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Electrochemical CO_(2) reduction catalyzed by organic/inorganic hybrids

eScience 2023年第2期3卷 1-15页

作者： Daqi Song Yuebin Lian Min Wang Yanhui Su Fenglei Lyu Zhao Deng Yang Peng College of Energy Soochow Institute for Energy and Materials Innovations(SIEMIS)Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu ProvinceSoochow UniversitySuzhou 215006China Jiangsu Key Laboratory of Advanced Negative Carbon Technologies Soochow UniversitySuzhou 215006JiangsuChina Key Laboratory of Core Technology of High Specific Energy Battery and Key Materials for Petroleum and Chemical Industry Suzhou 215006JiangsuChina School of Photoelectric Engineering Changzhou Institute of TechnologyChangzhou 213032People's Republic of China

Electroreduction of CO_(2) into value-added chemicals and fuels utilizing renewable electricity offers a sustainable way to meet the carbon-neutral goal and a viable solution for the storage of intermittent green energy *** the core of this technology is the development of electrocatalysts to accelerate the redox kinetics of CO_(2) reduction reactions(CO_(2)RR)toward high targeted-product yield at minimal energy *** perspective focuses on a unique category of CO_(2)RR electrocatalysts embodying both inorganic and organic components to synergistically promote the reaction activity,selectivity and ***,we summarize recent progress on the design and fabrication of organic/inorganic hybrids CO_(2)RR electrocatalysts,with special attention to the assembly protocols and structural *** then carry out a comprehensive discussion on the mechanistic understanding of CO_(2)RR processes tackled jointly by the inorganic and organic phases,with respect to the regulation of mass and charge transport,modification of double-layer configuration,tailoring of intermediates adsorption,and establishment of tandem *** the end,we outline future challenges in the rational design of organic/inorganic hybrids for CO_(2)RR and further extend the scope to the device *** hope this work could incentivize more research interests to construct organic/inorganic hybrids for mobilizing electrocatalytic CO_(2)RR towards industrialization.

关键词： CO_(2)reduction reaction Electrocatalysts Organic/inorganic hybrids Intermediates adsorption Local chemical environment

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The aging behavior,microstructure and mechanical properties of AlN/AZ91 composite

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Journal of Magnesium and Alloys 2023年第7期11卷 2458-2468页

作者： Yunxia Sun Changlin Yang Bin Zhang Jianfeng Fan Hongxiang Li Tianhao Zhao Jing Li State Key Laboratory of Solidification Processing Northwestern Polytechnical UniversityXi’anShaanxi 710072PR China Yangtze River Delta Research Institute of NPU TaicangJiangsu 215400PR China Key Laboratory of Interface Science and Engineering in Advanced Materials Ministry of EducationTaiyuan University of TechnologyTaiyuan 030024PR China State Key Laboratory for Advanced Metals and Materials University of Science and Technology BeijingBeijing 100083PR China

Microstructure evolution and mechanical properties of the aging treated AlN/AZ91 composites were systematically investigated by optical microscopy(OM),high resolution scanning electron microscopy(HRSEM)with an energy dispersive spectrum(EDS),and high-angle annular dark field scanning transmission electron microscopy(HAADF-STEM).The results show that the higher fracture elongation(14±1%)and ultimate tensile strength(275±6 MPa)were simultaneously obtained in the peak-aged AlN/AZ91 *** with AZ91 matrix alloy,the strength was increased by about 44%and the elongation was approximately five times higher,which mainly attributed to the precipitation of nano-sizedγ-Mg_(17)Al_(12)phase and the activation of non-basal slip systems induced by in-situ AlN particles at room ***,the in-situ formation of AlN reinforcements consumed part of Al element in the matrix alloy,which resulted into the volume fraction decreasing ofγ-Mg_(17)Al_(12)precipitates,and then the age hardening and strengthening efficiency were reduced in the AlN/AZ91 *** the other hand,the mismatch of thermal expansion coefficient between AlN particles and AZ91 matrix generated high density dislocations around AlN particles,which promoted the precipitation ofγ-Mg_(17)Al_(12)phase,and then the peak aging time and temperature were decreased.

关键词： Magnesium matrix composites In-situ AlN particles Aging behavior Microstructure Mechanical properties

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Synthesis of hierarchical SAPO-11-based catalysts with Al-based metal-organic framework derivative as mesoporogen to improve n-decane branched isomerization

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Petroleum Science 2022年第6期19卷 3171-3181页

作者： Xue-Man Wang Cheng-Long Wen Yu Fan State Key Laboratory of Heavy Oil Processing China University of PetroleumBeijing102249China Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology Advanced Catalysis and Green Manufacturing Collaborative Innovation Centerand School of Petrochemical EngineeringChangzhou UniversityChangzhouJiangsu213164China

Hierarchical SAPO-11 molecular sieve(ACS-11) was successfully synthesized employing the Al2O3/carbon(Al_(2)O_(3)/C) composite obtained through the pyrolysis of Al-based metal-organic framework(Al-MOF-96)as *** other carbon-based mesoporogens with strong hydrophobicity,the Al_(2)O_(3)/C interacts with phosphoric acid and generates the AlPO_(4)/C structure,which promotes the Al2O3/C dispersion in the synthesis gel of SAPO-11 and avoids the phase separation between *** Al_(2)O_(3)/C as mesoporogen decreases the crystallite size of SAPO-11 via preventing the aggregation of ***,the addition of Al_(2)O_(3)/C improves the Si distribution in the ACS-11 ***,ACS-11 has smaller crystallites,more mesopores,and a greater amount of medium Bronsted acid centers than the conventional microporous SAPO-11 and the SAPO-11 synthesized using activated carbon as *** corresponding Pt/ACS-11 catalyst exhibits the maximal selectivity to multi-branched C10isomers(23.28%) and the minimal cracking selectivity(15.83%) in n-decane hydroisomerization among these *** research provides a new approach for preparing hierarchical silicoaluminophosphate molecular sieve-based catalysts to produce high-quality fuels.

关键词： Hierarchical SAPO-11 Al_(2)O_(3)/C composite Hydroisomerization Branched isomers

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Ligand-tuning of coordination compound for improved oxygen evolution

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Chinese Journal of Chemical Engineering 2024年第12期76卷 292-300页

作者： Kunpeng Yang Yuanjun Liu Yuyu Liu Xingmei Guo Xiangjun Zheng Junhao Zhang Guoxing Zhu School of Environmental and Chemical Engineering Jiangsu University of Science and TechnologyZhenjiang 202018China School of Chemistry and Chemical Engineering Jiangsu UniversityZhenjiang 202013China Key Laboratory of Advanced Electrode Materials for Novel Solar Cells for Petroleum and Chemical Industry of China School of Chemistry and Life SciencesSuzhou University of Science and TechnologySuzhou 215009China

Controllable regulation of the reconstruction process for the pre-catalysts towards oxygen evolution remains as a great *** this study,we report a bi-ligand strategy to facilitate the structural transformation of coordination compounds to metal oxyhydroxides during oxygen evolution with enhanced activity.A coordination compound consisting of 1,10-ferrocene acid(Fc)and Ni^(2+)was synthesized,in which terephthalic acid was *** second ligand of terephthalic acid facilitates the reconstruction process,inducing an enhanced catalytic *** 1 mol·L^(-1)KOH aqueous solution,the optimized catalyst can drive a current density of 10 mA·cm^(-2)under a lower overpotential of 220 *** this catalyst,zinc-air batteries can be *** obtained zinc-air battery presents a large specific capacity of 718 mA·h·g^(-1)with excellent cycling stability for over 100 h far exceeding that of Pt/C+RuO_(2)battery fabricated with commercial *** excellent performance and low cost of this catalyst will open up broad prospects for the development of advanced systems for water electrolysis and zinc air batteries.

关键词： Catalysis Electrochemistry Zinc-air battery Coordination compounds Oxygen evolution

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Effect of electrolyte cation-mediated mechanism on electrocatalytic carbon dioxide reduction

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Chinese Chemical Letters 2024年第7期35卷 139-146页

作者： Yuan Dong Mutian Ma Zhenyang Jiao Sheng Han Likun Xiong Zhao Deng Yang Peng Soochow Institute of Energy and Material Innovations College of EnergyJiangsu Key Laboratory of Advanced Carbon Materials and Wearable Energy TechnologiesSoochow UniversitySoochow 215006China Jiangsu Key Laboratory of Advanced Negative Carbon Technologies Soochow UniversitySoochow 215123China School of Chemistry and Chemical Engineering Shihezi UniversityShihezi 832003China School of Chemical and Environmental Engineering Shanghai Institute of TechnologyShanghai 201418China

The steep reduction in costs and systematic optimization of renewable electricity has ignited an intensifying interest in harnessing electroreduction of carbon dioxide(CO_(2)RR)for the generation of chemicals and *** focus of research over the past few decades has been on the optimization of the electrode and the electrolyte ***,cation species in the latter have recently been found to dramatically alter the selectivity of CO_(2)RR and even their catalytic activity by multiple orders of *** a result,the selection of cations is a critical factor in designing catalytic interfaces with high selectivity and efficiency for targeted *** decision-making regarding cation selection relies on a comprehensive understanding of prevailing electrolyte effect models that have been used to elucidate observed experimental *** this perspective,we review the hypotheses that explain how electrolyte cations influence CO_(2)RR by mechanisms such as through tuning of the interfacial electric field,buffering of the local pH,stabilization of the key intermediates and regulation of the interfacial *** endeavor is to elucidate the molecular mechanisms underpinning cation effects,thus fostering the evolution of more holistic and universally applicable predictive *** this regard,we highlight the current challenges in this area of research,while also identifying potential avenues for future investigations.

关键词： CO_(2)electrocatalytic reduction Cation effects Catalytic mechanisms Catalytic interfaces Electric double layer

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Chiral induction and Sb3+doping in indium halides to trigger second harmonic generation and circularly polarized luminescence

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Chinese Chemical Letters 2024年第8期35卷 503-507页

作者： Yongjing Deng Feiyang Li Zijian Zhou Mengzhu Wang Yongkang Zhu Jianwei Zhao Shujuan Liu Qiang Zhao State Key Laboratory of Organic Electronics and Information Displays&Jiangsu Key Laboratory for Biosensors Institute of Advanced Materials(IAM)&Institute of Flexible Electronics(Future Technology)Nanjing University of Posts&Telecommunications(NJUPT)Nanjing 210023China School of Environmental and Chemical Engineering Jiangsu University of Science and TechnologyZhenjiang 212100China Shenzhen HUASUAN Technology Co. Ltd.Shenzhen 518000China

Recently,organic-inorganic hybrid metal halides(HMHs)have attracted extensive attention as promis-ing multifunctional materials by virtue of their structural diversity and tunable photophysical ***,it remains a challenge to design HMHs with specific functions on ***,by introduc-ing R/S-methylbenzylamine(R/S-MBA)and doping Sb^(3+),we have achieved both second harmonic gen-eration(SHG)and circularly polarized luminescence(CPL)properties in lead-free indium *** introduction of chiral organic cations can break the symmetry and induce the indium halides to crys-tallize in the chiral space *** Sb^(3+)with ns2 electronic configuration can serve as the dopants to promote the formation of self-trapped excitons,so as to activate highly efficient *** a re-sult,the as-prepared Sb3+doped(R/S-MBA)3 InCl6 show not only SHG responses but also CPL signals with luminescence dissymmetry factor of−5.3×10^(−3) and 4.7×10^(−3).This work provides a new inspiration for the exploitation of chiral multifunctional materials.

关键词： Hybrid metal halides Self-trapped excitons Chiral induction Second-harmonic generation Circularly polarized luminescence

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Tin whisker growth from titanium-tin intermetallic and the mechanism

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Journal of Materials Science & technology 2022年第34期129卷 79-86页

作者： Zhihua Tian Peigen Zhang Yan Zhang Jingwen Tang Yushuang Liu Jian Liu ZhengMing Sun Jiangsu Key Laboratory of Advanced Metallic Materials School of Materials Science and EngineeringSoutheast UniversityNanjing 211189China Jiangsu Key Laboratory of Advanced Structural Materials and Application Technology School of Materials Science and EngineeringNanjing Institute of TechnologyNanjing 211167China Wuxi Lintex Advanced Materials Co. Ltd.Wuxi 214145China

Spontaneous growth of metal whiskers, represented by tin whiskers, has haunted tin-based platings and solder joints for decades and caused huge losses to the electronics industry. Despite numerous efforts, the underlying growth mechanism has been resisting interpretation, and the whiskering phenomenon even continues to expand its territory. Here, we report the growth of tin whiskers from a *** tin whiskers share similar characteristics with those found on the platings or solder joints, but grow more and faster, with finer diameters. After tin whisker growth, Ti6Sn5retains its crystal structure,implying a dealloying process. Combining experimental and first-principles calculation results, we analyzed the growth mechanism of tin whiskers in detail, and proposed a diffusion-based growth *** strain energy stored in Ti6Sn5during deformation provides a driving force for whisker growth, and the short-circuit diffusion paths generated by such deformation accelerate whisker growth. These findings identify the critical role of intermetallic substrate in the whiskering phenomenon, shedding new light for comprehensively understanding the whisker growth mechanisms. Furthermore, the plenty and rapid growth of tin whiskers also means a new method for the preparation of one-dimensional metallic materials.

关键词： Tin whisker Intermetallics Vacancy DFT

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Evetac Meets Sparse Probabilistic Spiking Neural Network: Enhancing Snap-Fit Recognition Efficiency and Performance

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IEEE robotics and Automation Letters 2025年第6期10卷 5353-5360页

作者： Fang, Senlin Ding, Haoran Liu, Yangjun Liu, Jiashu Zhang, Yupo Li, Yilin Kong, Hoiio Yi, Zhengkun Faculty of Data Science City University of Macau 999078 China Chinese Academy of Sciences Guangdong Provincial Key Laboratory of Robotics and Intelligent System Shenzhen Institutes of Advanced Technology Shenzhen518055 China City University of Hong Kong Hong Kong University of Macau 999078 China Shenzhen Institute of Advanced Technology Shenzhen518055 China City University of Macau 999078 China Guangdong Provincial Key Laboratory of Robotics and Intelligent System Shenzhen Institutes of Advanced Technology Chinese Academy of Sciences Shenzhen518055 China City University of Macau Faculty of Data Science 999078 China Chinese Academy of Sciences Key Laboratory of Biomedical Imaging Science and System Shenzhen518055 China

Snap-fit peg-in-hole assembly is common in industrial robotics, particularly for 3 C electronics, where fast and accurate tactile recognition is crucial for protecting fragile components. Event-based optical sensors, such as Evetac, are well-suited for this task due to their high sparsity and sensitivity in detecting small, rapid force changes. However, existing research often converts event data into dense images and processing them with dense methods, leading to higher computational complexity. In this letter, we propose a Sparse Probabilistic Spiking Neural Network (SPSNN) that utilizes sparse convolutions to extract features from the event data, avoiding computations on non-zero cells. We introduce the Forward and Backward Propagation Through Probability (FBPTP) method, which enables simultaneous gradient computation across all time steps, eliminating the need for the step-by-step traversal required by traditional Forward and Backward Propagation Through Time (FBPTT). Additionally, the Temporal Weight Prediction (TWP) method dynamically allocates weights for different time outputs, enhancing recognition performance with minimal impact on model efficiency. We integrate the Evetac sensor compactly into our robotic system and collected two datasets, named Tactile Event Ethernet (TacEve-Eth) and Tactile Event Type-C (TacEve-TC), corresponding to cantilever and annular snap-fit structures. Experiments show that the SPSNN achieves the superior trade-off between recognition performance and efficiency compared to other widely used methods, achieving the highest average recognition performance while reducing inference time by over 90% compared to FBPTT-based dense SNN baselines. © 2016 IEEE.

关键词： Robotic assembly

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Ultrasonic scalpel based on fusiform phononic crystal structure

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Chinese Physics B 2024年第10期33卷 302-310页

作者： Sha Wang Junjie Shan Shuyu Lin Ocean College Jiangsu University of Science and TechnologyZhenjiang 212100China Shaanxi Key Laboratory of Ultrasonics School of Physics and Information TechnologyShaanxi Normal UniversityXi’an 710119China National Laboratory of Solid State Microstructures School of PhysicsCollaborative Innovation Center of Advanced MicrostructuresNanjing UniversityNanjing 210093China

In response to the ultrasonic scalpels with the vibrational modal coupling which leads to a decrease in efficiency,an ultrasonic scalpel based on fusiform phononic crystals(PnCs)is *** accurate theoretical model is constructed,which is mainly composed of electromechanical equivalent circuit models to analyze the frequency response function and the frequency response curves of the *** band gaps exist in the fusiform PnCs owing to the periodic constraint,which can suppress the corresponding vibrational *** vibration characteristics(vibration mode,frequency,and displacement distribution)of the ultrasonic scalpel are analyzed,and the validity of the electromechanical equivalent circuit method is *** results indicate that other vibration modes near the working frequency can be *** addition,blades based on fusiform PnCs have a function akin to that of the horn,which enables displacement amplification.

关键词： phononic crystals ultrasonic scalpel bandgap vibration characteristics

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Nonstoichiometric In-S group yielding efficient carrier transfer pathway in In_(2)S_(3) photoanode for solar water oxidation

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SusMat 2024年第1期4卷 154-165页

作者： Runyu Chen Linxing Meng Changda Wang Weiwei Xu Yulong Huang Li Song Liang Li School of Physical Science and Technology Jiangsu Key Laboratory of Thin FilmsCenter for Energy Conversion Materials&PhysicsSoochow UniversitySuzhouJiangsuP.R.China Jiangsu Key Laboratory of Advanced Negative Carbon Technologies Soochow UniversitySuzhouJiangsuP.R.China National Synchrotron Radiation Laboratory CAS Center for Excellence in NanoscienceUniversity of Science and Technology of ChinaHefeiAnhuiP.R.China School of Electronic and Information Engineering Changshu Institute of TechnologyChangshuJiangsuP.R.China

The construction of high-efficiency photoanodes is essential for developing outstanding photoelectrochemical(PEC)water splitting ***,insufficient carrier transport capabilities and sluggish surface water oxidation kinetics limit its *** a solvothermal annealing strategy,we prepared a nonstoichiometric In-S(NS)group on the surface of an In_(2)S_(3) photoanode in situ and unexpectedly formed a type II transfer path of carrier,thereby reducing the interfacial recombination and promoting the bulk *** calculations and comprehensive characterizations demonstrated NS group as an excellent oxygen evolution cocatalyst(OEC)that effectively facilitated carrier transport,lowered the surface overpotential,increased the surface active site,and accelerated the surface oxygen evolution reaction kinetics by precisely altering the rate-determining steps of*to*OH and*O to**** synergistic effects remarkably enhanced the PEC performance,with a high photocurrent density of 5.02 mA cm^(−2)at 1.23 V versus reversible hydrogen electrode and a negative shift in the onset potential by 310 *** work provides a new strategy for the in situ preparation of high-efficiency OECs and provides ideas for constructing excellent carrier transfer and transport channels.

关键词： In_(2)S_(3) photoanode water splitting

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