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Pyrometallurgical recycling of spent lithium-ion batteries from conventional roasting to synergistic pyrolysis with organic wastes

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Journal of Energy Chemistry 2023年第10期85卷 547-561,I0014页

作者： Chao Pan Yafei Shen China Energy Science and Technology Research Institute Co.Ltd. Nanjing 210023JiangsuChina Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control(AEMPC) Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and EngineeringNanjing University of Information Science and TechnologyNanjing 210044JiangsuChina

The synergistic pyrolysis has been increasingly used for recycling spent lithium-ion batteries(LIBs)and organic wastes(hydrogen and carbon sources),which are in-situ transformed into various reducing agents such as H_(2),CO,and char via carbothermal and/or gas thermal *** with the conventional roasting methods,this“killing two birds with one stone”strategy can not only reduce the cost and energy consumption,but also realize the valorization of organic *** paper concluded the research progress in synergistic pyrolysis recycling of spent LIBs and organic *** the one hand,valued metals such as Li,Co,Ni,and Mn can be recovered through the pyrolysis of the cathode materials with inherent organic materials(e.g.,separator,electrolyte)or graphite *** the pyrolysis process,the organic materials are decomposed into char and gases(e.g.,CO,H_(2),and CH_(4))as reducing agents,while the cathode material is decomposed and then converted into Li_(2)CO_(3) and low-valent transition metals or their oxides via in-situ thermal *** formed Li_(2)CO_(3) can be easily recovered by the water leaching process,while the formed transition metals or their oxides(e.g.,Co,CoO,Ni,MnO,etc.)can be recovered by the reductant-free acid leaching or magnetic separation *** the other hand,organic wastes(e.g.,biomass,plastics,etc.)as abundant hydrogen and carbon sources can be converted into gas(e.g.,H_(2),CO,etc.)and char via *** cathode materials are decomposed and subsequently reduced by the pyrolysis gas and *** addition,the pyrolysis oil and gas can be upgraded by catalytic reforming with the active metals derived from cathode ***,great challenges are proposed to promote this promising technology in the industrial applications.

关键词： Synergistic pyrolysis Spent LIBs Biomass Recycling Reduction roasting

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Exceptional kinetics of heavy metals adsorption from wastewater through tannic-mediated nano-hydrous zirconium oxide (HZO) encapsulated within mesoporous carbon

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Journal of Hazardous Materials 2025年 494卷 138576页

作者： Qiu, Hui Chen, Shuxin Zhang, Jiakang Zhang, Qingrui Collaborative Innovation Center of Atmospheric Environment and Equipment Technology Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control School of Environmental Science and Engineering Nanjing University of Information Science & Technology Nanjing210044 China State Key Laboratory of Metastable Materials Science and Technology Hebei Key Laboratory of Heavy Metal Deep-Remediation in Water and Resource Reuse Yanshan University Qinhuangdao066004 China

Conventional immobilization techniques for nanosized metal oxides frequently result in nanoparticle aggregation within the carrier matrix pores, causing severe pore blockage and compromised mass transfer efficiency. A novel hydrous zirconium oxide-based nanocomposite (denoted as ZrTA@CMK-3) was successfully synthesized by leveraging ordered mesoporous carbon (CMK-3) as a structural scaffold, pre-functionalized with a highly negatively charged tannic acid-zirconium (TA-Zr) macromolecular network. Adsorption kinetics evaluation revealed that 85.5 % of the Pb(II) adsorption capacity was achieved within 1 min, with complete equilibrium reached in 5 min, and a kinetic rate constant (k2) of 0.0537 g‧mg−1‧min−1, which is up to 100 times higher than that of other adsorbents. The strongly negatively charged TA-Zr network synergizes with CMK-3’s ordered meso-structure to enable accelerated heavy metal ion transport through the pore channels, achieving outstanding Pb(II) adsorption kinetics. X-ray photoelectron spectroscopy analyses indicated that the dominant adsorption mechanism of ZrTA@CMK-3 for Pb(II) is attributed to the inner-sphere complexation between Zr−O−H groups and Pb(II) ions. Fixed-bed column test demonstrated that ZrTA@CMK-3 column sustained treatment capacity of 2050 bed volumes (BV) for simulated industrial wastewater (pH 6.0), maintaining effluent Pb(II) concentrations TA@CMK-3 enable significant reductions in hydraulic retention requirements while maintaining operational efficiency, positioning this composite as a promising solution for cost-effective heavy metal removal in industrial wastewater treatment systems. © 2025 Elsevier B.V.

关键词： Mesoporous materials

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Contrasting trends of PM2.5 and surface-ozone concentrations in China from 2013 to 2017

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National Science Review 2020年第8期7卷 1331-1339页

作者： Yonghong Wang Wenkang Gao Shuai Wang Tao Song Zhengyu Gong Dongsheng Ji Lili Wang Zirui Liu Guiqian Tang Yanfeng Huo Shili Tian Jiayun Li Mingge Li Yuan Yang Biwu Chu Tuukka Pet?j? Veli-Matti Kerminen Hong He Jiming Hao Markku Kulmala Yuesi Wang Yuanhang Zhang State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry (LAPC) Institute of Atmospheric Physics Chinese Academy of Sciences Institute for Atmospheric and Earth System Research University of Helsinki China National Environmental Monitoring Center (CNEMC) Anhui Institute of Meteorological Sciences State Key Joint Laboratory of Environment Simulation and Pollution Control Research Center for Eco-Environmental Sciences Chinese Academy of Sciences Center for Excellence in Regional Atmospheric Environment Institute of Urban Environment Chinese Academy of Sciences State Key Joint Laboratory of Environment Simulation and Pollution Control School of Environment Tsinghua University State Key Joint Laboratory of Environmental Simulation and Pollution Control College of Environmental Sciences and Engineering Peking University

Although much attention has been paid to investigating and controlling air pollution in China, the trends of air-pollutant concentrations on a national scale have remained unclear. Here, we quantitatively investigated the variation of air pollutants in China using long-term comprehensive data sets from 2013 to 2017, during which Chinese government made major efforts to reduce anthropogenic emission in polluted regions. Our results show a significant decreasing trend in the PM2.5concentration in heavily polluted regions of eastern China, with an annual decrease of ～7% compared with measurements in 2013. The measured decreased concentrations of SO2, NO2and CO（a proxy for anthropogenic volatile organic compounds） could explain a large fraction of the decreased PM2.5concentrations in different regions. As a consequence, the heavily polluted days decreased significantly in corresponding regions. Concentrations of organic aerosol,nitrate, sulfate, ammonium and chloride measured in urban Beijing revealed a remarkable reduction from 2013 to 2017, connecting the decreases in aerosol precursors with corresponding chemical components closely. However, surface-ozone concentrations showed increasing trends in most urban stations from 2013 to 2017, which indicates stronger photochemical pollution. The boundary-layer height in capital cities of eastern China showed no significant trends over the Beijing–Tianjin–Hebei, Yangtze River Delta and Pearl River Delta regions from 2013 to 2017, which confirmed the reduction in anthropogenic emissions. Our results demonstrated that the Chinese government was successful in the reduction of particulate matter in urban areas from 2013 to 2017, although the ozone concentration has increased significantly, suggesting a more complex mechanism of improving Chinese air quality in the future.

关键词： air pollution clean-air action particulate matter surface ozone China chemical composition

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MOF-derived Co-MOF,O-doped carbon as trifunctional electrocatalysts to enable highly efficient Zn-air batteries and water-splitting

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Journal of Energy Chemistry 2021年第5期30卷 290-298页

作者： Xinde Duan Na Pan Can Sun Kexin Zhang Xukun Zhu Mingdao Zhang Li Song Hegen Zheng School of Environmental Science and Engineering Nanjing University of Information Science&TechnologyJiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution ControlCollaborative Innovation Center of Atmospheric Environment and Equipment TechnologyNanjing 210044JiangsuChina State Key Laboratory of Coordination Chemistry School of Chemistry and Chemical EngineeringCollaborative Innovation Center of Advanced MicrostructuresNanjing UniversityNanjing 210023JiangsuChina

Development of high-efficiency non-noble electrocatalysts for oxygen reduction reaction(ORR),oxygen evolution reaction(OER)and hydrogen evolution reaction(HER)is urgently needed for high-performance Zn-air batteries and overall water ***,a facile strategy to synthesize novel Co-MOF,O-doped carbon(Co-MOF-T)based on Zn,Co-doped glucosamine and ZIF-8 by pyrolysis at temperature T was *** prepared Co-MOF-800 showed a superior oxygen reduction reaction(ORR)activity comparable to that of commercial Pt/C *** addition,this catalyst shows great potential in the overall water splitting due to the excellent oxygen evolution reaction(OER)and hydrogen evolution reaction(HER)*** on the trifunctional activity,the primary Zn-air batteries using a Co-MOF-800 air electrode achieved a high open-circuit voltage of 1.38 V,a specific capacity of 671.6 mAh g^(-1) Zn,and a prominent peak power density of 144 mW cm^(-2).Also,the rechargeable Zn-air batteries based on CoMOF-800 air electrode could be smoothly run for 510 cycles with a low voltage gap of 0.58 ***,the trifunctional Co-MOF-800 catalyst was applied to boost the electrochemical water splitting,demonstrating its promising potential as a green energy material for practical applications.

关键词： Metal-organic frameworks Carbon catalysts Trifunctional electrocatalyst Metal-air batteries Water splitting

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The Physical Chemistry for the Self-assembly of Peptide Hydrogels

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Chinese Journal of Polymer Science 2018年第3期36卷 366-378页

作者： Ying Li Yi Cao Collaborative Innovation Center of Atmospheric Environment and Equipment Technology School of Environmental Science and EngineeringJiangsu Engineering Technology Research Centre of Environmental Cleaning MaterialsJiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution ControlJiangsu Joint Laboratory of Atmaspheric Pollution ControlNanjing University of Information Science&TechnologyNanjing 210044China Collaborative Innovation Center of Advanced Microstrucures National Laboratony of Solid State MicrostrucureDepartment of PhysicsNanjing UniversityNanjing 210093China

Peptide hydrogels have been widely used for diverse biomedical applications. However, our current understanding of the physical principles underlying the self-assembly process is still limited. In this review, we summarize our current understanding on the physical chemistry principles from the basic interactions that drive the self-assembly process to the energy landscapes that dictate the thermodynamics and kinetics of the process. We discuss the effect of different factors that affect the kinetics of the self-assembly of peptide fibrils and how this is related to the macroscopic gelation process. We provide our understanding on the molecular origin of the complex and rugged energy landscape for the self-assembly of peptide hydrogels. The hierarchical self-assembled structures and the diverse self-assembling mechanism make it difficult and challenging to rationally design the physical and chemical properties of peptide hydrogels at the molecular revel. We also give our personal perspective to the potential future directions in this field.

关键词： Hydrogel Peptide Self-assembly Kinetics Thermodynamics

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Designing the mechanical properties of peptide-based supramolecular hydrogels for biomedical applications

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Science China(Physics,Mechanics & Astronomy) 2014年第5期57卷 849-858页

作者： LI Ying QIN Meng CAO Yi WANG Wei Jiangsu Key Laboratory of Atmospheric Environment Monitoring & Pollution Control Chemistry DepartmentSchool of Environmental Science & EngineeringNanjing University of Information Science & Technology National Laboratory of Solid State Microstructure Department of PhysicsNanjing University

Hydrogels are a class of special materials that contain a large amount of water and behave like *** materials have found broad applications in tissue engineering,cell culturing,regenerative medicine ***,the exploration of peptide-based supramolecular hydrogels has greatly expanded the repertoire of hydrogels suitable for biomedical ***,the mechanical properties of peptide-based hydrogels are intrinsically ***,it is crucial to develop methods that can improve the mechanical stability of such peptide-based *** this review,we explore the factors that determine or influence the mechanical stability of peptide-based hydrogels and summarize several key elements that may guide scientists to achieve mechanically improved *** addition,we exemplified several methods that have been successfully developed to prepare hydrogels with enhanced mechanical *** mechanically strong peptide-based hydrogels may find broad applications as novel *** is still challenging to engineer hydrogels in order to mimic the mechanical properties of biological *** hydrogel materials with optimal mechanical properties suitable for various types of biological applications will be available in the near future.

关键词： low molecular weight gelators (LMWG) peptide-based hydrogel hydrogelation mechanical properties (stability) modulus rheology

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Synthesis of Mesostructured Iron Oxides with Potential As(V) Adsorption Application

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Chemical Research in Chinese Universities 2012年第4期28卷 559-562页

作者： LI Fei-hu FU Xiao-ru HUANG Jie ZHAI Jian-ping Jiangsu Provincial Key Laboratory of Atmospheric Environment Monitoring and Pollution Control School of Environmental Science and EngineeringNanjing University of Information Science and TechnologyNanjing 210044P.R.China State Key Laboratory of Pollution Control and Resource Reuse School of EnvironmentNanjing UniversityNanjing 210046P.R.China

Mesostructured iron oxides（MIOs） were nanocasted from a plugged hexagonal templated silica（PHTS） with a Brunauer-Emmett-Teller（BET） surface area of 694 m 2 /*** of X-ray diffraction（XRD）,transmission electron microscopy（TEM） and N 2 adsorption-desorption suggest that the nanocasted MIOs are synthetic hematite（α-Fe2O3） with a wormhole-like mesoporous ***（V） adsorption test shows that the selected MIO—MIO-500（calcinated at 500 °C） with a BET surface area of 82 m^ 2 /g has a maximum adsorption capacity of 5.39 mg/g for As（V）,which is 2.5 times as large as that of natural hematite *** study suggests that MIOs could be potentially used as the adsorbent of As（V） in wastewater.

关键词： Mesostructured iron oxide Plugged hexagonal templated silica(PHTS) Nanocasting Arsenate Adsorption

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Impacts of ENSO on wintertime PM_(2.5)pollution over China during 2014-2021

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atmospheric and Oceanic Science Letters 2022年第4期15卷 1-5页

作者： Biyin Xie Yang Yang Pinya Wang Hong Liao Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and EngineeringNanjing University of Information Science and TechnologyNanjingChina

China has implemented a series of emission reduction policies since 2013,and the concentration of air pollutants has consequently decreased ***,PM_(2.5)(particulate matter with an aerodynamic diameter less than_(2.5)μm)pollution still occurs in China in relation to the interannual variations in meteorological *** that El Nino-Southern Oscillation(ENSO)is the strongest signalmodulating the interannual variation in the atmosphere-ocean system,in this study the authors investigate the variations in PM_(2.5)concentrations in four megacity clusters of China during the winter season associated with four individual ENSO events from 2014 to *** show that the wintertime PM_(2.5) concentrations in the Beijing-Tianjin-Hebei and Fenwei Plain regions during El Nino years are higher than those during La Nina years,which can be explained by the anomalous southerly(northerly)winds during El Nino(La Nina) favoring PM_(2.5) accumulation(diffusion).In the Pearl River Delta region,PM_(2.5)concentrations decrease in El Nino relative to La Nina years owing to the enhanced water vapor flux and precipitation,removing more PM_(2.5)from the *** comprehensive effects of wind and precipitation anomalies lead to the unpredictability of the impacts of ENSO on PM_(2.5)over the Yangtze River Delta region,which should be analyzed case by case.

关键词： PM_(2.5) ENSO atmospheric circulation precipitation

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Particle number size distributions and formation and growth rates of different new particle formation types of a megacity in China

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Journal of environmental Sciences 2023年第9期131卷 11-25页

作者： Liang Dai Yu Zhao Lei Zhang Dong Chen Rongrong Wu State Key Laboratory of Pollution Control and Resource Reuse and School of the Environment Nanjing UniversityJiangsu 210023China Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment Technology(CICAEET) Nanjing University of Information Science and TechnologyJiangsu 210044China

To understand the contribution of new particle formation(NPF)events to ambient fine particle pollution,measurements of particle size distributions,trace gases and meteorological conditions,were conducted at a suburban site(NJU)from October to December 2016 and at an industrial site(NUIST)from September to November 2015 in *** to the temporal evolution of the particle size distributions,three types NPF events were observed:typical NPF(Type A),moderate NPF events(Type B)and strong NPF(Type C)*** favorable conditions for Type A events included low relative humidity,low concentration of pre-existing particles,and high solar *** favorable conditions of Type B events were similar to Type A,except for a higher concentration of pre-existing *** C events were more likely to happen with the higher relative humidity,lower solar radiation and continuous growth of pre-existing particle *** formation rate of 3 nm(J3)was the lowest for Type A events and highest for Type C *** contrast,the growth rates of 10 nm and 40 nm particles were the highest for Type A,and lowest for Type *** show that NPF events with only higher J3 would lead to the accumulation of nucleation mode *** acid was important for the formation of particles but had little effect on the growth of particle size.

关键词： New particle formation Size distribution Formation and growth rate Aerosol pollution

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Luminescent metal-organic frameworks for nitro explosives detection

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Science China Chemistry 2016年第8期59卷 929-947页

作者： Tingting Cheng Jinsong Hu Chunhui Zhou Yueming Wang Mingdao Zhang School of Chemical Engineering Anhui University of Science and Technology Huainan 232001 China Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control School of Environmental Sciences and EngineeringNanjing University of &fbrmation Science and Technology Nanjing 210044 China

Metal-organic frameworks （MOFs） have been emerging as important multifunctional hybrid materials, not only due to the diversify framework architectures, but also contribute to the rich interactions among metals, ligands and guests. Nitro explosives have important influences tbr environmental protection and national homeland security, in this review, a brief description of luminescent MOFs is presented, accompanied by a short comment on the four types of metal-based luminescent MOFs as sensing materials for nitro explosives detection. Then the trends and challenges of luminescent MOFs as sensing materials ibr nitro explosives are also prospected.

关键词： metal-organic frameworks nitro explosives luminescence quench

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