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Palladium-catalyzed annulative allylic alkylation for regioselective construction of indole-fused medium-sized cyclic etherS

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Chinese Chemical Letters 2023年第12期34卷 155-158页

作者： Ling-Qi Chen Chi-Fan Zhu Su Zhang Bao-Yang Liu Shu-Jjiang Tu Wen-Jjuan Hao Bo Jiang School of Chemistry&Materials Science Jiangsu Normal UniversityXuzhou 221116China jiangsu Key Laboratory of Advanced Catalytic Materials&Technology School of PharmacyChangzhou UniversityChangzhou 213164China

A new palladium-catalyzed annulative allylic alkylation(AAA)reaction of 2-(indol-2-yl)phenols with dual allylic electrophiles such as isobutylene dicarbonate and butene dicarbonate is described,leading to the regioselective synthesis of tetracyclic medium-sized cyclic ethers possessing a bridged aryl-indole scaf-fold,namely,benzo[2,3]oxocino[4,5-b]indoles and benzo[2,3]oxepino[4,5-b]indoles,in good to excellent *** protocol demonstrates a broad substrate scope,good compatibility with substituents and high regioselectivity,providing a catalytic and flexible method for creating bridged aryl-indole skeletons.

关键词： Palladium-catalysis Annulative allylic alkylation [5+n]annulation Regioselectivity Medium-sized cyclic ethers

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Vertical two-dimensional WS_(2)flakes grown on flexible CNT film for excellent electrochemical performance

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Rare Metals 2024年第1期43卷 164-174页

作者： Qian Gong Jing-Yun Zou Ming Ren Si-Qi Zhu Yu-Rong Zhou Li-Ming Zhao Jian Chen Yu-Long Wu Jiang-Tao Di Li-Xing Kang Qing-Wen Li School of Nano-Tech and Nano-Bionics University of Science and Technology of ChinaHefei 230026China Key Laboratory of Multifunctional Nanomaterials and Smart Systems Division of Advanced MaterialsSuzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesSuzhou 215123China Jiangsu Key Laboratory of Micro and Nano Heat Fluid Flow Technology and Energy Application School of Physical Science and TechnologySuzhou University of Science and TechnologySuzhou 215009China

Soft electrochemical actuators that can generate mechanical motions in response to electrical stimuli can be used as artificial muscles in microscale *** electrode materials are the key component of the electrochemical actuator because they limit the ion diffusion and accumulation processes and thus affect the deformation in fast response-time and potential engineering ***-dimensional materials,such as one-dimensional(1D)CNT and two-dimensional(2D)vertically stood WS_(2),are great electrode due to their good electrochemical stability and high surface-to-volume ratios,but show limited performances when being used on their own in the actuators because of low reconstruction or low conductivity.A combination of 1D CNT and 2D WS_(2)could form a heterojunction with both high electrochemical activity and great mechanical ***,by depositing highly disordered graphene nanosheets(HDGNs)on CNT films and then WS_(2)on the formed low-dimensional nanocarbon film,a hybrid WS_(2)/HDGN/CNT film was synthesized through a multistep CVD *** grown WS_(2)nanosheets were achieved by taking advantage of HDGNs which limits CNTs ***,the volume expansion caused by the transition from WO_(3)to WS-2can force the vertical growth of WS_(2).This hybrid film shows excellent electrochemical properties,such as high specific capacitance and high rate *** actuators based on the WS_(2)/HDGN/CNT films show good actuating performance,including stability and reconfigurability.

关键词： CNT Graphene Vertically growth WS_(2) Electrochemical actuators

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Suppression of deep‑level traps via semicarbazide hydrochloride additives for high‑performance tin‑based perovskite solar cells

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Frontiers of Optoelectronics 2023年第4期16卷 205-213页

作者： Wenbo Jia Yi Jing Han Zhang Baoyan Tian Huabo Huang Changlei Wang Ligang Xu Key Laboratory for Organic Electronics and Information Displays(KLOEID)and Jiangsu Key Laboratory for Biosensors Institute of Advanced Materials(IAM)Nanjing University of Posts and TelecommunicationsNanjing 210023China Hubei Key Laboratory of Plasma Chemistry and Advanced Materials Key Laboratory for Green Chemical Process of Ministry of EducationSchool of Materials Science and EngineeringWuhan Institute of TechnologyWuhan 430205China School of Optoelectronic Science and Engineering and Collaborative Innovation Center of Suzhou Nano Science and Technology Key Lab of Advanced Optical Manufacturing Technologies of Jiangsu Province and Key Lab of Modern Optical Technologies of Education Ministry of ChinaSoochow UniversitySuzhou 215006China Wuhan National Laboratory for Optoelectronics Huazhong University of Science and TechnologyWuhan 430074China

Tin perovskites with exemplary optoelectronic properties ofer potential application in lead-free perovskite solar ***,Sn vacancies and undercoordinated Sn ions on the tin perovskite surfaces can create deep-level traps,leading to nonradiative recombination and absorption of nucleophilic O_(2)molecules,impeding further device efciency and ***,in this study,a new additive of semicarbazide hydrochloride(SEM-HCl)with a N–C=O functional group was introduced into the perovskite precursor to fabricate high-quality flms with a low concentration of deep-level trap ***,in turn,serves to prevent undesirable interaction between photogenerated carriers and adsorbed oxygen molecules in the device’s operational environment,ultimately reducing the proliferation of superoxide *** the result,the SEM-HCl-derived devices show a peak efciency of 10.9%with improved device *** unencapsulated devices maintain almost 100%of their initial efciencies after working for 100 h under continuous AM1.5 illumination conditions.

关键词： Lead-free perovskite solar cells Deep-level traps Power conversion efciency Semicarbazide hydrochloride Stability

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Broadband, high-linearity TFLN electro-optic modulator for integrated microwave photonics using reconfigurable dual-parallel modulation

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Optics Express 2025年第6期33卷 13805-13815页

作者： Qin, Yan-Yan Gu, Xiao-Wen Tang, Jie Ye, Hui-Yan Dong, Wen-Hao Song, Yuan-Jun Qian, Guang Zhang, Xiao-Yang Zhang, Tong Southeast University Joint International Research Laboratory of Information Display and Visualization School of Electronic Science and Engineering Jiangsu Nanjing210096 China National Key Laboratory of Solid-state Microwave Devices and Circuits Nanjing210016 China Nanjing Electronic Devices Institute Nanjing210016 China Key Laboratory of Micro-inertial Instrument and Advanced Navigation Technology Ministry of Education School of Instrument Science and Engineering Southeast University Jiangsu Nanjing210096 China Suzhou Key Laboratory of Metal Nano-optoelectronic Technology Southeast University Suzhou Campus Jiangsu Suzhou215123 China

Integrated electro-optic modulators with large bandwidth, high linearity and low driving voltage are key building blocks for integrated microwave photonic (IMWP) links to transmit broadband signals with high fidelity. In this work, thin-film lithium niobate electro-optic modulator consisting of a thermo-optic reconfigurable coupler and dual-parallel Mach-Zehnder modulation scheme is proposed and demonstrated to achieve spurious-free dynamic range of 112.87/107.71 dB·Hz2/3 at 1/10 GHz while keeping large bandwidth (>67 GHz) and low half-wave voltage (2.7 V) simultaneously. The demonstration of this device paves a new route for high-performance electro-optic modulators in future functional IMWP systems. © 2025 Optica Publishing Group under the terms of the Optica Open Access Publishing Agreement.

关键词： Fiber optic communications Integrated photonics Lithium niobate Microwave photonics Optical components Silicon modulators

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Corrosion mechanism of Mg alloys involving elongated long-period stacking ordered phase and intragranular lamellar structure

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Journal of Materials Science & technology 2023年第20期151卷 190-203页

作者： Jinshu Xie Jinghuai Zhang Zhi Zhang Zijian Yu Zhihao Xu Ru Wang Daqing Fang Xiaobo Zhang Xiaoru Zhang Ruizhi Wu Key Laboratory of Superlight Material and Surface Technology Ministry of EducationCollege of Materials Science and Chemical EngineeringHarbin Engineering UniversityHarbin 150001China Faculty of Materials and Manufacturing Beijing University of TechnologyBeijing 100124China State Key Laboratory for Mechanical Behavior of Materials Xi’an Jiaotong UniversityXi’an 710049China Jiangsu Key Laboratory of Advanced Structural Materials and Application Technology Nanjing Institute of TechnologyNanjing 211167China

It is a long-term challenge to further improve the corrosion resistance while ensuring the strength of magnesium(Mg)*** the effect of potential fluctuation on the micro-galvanic corrosion and the subsequent film formation is important for understanding the corrosion mechanism of Mg alloys with multiple strengthening phases/***,we prepared the high-strength Mg-14.4Er-1.44Zn-0.3Zr(wt.%)alloys containing hybrid structures,i.e.,elongated long-period stacking ordered(LPSO)blocks+intragranular stacking faults(SFs)/LPSO *** Mg alloy with elongated LPSO blocks and intragranular LPSO lamellae(EZ-500 alloy)obtains good corrosion resistance(2.2 mm y^(–1)),while the Mg alloy containing elongated LPSO blocks and intragranular SFs(EZ-400 alloy)shows a significantly higher corrosion rate(6.9 mm y^(–1)).The results of scanning Kelvin probe force microscopy(SKPFM)show the elongated LPSO blocks act as cathode phase(87 mV in EZ-400 alloy),and the SFs serve as the weak anode(30 mV in EZ-400 alloy),resulting in high potential fluctuation in EZ-400 *** the contrary,both elongated blocks and intragranular lamellae are cathodic LPSO phase(67–69 mV)in EZ-500 alloy,leading to a lower potential *** in-situ atomic force microscope(AFM)observation indicates that high potential fluctuation would cause strong micro-galvanic corrosion,and subsequently leads to the failure in rapid formation of corrosion film,finally forming a loose and porous film,while relatively low potential fluctuation could result in more uniform corrosion mode and facilitate the rapid formation of protective ***,we propose that it is an effective way to develop high-strength corrosionresistant Mg alloys by controlling the potential fluctuation to form a“uniform potential”strengthening microstructure。

关键词： Mg alloys Stacking faults LPSO phase SKPFM Quasi in-situ AFM Corrosion behavior Potential fluctuation

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Magnetic behaviors and magnetocaloric effects in rare earth high-entropy amorphous/nanocrystalline alloys

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Journal of Rare Earths 2024年第1期42卷 129-136,I0005页

作者： Lin Xue Liliang Shao Baosen Zhang Zongzhen Li Jiangbo Cheng Baolong Shen College of Mechanics and Materials Hohai UniversityNanjing211106China School of Materials Science and Engineering Jiangsu Key Laboratory of Advanced Metallic MaterialsSoutheast UniversityNanjing211189China School of Materials Science and Engineering Nanjing Institute of TechnologyNanjing211167China Jiangsu JITRI Advanced Energy Materials Research Institute Co. Ltd.Changzhou213000China

Rare earth high-entropy alloys(RE-HEAs)exhibit great potential to be applied as refrigerants due to their good comprehensive magnetocaloric *** this work,octary GdTbDyHoErTmCoAl and GdTbDyHoErTmCoNi RE-HEAs with amorphous/nanocrystalline structure exhibiting comparable magnetocaloric effect were *** RE-HEAs show a second-order magnetic phase transition in the temperature range of hydrogen *** to the complex magnetic interactions,a spin glasslike behavior at low temperatures is observed in the RE-HEAs.A superior magnetocaloric effect is obtained in the nanocrystalline GdTbDyHoErTmCoNi high-entropy alloy that is multiphase attributed to a stronger magnetic exchange interaction when compared with the other that exhibits single amorphous *** heterogeneous microstructure,homogeneous chemical distributions are observed in the partially crystallized high-entropy *** addition,the magnetocaloric effect and magnetic transition behavior of rare earth medium-and high-entropy alloys,including the RE-HEAs in this study,are summarized and *** results in this work provide a helpful guide for the design of RE-HEAs for hydrogen liquefaction applications with excellent magnetocaloric effects.

关键词： Rare earths High-entropy alloy Metallic glass Magnetocaloric effect

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Effects of Nd on microstructure and mechanical properties of as-cast Mg-12Gd-2Zn-xNd-0.4Zr alloys with stacking faults

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International Journal of Minerals,Metallurgy and Materials 2022年第8期29卷 1570-1577页

作者： Lixin Hong Rongxiang Wang Xiaobo Zhang School of Materials Science and Engineering Nanjing Institute of TechnologyNanjing 211167China Jiangsu Key Laboratory of Advanced Structural Materials and Application Technology Nanjing 211167China

In order to study the effects of Nd addition on microstructure and mechanical properties of Mg-Gd-Zn-Zr alloys,the microstruc-ture and mechanical properties of the as-cast Mg-12Gd-2Zn-xNd-0.4Zr(x=0,0.5wt%,and 1wt%)alloys were investigated by using optical microscope,scanning electron microscope,X-ray diffractometer,nano indentation tester,microhardness tester,and tensile testing *** results show that the microstructures mainly consist ofα-Mg matrix,eutectic phase,and stacking *** addition of Nd plays a significant role in grain refinement and uniform *** tensile yield strength and microhardness increase but the compression yield strength decreases with increasing Nd addition,leading to weakening tension-compression yield asymmetry in reverse of the Mg-12Gd-2Zn-xNd-0.4Zr *** highest ultimate tensile strength(194 MPa)and ultimate compression strength(397 MPa)are obtained with 1wt%Nd addition of the alloy.

关键词： magnesium alloy neodymium microstructure stacking fault mechanical properties

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Influence of 3D helical magnetic perturbations on runaway electron generation in J-TEXT tokamak

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Plasma Science and technology 2025年第3期27卷 36-44页

作者： Wei YAN Guinan ZOU Zhongyong CHEN You LI Jiangang FANG Zhifang LIN Zhonghe JIANG Nengchao WANG Bo RAO Yangbo LI Zhengkang REN Chuanxu ZHAO Yu ZHONG Fanxi LIU Yinlong YU Zisen NIE Xun ZHOU Yuan SHENG Yuwei SUN Song ZHOU Xiaoqing ZHANG Zhoujun YANG Zhipeng CHEN Yonghua DING the J-TEXT Team State Key Laboratory of Advanced Electromagnetic Technology International Joint Research Laboratory of Magnetic Confinement Fusion and Plasma PhysicsSchool of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan 430074People’s Republic of China School of Electrical Engineering&Automation Jiangsu Normal UniversityXuzhou 221116People’s Republic of China 不详

A large number of runaway electrons(REs)generated during disruption can cause significant damage to next-generation large-scale *** influence of three-dimensional(3D)helical magnetic perturbations on the suppression of RE generation was explored using a set of 3D helical coils in J-TEXT tokamak,which can excite m/n=-2/2 helical magnetic *** evidence shows that the-2/2 magnetic perturbations caused by the opposite coil current direct plasma toward the high-field side,simultaneously enhancing the magnetic fluctuations,which would enhance the radial loss of REs and even prevent RE *** the other hand,-2/2 magnetic perturbations can also reduce the cooling time during the disruption phase and generate a population of high-energy REs,which can interact with high-frequency magnetic fluctuations and in turn suppress RE *** critical helical coil current was found to correlate with electron density,requiring higher coil currents at higher *** to the statistical analysis of RE generation at different electron densities,the applied-2/2 magnetic perturbations can increase the magnetic fluctuations to the same level at lower electron densities,which can decrease the threshold electron density for RE *** will be beneficial for RE mitigation in future large tokamak devices.

关键词： 3D helical magnetic perturbations runaway electron J-TEXT tokamak

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Opportunities and challenges of high-entropy materials in lithium-ion batteries

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Rare Metals 2024年第10期43卷 4884-4902页

作者： Tong-Yue Xu Huai-Wei Feng Wei Liu Yan Wang Hong-He Zheng College of Energy&Jiangsu Key Laboratory of Advanced Negative Carbon Technologies& Collaborative Innovation Center of Suzhou Nano Science and TechnologySoochow UniversitySuzhou 215006China NARI Technology Co. Ltd.Nanjing 211100China

Lithium-ion batteries(LIBs)currently occupy an important position in the energy storage market,and the development of advanced LIBs with higher energy density and power density,better cycle life and safety is a hot topic for both academia and *** recent years,high-entropy materials(HEMs)with complex stoichiometric ratios have attracted great attention in the field of LIBs due to their various promising functional *** adjustability and synergistic effects of multiple elements in HEMs make them possible to break through the bottleneck of traditional electrode materials and electrolytes,providing new opportunities for the development of high-performance *** article provides an overview of the opportunities and challenges of HEMs in LIBs,including cathodes,anodes and *** progress of HEMs in LIBs is first summarized and analyzed,then the potential advantages and limitations of HEMs used in LIBs are concluded,finally some envisioned solutions are proposed to develop more advanced LIBs through HEMs.

关键词： High-entropy materials Lithium-ion batteries Entropy stability Electrode Electrolyte

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Dynamic modeling of a three-dimensional braided composite thin plate considering braiding directions

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Applied Mathematics and Mechanics(English Edition) 2025年第1期46卷 123-138页

作者： Chentong GAO Huiyu SUN Jianping GU W.M.HUANG College of Aerospace Engineering Nanjing University of Aeronautics and AstronauticsNanjing 210016China School of Mechanical and Aerospace Engineering Nanyang Technological UniversitySingapore 639798Singapore Jiangsu Key Laboratory of Advanced Structural Materials and Application Technology School of Materials Science and EngineeringNanjing Institute of TechnologyNanjing 211100China

Currently,there are a limited number of dynamic models available for braided composite plates with large overall motions,despite the incorporation of three-dimensional(3D)braided composites into rotating blade *** this paper,a dynamic model of 3D 4-directional braided composite thin plates considering braiding directions is *** on Kirchhoff's plate assumptions,the displacement variables of the plate are *** incorporating the braiding directions into the constitutive equation of the braided composites,the dynamic model of the plate considering braiding directions is *** effects of the speeds,braiding directions,and braided angles on the responses of the plate with fixed-axis rotation and translational motion,respectively,are *** paper presents a dynamic theory for calculating the deformation of 3D braided composite structures undergoing both translational and rotational *** also provides a simulation method for investigating the dynamic behavior of non-isotropic material plates in various applications.

关键词： three-dimensional(3D)braided composite braiding direction composite thin plate large overall motion dynamic model

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