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Cover Picture: Single-Atom Iron Catalysts on Overhang-Eave Carbon Cages for High-Performance Oxygen Reduction Reaction (Angew. Chem. Int. Ed. 19/2020)

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Angewandte Chemie International Edition 2020年第19期59卷

作者： Dr. Chun-Chao Hou Dr. Lianli Zou Dr. Liming Sun Dr. Kexin Zhang Dr. Zheng Liu Prof. Yinwei Li Dr. Caixia Li Prof. Ruqiang Zou Prof. Jihong Yu Prof. Qiang Xu AIST-Kyoto University Chemical Energy Materials Open Innovation Laboratory (ChEM-OIL) National Institute of Advanced Industrial Science and Technology (AIST) Sakyo-ku Kyoto 606-8501 Japan Graduate School of Engineering Kobe University Nada Ku Kobe Hyogo 657-8501 Japan Laboratory of Quantum Materials Design and Application School of Physics and Electronic Engineering Jiangsu Normal University Xuzhou 221116 P. R. China Beijing Key laboratory for Theory and Technology of Advanced Battery Materials Department of Materials Science and Engineering College of Engineering Peking University Beijing 100871 P. R. China Inorganic Functional Materials Research Institute National Institute of Advanced Industrial Science and Technology (AIST) 2266-98 Anagahora Shimoshidami Moriyamaku Nagoya Aichi 463-8560 Japan State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry International Center of Future Science Jilin University Changchun 130012 P. R. China

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Novel Molecular Composites Based on Poly(esterimide)s

Novel Molecular Composites Based on Poly(esterimide)s

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第二十一届国际复合材料大会

作者： Qingbao Guan Li Yuan Aijuan Gu Guozheng Liang Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application Department of Materials Science and EngineeringCollege of Chemistry Chemical Engineering and Materials ScienceSoochow University

We are currently exploring all-aromatic copoly（ester-imide）s based on N-（3'-hydroxyphenyl）trimellitimide（IM） and 4-hydroxybenzoic acid（HBA）.Two different crystal phase polymers with molar ratio of IM/HBA as 0.3/0.7（semi-crystalline） and 0.7/0.3（amorphous） were obtained from a one-step melt polymerization method, namely 3-IM/7-HBA and 7-IM/3-HBA, *** both cases, thermoplastic polymers were obtained with a high volume fraction of infusible crystalline poly（HBA） or amorphous poly（IM）.Composite films prepared by melt pressing are brittle but upon stretching（stretch ratios of 4 are possible） above their glass transition temperature（T） their ductility improves *** to different reinforcement mechanisms, the two molecular composites exhibit different thermo-mechanical properties.3-IM/7-HBA composite films show a strong dependence of the T on the stretch *** as prepared films exhibit a T of 205 ℃ and the T increased to 248 ℃ after stretching the films 3 times above *** tensile strength and elongation at break of the film increased by 0%（78 MPa） and 5%（3% elongation）, respectively after one stretching *** the case of 7-IM/3-HBA, an increasing trend was observed in storage modulus（E'）.The room temperature storage modulus increased from 7 to 28 GPa after 3 stretching *** this case, however, there is no effect on *** as-prepared films could not be handled（too brittle） but after stretching the film once above T, a tensile strength of 161 MPa and elongation of 9% was *** the best of our knowledge, such improvements in thermo-mechanical properties in all-aromatic main-chain polymers have not been reported before.

关键词： polyesterimide molecular composite stretched films

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Titelbild: Single‐Atom Iron Catalysts on Overhang‐Eave Carbon Cages for High‐Performance Oxygen Reduction Reaction (Angew. Chem. 19/2020)

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Angewandte Chemie 2020年第19期132卷

作者： Chun‐Chao Hou Lianli Zou Liming Sun Kexin Zhang Zheng Liu Yinwei Li Caixia Li Ruqiang Zou Jihong Yu Qiang Xu AIST-Kyoto University Chemical Energy Materials Open Innovation Laboratory (ChEM-OIL) National Institute of Advanced Industrial Science and Technology (AIST) Sakyo-ku Kyoto 606-8501 Japan Graduate School of Engineering Kobe University Nada Ku Kobe Hyogo 657-8501 Japan Laboratory of Quantum Materials Design and Application School of Physics and Electronic Engineering Jiangsu Normal University Xuzhou 221116 P. R. China Beijing Key laboratory for Theory and Technology of Advanced Battery Materials Department of Materials Science and Engineering College of Engineering Peking University Beijing 100871 P. R. China Inorganic Functional Materials Research Institute National Institute of Advanced Industrial Science and Technology (AIST) 2266-98 Anagahora Shimoshidami Moriyamaku Nagoya Aichi 463-8560 Japan State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry International Center of Future Science Jilin University Changchun 130012 P. R. China

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Synthesis and properties of three novel rhodamine-based fluorescent sensors for Hg^(2+)

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Chinese Chemical Letters 2016年第6期27卷 989-992页

作者： Miao-Miao Hong Ai-Feng Liu Ying Xu Dong-Mei Xu College of Chemistry Chemical Engineering and Materials Science Soochow University Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application Soochow University Testing and Analysis Center Soochow University

Three novel rhodamine-based Hg^2＋ fluorescent sensors were designed and synthesized. The sensors could work in semi-aqueous solutions with nearly neutral p H and showed high selectivity and sensitivity to Hg^2＋ with remarkable fluorescence enhancement. For these three sensors, the linear working range broadened（0–80, 0–100 and 0–140 μmol/L, respectively） and the sensitivity increased（7.7, 15.5 and 17.6 folds of the fluorescence enhancement and 512, 66.2 and 37.6 ppb of the detection limit） with the rising of the thiourea-unit numbers. Furthermore the sensors exhibited excellent interference immunity to multiple environmentally and biologically relevant metal ions. Pond and tap water assay showed good practicability of the sensors. The number of the bound Hg^（2＋） equaling to that of the thiourea units and the irreversible recognition process implied a new interaction way between Hg^（2＋） and the sensor.

关键词： Rhodamine Polyethylenepolyamine Thiourea Fluorescent sensor Hg2＋

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Conformational Chirality of the Biphenyl Groups Induced by the Aggregation of Poly {bis[4-(4＇-(S)-2-methylbutoxy)- Biphenoxy] Phosphazene}

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Journal of Wuhan University of Technology(Materials Science) 2016年第5期31卷 1162-1166页

作者：唐贤慧 LI Baozong 李艺 YANG Yonggang Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application Department of Polymer Science and Engineering College of Chemistry Chemical Engineering and Materials Science Soochow University Suzhou 215123 China

Poly{bis[4-（4＇-（S）-2-methylbutoxy）biphenyloxy]phosphazene}（PP-C） was designed and successfully synthesized, and then characterized by means of FT-IR spectroscopy, ~1H- and ^（31）P-NMR, GPC spectroscopy, wide angle X-ray diffraction and differential scanning calorimetry. The results indicated that for PP-C, the M_w is 2.18×10~5 and the PDI is 1.96. PP-C was a kind of crystallized polymer with a crystallizing point of -2.0 ℃ and a melting point of 28 ℃. The conformational chirality of the PP-C molecules was studied using circular dichroism spectrum. It was found that in dilute THF solution, the biphenyl groups in the PP-C molecules twisted randomly. However, when the PP-C formed aggregates, the biphenyl groups tended to twist single-handedly, which was controlled by the adjacent chiral alkoxy groups.

关键词： polyphosphazene biphenyl chirality aggregates

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Photoconversion-Tunable Bodipy Vesicles forWavelength-Dependent Photo-Induced Cancer Therapy

Photoconversion-Tunable Bodipy Vesicles forWavelength-Depend...

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中国化学会第四届卟啉与酞菁学术研讨会

作者： Hui He Shuangshuang Ji Zhengqing Guo Youliang Zhao Huabing Chen Jiangsu Key Laboratory of Translational Research and Therapy for Neuro-Psycho-Diseases College of Pharmaceutical SciencesSoochow University School of Radiological and Interdisciplinary Sciences(RAD-X) Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutionsand School of Radiation Medicine and ProtectionSoochow University Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis Jiangsu Key Laboratory of Advanced Functional Polymer Design and ApplicationState and Local Joint Engineering Laboratory for Novel Functional Polymeric MaterialsCollege of ChemistryChemical Engineering and Materials ScienceSoochow University

Photo-induced cancer therapy,such as photodynamic therapy（PDT） or photothermal therapy（PTT） treatment has shown great promise in precision nanomedicine owing to their selectivity,low systemic toxicity,negligible drug resistance,and non-invasive modality.1-3 In this presentation,we will demonstrate wavelength-dependent photoconversion regulation of Bodipy fluorophores through polymeric vesicles for either PDT or PTT treatment（Scheme 1）.Bodipy is assembled with the terpolymer into polymeric vesicles in the conformation of both J-type and H-type aggregates,causing the red-shifted absorption into the near-infrared（NIR） region,low radiative transition,and ideal resistance to *** 660 nm irradiation,the vesicles mainly display remarkable singlet oxygen quantum yield through singlet-to-triplet transition,thereby leading to abundant intracellular singlet oxygen at the tumor for effective ***,under 785 nm irradiation,they primarily possess distinct photothermal conversion efficiency through non-radiative transition together with mild singlet oxygen generation,thus leading to potent hyperthermia at the tumor for robust PDT-synergized ***,the vesicles have preferable cellular uptake,effective cytoplasmic drug translocation through singlet oxygen-mediated lysosomal disruption,and enhanced tumor accumulation,which contribute to the total tumor ablation without any regrowth.4

关键词： Bodipy photodynamic therapy photothermal therapy polymeric vesicles tumor ablation

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Energy Storage: Confined Assembly of Hollow Carbon Spheres in Carbonaceous Nanotube: A Spheres-in-Tube Carbon Nanostructure with Hierarchical Porosity for High-Performance Supercapacitor (Small 19/2018)

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Small 2018年第19期14卷

作者： Ze Chen Sunjie Ye Stephen D. Evans Yuanhang Ge Zhifeng Zhu Yingfeng Tu Xiaoming Yang State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application Department of Polymer Science and Engineering College of Chemistry Chemical Engineering and Materials Science Soochow University Suzhou 215123 P. R. China School of Physics and Astronomy University of Leeds Leeds LS2 9JT UK

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Macromol. Rapid Commun. 5/2018

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Macromolecular Rapid Communications 2018年第5期39卷

作者： Xiao‐Yan Tu Chao Meng Yun‐Fei Wang Li‐Wei Ma Bao‐Yan Wang Jin‐Lin He Pei‐Hong Ni Xiang‐Ling Ji Ming‐Zhu Liu Hua Wei State Key Laboratory of Applied Organic Chemistry Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province College of Chemistry and Chemical Engineering Lanzhou University Lanzhou 730000 Gansu China College of Chemistry Chemical Engineering and Materials Science State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application Soochow University Suzhou 215123 China State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun 130022 China

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Chiral Nanoparticles: Chiral Nanoparticle‐Induced Enantioselective Amplification of Molecular Optical Activity (Adv. Funct. Mater. 8/2019)

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advanced functional Materials 2019年第8期29卷

作者： Lin Yang Chak‐Shing Kwan Lianglin Zhang Xinghua Li Yu Han Ken Cham‐Fai Leung Yonggang Yang Zhifeng Huang Department of Physics Hong Kong Baptist University (HKBU) Kowloon Tong Kowloon Hong Kong SAR China Department of Chemistry HKBU Kowloon Tong Kowloon Hong Kong SAR China Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application Department of Polymer Science and Engineering State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials College of Chemistry Chemical Engineering and Materials Science Soochow University Suzhou 215123 China King Abdullah University of Science & Technology Physical Science and Engineering Division Thuwal 23955‐6900 Kingdom of Saudi Arabia Partner State Key Laboratory of Environmental and Biological Analysis HKBU Kowloon Tong Kowloon Hong Kong SAR China Institute of Advanced Materials HKBU Kowloon Tong Kowloon Hong Kong SAR China HKBU Institute of Research and Continuing Education 9F The Industrialization Complex of Shenzhen Virtual University Park No. 2 Yuexing 3rd Road South Zone Hi‐tech Industrial Park Nanshan District Shenzhen Guangdong 518057 China

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Special Odd-Even Effect of Degree of Oligomerization on Properties of Cyclic Oligoesters

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Chinese Journal of Polymer Science 2015年第8期33卷 1069-1069,1070-1073页

作者： Jun Wu Tao-guang Qu Ling-feng Gao Xiao-ming Yang Xiao-hong Li 屠迎锋 Xiu-lin Zhu Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis Jiangsu Key Laboratory of Advanced Functional Polymer Design and ApplicationCollege of ChemistryChemical Engineering and Materials ScienceSoochow University

We demonstrate here seven pure cyclic samples, which belongs to two series of oligoesters, cyclic oligo（trimethylene terephthalate）s （COTTs） and cyclic oligo（butylene terephthalate）s （COBTs）, showing odd-even effect of degree of oligomerization （repeating units number） on properties. The pentamer of COTT and trimer of COBT show much lower melting temperature, and the trimer of COTT and trimer of COBT show significant lower refractive index, which can be ascribed to the low packing density of cyclic oligoesters with odd number of degree of oligomerization. Our results reveal the discrete property change as a function of cyclic size of oligomers, which can be used to design materials with special properties.

关键词： Cyclic polymer Oligomer Odd-even effect Refractive index.

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