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Correction: N-doped carbon nanoparticles on highly porous carbon nanofiber electrodes for sodium ion batteries

RSC advances 2025年第8期15卷 6370页

作者： Meltem Yanilmaz Bülin Atıcı Jiadeng Zhu Ozan Toprakci Juran Kim Nano-Science and Nano-Engineering Program Graduate School of Science Engineering and Technology Istanbul Technical University Istanbul 34469 Turkey yanilmaz@itu.edu.tr. Textile Engineering Istanbul Technical University Istanbul 34469 Turkey. Smart Devices Brewer Science Inc. Springfield MO 65806 USA. Department of Polymer Materials Engineering Yalova University 77200 Yalova Turkey. Advanced Textile R&D Department Korea Institute of Industrial Technology (KITECH) Ansan 15588 Korea jkim0106@kitech.re.kr.

[This corrects the article DOI: 10.1039/D3RA00635B.].

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Block Copolymer Thin Films Above and Below the Order-Disorder Transition Temperature

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MRS Online Proceedings Library 2011年第1期629卷 1-6页

作者： Ratchana Limary Peter F. Green Dept. of Chemical Engineering and the Graduate Program in Materials Science The University of Texas at Austin Austin USA

Symmetric diblock copolymers undergo a disorder to order transition below a microphase separation transition temperature. In this temperature range the structure is characterized by alternating lamellae of thickness L. In thin film geometries, the lamellae are oriented normal to the substrate if there is a preferential interaction between either of the block constituents and the substrate/copolymer or copolymer/vacuum interfaces. Depending on the relation between the film thickness and L, the topography of the film might comprise of holes, islands or spinodal-like structures. We show that in a polystyrene-b-poly(methyl methacrylate) diblock copolymer of molecular weight 20, 000 g/mol, above the microphase separation transition temperature, the topography of the film depends on the thickness. A heirarchy of bicontinuous patterns and holes is observed with increasing film thickness for films thinner than 35 nm.

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The Alumina Film Nanomorphology Formed to Improve the Corrosion Resistance of Al-2.0 wt% Fe Alloy as Result of the Laser Surface Melting Technique Applied

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Advances in Chemical engineering and science 2017年第1期7卷 10-22页

作者： Moises Meza Pariona Katieli Tives Micene Graduate Program in Engineering and Materials Science State University of Ponta Grossa (UEPG) Ponta Grossa Brazil

The laser surface remelting (LSR) treatment was performed to Al-2.0 wt% Fe alloy with a 2 kW Yb-fiber laser (IPG YLR-2000S). The substrate and laser-treated material characterization were executed using different techniques. Among them, the microstructure was analyzed by optical microscope, SEM, low-angle X-ray diffraction (LAXRD) and the corrosion test was made in aerated solution of 0.1 M H2SO4 at a temperature of 25°C ± 0.5°C. As result was shown, the micrograph of LSR-treated material displaying can be a fine cellular structure and the existence of certain nano-porosities and a similar to a nano-dendritic growth was observed too. The characteristic of melted zone was constituted of metastable phases according to the result of x-rays and the behavior corrosion as a result of the LSR-treated sample, which it was shown to be more resistant to corrosion than the untreated sample. A comparative study was carried out of the cyclic polarization of the laser-treated and untreated samples, demonstrating that the reduction and oxidation reverse peaks were not observed and being the cyclic polarization behavior was of irreversible character in both samples, however, the LSR-treated sample propitious the passivity on the surface also reduced the corrosion phenomena. Wherefore, this type of laser-treated alloy can be applied in the aerospace, aeronautic and automobilist industries.

关键词： Al-2.0 wt% Fe Alloy Laser-Treated Microstructure Low-Angle X-Ray Diffraction Cyclical Polarization

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Effect of Surface Roughness on the Magnetism, Nano-indentation, Surface Energy, and Electrical Properties of Co60Fe20Dy20 Films on Si (100) Substrate

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Journal of Electronic materials 2024年第4期53卷 1752-1762页

作者： Liu, Wen-Jen Chang, Yung-Huang Chiang, Chia-Chin Chen, Yuan-Tsung Lin, Chih-Chien Chen, Pei-Ling Lin, Shih-Hung Department of Materials Science and Engineering I-Shou University Kaohsiung840 Taiwan Bachelor Program in Industrial Technology National Yunlin University of Science and Technology 123 University Road Section 3 Yunlin Douliou64002 Taiwan Department of Mechanical Engineering National Kaohsiung University of Science and Technology Kaohsiung City80778 Taiwan Graduate School of Materials Science National Yunlin University of Science and Technology 123 University Road Section 3 Yunlin Douliou64002 Taiwan Department of Electronic Engineering National Yunlin University of Science and Technology 123 University Road Section 3 Yunlin Douliou64002 Taiwan

In this study, we focused on depositing a target material, cobalt-iron-dysprosium (Co60Fe20Dy20), onto silicon (Si) (100) substrates with thickness varying from 10 nm to 50 nm through a direct-current (DC) magnetron sputtering technique. The subsequent step involved subjecting the samples to an hour-long annealing process in a vacuum annealing furnace at temperatures of 100°C, 200°C, and 300°C. To assess the elemental composition of the CoFeDy films, energy-dispersive X-ray spectroscopy (EDS) was employed. An observed trend indicated an increase in low-frequency alternating-current magnetic susceptibility (χac) with the increasing thickness. Remarkably, the CoFeDy films exhibited their peak χac following annealing at 300°C, with an optimal resonance frequency of 50 Hz. After annealing at 300°C, the CoFeDy film’s surface energy peaked at 50 nm. The magnetic, electrical, and adhesive properties of the CoFeDy films were notably influenced by surface roughness at different annealing temperatures. Atomic force microscopy (AFM) analysis revealed a gradual reduction in film roughness post-annealing, corresponding to smoother surfaces indicative of a weaker domain wall pinning effect, heightened carrier conductivity, and increased liquid spreading. Collectively, these outcomes contributed to diminished χac, reduced electrical resistance, and enhanced adhesion. Graphical Abstract: (Figure presented.) © The Minerals, Metals & materials Society 2024.

关键词： Adhesion

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A Thermally Stable, Infrared-Transparent High-Sulfur-Containing Polymer for High Aspect-Ratio Nanostructured MWIR Polarizer

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Small 2025年 e2504090页

作者： Kang, Minjeong Jang, Wontae Lee, Junghyun Kim, Sanghyun Lee, Gyuwon Choi, Keonwoo Kim, Jun Oh Ku, Zahyun Ahn, Junhyoung Lim, Hyungjun Lim, Jeewoo Wie, Jeong Jae Im, Sung Gap Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology (KAIST) 291 Daehak-ro Yuseong-gu Daejeon 34141 South Korea Advanced Instrumentation Institute Korea Research Institute of Standards and Science 267 Gajeong-ro Yuseong-gu Daejeon 34113 South Korea Apex Microdevices 4871 Misrach Ct West Chester 45069 OH United States Department of Nano Manufacturing Technology Korea Institute of Machinery & Materials (KIMM) 156 Gajeongbuk-ro Yuseong-gu Daejeon 34103 South Korea Department of Chemistry and Research Institute for Basic Science Kyung Hee University 26 Kyungheedae-ro Dongdaemun-gu Seoul 02447 South Korea Human-Tech Convergence Program Hanyang University 222 Wangsimni-ro Seongdong-gu Seoul 04763 South Korea Department of Chemical Engineering State University of New York College of Environmental Sciences and Forestry Syracuse NY 13210 United States Graduate school of Semiconductor Technology Korea Advanced Institute of Science and Technology (KAIST) 291 Daehak-ro Yuseong-gu Daejeon 34141 South Korea

Infrared (IR) polarizer is essential for thermal imaging applications such as mobility and military operations. High-sulfur-containing polymers have emerged as promising candidates for IR polarizers due to their mid-wave IR (MWIR) transparency, addressing the limitations of inorganic materials, including their brittleness and high cost. However, poor thermal stability and limited IR range restrict their applicability. This study introduces a glassy IR polarizer based on poly(sulfur-co-hexavinyl disiloxane) (pSHVDS), a highly crosslinked sulfur-rich polymer synthesized via sulfur chemical vapor deposition (sCVD). Self-crosslinking of pSHVDS at high temperatures provided thermal stability during nanoimprint lithography, enabling the fabrication of high-fidelity nano-grating patterns (400 nm pitch, 150 nm width, 300 nm height). The broad transmittance and high aspect ratio of the nanopattern enabled the glassy-pSHVDS MWIR polarizer to achieve over 50% transmittance of transverse magnetic field (T_TM) and an extinction ratio (ER) exceeding 6000 across a broad IR range (3-8 µm). An additional pSHVDS anti-reflection coating further enhanced T_TM to 84% and ER to 7200 at a wavelength of 4 µm, the highest ER reported for organic MWIR polarizers to date. The polarizer maintained its performance after 24 h at 100 °C, demonstrating exceptional thermal stability. These findings underscore the potential of glassy pSHVDS-based polarizers for IR applications. © 2025 Wiley-VCH GmbH.

关键词： bilayer wire grid polarizer high sulfur-content polymer (HSCP) MWIR polarizer sulfur chemical vapor deposition (sCVD) thermal stability

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On-Chip Perovskite Nanocrystal Laser Integrated with Long-Range Surface Plasmon Polariton Waveguide by Etching-Free Lithographic Patterning

On-Chip Perovskite Nanocrystal Laser Integrated with Long-Ra...

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2022 JSAP-Optica Joint Symposia, JSAP 2022

作者： Lee, Yang-Chun Lin, Hsin-Chang Lin, Cheng-Chieh Ho, Ya-Lun Xing, Di Chen, Mu-Hsin Lin, Bo-Wei Chen, Li-Yin Chen, Chun-Wei Delaunay, Jean-Jacques School of Engineering The University of Tokyo Japan Department of Photonics National Sun Yat-sen University Taiwan International Graduate Program of Molecular Science and Technology National Taiwan University Academia Sinica Taiwan Department of Materials Science and Engineering National Taiwan University Taiwan Molecular Science and Technology Program Taiwan International Graduate Program Academia Sinica Taiwan Department of Photonics National Yang Ming Chiao Tung University Taiwan Center of Atomic Initiative for New Materials National Taiwan University Taiwan

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Plasmonic Nanolaser by Silver Nanowire Embedded in CsPbBr3 Quantum Dots

Plasmonic Nanolaser by Silver Nanowire Embedded in CsPbBr3 Q...

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JSAP-OSA Joint Symposia, JSAP 2021

作者： Xing, Di Lin, Cheng-Chieh Won, Phillip Xiang, Rong Chen, Tzu-Pei A. Kamal, A. Syazwan Lee, Yang-Chun Ho, Ya-Lun Maruyama, Shigeo Ko, Seung Hwan Chen, Chun-Wei Delaunay, Jean-Jacques School of Engineering The University of Tokyo Japan International Graduate Program of Molecular Science and Technology National Taiwan University Taiwan Department of Materials Science and Engineering National Taiwan University Taiwan Department of Mechanical Engineering Seoul National University Korea Republic of Center of Atomic Initiative for New Materials National Taiwan University Taiwan

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Effects of nanopores and sulfur doping on hierarchically bunched carbon fibers to protect lithium metal anode

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Carbon Energy 2021年第5期3卷 784-794页

作者： Ji In Jung Sunwoo Park Son Ha Se Youn Cho Hyoung-Joon Jin Young Soo Yun Program in Environmental and Polymer Engineering Inha UniversityIncheonSouth Korea KU-KIST Graduate School of Converging Science and Technology Korea UniversitySeoulSouth Korea Carbon Composite Materials Research Center Korea Institute of Science and TechnologyWanju-gunJeollabuk-doSouth Korea Department of Polymer Science and Engineering Inha UniversityIncheonSouth Korea Department of Integrative Energy Engineering Korea UniversitySeoulSouth Korea

Studies on three-dimensional structured carbon templates have focused on how to guide homogeneous lithium metal nucleation and growth for lithium metal anodes(LMAs).However,there is still insufficient evidence for a key factor to achieve their high electrochemical ***,the effects of nanopores and sulfur doping on carbon-based nanoporous host(CNH)electrode materials for LMAs were investigated using natural polymer-derived *** pore-filling behaviors of lithium metal in the nanopores of the CNH electrode materials were first observed by ex situ scanning electron microscopy analysis,where the protective lithium metal nucleation and growth process led to significantly high Coulombic efficiency(CE)of~99.4%and stable 600 *** addition,a comparison study of CNH and sulfurdoped CNH(S-CNH)electrodes,which differ only in the presence or absence of sulfur,revealed that sulfur doping can cause lower electrochemical series resistance,higher CE value,and better cycling stability in a wide range of current densities and number of ***,S-CNH-based LMAs showed high electrochemical performance in full-cell Li-S battery tests using a sulfur copolymer cathode,where a high energy density of 1370Wh kgelectrode−1 and an excellent power density of 4120Wkgelectrode−1 were obtained.

关键词： carbon template Li-S batteries lithium metal anode lithium metal batteries nanoporous carbon sulfur doping

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Characterizations of trimetallic heteronuclear Bi1-xLa x[Fe(CN)6]·n(H2O) complexes and their thermal decomposition products

Characterizations of trimetallic heteronuclear Bi1-xLa x[Fe(...

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作者： Aono, Hiromichi Kondo, Nobuyuki Katagishi, Haruo Kurihara, Masato Sakamoto, Masatomi Sadaoka, Yoshihiko Department of Materials Science and Engineering Faculty of Engineering Ehime University Matsuyama 790-8577 Japan Graduate Program of Human Sensing and Functional Sensor Engineering Graduate School of Science and Engineering Yamagata University Yamagata 990-8560 Japan Department of Material and Biological Chemistry Faculty of Science Yamagata University Yamagata 990-8560 Japan

Heteronuclear Bi1-x La x [Fe(CN)6] &middotnH2O complexes were synthesized, and their crystal structures and thermal decomposition process were investigated by X-ray diffraction (XRD), thermogravimetry analysis (TG... 详细信息

Heteronuclear Bi1-x La x [Fe(CN)6] ·nH2O complexes were synthesized, and their crystal structures and thermal decomposition process were investigated by X-ray diffraction (XRD), thermogravimetry analysis (TGA), Auger electron spectroscopy (AES) with scanning electron microscope (SEM), and transmission electron microscopy (TEM). The crystal system of the complexes was orthorhombic having n = 4 for x = 0-0.7 and was hexagonal having n = 5 for x = 1.0. Their mixture was confirmed for x = 0.8 and 0.9. The lattice parameters for the orthorhombic increased with increasing the x value for the complexes. The single phase of trimetallic perovskite-type Bi1-x La x FeO3 was obtained by its thermal decomposition at low temperature. The crystal system was hexagonal for BiFeO3 (x = 0) and orthorhombic for x = 0.1-1.0. In the case of the decomposed perovskite sample, the lattice parameters decreased with increasing x values for Bi1-x La x FeO3. The particle size was ca. 30 nm for Bi0.2La0.8FeO3 obtained by thermal decomposition at 500 °C and it grew with an increase in decomposition temperature. For the Bi0.5La0.5FeO 3, AES showed that the elemental distributions of Bi, La, and Fe on the surface were very homogeneous for the sample decomposed at 700 °C.

关键词： Bismuth compounds

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Pueraria lobata (Kudzu) photosystem i improves the photoelectrochemical performance of silicon

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Industrial Biotechnology 2013年第1期9卷 37-41页

作者： Gunther, Darlene Leblanc, Gabriel Cliffel, David E. Kane Jennings, G. Interdisciplinary Materials Science Graduate Program Vanderbilt University Nashville TN United States Department of Chemistry Vanderbilt University Nashville TN United States Department of Chemical and Biomolecular Engineering Vanderbilt University 2301 Vanderbilt Place Nashville TN 37235 United States

Photosystem I (PSI), a protein complex found within the thylakoid membrane of green plants and some bacteria, drives nature's 90-terawatt solar energy conversion process known as photosynthesis. Kudzu (Pueraria lobata) is an invasive vine from eastern Asia that grows in the southern United States, spreading at ∼500 km2 per year and causing extensive environmental damage. This article reports the first integration of nature's optimized solar energy converter-PSI from the fast-growing, invasive leaves of kudzu-with the ubiquitous platform of integrated circuits-silicon-to prepare a "wet" photoelectrochemical cell. Herein, we report on the success of PSI films extracted from the kudzu leaf and deposited on boron-doped silicon (p-Si) to enhance photoelectrochemical current over p-Si alone. © 2013, Mary Ann Liebert, Inc.

关键词： Solar energy

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