Nowadays,cancers remain the most disastrous diseases worldwide with more than ten million new cases every *** one of the main therapeutic approaches,chemotherapy can destroy tumors and inhibit cancer ***,it is usually...
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Nowadays,cancers remain the most disastrous diseases worldwide with more than ten million new cases every *** one of the main therapeutic approaches,chemotherapy can destroy tumors and inhibit cancer ***,it is usually restricted by the severe cytotoxicity of anticancer drugs to normal tissues and *** this end,researchers have paid much attention to various drug formulations to reduce the side effects and improve the therapeutic efficacy of anticancer *** them,
As we known,star polymers generally posses several polymer arms emanating from a central *** to now,various controlled/living polymerizations have been employed to generate desired multi-armed macromolecular ***,since...
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As we known,star polymers generally posses several polymer arms emanating from a central *** to now,various controlled/living polymerizations have been employed to generate desired multi-armed macromolecular ***,since its first introduction by Sharpless in 2001,1"click"chemistry has recently become a powerful and versatile synthetic tool because of some unique
Stimuli-responsive polymeric aggregates have attracted wide attention due to their multipurpose applications involving the enhanced selectivity and efficiency of drug delivery to targeting sites.1-
Stimuli-responsive polymeric aggregates have attracted wide attention due to their multipurpose applications involving the enhanced selectivity and efficiency of drug delivery to targeting sites.1-
Stimuli-responsive polymeric aggregates have attracted wide attention due to their multipurpose applications involving the enhanced selectivity and efficiency of drug delivery to targeting sites.1-7 Some dually and mu...
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Stimuli-responsive polymeric aggregates have attracted wide attention due to their multipurpose applications involving the enhanced selectivity and efficiency of drug delivery to targeting sites.1-7 Some dually and multiply stimuli-sensitive copolymers have been synthesized and self-assembled into functional aggregates with great potential in smart release systems,in which various internal and external stimuli have been applied to induce the dissociation or morphology changes of copolymer aggregates and
The ever growing biomedical technology such as regenerative medicine and controlled drug release intimately relies on the development of advancedfunctional biomaterials,among which aliphatic polycarbonates and polype...
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The ever growing biomedical technology such as regenerative medicine and controlled drug release intimately relies on the development of advancedfunctional biomaterials,among which aliphatic polycarbonates and polypeptides due to their excellent biocompatibility and biodegradability have received the most *** the past years,various types of functional polycarbonates and polypeptides
Star-shaped polymers refer to one kind of branched polymer in which multiple linear polymeric chains are attached to a central core1,*** unique chain topology imparts valuable properties dependin
Star-shaped polymers refer to one kind of branched polymer in which multiple linear polymeric chains are attached to a central core1,*** unique chain topology imparts valuable properties dependin
The ever growing biomedical technology such as regenerative medicine and controlled drug release intimately relies on the development of advancedfunctional biomaterials,among which aliphatic polyc
The ever growing biomedical technology such as regenerative medicine and controlled drug release intimately relies on the development of advancedfunctional biomaterials,among which aliphatic polyc
The ＂living＇/controlled radical polymerization （LRP） of styrene （St） at room temperature is rarely reported. In this work, copper（0） （Cu（0））-mediated radical polymerization of St at room temperature was in...
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The ＂living＇/controlled radical polymerization （LRP） of styrene （St） at room temperature is rarely reported. In this work, copper（0） （Cu（0））-mediated radical polymerization of St at room temperature was investigated in detail. Dimethyl sulfoxide （DMSO）, N,N-dimethylformamide （DMF） as well as a binary solvent, tetrahydrofuravdl,l,l,3,3,3-hexafluoro-2- propanol were used as the solvents, respectively. Methyl-2-bromopropionate and ethyl 2-bromoisobutyrate were used as the initiators, respectively. The polymerization proceeded smoothly with moderate conversions at room temperature. It was found that DMF was a good solvent with the essential features of LRP, while DMSO was a poor solvent with uncontrollable molecular weights. Besides, the match among the initiator, solvent and molar ratios of reactants can modulate the livingness of the polymerization, and the proper selection of ligand was also crucial to a controlled process. This work provided a first example of Cu（0）-mediated radical polymerization of St at room temperature, which would enrich and strength the LRP technique.
Star-shaped polymers refer to one kind of branched polymer in which multiple linear polymeric chains are attached to a central core1,*** unique chain topology imparts valuable properties depending critically on the mo...
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Star-shaped polymers refer to one kind of branched polymer in which multiple linear polymeric chains are attached to a central core1,*** unique chain topology imparts valuable properties depending critically on the molecular parameters such as number of arms,molecular weight of each arm,chemical identity of each arm,and *** general,with the growth of living anionic
A series of acceptor-donor-acceptor alternative small molecules were synthesized containing electron-donating central building moieties of phenothiazine, 2,7-carbazole and thieno[3,4-b]thiophene and electron-accepting...
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A series of acceptor-donor-acceptor alternative small molecules were synthesized containing electron-donating central building moieties of phenothiazine, 2,7-carbazole and thieno[3,4-b]thiophene and electron-accepting moie- ties of tetrazine on both sides. The various conformations of the central blocks, with the coplanarity in an order of phenothiazine〈2,7-carbazole〈thieno[3,4-b]thiophene, have an obvious influence on the optical, electrochemical property and the crystallinity of small molecule. In addition, the blend films between small molecule and （6,6）-phenyl-C6rbutyric acid methyl ester offered significantly various morphologies, changing from uniform sur- face to interpenetrated networks. As a result, the bulk heterojunction photovoltaic devices based on the three small molecules provided varied performance, and the highest coplanar molecule based device exhibited the best photo- voltaic performance.
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