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Inside Cover: Dithienyl Acenedithiophenediones as New π-Extended Quinoidal Cores: Synthesis and Properties (Chem. Eur. J. 19/2017)

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Chemistry – A European Journal 2017年第19期23卷 4465-4465页

作者： Dr. Kohsuke Kawabata Prof. Dr. Itaru Osaka Masanori Sawamoto Dr. José L. Zafra Dr. Paula Mayorga Burrezo Prof. Dr. Juan Casado Dr. Kazuo Takimiya Emergent Molecular Function Research Group RIKEN Center for Emergent Matter Science Wako Saitama 351-0198 Japan Current address: Department of Chemical and Environmental Engineering Yale University New Haven Connecticut 06511 USA Current address: Department of Applied Chemistry Graduate School of Engineering Hiroshima University Higashi-Hiroshima 739-8527 Japan Program in Physics and Functional Materials Science Graduate School of Science and Engineering Saitama University Saitama 338-8570 Japan Department of Physical Chemistry Faculty of Science University of Málaga Campus de Teatinos s/n Málaga Spain

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Publisher Correction: Alpha-synuclein facilitates to form short unconventional microtubules that have a unique function in the axonal transport

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Scientific reports 2018年第1期8卷 8019页

作者： Shiori Toba Mingyue Jin Masami Yamada Kanako Kumamoto Sakiko Matsumoto Takuo Yasunaga Yuko Fukunaga Atsuo Miyazawa Sakiko Fujita Kyoko Itoh Shinji Fushiki Hiroaki Kojima Hideki Wanibuchi Yoshiyuki Arai Takeharu Nagai Shinji Hirotsune Department of Genetic Disease Research Osaka City University Graduate School of Medicine Asahi-machi 1-4-3 Abeno Osaka 545-8585 Japan. Department of Bioscience and Bioinformatics Faculty of Computer Science and Systems Engineering Kyushu Institute of Technology Kawazu 680-4 Iizuka Fukuoka 820-850 Japan. JST-SENTAN 4-1-8 Honcho Kawaguchi Saitama 332-0012 Japan. JST-CREST 4-1-8 Honcho Kawaguchi Saitama 332-0012 Japan. Graduate School of Life Science University of Hyogo 3-2-1 Kouto Kamigori-cho Ako-gun Hyogo 678-1297 Japan. RSC-University of Hyogo Leading Program Center RIKEN SPring-8 Center 1-1-1 Kouto Sayo-cho Sayo-gun Hyogo 679-5148 Japan. Graduate School of Materials Science Nara Institute of Science and Technology 8916-5 Takayama Ikoma Nara 630-0101 Japan. Department of Pathology and Applied Neurobiology Kyoto Prefectural University of Medicine Graduate School of Medical Sciences Kajii-cho Kawaramachi-Hirokoji Kamigyo-ku Kyoto 602-8566 Japan. Advanced ICT Research Institute National Institute of Information and Communications Technology 588-2 Iwaoka Nishi-ku Kobe 651-2492 Japan. Department of Pathology Osaka City University Graduate School of Medicine Asahi-machi 1-4-3 Abeno Osaka 545-8586 Japan. Department of Biomolecular Science and Engineering Institute of Scientific and Industrial Research Osaka University Mihoga-oka 8-1 Osaka 567-0047 Japan. Department of Genetic Disease Research Osaka City University Graduate School of Medicine Asahi-machi 1-4-3 Abeno Osaka 545-8585 Japan. shinjih@med.osaka-cu.ac.jp.

A correction to this article has been published and is linked from the HTML and PDF versions of this paper. The error has not been fixed in the paper.

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Random close packing in protein cores

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Physical Review E 2016年第3期93卷 032415-032415页

作者： Jennifer C. Gaines W. Wendell Smith Lynne Regan Corey S. O'Hern Program in Computational Biology and Bioinformatics Yale University New Haven Connecticut 06520 USA Integrated Graduate Program in Physical and Engineering Biology (IGPPEB) Yale University New Haven Connecticut 06520 USA Department of Physics Yale University New Haven Connecticut 06520 USA Department of Molecular Biophysics & Biochemistry Yale University New Haven Connecticut 06520 USA Department of Chemistry Yale University New Haven Connecticut 06520 USA Department of Mechanical Engineering & Materials Science Yale University New Haven Connecticut 06520 USA Department of Applied Physics Yale University New Haven Connecticut 06520 USA

Shortly after the determination of the first protein x-ray crystal structures, researchers analyzed their cores and reported packing fractions ϕ≈0.75, a value that is similar to close packing of equal-sized spheres. A limitation of these analyses was the use of extended atom models, rather than the more physically accurate explicit hydrogen model. The validity of the explicit hydrogen model was proved in our previous studies by its ability to predict the side chain dihedral angle distributions observed in proteins. In contrast, the extended atom model is not able to recapitulate the side chain dihedral angle distributions, and gives rise to large atomic clashes at side chain dihedral angle combinations that are highly probable in protein crystal structures. Here, we employ the explicit hydrogen model to calculate the packing fraction of the cores of over 200 high-resolution protein structures. We find that these protein cores have ϕ≈0.56, which is similar to results obtained from simulations of random packings of individual amino acids. This result provides a deeper understanding of the physical basis of protein structure that will enable predictions of the effects of amino acid mutations to protein cores and interfaces of known structure.

关键词： Protein structure Proteins

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Correction: Advanced anti-corrosion coatings prepared from α-zirconium phosphate/polyurethane nanocomposites

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RSC Advances 2017年第36期7卷 22540-22540页

作者： Tsao-Cheng Huang Guan-Hui Lai Chen-En Li Mei-Hui Tsai Peng-Yun Wang Yi-Hsiu Chung Meng-Hung Lin Department of Chemical and Materials Engineering National Chin-Yi University of Technology 41170 Taichung Taiwan Republic of China Ph. D. Program Graduate Institute of Precision Manufacturing National Chin-Yi University of Technology 41170 Taichung Taiwan Republic of China Department Chemical Engineering Tatung University 104 Taipei Taiwan Republic of China National Chung-Shan Institute of Science and Technology Aeronautical Systems Research Division 40722 Taichung Taiwan Republic of China

Correction for ‘Advanced anti-corrosion coatings prepared from α-zirconium phosphate/polyurethane nanocomposites’ by Tsao-Cheng Huang et al., RSC Adv., 2017, 7, 9908–9913.

Correction for ‘Advanced anti-corrosion coatings prepared from α-zirconium phosphate/polyurethane nanocomposites’ by Tsao-Cheng Huang et al., RSC Adv., 2017, 7, 9908–9913.

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Production and characterisation of ceramic foams from industrial solid waste

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Chemical engineering Transactions 2015年 43卷 1783-1788页

作者： Zilli, Marina Arcaro, Sabrina Cesconeto, Francielly R. De Oliveira Maia, Bianca G. Pereira, Fabiano R. Novaes De Oliveira, Antonio P. Graduate Program in Materials Science and Engineering - PGMAT Laboratory of Glass-Ceramic Materials - VITROCER Federal University of Santa Catarina - UFSC Florianópolis-SC88040-900 Brazil

ISBN: (纸本)9788895608341

This work has as objective to produce and to characterize ceramic foams from glass bottles, sludge from sewage treatment station and graphite (0 - 10 wt%) as a foaming agent. Different compositions were formulated and prepared to obtain materials with controlled porosity for applications where thermal insulation is the main requirement. The raw materials of the prepared compositions were mixed and uniaxially pressed at 40 MPa. Subsequently, the prepared samples were dried and fired at different temperatures (800 - 950 °C) for 30 minutes, respectively. The raw materials and obtained ceramic foams were characterized in terms of their chemical, morphological, thermal and mechanical properties. The results showed that it is possible to produce ceramic foams for thermal insulation with optimized compositions containing 90 vol% glass and 10 vol% sludge with addition of 10 wt% graphite. The ceramic foams showed porosities between 40 and 70 %, thermal conductivity from 0.101 to 0.175 W/mK and compressive strength between 6.4 and 12.5 MPa. Copyright © 2015, AIDIC Servizi S.r.l.

关键词： Thermal insulation

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MgAl2O4 foams obtained by combustion synthesis

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Chemical engineering Transactions 2015年 43卷 1801-1806页

作者： Moraes, Graziela G. Pozzobom, Ida E.F. Fernandes, Celso P. Novaes De Oliveira, Antonio P. Graduate Program in Materials Science and Engineering - PGMAT Laboratory of Glass-Ceramic Materials - VITROCER Federal University of Santa Catarina - UFSC Florianópolis - SC88040 900 Brazil

ISBN: (纸本)9788895608341

This work aims to study magnesium aluminate (MgAl2O4) ceramic foams obtained by combustion synthesis in solution without the need of surfactants to stabilize *** ceramic suspension containing acetone (75 wt%), calcined powder (25 wt%) and a mixture of glycerine (80 % blonde glycerine and 20 % crude glycerine) in the fraction of 100 % with respect to solids was prepared in an alumina ball mill, for 60 min. Subsequently, the suspension was heated at 40 °C, for 30 min, until it became rigid. In order to promote foaming, the suspension was heated to 70 °C and then the following substances were added to it: 2.5 wt% distilled water, 25 wt% Al(NO3)3.9H2O), 12.5 wt% (Mg(NO3)2.6H2O) and 0.625 wt% of a glycerine mixture (80 % blonde glycerine and 20% crude glycerine). After additions the suspension was stirred for 5 min at 950 rpm in a mixer. The resulting foams were dried at 40 °C, for 24 h, in a muffle and fired in two steps, i.e., heating at 0.5 °C/min up to 600 °C/120 min and at 5 °C/min up to 1600 °C/120 *** obtained materials were characterized by SEM,TEM and from tomographic images. The results showed that the obtained magnesium aluminate foams have a high porosity (97 %), a high connectivity and pore sizes (diameters) between 30 and 1200 μm. Copyright © 2015, AIDIC ServiziS.r.l.

关键词： Pore size

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Production and characterisation of glass foams for thermal insulation

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Chemical engineering Transactions 2015年 43卷 1777-1782页

作者： Dias, Gabriella M.V. Arcaro, Sabrina Cesconeto, Francielly R. De Oliveira Maia, Bianca G. Pereira, Fabiano R. Novaes De Oliveira, Antonio P. Graduate Program in Materials Science and Engineering - PGMAT Laboratory of Glass-Ceramic Materials - VITROCER Federal University of Santa Catarina - UFSC Florianópolis-SC88040-900 Brazil

ISBN: (纸本)9788895608341

In this work, glass compositions from glass bottles with different colours and graphite (2 - 12 vol%) as the pore-forming agent were prepared for the production of materials with controlled porosity for applications where thermal and acoustic insulations are main technical requirements. The formulated compositions were, in a later stage, uniaxially pressed (40 MPa) and fired at different temperatures (800 - 950 °C) and cycles with holding times between 15 and 120 minutes. The results showed that it is possible to produce glass foams for thermal insulation from optimized compositions containing 90 vol% glass and 10 vol% graphite, fired between 800 and 950 °C for 30 minutes, which showed porosities between 53 and 76 %, with thermal conductivities between 0.16 and 0.08 W/mK and compressive strength between 20 and 4.6 MPa. The obtained glass foams are strong candidates for applications requiring thermal insulation with suitable combination of thermal conductivity, porosity and mechanical strength. Copyright © 2015, AIDIC Servizi S.r.l.

关键词： Thermal insulation

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Atmospheric Pressure Plasma Jet Treatment of Human Hair Fibers

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Journal of Bio- and Tribo-Corrosion 2015年第1期1卷 1-10页

作者： Öngel, Cansu Keleş, Merve Acar, Erhan Birer, Özgür Department of Chemistry Koç University Rumeli Feneri Yolu Sariyer Istanbul34450 Turkey Department of Molecular Biology and Genetics Koç University Rumeli Feneri Yolu Sariyer Istanbul34450 Turkey Materials Science and Engineering Graduate Program Koç University Rumeli Feneri Yolu Sariyer Istanbul34450 Turkey KUYTAM Surface Science and Technology Center Koç University Rumeli Feneri Yolu Sariyer Istanbul34450 Turkey

Human hair fibers in virgin and dyed forms were treated with atmospheric pressure helium, helium/oxygen, argon, and argon/oxygen plasma jets at 20 W of power. The effects of 10-min plasma treatment on surface morphology and chemistry were studied by scanning electron microscopy and X-ray photoelectron spectroscopy, respectively. The plasma treatment was quite effective for removing the organic residues from the surface and creating oxidized functional groups. Helium plasma had a mild cleaning effect on the surfaces while argon/oxygen plasma had the strongest corrosive effect. Mild hydrogen peroxide treatment for the same duration had neither the cleaning nor the oxidizing power of the plasma jets. These types of plasma jets have the potential to replace peroxide treatment. The corrosive jets can be used to restore dyed hair fibers. In addition, the jets can be used to clean the surfaces of hair fibers to prepare samples for analytical investigations where the organic residues may induce problems. © 2015, Springer International Publishing AG.

关键词： Plasma jets

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Assessment of sound transmission characteristics of traditional timber-framed dwellings in Ankara, Turkey 10

Assessment of sound transmission characteristics of traditio...

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10th European Congress and Exposition on Noise Control engineering, Euronoise 2015

作者： Erdil, Meltem Tavukçuoğlu, Ayşe Çalışkan, Mehmet Department of Architecture Graduate Program in Building Science Middle East Technical University Ankara Turkey Department of Architecture Materials Conservation Laboratory Middle East Technical University Ankara Turkey Department of Mechanical Engineering Middle East Technical University Ankara Turkey

The impact and airborne sound transmission characteristics of interior wall and floor components in traditional timber-framed dwellings (Ankara, Turkey) were examined by in-situ acoustical measurements and simulation analyses. Presence of voids for the running of pipework or door/ window openings existed in the composition of timber framed wall and floor components was found to reduce their sound insulation performances in the range of 12-22dB. Air/sound leakages through the openings should be sealed properly in order to provide the required Rw and Lnw values for dwellings. In case that the dwelling units/spaces are used as exhibition, meeting, office or hotel rooms, some acoustical improvements in existing wall and floor components can be provided by demountable attachments with sound insulation infill and sound breaks. Copyright ©(2015) by EAA-NAG-ABAV, ISSN2226-5147 All rights reserved

关键词： Timber

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Magnetoelectric memory function with optical readout

arXiv

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arXiv 2017年

作者： Kocsis, V. Penc, K. Rõõm, T. Nagel, U. Vít, J. Romhányi, J. Tokunaga, Y. Taguchi, Y. Tokura, Y. Kézsmárki, I. Bordács, S. Wako Saitama351-0198 Japan Department of Physics Budapest University of Technology and Economics and MTA-BME Lendület Magneto-optical Spectroscopy Research Group Budapest1111 Hungary Institute for Solid State Physics and Optics Wigner Research Centre for Physics Hungarian Academy of Sciences P.O.B. 49 BudapestH-1525 Hungary National Institute of Chemical Physics and Biophysics Tallinn12618 Estonia Institute of Physics ASCR Na Slovance 2 Prague 8182 21 Eue Faculty of Nuclear Science and Physical Engineering Czech Technical University Břehová 7 Prague 1115 19 Eue Okinawa Institute of Science and Technology Graduate University Onna-sonOkinawa904-0395 Japan Department of Advanced Materials Science University of Tokyo Kashiwa277-8561 Japan Quantum-Phase Electronics Center Department of Applied Physics University of Tokyo Tokyo113-8656 Japan Department of Applied Physics University of Tokyo Hongo Tokyo113-8656 Japan Experimental Physics 5 Center for Electronic Correlations and Magnetism Institute of Physics University of Augsburg Augsburg86159 Germany Hungarian Academy of Sciences Premium Postdoctor Program Budapest1051 Hungary

The ultimate goal of multiferroic research is the development of new-generation non-volatile memory devices1, the so-called magnetoelectric (ME) memories, where magnetic bits are controlled via electric fields without the application of electrical currents subject to dissipation. This low-power operation exploits the entanglement of the magnetization and the electric polarization coexisting in multiferroic materials2,3. Here we demonstrate the optical readout of ME memory states in the antiferromagnetic (AFM) and antiferroelectric (AFE) LiCoPO4, based on the strong absorption difference of THz radiation between its two types of ME domains. This unusual contrast is attributed to the dynamic ME effect of the spin-wave excitations, as confirmed by our microscopic model, which also captures the characteristics of the observed static ME effect. Our proof-of-principle study, demonstrating the control and the optical readout of ME domains in LiCoPO4, lays down the foundation for future ME memory devices based on antiferroelectric-antiferromagnetic insulators. Copyright © 2017, The Authors. All rights reserved.

关键词： Digital storage

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