang414006China Hunan Province Key Laboratory of Materials Surface&Interface Science and Technology Material Science and Engineering SchoolCentral South University of Forestry and TechnologyChangsha 410004China International Iberian Nanotechnology Laboratory(INL) AvMestre Jose Veiga4715-330 BragaPortuga

Two-dimensional MoSe_(2) is a promising candidate for lithium-ion battery ***,its conductivity and lithium storage volumetric effect still need to be *** this work,W-doped MoSe_(2)/rGO paper-like microspheres are successfully prepared through ultrasonic spray pyrolysis,achieving optimization at both the microstructure and mesostructure to enhance the lithium storage performance of the ***,by utilizing the similar two-dimensional structure between MoSe_(2) and rGO,self-assembly is achieved through spray pyrolysis,resulting in a well-defined van der Waals heterostructure at the interface on the microscale,enhancing the electron and ion transfer capability of the ***,the mesoscale paper-like microsphere morphology provides additional volume expansion buffering ***,W-doping not only increases the interlayer spacing of MoSe_(2)(0.73 nm),thereby reducing the diffusion resistance of Li+,but also allow for the modulation of the energy band structure of the *** functional theory(DFT)calculations confirm that W-doped MoSe_(2)/rGO exhibits the narrowest bandgap(0.892 eV).Therefore,the composite demonstrates excellent lithium storage performance,maintaining a specific capacity of 732.9 mAh·g^(-1)after 300 cycles at a current density of 1 A·g^(-1).

关键词： Molybdenum selenide Heterostructure Microspheres Li-ion batteries Kinetics

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Creating Sodium Ion Channels via De Novo Encapsulation of Ionophores for Enhanced Water Energy Harvesting

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Advanced materials 2025年第0期 e2420636页

作者： Guo, Qing Xing, Zhiwei Guo, Huaxi Lai, Zhuozhi Yi, Jiaming Wu, Di Dai, Zhifeng Zhang, Li Wang, Sai Ma, Shengqian Q., Sun Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology College of Chemical and Biological Engineering Zhejiang University Hangzhou310027 China Key Laboratory of Surface & Interface Science of Polymer Materials of Zhejiang Province School of Chemistry and Chemical Engineering Zhejiang Sci-Tech University Hangzhou310018 China Hangzhou Institute of Advanced Studies Zhejiang Normal University Hangzhou311231 China Department of Chemistry University of North Texas 1508 W Mulberry St DentonTX76201 United States

Biological ion channels achieve remarkable permselectivity and cation discrimination through the synergy of their intricate architectures and specialized ionophores within confined nanospaces, enabling efficient energy conversion. Emulating such selectivity in synthetic nanochannels, however, remains a persistent challenge. To address this, a novel host-guest assembly membrane is developed by incorporating sodium-selective ionophores into a β-ketoenamine-linked covalent organic framework (COF). This design confers exceptional permselectivity and Na+ selectivity, achieving Na+/K+ and Na+/Li+ selectivity ratios of 3.6 and 103, respectively, along with near-perfect Na+/Cl− selectivity under a 0.5 M || 0.01 M salinity gradient. Notably, the membrane dynamically switches its permselectivity to favor anion transport in the presence of high-valent cations (e.g., Ca2+), overcoming limitations such as uphill cation diffusion and back currents observed in conventional cation-selective membranes. This adaptive behavior yields a 4.6-fold increase in output power density in Ca2+-rich environments. These findings advance the design of biomimetic nanochannels with unparalleled ion selectivity and enhanced energy conversion efficiency. © 2025 Wiley-VCH GmbH.

关键词： Ionophores

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Progress of copper-based friction materials for high-speed train: Tribological property involving components, interfaces, and tribo-layers

Review of Materials Research

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Review of materials Research 2025年第1期1卷

作者： Yuxuan Xu Haibin Zhou Qi Chen Donglin Liu Yong Han Minwen Deng Pingping Yao State Key Laboratory of Powder Metallurgy Central South University Changsha 410083 China Hunan Province Key Laboratory of Materials Surface/Interface Science & Technology Central South University of Forestry and Technology Changsha 410004 China

With the continuous increase in operating speed of high-speed trains, enhanced safety and stability in braking systems are necessitated. Copper-based friction materials (CBFMs) are predominantly utilized in brake pads for high-speed trains exceeding 300 km/h. Substantial braking energy is dissipated by CBFMs through direct interaction with counterpart materials, and their pivotal role in maintaining the safety and reliability of high-speed braking systems is ensured. The components and intrinsic properties, the multiple variations at the interface, and the distinctive characteristics of brake conditions are regarded as the primary factors influencing the braking properties of CBFMs. Recent advancements in CBFMs and tribological properties are systematically explored in this review from three critical perspectives: components, interfaces, and tribo-layers. Firstly, the emerging trends in matrix, lubricant components, and abrasive components in CBFMs are detailed. Secondly, the correlation between interfacial and tribological properties at both micro and macro scales is investigated. Thirdly, the characteristics of tribo-layers at different scales and the associated wear mechanisms of CBFMs are examined. Lastly, the challenges CBFMs face and the constraints of multi-component synergistic design, evaluation methodologies, and novel wear mechanisms are highlighted.

关键词： Copper-based friction materials High-speed train brake Tribological property Components interfaces Tribo-layers

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Interlayer engineering in 3D graphene skeleton realizing tunable electronic properties at a highly controllable level for piezoresistive sensors

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Nano Research 2023年第7期16卷 8512-8521页

作者： Xunxiang Hu Lingling Tan Xianzhang Wu Jinqing Wang College of Material Science and Engineering Hunan Province Key Laboratory of Materials Surface&Interface Science and TechnologyCentral South University of Forestry and TechnologyChangsha 410004China State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhou 730000China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China

Three-dimensional(3D)graphene is a promising active component for various engineering fields,but its performance is limited by the hidebound electrical conductivity levels and hindered electrical *** we present a novel approach based on interlayer engineering,in which graphene oxide(GO)nanosheets are covalently functionalized with varied molecular lengths of diamine *** has led to the creation of an unprecedented class of 3D graphene with highly adjustable electronic *** calculations and experimental results demonstrate that ethylenediamine,with its small diameter acting as a molecular bridge for facilitating electron transport,has the potential to significantly improve the electrical conductivity of 3D *** contrast,butylene diamine,with its larger diameter,has a reverse effect due to the enlarged spacing of the graphene interlayers,resulting in conductive *** importantly,the moderate conductive level of 3D graphene can be achieved by combining the interlayer spacing expansion effect and theπ-electronic donor ability of aromatic *** resulting 3D graphene exhibits highly tunable electronic properties,which can be easily adjusted in a wide range of 2.56-6.61 S·cm^(-1)compared to pristine GO foam(4.20 S·cm^(-1)).This opens up new possibilities for its use as an active material in a piezoresistive sensor,as it offers remarkable monitoring abilities.

关键词： graphene tunable electronic properties multifunctional composites piezoresistive sensor

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Electronic and Thermoelectric Properties in SnS-Nanoribbon-Based Heterojunctions

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Chinese Physics Letters 2024年第9期41卷 63-68页

作者： Kai-Bo Zhang Shi-Hua Tan Xiao-Fang Peng Meng-Qiu Long Hunan Province Key Laboratory of Materials Surface or Interface Science and Technology Central South University of Forestry and TechnologyChangsha 410004China School of Physics and Electronics Central South UniversityChangsha 410083China

As an earth-abundant and environmentally friendly material,tin sulfide(SnS)is not only a high-performance photovoltaic material,but also a new promising thermoelectric *** extensive research on the thermoelectric properties of this material in recent years,the room-temperature thermoelectric figure of merit(ZT)of SnS has not been broke through 2[2022 *** Mater.651143].In this work,based on a combination of density functional theory and non-equilibrium Green’s function method,the electronic and thermoelectric properties in SnS-nanoribbon-based heterojunctions are *** results show that although SnS nanoribbons(SNSNRs)with zigzag edges(ZSNSNRs)and armchair edges(ASNSNRs)both have semiconductor properties,the bandgaps of ASNSNRs are much wider than those of ZSNSNRs,which induces much wider conductance gaps of𝑁N-ASNSNR(N is the number of tin-sulfide lines across the ribbon width)).In the positive energy region,the ZT peaks of𝐿L-SNS-Au are much larger than those of𝐿L-SNS-GNR(L represents the number of longitudinal repeating units of SNSNR in the scattering region).While in the positive energy region,the ZT peaks of L-SNSGNR are larger than those of *** calculations reveal that the figure of merit will be over 3.7 in L-SNS-Au and 2.2 in L-SNS-GNR at room temperature,and over 4 in L-SNS-Au and 2.6 in L-SNS-GNR at 500 K.

关键词： material sulfide ribbon

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In-Situ Supramolecular Self-Assembly Strategy to Fabricate Carbon-Doped G-C3n4 Microtubes: Efficient Photocatalytic Removal of Antibiotics and Bacterial Inactivation

SSRN

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SSRN 2025年

作者： Lei, Hua Bian, Changhao Guo, Fengyu Xiao, Xingning Lin, Jianhan Wang, Wen Yang, Hua Dong, Xiaoping Hu, Ruibin Xianghu Laboratory Hangzhou311231 China Key Laboratory of Agricultural Information Acquisition Technology Ministry of Agriculture and Rural Affairs China Agricultural University Beijing100083 China School of Chemistry and Chemical Engineering Key Laboratory of Surface & Interface Science of Polymer Materials of Zhejiang Province Zhejiang Sci-Tech University Hangzhou310018 China Institute of Agro-Product Safety and Nutrition Zhejiang Academy of Agricultural-Sciences Hangzhou310021 China Key Laboratory of Microbiological Metrology Measurement & Bio-product Quality Security State Administration for Market Regulation College of Life Sciences China Jiliang University Hangzhou310018 China

The poor utilization of visible light and the rapid recombination of charge carriers in graphitic carbon nitride (g-C3N4) constrain its application for photocatalytic degradation of antibiotics and sterilization. In this study, a hydrogen bond-induced supramolecular self-assembly strategy was developed to fabricate carbon-doped g-C3N4 microtubes (CTCN) through the pyrolysis method. Specifically, 2,4,6-triaminopyrimidine as a dopant to replace a portion of melamine and co-assemble with cyanuric acid. Compared to bulk g-C3N4, CTCN displayed advantageous visible light absorption capability and enhanced charge carrier separation and transfer efficiency. CTCN demonstrated superior photocatalytic degradation of tetracycline hydrochloride (TC), achieving an efficiency of 99.2% in 18 min. It achieved reaction kinetics (~0.261 min-1) was up to 26.6 times higher than that of bulk g-C3N4. Additionally, CTCN exhibited almost complete photocatalytic antibacterial efficacy, inactivating ~100% of bacteria (including Escherichia coli, Salmonella typhimurium, and Pseudomonas aeruginosa) within 120 min. The mechanism underlying the photocatalytic degradation of TC and the possible degradation pathways were proposed, where the superoxide radical was considered to exert a predominant function. Toxicity assessment of TC and its intermediates revealed that the degradation of TC was a gradual detoxification course. This study presents a novel self-assembly strategy for the design and fabrication of highly active and durable visible-light-responsive photocatalysts, which can effectively degrade antibiotics and kill bacteria. © 2025, The Authors. All rights reserved.

关键词： Escherichia coli

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Built-in piezoelectric field improved photocatalytic performance of nanoflower-like Bi_(2)WO_(6) using low-power white LEDs

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Chinese Chemical Letters 2021年第7期32卷 2317-2321页

作者： Hua Lei Meixuan Wu Ying Liu Fan Mo Jiayao Chen Shilong Ji Yan Zou Xiaoping Dong Department of Chemistry Key Laboratory of Surface&Interface Science of Polymer Materials of Zhejiang ProvinceZhejiang Sci-Tech UniversityXiasha Higher Education ZoneHangzhou 310018China

Photocatalysis technology has been proved to be a potential strategy for removal of organic dyes,however high-power light sources are generally necessary to initiate photocatalytic *** this work,we employed an excellent photocatalyst of Bi_(2)WO_(6) with visible light harvest and meanwhile an intrinsic ferroelectricity,which realized the efficient degradation of organic dye via the synergetic *** coupling the illumination by a low-power(9 W)LED and the ultrasonic vibration(120 W)by an ultrasonic cleaner,the nano flower-like Bi_(2)WO_(6) composed of ultrathin nanosheets showed a much more enhanced photopiezocatalysis performance for purification of organic dye than the individual photocatalysis and ***,the high mineralization efficiency and the good durability of the Bi_(2)WO_(6) catalyst were *** possible mechanism of photopiezocatalysis was finally proposed,where the ultrasound-induced piezoelectric field in Bi_(2)WO_(6) drove photo-generated electrons and holes to diffuse along opposite directions,consequently promoting the separation efficiency of charge *** work indicates that the synergetic photopiezocatalysis by coupling irradiation and ultrasonic vibration is a promising strategy to purify organic pollutants in wastewater.

关键词： Photopiezocatalysis LED illumination Ultrasonic vibration Piezoelectric effect Dye degradation

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CoS_(2)/N,S co-doped mesoporous carbon with 3D micro-nano crosslinked structure as efficient bifunctional oxygen electrocatalysts for zinc-air batteries

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Chinese Chemical Letters 2023年第5期34卷 604-609页

作者： Wei Wang Liqin Li Jie Ouyang Jialin Gong Jie Tian Liang Chen Junlin Huang Binhong He Zhaohui Hou Key Laboratory of Hunan Province for Advanced Carbon-based Functional Materials School of Chemistry and Chemical EngineeringHunan Institute of Science and TechnologyYueyang 414006China Guangxi Key Laboratory of Low Energy Material Guangxi Normal UniversityGuilin 541004China Hubei Key Laboratory of Pollutant Analysis&Reuse Technology Hubei Normal UniversityHuangshi 435002China Hunan Province Key Laboratory of Materials Surface&Interface Science and Technology Material Science and Engineering SchoolCentral South University of Forestry and TechnologyChangsha 410004China

This work describes a bifunctional oxygen catalyst made of cobalt disulfide encapsulated in N,S codoped mesoporous carbon with a novel three-dimensional micro-nano crosslinking *** proposed composite materials exhibit promising oxygen electrocatalytic activity and *** composite assembled rechargeable zinc-air battery can achieve a high power density of 208.9 m W/cm^(2),and can be stably cycled for more than 160 ***,the all-solid zinc-air battery assembled with the electrocatalyst also performs *** micro-nano crosslinking and high porosity structure,as well as the large number of active sites generated by the synergy of N,S doping and the close interface between carbon matrix and CoS_(2),contribute to the composite's exceptional electrochemical *** study's rational strategy lays the path for the development of other high-performance bifunctional electrocatalysts.

关键词： Micro-nano crosslinked CoS_2 ORR OER Zn-air battery

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Li-ion charge storage performance of wood-derived carbon fibers@MnO as a battery anode

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Chinese Chemical Letters 2022年第2期33卷 1091-1094页

作者： Qinyuan Huang Jinbo Hu Mei Zhang Mengxiao Li Ting Li Guangming Yuan Yuan Liu Xiang Zhang Xiaowei Cheng College of Materials Science and Engineering Central South University of Forestry and TechnologyChangsha 410004China Hunan Province Key Laboratory of Materials Surface&Interface Science and Technology Central South University of Forestry and TechnologyChangsha 410004China Hunan Taohuajiang Bamboo Science&Technology Co. Ltd.Taojiang 413400China Department Chemistry Fudan UniversityShanghai 200433China

Wood-derived carbons have been demonstrated to have large specific capacities as the anode materials of lithium-ion batteries(LIBs). However, these carbons generally show low tap density and minor volumetric capacity because of high specific surface area and pore volume. Combination with metal oxide is one of the expected methods to alleviate the obstacles of wood-derived carbons. In this work, the composites of Mn O loaded wood-derived carbon fibers(CF@Mn O) were prepared via a simple and environmentally friendly method, showing decreased specific surface area due to the generation of Mn O nanoparticles on carbon fibers. Furthermore, the CF@Mn O compostites exhibit superior electrochemical performance as anode materials of LIBs, which show high reversible capacity in the range of 529-734 m Ah/g at a current density of 100 m A/g. The optimal CF@Mn O product(Mn O:carbon = 1:2) delivers reversible capacity of 734 and 265.3 m Ah/g at current density of 100 and 2000 m A/g, respectively. Besides, the material presents outstanding stability with coulombic efficiency around 100% after 200 cycles at a high current density of 400 m A/g, revealing a potential as promising anode materials for high-performance LIBs.

关键词： Wood-derived carbons Environmentally friendly MnO nanoparticles Anode materials Lithium-ion batteries

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Accelerating solar driven CO_(2) reduction via sulfur-doping boosted water dissociation and proton transfer

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Nano Research 2024年第3期17卷 1056-1065页

作者： Ke Yan Liang Chen Yangguang Hu Ting Wang Cong Chen Chao Gao Youju Huang Benxia Li School of Chemistry and Chemical Engineering Key Laboratory of Surface&Interface Science of Polymer Materials of Zhejiang ProvinceZhejiang Sci-Tech UniversityHangzhou 310018China College of Material Chemistry and Chemical EngineeringKey Laboratory of Organosilicon Chemistry and Material TechnologyMinistry of EducationHangzhou Normal UniversityHangzhou 311121China School of Chemistry and Materials Science University of Science and Technology of ChinaHefei 230026China

Exploring efficient photocatalysts for solar driven CO_(2) reduction with water(H_(2)O)as a proton donor is highly imperative but remains a great challenge because the synchronous enhancement of CO_(2) activation,H_(2)O dissociation and proton transfer is hardly achieved on a ***,the sluggish H_(2)O dissociation impedes the photocatalytic CO_(2) reduction reaction involving multiple proton–electron coupling transfer ***,a sulfur-doped BiOCl(S-BiOCl)photocatalyst with abundant oxygen vacancies(OV)is developed,which exhibits broadband-light harvesting across solar spectrum and distinct photothermal effect due to *** photocatalytic CO_(2) reduction with H_(2)O in a gas–solid system,the high CO yield of 49.76μmol·g_(cat)^(-1)·h^(-1) with 100%selectivity is achieved over the S-BiOCl catalyst under a simulated *** H_(2)O-assisted CO_(2) reduction reaction on S-BiOCl catalyst is triggered by photocatalysis and the photothermal heating further enhances the reaction *** kinetic isotope experiments indicate that the sluggish H_(2)O dissociation affects the whole photocatalytic CO_(2) reduction *** presence of oxygen vacancies promotes the adsorption and activation of H_(2)O and CO_(2),and the doped S sites play a crucial role in boosting H_(2)O dissociation and accelerating the dynamic migration of hydrogen *** a result,the ingenious integration of OV defects,S sites and photothermal effect in S-BiOCl catalyst conjointly contributes to the significant improvement in photocatalytic CO_(2) reduction performance.

关键词： BiOCl sulfur doping photocatalytic CO_(2)reduction H_(2)O activation proton feeding

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