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Confinement of Fe atoms between MoS_(2) interlayers drives phase transition for improved reactivity in Fenton-like reactions

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Nano Research 2024年第3期17卷 1132-1139页

作者： Yibing Sun Yu Zhou Hongchao Li Chuan Wang Xuan Zhang Qian Ma Yingchun Cheng Jieshu Qian Bingcai Pan Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse School of Environmental and Biological EngineeringNanjing University of Science and TechnologyNanjing 210094China Key Laboratory of Flexible Electronics and Institute of Advanced Materials Jiangsu National Synergetic Innovation Center for Advanced MaterialsNanjing Tech UniversityNanjing 211816China Department of General Dentistry Affiliated Stomatological Hospital of Nanjing Medical UniversityJiangsu Province Key Laboratory of Oral DiseasesNanjing 210029China Research Center for Environmental Nanotechnology(ReCENT) State Key Laboratory of Pollution Control and Resources ReuseSchool of EnvironmentNanjing UniversityNanjing 210023China

Phase manipulation of MoS_(2) from thermodynamically stable 2H phase to the unstable but more reactive 1T phase represents a crucial strategy for improving the reactivity in many *** widely adopted wet chemistry approach uses intercalating entities especially alkali metal ions to achieve the phase transition;however,these entities are normally inert for the target ***,we describe the first use of iron atoms for the intercalation of 2H-MoS_(2) layers,driving the partial transition from 2H to 1T ***,in the peroxymonosulfate(PMS)-based Fenton-like reactions,the interlayered confinement of Fe atoms not only activates the inert basal plane,but also adds more reactive Fe sites for the formation of metal-PMS complex as primary reactive species for pollutant *** the degradation of a model pollutant carbamazepine(CBZ),the Fe-intercalated MoS_(2) exhibits a first order rate constant 13.3 times higher than 2H-MoS_(2).This strategy is a new direction for manipulating the phase composition and boosting the catalytic reactivity of MoS_(2)-based catalysts in various scenarios,including environmental remediation and energy applications.

关键词： confinement MoS_(2) Fe atoms Fenton-like reactions hydrogen evolution reaction

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Molecular-level proton acceptor boosts oxygen evolution catalysis to enable efficient industrial-scale water splitting

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Green Energy & Environment 2024年第2期9卷 344-355页

作者： Yaobin Wang Qian Lu Xinlei Ge Feng Li Le Chen Zhihui Zhang Zhengping Fu Yalin Lu Yang Song Yunfei Bu Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment Technology(CICAEET) Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control(AEMPC)UNIST-NUIST Energy and Environment Jointed Lab(UNNU)School of Environmental Science and TechnologyNanjing University of Information Science and Technology(NUIST)219 NingliuNanjing210044China Laboratory of Advanced Materials Shanghai Key Laboratory of Molecular Catalysis and Innovative MaterialsFudan University220 HandanShanghai200433China Jiangsu Key Laboratory of Advanced Materials and Technology School of Petrochemical EngineeringChangzhou University1 GehuChangzhou213164China Anhui Laboratory of Advanced Photon Science and Technology University of Science and Technology of China(USTC)96 JinzhaiHefeiAnhui 230026China School of Chemistry and Chemical Engineering Nanjing University of Science and Technology200 Xiaolingwei210094China

Industrial water splitting has long been suppressed by the sluggish kinetics of the oxygen evolution reaction(OER),which requires a catalyst to be ***,we propose a molecular-level proton acceptor strategy to produce an efficient OER catalyst that can boost industrial-scale water ***-level phosphate(-PO_(4))group is introduced to modify the surface of PrBa_(0.5)Ca_(0.5)Co_(2)O_(5)+δ(PBCC).The achieved catalyst(PO_(4)-PBCC)exhibits significantly enhanced catalytic performance in alkaline *** on the X-ray absorption spectroscopy results and density functional theory(DFT)calculations,the PO_(4)on the surface,which is regarded as the Lewis base,is the key factor to overcome the kinetic limitation of the proton transfer process during the *** use of the catalyst in a membrane electrode assembly(MEA)is further evaluated for industrial-scale water splitting,and it only needs a low voltage of 1.66 V to achieve a large current density of 1 A cm^(-2).This work provides a new molecular-level strategy to develop highly efficient OER electrocatalysts for industrial applications.

关键词： Oxygen evolution reaction Nanofiber Water splitting Proton acceptor Perovskite

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Solar evaporation for simultaneous oil-water separation and electricity generation with Janus wood-based absorbers

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Frontiers of Environmental Science & Engineering 2024年第2期18卷 13-23页

作者： Yue Yang Ze Fu Qi Zhang Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse School of Environmental and Biological EngineeringNanjing University of Science&TechnologyNanjing 210094China Key Laboratory of Industrial Ecology and Environmental Engineering(Ministry of Education) School of Environmental Science and TechnologyDalian University of TechnologyDalian 116024China National Laboratory of Solid State Microstructures Collaborative Innovation Center of Advanced MicrostructuresCollege of Engineering and Applied SciencesKey Laboratory of Intelligent Optical Sensing and Manipulation(Ministry of Education)Jiangsu Key Laboratory of Artificial Functional MaterialsNanjing UniversityNanjing 210093China

Oily wastewater from ocean oil spills endangers marine ecosystems and human health. Therefore, developing an effective and sustainable solution for separating oil-water mixtures is urgent. Interfacial solar photothermal evaporation is a promising approach for the complete separation of two-phase mixtures using only solar energy. Herein, we report a carbonized wood-based absorber with Janus structure of comprising a hydrophobic top-layer and an oleophobic bottom-layer for simultaneous solar-driven oil-water separation and electricity generation. Under sunlight irradiation, the rapid evaporation of seawater will induce a separation of oil-water mixtures, and cause a high salt concentration region underlying the interface, while the bottom “bulk water” maintains in a low salt concentration, thus forming a salinity gradient. Electricity can be generated by salinity gradient power. Therefore, oil-water separation efficiency of > 99% and derived extra electricity power of ~0.1 W/m2 is achieved under solar radiation, demonstrating the feasibility of oil-water separation and electricity production synchronously directly using solar energy. This work provides a green and cost-effective path for the separation of oil-water mixtures.

关键词： Oily wastewater Carbonized wood Salinity gradient Electricity generation Solar irradiation

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Multi-anion electrolyte modulates the interactions in solvation structure to construct robust lithium metal batteries

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Journal of Energy Chemistry 2025年第5期104卷 36-43页

作者： Ke-Feng Ren Yun-Fei Du Jia-Xin Guo Zhen-Hui Luo Xin Sun Wen-Bo Tang Tian-Qi Li Cong Guo Weizhai Bao Feng Yu He Liu Xin-Bing Cheng Jingfa Li Jiangsu Key Laboratory of New Energy Devices & Interface Science School of Chemistry and Materials Science Nanjing University of Information Science and Technology Z Energy Storage Center Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education School of Energy and Environment Southeast University Tianmu Lake Institute of Advanced Energy Storage Technologies

Designing anion-dominated weak solvation structures is often achieved by elevating the concentration of Li ***,this is accompanied by the increase in the ***,a medium concentration electrolyte （1 M） with weak solvation structures is established by the multi-anion *** anions in the electrolyte strengthen the anion-solvent interactions through stronger ion–dipole *** reduces the quantity of free solvent and improves the reduction resistance of *** addition,the Li ion–solvent interaction is weakened,facilitating the anions to enter the solvation sheaths of Li *** multi-anion-dominated weak solvation structures boost Li ion diffusion in the electrolyte,accelerate the desolvation process of Li ions,and induce inorganic-rich solid electrolyte interphase and uniform Li *** average Coulombic efficiency of 99.1%for repeated Li plating/stripping can be ***||LiNi0.5Co0.2Mn0.3O2cells with a high cathode loading of 3.0 m A h cm-2can maintain a capacity retention as high as 95% after 150 *** finding provides novel standpoints to modulate the interaction of solvation structures and extend the lifespan of high-energy–density Li metal batteries.

关键词： Desolvation Lithium metal battery Multi-anion electrolyte Solid electrolyte interphase Weak solvation structure

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Water-Driven Malleable,Weldable and Eco-Friendly Recyclable Carbon Fiber Reinforced Dynamic Composites

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Chinese Journal of Chemistry 2024年第5期42卷 516-522页

作者： Ping Yu Qirui Huang Yi Wang Wan Peng Zichen Jia Haiyue Wang Juanjuan Ma Chunyu Wang Xuzhou Yan School of Environmental and Chemical Engineering Jiangsu Key Laboratory of Function Control Technology for Advanced MaterialsJiangsu Ocean UniversityLianyungangJiangsu222005 China School of Chemistry and Chemical Engineering Frontiers Science Center for Transformative MoleculesShanghai Jiao Tong UniversityShanghai200240 China

Traditional carbon fiber-reinforced polymers based on thermoset matrix have been extensively used in the fields of wind turbine blades,automotive sector,and aerospace,among many ***,there is still a major challenge of recycling those polymers due to the high cost and adverse impacts on the *** this work,we apply a polyimine network as matrix,which possess considerable tensile and thermal properties,to prepare the carbon fiber reinforced polyimine materials with trifluoromethyl diphenoxybenzene units(CFRFP)using a prepreg-based compression molding *** CFRFP can be reshaped or reprocessed by heat or with water rapidly,and exhibited multifunction,including welding,chemical recycling,*** unique findings gained from our study will facilitate the manufacturing capability and enrich the types of fiber-reinforced composites.

关键词： Dynamic chemistry Green chemistry Fiber-reinforced composites Fluoropolyimine Welding Reshaping Recycling Renewable resources

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Design and Performance Analysis of HMDV Dynamic Inertial Suspension Based on Active Disturbance Rejection control

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Computer Modeling in Engineering & Sciences 2024年第8期140卷 1485-1506页

作者： Xiaofeng Yang Wei Wang Yujie Shen Changning Liu Tianyi Zhang School of Automotive and Traffic Engineering Jiangsu UniversityZhenjiang212013China Automotive Engineering Research Institute Jiangsu UniversityZhenjiang212013China Chongqing Key Laboratory of Urban Rail Transit System Integration and Control Chongqing400074China State Key Laboratory of Advanced Design and Manufacturing Technology for Vehicle Hunan universityChangsha410082China

This paper addresses the impact of vertical vibration negative effects,unbalanced radial forces generated by the static eccentricity of the hub motor,and road excitation on the suspension performance of Hub Motor Driven Vehicle(HMDV).A dynamic inertial suspension based on Active Disturbance Rejection control(ADRC)is proposed,combining the vertical dynamic characteristics of dynamic inertial suspension with the features of ADRC,which distinguishes between internal and external disturbances and arranges the transition ***,a simulation model of the static eccentricity of the hub motor is established to simulate the unbalanced radial electromagnetic force generated under static eccentricity.A quarter-vehicle model of an HMDV with a controllable dynamic inertial suspension is then ***,the passive suspension model is studied under different grades of road excitation,and the impact mechanism of suspension performance at speeds of 0–20 m/s is ***,the three main components within the ADRC controller are designed for the second-order controlled system,and optimization algorithms are used to optimize its internal ***,the performance of the traditional passive suspension,the PID-based controllable dynamic inertial suspension,and the ADRC-based controllable dynamic inertial suspension are analyzed under different road *** results show that,under sinusoidal road input,the ADRC-based controllable dynamic inertial suspension exhibits a 52.3%reduction in the low-frequency resonance peak in the vehicle body acceleration gain diagram compared to the traditional passive suspension,with significant performance optimization in the high-frequency *** random road input,the ADRC-based controllable dynamic inertial suspension achieves a 29.53%reduction in the root mean square value of vehicle body acceleration and a 14.87%reduction in dynamic tire *** indicates that the designed controllable dynamic inertia

关键词： HMDV static eccentricity ADRC dynamic inertial suspension road excitation

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SVM-based Fault Detection Method for Air Conditioners in EMU Train 7

SVM-based Fault Detection Method for Air Conditioners in EMU...

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7th International Conference on Data Science and Information technology, DSIT 2024

作者： Wei, Rongjiao Pan, Chao Wei, Pu An, Yangyang Zhu, Hao Wang, Mulan Nanjing Institute of Technology School of Communications and Information Engineering Nanjing China China Railway Shanghai Group Co. Ltd. Nanjing EMU Depot Nanjing China Nanjing Institute of Technology Jiangsu Key Laboratory of Advanced Numerical Control Technology Nanjing China

ISBN: (纸本)9798350384093

In this paper, we introduce and experimentally demonstrate a fault detection method for the air conditioner in the EMU train, which usually generates abnormal sounds when the faults occur. The technique utilizes the Support Vector Machine (SVM) to recognize the time-frequency characteristics of the sound generated by the air conditioner, which is extracted using the short-time Fourier transform (STFT). In addition, a detection system is built for the experiment, in which an FPGA and an embedded system are employed for sound acquisition and acoustic signal process, respectively. The penalty factor of the SVM model is optimized and accuracy of 0.977 is achieved. Our method will improve the efficiency and accuracy of fault detection for the air conditioner in the EMU train. © 2024 IEEE.

关键词： Support vector machines

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Research On HEV Multi-Agent control Based on Working Condition Recognition 8

Research On HEV Multi-Agent Control Based on Working Conditi...

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8th International Conference on Energy System, Electricity, and Power, ESEP 2023

作者： Yin, Jianhua Niu, Limin Zhu, Fentian Si, Ming Zhou, Tianpeng School of Mechanical Engineering Anhui University of Technology Ma'anshan243032 China Key Laboratory of Advanced Numerical Control & Servo Technology of Anhui Province Anhui Polytechnic University Wuhu241000 China

ISBN: (数字)9781510679801

ISBN: (纸本)9781510679795

Aiming at the adaptive problem of driving conditions in the energy management process of Hybrid Electric Vehicle (HEV), the research of HEV powertrain multi-intelligent body control system based on condition recognition is carried out with two-axle parallel HEV as the research object. Firstly, the theory of Multi-Agent System (MAS) is introduced into the vehicle power system, and a vehicle powertrain control model is constructed;the working condition recognition module is established, and it is embedded into the ADVISOR vehicle simulation software together with the energy management strategies of four different working condition control types, and compared and analyzed with the electrically-assisted strategies, and the experiments are carried out on the basis of the D2P technology. Based on D2P technology, an experimental rig is built to verify the effectiveness and feasibility of the proposed strategies. © 2024 SPIE.

关键词： Multi agent systems

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Alkaline hydrogen production promoted by small-molecule modification on flowerlike Co_(2)(OH)_(2)CO_(3)

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Journal of Energy Chemistry 2023年第9期84卷 73-80页

作者： Yue Liu Huan Zhang Chen Yang Ziyang Xu Yiyang Shi Xukun Zhu Xinde Duan Ling Qin Yachao Jin Li Song Mingdao Zhang Hegen Zheng Institute of Energy Supply Technology for High-end Equipment Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution ControlJiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and EngineeringNanjing University of Information Science&TechnologyNanjing 210044JiangsuChina State Key Laboratory of Coordination Chemistry School of Chemistry and Chemical EngineeringCollaborative Innovation Center of Advanced MicrostructuresNanjing UniversityNanjing 210023JiangsuChina School of Chemistry and Chemical Engineering Hefei University of TechnologyHefei 230009AnhuiChina

Developing a low-cost and high-efficiency nonprecious metal-based catalyst for hydrogen evolution reaction(HER) is of great significance for the utilization of hydrogen *** this work,we report a molecular-modification strategy to fabricate a self-supported hydrogen evolution electrode,specially by grafting the macrocyclic molecules(HHTP=2,3,6,7,10,11-hexahydroxytriphenylene) on the surface of a cobaltous dihydroxy carbonate(COC) seed *** HHTP-COC electrode is endowed with a rodlike structure,which provides favorable access for charge transportation and mass *** macrocyclic molecule structure in HHTP can be grafted on COC and improve the electrical conductivity,while the interaction between HHTP and COC induces the rearrangement of charge configuration on the *** to the combination effects of several aspects,the HHTP-COC electrode achieves astonishing HER activity,with a low overpotential of 61.0 mV(η_(10),at the current density of 10 mA cm^(-2)) and excellent stability in alkaline *** kind of interface engineering based on the organic molecules can be applied to the design and manufacture of electrocatalysts in the field of energy conversion and storage.

关键词： Interfacial interaction Hydrogen evolution Molecule modification DFT calculation

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Coordinated control of decarbonization efficiency and oxygen absorption rate in Ruhrstahl–Heraeus degasser based on mechanism model and BP neural network

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Journal of Iron and Steel Research International 2025年第3期32卷 606-618页

作者： Lu-heng Jiang Min Wang Jia-qi Zhao Cheng Yao Li-dong Xing Xin-gang Ai State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing100083China Technical Support Centre for Prevention and Control of Disastrous Accidents in Metal Smelting University of Science and Technology BeijingBeijing100083China Institute of Research of Iron&Steel Zhangjiagang215600JiangsuChina School of Materials and Metallurgy University of Science and Technology LiaoningAnshan114051LiaoningChina

A mathematical model of the decarburization reaction zone was established for the Ruhrstahl–Heraeus (RH) forced oxygen blowing decarburization process by Matlab R2022b software. For the problem of inaccurate prediction due to the large variation range of oxygen absorption rate under different process conditions, we statistically analyzed the main factors affecting the oxygen absorption rate. The backpropagation neural network was used to train and predict the oxygen absorption rate and was used to calculate the RH decarburization reaction zone model. We designed and developed a mathematical modeling software with process control of decarburization in RH degasser, which can realize the change of operating process parameters in the dynamic prediction process. The optimized mathematical model has more than 95% of the furnaces whose absolute error in calculation of carbon content is within ± 5 × 10^(−6), more than 90% of the heats whose relative error in calculation of oxygen content is within ± 15%, and the average absolute error of calculation of oxygen content is 26.4 × 10−6. Finally, we studied the influence of oxygen blowing timing, oxygen blowing volume and initial oxygen content on the forced decarburization process.

关键词： Ruhrstahl-Heraeus degasser Mathematical model Forced decarburization Oxygen absorption rate Process control

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