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PtPdAg nanotrees with low Pt content for high CO tolerance within formic acid and methanol electrooxidation

Rare Metals 2025年第1期44卷 300-310页

作者： Yu-Fei Wang Shou-Lin Zhang Yu-Xin Deng Shi-Han Luan Cai-Kang Wang Lin-Fei Ding Xian Jiang Dong-Mei Sun Ya-Wen Tang Jiangsu Key Laboratory of New Power Batteries Jiangsu Collaborative Innovation Centre of Biomedical Functional MaterialsSchool of Chemistry and Materials ScienceNanjing Normal UniversityNanjing 210023China School of New Energy Nanjing University of Science and TechnologyJiangyin 214443China Advanced Analysis and Testing Center Nanjing Forestry UniversityNanjing 210037China

To efficiently diminish the Pt consumption while concurrently enhancing the anodic reaction kinetics,a straightforward synthesis for PtPdAg nanotrees(NTs)with exceedingly low Pt content is presented,utilizing the galvanic replacement reaction between the initially prepared PdAg NTs and Pt *** to the multilevel porous tree-like structure and the incorporation of low amounts of Pt,the electrocatalytic activity and stability of PtPdAg NTs are markedly enhanced,achieving 1.65 and 1.69 A·mg^(-1)Pt+Pd for the anodic reactions of formic acid oxidation(FAOR)and methanol oxidation(MOR)within DLFCs,surpassing the performance of PdAg NTs,as well as that of commercial Pt and Pd *** functional theory(DFT)calculations reveal that the addition of low amounts of Pt leads to an increase in the d-band center of PtPdAg NTs and lower the COads adsorption energy to-1.23 eV,enhancing the anti-CO toxicity properties *** approach offers an effective means for designing low Pt catalysts as exceptional anodic electrocatalysts for direct liquid fuel cells.

关键词： PtPdAg nanotrees Low Pt Bifunctional electrocatalysts Methanol oxidation reaction Formic acid oxidation

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Promoting effect of d-band center and in-situ precipitation strategy on sulfur evolution reaction

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Journal of Energy Chemistry 2025年第5期104卷 740-748页

作者： Jun Pu Yun Tan Jiasen Yin Zihan Shen Shoujie Liu Kai Zhang Lei Zhou Yagang Yao Key Laboratory of Functional Molecular Solids Ministry of Education Anhui Provincial Engineering Laboratory for New-Energy Vehicle Battery Energy-Storage Materials College of Chemistry and Materials Science Anhui Normal University National Laboratory of Solid State Microstructures College of Engineering and Applied Sciences Jiangsu Key Laboratory of Artificial Functional Materials Collaborative Innovation Center of Advanced Microstructures Nanjing University State Key Laboratory of Multiphase Complex Systems Institute of Process Engineering Chinese Academy of Sciences School of Materials Science and Engineering Anhui University School of Energy and Power Engineering Jiangsu University Department of Electrical Engineering Eindhoven University of Technology

The slow conversion of polyphase in lithium-sulfur （Li-S） batteries not only intensifies the shuttle effect of lithium polysulfides （LiPSs）,but also causes the continuous accumulation of inactive sulfur species,resulting in rapid capacity attenuation and sluggish dynamic ***,the promoting effect of atomic interface stress on sulfur reaction was investigated via CoFe-CoFe2O4heterogeneous nanosheets with a cavity *** strain force induced by the in-situ precipitation of Co Fe bimetallic alloy in oxide matrix increased the d-band center,which was conducive to the interaction between catalyst and Li *** sulfur cathode based on this two-dimensional （2D） nanosheet design showed an extremely high capacity of 751 mAh g-1at 4 *** with a sulfur loading of 5.55 mg cm-2,its area capacity was still as high as 7.15 mAh ***,the enhanced stability greatly improved the practical potential of Li-S batteries.

关键词： 2D nanosheets D-band center In-situ precipitation Li-S batteries Strain effect

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Pulse Signal Acquisition Using Flexible Sensing Dense Array with High Spatial Resolution 38

Pulse Signal Acquisition Using Flexible Sensing Dense Array ...

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38th IEEE International Conference on Micro Electro Mechanical Systems, MEMS 2025

作者： He, Yue Sun, Ke Wang, Fang Tao, Tiger H Yang, Heng Sun, Yi Wang, Quan Li, Xinxin Jiangsu University Zhenjiang Key Laboratory of Advanced Sensing Materials and Devices Zhenjiang212013 China Shanghai Institute of Microsystem and Information Technology Chinese Academy of Sciences State Key Laboratory of Transducer Technology Shanghai200050 China

ISBN: (纸本)9798331508890

This paper reports a pressure sensing array with high spatial resolution, which, in combination with the proposed cross-sectional feature algorithm, enables measurements with a positional accuracy of at least 0.1 mm. For the first time in human pulse wave testing experiments, we have visualized the lateral offset of the pulse wave. In addition, we found that some people, such as patients with fever and pain, have slightly larger pulse wave offsets than others, which may be described as 'tight pulse' in traditional Chinese medicine (TCM). © 2025 IEEE.

关键词： Pressure transducers

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Integrated Cross-Scale Manipulation and Modulable Encapsulation of Cell-Laden Hydrogel for Constructing Tissue-Mimicking Microstructures

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Research 2025年第1期2024卷 704-717页

作者： Yanfeng Zhao Xinyi Dong Yang Li Juan Cui Qing Shi Hen-Wei Huang Qiang Huang Huaping Wang Intelligent Robotics Institute School of Mechatronical EngineeringBeijing Institute of TechnologyBeijing 100081China Peking University First Hospital Xicheng DistrictBeijing 100034China Key Laboratory of Instrumentation Science and Dynamic Measurement Ministry of EducationNorth University of ChinaTaiyuan 030051China Beijing Advanced Innovation Center for Intelligent Robots and Systems Beijing Institute of TechnologyBeijing 100081China Laboratory for Translational Engineering Harvard Medical SchoolCambridgeMA 02139USA Key Laboratory of Biomimetic Robots and Systems (Beijing Institute of Technology) Ministry of EducationBeijing 100081China

Engineered microstructures that mimic in vivo tissues have demonstrated great potential for applications in regenerative medicine,drug screening,and cell behavior ***,current methods for engineering microstructures that mimic the multi-extracellular matrix and multicellular features of natural tissues to realize tissue-mimicking microstructures in vitro remain ***,we propose a versatile method for constructing tissue-mimicking heterogeneous microstructures by orderly integration of macroscopic hydrogel exchange,microscopic cell manipulation,and encapsulation ***,various cell-laden hydrogel droplets are manipulated at the millimeter scale using electrowetting on dielectric to achieve efficient hydrogel ***,the cells are manipulated at the micrometer scale using dielectrophoresis to adjust their density and arrangement within the hydrogel ***,the photopolymerization of these hydrogel droplets is triggered in designated regions by dynamically modulating the shape and position of the excitation ultraviolet ***,heterogeneous microstructures with different extracellular matrix geometries and components were constructed,including specific cell densities and *** resulting heterogeneous microstructure supported long-term culture of hepatocytes and fibroblasts with high cell viability(over 90%).Moreover,the density and distribution of the 2 cell types had significant effects on the cell proliferation and urea *** propose that our method can lead to the construction of additional biomimetic heterogeneous microstructures with unprecedented potential for use in future tissue engineering applications.

关键词： cell behavior explorationhowevercurrent tissue mimicking microstructures cell laden hydrogel electrowetting dielectric regenerative medicinedrug screeningand heterogeneous microstructures engineered microstructures orderly integration

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Space-confined vapor deposited molecular ferroelectric film for photovoltaic devices

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Nano Research 2025年第3期18卷 611-618页

作者： Chen Wang Shan Cong Lingbo Xiao Chao-ran Huang Ruonan Wang Ruijie Li Lutao Li Guifu Zou Qiang Zhang College of Mechanical and Electronic Engineering Shandong University of Science and TechnologyQingdao 266590China College of Energy Soochow Institute for Energy and Materials Innovationsand Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu ProvinceSoochow UniversitySuzhou 215000China Department of Applied Physics Zhejiang University of Science and TechnologyHangzhou 310023China School of Advanced Energy Sun Yat-sen UniversityShenzhen 518107China

Molecular ferroelectrics,characterized by outstanding photoelectric and unique ferroelectric properties,invigorate the field of ferroelectric ***,the performance of molecular ferroelectric devices is hindered by fine grains resulting from poor high-temperature *** this work,we successfully achieved micron-grained molecular ferroelectric films by using the space-confined vapor deposited *** optimized film exhibited a significant increase in grain size from the nanometer level(0.08μm)to the micrometer level(~2μm),leading to improved optoelectronic and ***,it optimizes the energy level and enhances the photovoltaic performance of vertical *** on the mechanism shows that high annealing temperature and inhibiting component loss play an important role in obtaining large grain *** work provides new research ideas for improving the quality of molecular ferroelectric films and provides valuable reference for the fabrication of high performance molecular ferroelectric photovoltaic devices.

关键词： molecular ferroelectric large grain space confinement photovoltaic devices

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Enhancing performance of fullerene-based organic electrochemical transistors via side-chain engineering

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Nano Research 2025年第2期18卷 905-912页

作者： Wenxin Fang Zijie Li Chengdong Wang Xiaowei Zhao Junyu Li Gang Ye Fengwei Huo Li Qiu Yanxi Zhang Wei Huang Institute of Flexible Electronics(IFE Future Technologies)Xiamen UniversityXiamen 361005China Yunnan Key Laboratory of Electromagnetic Materials and Devices National Center for International Research on Photoelectric and Energy MaterialsSchool of Materials and EnergyYunnan UniversityKunming 650091China Sinopec Shanghai Research Institute of Petrochemical Technology Shanghai 201028China Key Laboratory for the Green Preparation and Application of Functional Materials Hubei Key Laboratory of Polymer MaterialsSchool of Materials Science and EngineeringHubei UniversityWuhan 430062China Key Laboratory of Flexible Electronics(KLOFE)&Institute of Advanced Materials(IAM) Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM)Nanjing Tech University(NanjingTech)Nanjing 211800China Frontiers Science Center for Flexible Electronics MIIT Key Laboratory of Flexible Electronics(KLoFE)Northwestern Polytechnical UniversityXi'an 710072China

The performance of organic electrochemical transistors(OECTs)relies on the interaction between organic semiconductors and ***,hydrophilic ethylene glycol(EG)side chains are incorporated into organic semiconductors to improve the channel’s capacity to absorb ***,the EG substituted organic semiconductors tend to swell when immersed in aqueous electrolytes and exhibit microstructural changes induced by dopant *** our research,we introduce an alkyl spacer to create distance between the fullerene and EG *** approach is designed to reduce the negative effects of swelling and balance the ion and electron *** conducted an analysis of OECTs using four fullerene derivatives:no alkyl spacer,butyl,hexyl,and octyl *** OECTs based on fullerene derivatives with butyl and hexyl spacers exhibit enhanced transconductance(g_(m)=11.8 and 19.4 mS)compared to the ones without alkyl *** has also been observed that the butyl and hexyl spacers lead to a more than tenfold increase in volumetric *** increasing the alkyl spacer(octyl group)leads to no transistor *** study uncovers the relationship between alkyl spacers and the performance of OECTs based on fullerene *** will serve as a guideline for designing n-type small molecules for ***,we showcased the potential of utilizing OECTs based on these fullerene derivatives in cation sensing,which is promising for developing sweat sensors.

关键词： organic electrochemical transistors fullerene derivatives ethylene glycol side chains ion and electron conduction

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Coordinated control of decarbonization efficiency and oxygen absorption rate in Ruhrstahl–Heraeus degasser based on mechanism model and BP neural network

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Journal of Iron and Steel Research International 2025年第3期32卷 606-618页

作者： Lu-heng Jiang Min Wang Jia-qi Zhao Cheng Yao Li-dong Xing Xin-gang Ai State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing100083China Technical Support Centre for Prevention and Control of Disastrous Accidents in Metal Smelting University of Science and Technology BeijingBeijing100083China Institute of Research of Iron&Steel Zhangjiagang215600JiangsuChina School of Materials and Metallurgy University of Science and Technology LiaoningAnshan114051LiaoningChina

A mathematical model of the decarburization reaction zone was established for the Ruhrstahl–Heraeus (RH) forced oxygen blowing decarburization process by Matlab R2022b software. For the problem of inaccurate prediction due to the large variation range of oxygen absorption rate under different process conditions, we statistically analyzed the main factors affecting the oxygen absorption rate. The backpropagation neural network was used to train and predict the oxygen absorption rate and was used to calculate the RH decarburization reaction zone model. We designed and developed a mathematical modeling software with process control of decarburization in RH degasser, which can realize the change of operating process parameters in the dynamic prediction process. The optimized mathematical model has more than 95% of the furnaces whose absolute error in calculation of carbon content is within ± 5 × 10^(−6), more than 90% of the heats whose relative error in calculation of oxygen content is within ± 15%, and the average absolute error of calculation of oxygen content is 26.4 × 10−6. Finally, we studied the influence of oxygen blowing timing, oxygen blowing volume and initial oxygen content on the forced decarburization process.

关键词： Ruhrstahl-Heraeus degasser Mathematical model Forced decarburization Oxygen absorption rate Process control

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Efficient and Stable Perovskite Light-Emitting Diodes Enabled by Oriented Growth Regulation

IEEE Electron Device Letters

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IEEE Electron Device Letters 2025年第6期46卷 952-955页

作者： Zhang, Kun Zhang, Xiaofei Zhang, Chengxi Feng, Jie Kong, Lingmei Wang, Sheng Yang, Yingguo Wang, Lin Yang, Xuyong Shanghai University Key Laboratory of Advanced Display and System Applications of Ministry of Education Shanghai200072 China Jiangsu University of Science and Technology School of Science Zhenjiang212100 China Zhangjiang Lab Shanghai Advanced Research Institute Shanghai China Fudan University School of Microelectronics Shanghai China

Metal halide perovskites have demonstrated remarkable progress in optoelectronic applications, including solar cells and light-emitting diodes (LEDs). However, the long-term stability of perovskite LEDs (PeLEDs) remains a critical challenge, impeding their practical applications and commercialization. Herein, we regulate the growth kinetics of perovskites in liquid-solid stages by introducing 2,3,4,5, 6-pentafluorophenylphosphonic acid (PFBPA) into the precursor solution. The PFBPA molecules will create a protective passivation layer by coordinating with uncoordinated lead (Pb2+) on the perovskite surface, which regulates the growth of perovskite crystals during the liquid-solid stages and results in the formation of uniform perovskite films with reduced grain size. Moreover, the coordination of PFBPA with Pb2+ also improves the moisture resistance of perovskites, favoring the operational stability of devices. The resulting PeLED devices achieved a maximum brightness of 12426 cd m-2, a peak external quantum efficiency (EQE) of 22.6%, and a remarkable operational stability with a half-lifetime exceeding 1187 hours at initial luminance of 100 cd m-2. © 1980-2012 IEEE.

关键词： Perovskite

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Preparation of a novel foam concrete for the carbonation of steel slag with low thermal conductivity and enhanced CO2 capture

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Materials Letters 2025年 394卷

作者： Wang, Yuhan Lu, Bao Hou, Guihua Key Laboratory for Advanced Technology in Environment Protection of Jiangsu Province Yancheng Institute of Technology Jiangsu Yancheng224051 China

The foam concrete was prepared using carbonation curing with steel slag as the raw material. The composition and moisture content of carbonated steel slag and hydrated Portland cement were compared. The optimal preparation parameters and properties of carbonated steel slag foam concrete were investigated. Results showed that the 14 d moisture content of carbonated steel slag (5.3 %) was significantly lower than that of hydrated Portland cement (13.5 %), indicating that carbonated steel slag contains fewer heat-transfer mediums, making it superior for foam concrete production. Under optimum conditions, the steel slag foam concrete exhibited a thermal conductivity of 0.0547 W/(m·K), compressive strength of 0.59 MPa, and CO2 sequestration capacity of 138.7 g/kg. This study offers a novel approach for preparing lightweight insulation wall materials while simultaneously utilizing steel slag and CO2. © 2025

关键词： Positive temperature coefficient

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Regulating crystallization and retarding oxidation in Sn-Pb perovskite via 1D cation engineering for high performance all-perovskite tandem solar cells

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Journal of Energy Chemistry 2025年第1期100卷 646-652页

作者： Ranran Liu Xin Zheng Zaiwei Wang Miaomiao Zeng Chunxiang Lan Shaomin Yang Shangzhi Li Awen Wang Min Li Jing Guo Xuefei Weng Yaoguang Rong Xiong Li Michael Grätzel Center for Mesoscopic Solar Cells Wuhan National Laboratory for OptoelectronicsHuazhong University of Science and TechnologyWuhan 430074HubeiChina Institute of Technology for Carbon Neutrality Shenzhen Institute of Advanced TechnologyChinese Academy of SciencesShenzhen 518055GuangdongChina School of Chemistry Chemical Engineering and Life SciencesState Key Laboratory of Advanced Technology for Materials Synthesis and ProcessingWuhan University of Technology430070HubeiChina Suzhou Institute of Nano-Tech and Nano-Bionics(SINANO) Chinese Academy of SciencesSuzhou 215123JiangsuChina School of Physics and Optoelectronic Engineering Hainan UniversityHaikou 570228HainanChina

All-perovskite tandem solar cells have the potential to surpass the theoretical efficiency limit of single junction solar cells by reducing thermalization ***,the challenges encompass the oxidation of Sn^(2+)to Sn^(4+)and uncontrolled crystallization kinetics in Sn-Pb perovskites,leading to nonradiative recombination and compositional heterogeneity to decrease photovoltaic efficiency and operational ***,we introduced an ionic liquid additive,1-ethyl-3-methylimidazolium iodide (EMIMI) into Sn-Pb perovskite precursor to form low-dimensional Sn-rich/pure-Sn perovskites at grain boundaries,which mitigates oxidation of Sn^(2+)to Sn^(4+)and regulates the film-forming dynamics of Sn/Pb-based perovskite *** optimized single-junction Sn-Pb perovskite devices incorporating EMIMI achieved a high efficiency of 22.87%.Furthermore,combined with wide-bandgap perovskite sub-cells in tandem device,we demonstrate 2-terminal all-perovskite tandem solar cells with a power conversion efficiency of 28.34%,achieving improved operational stability.

关键词： All-perovskite tandem solar cells Sn-Pb perovskite 1D Regulated crystallization Antioxidation

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