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Water-Driven Malleable,Weldable and Eco-Friendly Recyclable Carbon Fiber Reinforced Dynamic Composites

Chinese Journal of Chemistry 2024年第5期42卷 516-522页

作者： Ping Yu Qirui Huang Yi Wang Wan Peng Zichen Jia Haiyue Wang Juanjuan Ma Chunyu Wang Xuzhou Yan School of Environmental and Chemical Engineering Jiangsu Key Laboratory of Function Control Technology for Advanced MaterialsJiangsu Ocean UniversityLianyungangJiangsu222005 China School of Chemistry and Chemical Engineering Frontiers Science Center for Transformative MoleculesShanghai Jiao Tong UniversityShanghai200240 China

Traditional carbon fiber-reinforced polymers based on thermoset matrix have been extensively used in the fields of wind turbine blades,automotive sector,and aerospace,among many ***,there is still a major challenge of recycling those polymers due to the high cost and adverse impacts on the *** this work,we apply a polyimine network as matrix,which possess considerable tensile and thermal properties,to prepare the carbon fiber reinforced polyimine materials with trifluoromethyl diphenoxybenzene units(CFRFP)using a prepreg-based compression molding *** CFRFP can be reshaped or reprocessed by heat or with water rapidly,and exhibited multifunction,including welding,chemical recycling,*** unique findings gained from our study will facilitate the manufacturing capability and enrich the types of fiber-reinforced composites.

关键词： Dynamic chemistry Green chemistry Fiber-reinforced composites Fluoropolyimine Welding Reshaping Recycling Renewable resources

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Effects of highly dispersed Ni nanoparticles on the hydrogen storage performance of MgH_(2)

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International Journal of Minerals,Metallurgy and materials 2023年第1期30卷 54-62页

作者： Nuo Xu Zirui Yuan Zhihong Ma Xinli Guo Yunfeng Zhu Yongjin Zou Yao Zhang School of Materials Science and Engineering Jiangsu Key Laboratory of Advanced Metallic MaterialsSoutheast UniversityNanjing 211189China School of Materials Science and Engineering Baise UniversityBaise 533000China College of Materials Science and Engineering Jiangsu Collaborative Innovation Centre for Advanced Inorganic Function CompositesNanjing Tech UniversityNanjing 211816China Guangxi Key Laboratory of Information Materials Guilin University of Electronic TechnologyGuilin 541004China

MgH_(2)with a large hydrogen capacity is regarded as a promising hydrogen storage ***,it still suffers from high thermal stability and sluggish *** this paper,highly dispersed nano-Ni has been successfully prepared by using the polyol reduction method with an average size of 2.14 nm,which significantly improves the de/rehydrogenation properties of MgH_(2).The MgH_(2)–10wt%nano-Ni sample starts releasing H_(2)at 497 K,and roughly 6.2wt%H_(2)has been liberated at 583 *** rehydrogenation kinetics of the sample are also greatly improved,and the adsorption capacity reaches 5.3wt%H_(2)in 1000 s at 482 K and under 3 MPa hydrogen ***,the activation energies of de/rehydrogenation of the MgH_(2)–10wt%nano-Ni sample are reduced to(88±2)and(87±1)kJ·mol−1,*** addition,the thermal stability of the MgH_(2)–10wt%nano-Ni system is reduced by 5.5 kJ per mol H_(2)from that of pristine MgH_(2).This finding indicates that nano-Ni significantly improves both the thermodynamic and kinetic performances of the de/rehydrogenation of MgH_(2),serving as a bi-functional additive of both reagent and catalyst.

关键词： Ni nanoparticle kinetics thermodynamics MgH2 hydrogen storage performance

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Molecular-level proton acceptor boosts oxygen evolution catalysis to enable efficient industrial-scale water splitting

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Green Energy & Environment 2024年第2期9卷 344-355页

作者： Yaobin Wang Qian Lu Xinlei Ge Feng Li Le Chen Zhihui Zhang Zhengping Fu Yalin Lu Yang Song Yunfei Bu Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment Technology(CICAEET) Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control(AEMPC)UNIST-NUIST Energy and Environment Jointed Lab(UNNU)School of Environmental Science and TechnologyNanjing University of Information Science and Technology(NUIST)219 NingliuNanjing210044China Laboratory of Advanced Materials Shanghai Key Laboratory of Molecular Catalysis and Innovative MaterialsFudan University220 HandanShanghai200433China Jiangsu Key Laboratory of Advanced Materials and Technology School of Petrochemical EngineeringChangzhou University1 GehuChangzhou213164China Anhui Laboratory of Advanced Photon Science and Technology University of Science and Technology of China(USTC)96 JinzhaiHefeiAnhui 230026China School of Chemistry and Chemical Engineering Nanjing University of Science and Technology200 Xiaolingwei210094China

Industrial water splitting has long been suppressed by the sluggish kinetics of the oxygen evolution reaction(OER),which requires a catalyst to be ***,we propose a molecular-level proton acceptor strategy to produce an efficient OER catalyst that can boost industrial-scale water ***-level phosphate(-PO_(4))group is introduced to modify the surface of PrBa_(0.5)Ca_(0.5)Co_(2)O_(5)+δ(PBCC).The achieved catalyst(PO_(4)-PBCC)exhibits significantly enhanced catalytic performance in alkaline *** on the X-ray absorption spectroscopy results and density functional theory(DFT)calculations,the PO_(4)on the surface,which is regarded as the Lewis base,is the key factor to overcome the kinetic limitation of the proton transfer process during the *** use of the catalyst in a membrane electrode assembly(MEA)is further evaluated for industrial-scale water splitting,and it only needs a low voltage of 1.66 V to achieve a large current density of 1 A cm^(-2).This work provides a new molecular-level strategy to develop highly efficient OER electrocatalysts for industrial applications.

关键词： Oxygen evolution reaction Nanofiber Water splitting Proton acceptor Perovskite

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Synergistic effect of Pd single atoms and clusters on the de/re-hydrogenation performance of MgH_(2)

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Journal of materials Science & technology 2024年第24期191卷 49-62页

作者： Nuo Xu Haoran Zhou Mingqiang Zhang Yuchuan Ye Kaiwen Wang Yingtang Zhou Yunfeng Zhu Yao Zhang School of Materials Science and Engineering Jiangsu Key Laboratory of Advanced Metallic MaterialsSoutheast UniversityNanjing 211189China Zhejiang Key Laboratory of Petrochemical Environmental Pollution Control National Engineering Research Center for Marine AquacultureMarine Science and Technology CollegeZhejiang Ocean UniversityZhoushan 316004China ICFO-Institut de Ciències Fotòniques The Barcelona Institute of Science and TechnologyCastelldefels(Barcelona)08860Spain Faculty of Materials and Manufacturing Beijing University of TechnologyBeijing 100124China College of Materials Science and Engineering Jiangsu Collaborative Innovation Centre for Advanced InorganicFunction CompositesNanjing Tech UniversityNanjing 211816China

Hydrogen storage plays a pivotal role in the hydrogen industry,yet its current status presents a *** strategies have emerged in recent years to address this ***_(2) has stood out as a promising solid-state hydrogen storage material due to its impressive gravimetric and volumetric hydrogen density,but its practical application is hampered by elevated thermal stability and sluggish *** this study,we introduce a solution by synthesizing Pd metallene through a one-pot solvothermal method,revealing a distinctive highly curved lamellar structure with a thickness of around 1.6 *** this Pd metallene into MgH_(2) results in a composite system wherein the starting dehydrogenation temperature is significantly lowered to 439 K and complete dehydrogenation occurs at 583 K,releasing 6.14 wt.%*** activation energy of dehydrogenation for MgH_(2) was reduced from 170.4 kJ mol^(-1) to 79.85 kJ mol^(-1) after Pd metallene *** enthalpy of dehydrogenation of the MgH_(2)-10 wt.%Pd sample was calculated to be 73 kJ mol^(-1) H_(2)^(-1) and decreased by 4.4 kJ mol^(-1) H_(2)^(-1) from that of dehydrogenation of pure MgH_(2)(77.4 kJ mol^(-1) H_(2)-1).Theoretical calculations show that the average formation energy and average adsorption energy of hydrogen vacancies can be significantly reduced in the presence of both Pd clusters and Pd single atoms on the surface of MgH_(2)/Mg,*** suggests that the synergistic effect of in situ formed Pd single atoms and clusters significantly improves the hydrogenation and dehydrogenation *** identified active sites in this study hold potential as references for forthcoming multi-sized active site catalysts,underscoring a significant advancement toward resolving hydrogen storage limitations.

关键词： MgH_(2) Metallene Single atoms Clusters Hydrogen storage

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Confinement of Fe atoms between MoS_(2) interlayers drives phase transition for improved reactivity in Fenton-like reactions

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Nano Research 2024年第3期17卷 1132-1139页

作者： Yibing Sun Yu Zhou Hongchao Li Chuan Wang Xuan Zhang Qian Ma Yingchun Cheng Jieshu Qian Bingcai Pan Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse School of Environmental and Biological EngineeringNanjing University of Science and TechnologyNanjing 210094China Key Laboratory of Flexible Electronics and Institute of Advanced Materials Jiangsu National Synergetic Innovation Center for Advanced MaterialsNanjing Tech UniversityNanjing 211816China Department of General Dentistry Affiliated Stomatological Hospital of Nanjing Medical UniversityJiangsu Province Key Laboratory of Oral DiseasesNanjing 210029China Research Center for Environmental Nanotechnology(ReCENT) State Key Laboratory of Pollution Control and Resources ReuseSchool of EnvironmentNanjing UniversityNanjing 210023China

Phase manipulation of MoS_(2) from thermodynamically stable 2H phase to the unstable but more reactive 1T phase represents a crucial strategy for improving the reactivity in many *** widely adopted wet chemistry approach uses intercalating entities especially alkali metal ions to achieve the phase transition;however,these entities are normally inert for the target ***,we describe the first use of iron atoms for the intercalation of 2H-MoS_(2) layers,driving the partial transition from 2H to 1T ***,in the peroxymonosulfate(PMS)-based Fenton-like reactions,the interlayered confinement of Fe atoms not only activates the inert basal plane,but also adds more reactive Fe sites for the formation of metal-PMS complex as primary reactive species for pollutant *** the degradation of a model pollutant carbamazepine(CBZ),the Fe-intercalated MoS_(2) exhibits a first order rate constant 13.3 times higher than 2H-MoS_(2).This strategy is a new direction for manipulating the phase composition and boosting the catalytic reactivity of MoS_(2)-based catalysts in various scenarios,including environmental remediation and energy applications.

关键词： confinement MoS_(2) Fe atoms Fenton-like reactions hydrogen evolution reaction

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Multi-anion electrolyte modulates the interactions in solvation structure to construct robust lithium metal batteries

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Journal of Energy Chemistry 2025年第5期104卷 36-43页

作者： Ke-Feng Ren Yun-Fei Du Jia-Xin Guo Zhen-Hui Luo Xin Sun Wen-Bo Tang Tian-Qi Li Cong Guo Weizhai Bao Feng Yu He Liu Xin-Bing Cheng Jingfa Li Jiangsu Key Laboratory of New Energy Devices&Interface Science School of Chemistry and Materials ScienceNanjing University of Information Science and TechnologyNanjing 210044JiangsuChina Z Energy Storage Center Key Laboratory of Energy Thermal Conversion and Control of Ministry of EducationSchool of Energy and EnvironmentSoutheast UniversityNanjing 211189JiangsuChina Tianmu Lake Institute of Advanced Energy Storage Technologies Liyang 213300JiangsuChina

Designing anion-dominated weak solvation structures is often achieved by elevating the concentration of Li ***,this is accompanied by the increase in the ***,a medium concentration electrolyte (1 M) with weak solvation structures is established by the multi-anion *** anions in the electrolyte strengthen the anion-solvent interactions through stronger ion–dipole *** reduces the quantity of free solvent and improves the reduction resistance of *** addition,the Li ion–solvent interaction is weakened,facilitating the anions to enter the solvation sheaths of Li *** multi-anion-dominated weak solvation structures boost Li ion diffusion in the electrolyte,accelerate the desolvation process of Li ions,and induce inorganic-rich solid electrolyte interphase and uniform Li *** average Coulombic efficiency of 99.1%for repeated Li plating/stripping can be ***||LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) cells with a high cathode loading of 3.0 m A h cm^(-2) can maintain a capacity retention as high as 95% after 150 *** finding provides novel standpoints to modulate the interaction of solvation structures and extend the lifespan of high-energy–density Li metal batteries.

关键词： Lithium metal battery Multi-anion electrolyte Weak solvation structure Desolvation Solid electrolyte interphase

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Solar evaporation for simultaneous oil-water separation and electricity generation with Janus wood-based absorbers

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Frontiers of Environmental Science & Engineering 2024年第2期18卷 13-23页

作者： Yue Yang Ze Fu Qi Zhang Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse School of Environmental and Biological EngineeringNanjing University of Science&TechnologyNanjing 210094China Key Laboratory of Industrial Ecology and Environmental Engineering(Ministry of Education) School of Environmental Science and TechnologyDalian University of TechnologyDalian 116024China National Laboratory of Solid State Microstructures Collaborative Innovation Center of Advanced MicrostructuresCollege of Engineering and Applied SciencesKey Laboratory of Intelligent Optical Sensing and Manipulation(Ministry of Education)Jiangsu Key Laboratory of Artificial Functional MaterialsNanjing UniversityNanjing 210093China

Oily wastewater from ocean oil spills endangers marine ecosystems and human health. Therefore, developing an effective and sustainable solution for separating oil-water mixtures is urgent. Interfacial solar photothermal evaporation is a promising approach for the complete separation of two-phase mixtures using only solar energy. Herein, we report a carbonized wood-based absorber with Janus structure of comprising a hydrophobic top-layer and an oleophobic bottom-layer for simultaneous solar-driven oil-water separation and electricity generation. Under sunlight irradiation, the rapid evaporation of seawater will induce a separation of oil-water mixtures, and cause a high salt concentration region underlying the interface, while the bottom “bulk water” maintains in a low salt concentration, thus forming a salinity gradient. Electricity can be generated by salinity gradient power. Therefore, oil-water separation efficiency of > 99% and derived extra electricity power of ~0.1 W/m2 is achieved under solar radiation, demonstrating the feasibility of oil-water separation and electricity production synchronously directly using solar energy. This work provides a green and cost-effective path for the separation of oil-water mixtures.

关键词： Oily wastewater Carbonized wood Salinity gradient Electricity generation Solar irradiation

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Image Denoising of Fishing Nets Underwater with Range Selection Based on Convolutional Sparse Coding 4

Image Denoising of Fishing Nets Underwater with Range Select...

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4th International Symposium on Computer Engineering and Intelligent Communications, ISCEIC 2023

作者： Wu, Sheng Liu, Chao Zhang, Honglei Duan, Enyue Jiang, Nian Harbin Engineering University Yantai Research Institute China Jiangsu Ocean University Jiangsu Key Laboratory of Function Control Technology for Advanced Materials Jiangsu China Marine Photoelectric Imaging Project Team Shandong Aerospace Electronic Technology Institute Shandong China

ISBN: (纸本)9798350306323

The underwater detection imaging technology mainly includes sonar imaging and underwater optical imaging. In order to overcome the disadvantages of low resolution of sonar imaging and short detection range of traditional optical imaging, optical gating technology is applied to underwater fishing net detection. This technology has higher resolution compared to sonar imaging, and its detection range has also been shown to be three times larger than that of conventional optical imaging. However, underwater range gating imaging can suffer from large random noise and low signal-to-noise ratio. In order to solve this problem, this paper proposes a convolutional sparse coding denoising neural network based on deep learning to improve image quality. This network consists of a local residual channel and a global convolutional sparse coding channel. Compared with DnCNN, ECNDNet and other methods, the average Peak signal-to-noise ratio of the proposed method is improved by 1.572.11dB, which can effectively remove random noise and reconstruct clear underwater fishing net range-gated images. © 2023 IEEE.

关键词： Signal to noise ratio

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Effect of Room Temperature Ultrasonic Vibration Compression on the Microstructure Evolution and Mechanical Properties of AZ91 Alloy

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Acta Metallurgica Sinica(English Letters) 2024年第7期37卷 1135-1146页

作者： Ziyue Xu Huan Liu Luyao Li Chao Sun Xi Tan Baishan Chen Qiangsheng Dong Yuna Wu Jinghua Jiang Jiang Ma College of Materials Science and Engineering Hohai UniversityNanjing210000China Suzhou Research Institute of Hohai University Suzhou215000China Shenzhen Key Laboratory of High Performance Nontraditional Manufacturing College of Mechatronics and Control EngineeringShenzhen UniversityShenzhen518060China Institute of Medical Devices(Suzhou) Southeast UniversitySuzhou215163China Institute for Advanced Study Central South UniversityChangsha410083China Jiangsu Key Laboratory of Advanced Structural Materials and Application Technology Nanjing Institute of TechnologyNanjing211167China

To investigate the potential of direct ultrasonic vibration on improving the performance of magnesium alloys,this study first employed the ultrasonic vibration compression(UVC)on the solid solution treated AZ91 alloy,and explored its microstructure evolution and mechanical properties under *** only two seconds,the UVC alloys showed large deformation strains of 34.8–54.4%,and sudden increase of sample temperature to 243℃.Microstructure characterizations proved that UVC promoted the formation of abundant shear bands,fine grains,and the bimodal distribution of Mg17Al12 precipitates consisting of submicron particles located within the shear bands and nano-sized ones within the *** to the unique microstructure,the micro-hardness(and nano-hardness)value of UVC alloy was increased by 37.7%(35%)when compared with the solution-treated ***,the nano-modulus of the developed AZ91 alloy was also significantly increased to 62 GPa by statistical nanoindentation tests,which could be ascribed to increased Mg_(17)Al_(12) precipitates and decreased c/a value to some *** general,this work provides a new insight into the design and preparation of high-performance magnesium alloys by UVC at room temperature.

关键词： AZ91 alloys Ultrasonic vibration compression Precipitation Shear bands Mechanical properties

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Efficient electrooxidation of biomass-derived aldehydes over ultrathin Ni V-layered double hydroxides films

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Journal of Energy Chemistry 2023年第3期78卷 412-421,I0012页

作者： Biying Liu Zhikeng Zheng Yaoyu Liu Man Zhang Yuchen Wang Yangyang Wan Kai Yan Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology School of Environmental Science and EngineeringSun Yat-sen UniversityGuangzhou 510275GuangdongChina Guangdong Laboratory for Lingnan Modern Agriculture South China Agricultural UniversityGuangzhou 510642GuangdongChina Institute for Advanced Materials School of Materials Science and EngineeringJiangsu UniversityZhenjiang 212013JiangsuChina

Selective upgrading of C=O bonds to afford carboxylic acid is significant for the petrochemical industry and biomass *** we declared the efficient electrooxidation of biomass-derived aldehydes family over NiV-layered double hydroxides(LDHs) thin *** studies confirmed the hydroxyl active intermediate(-OH*) generated on the surface of NiV-LDHs films by employing electrochemical impedance spectroscopy and the electron paramagnetic resonance *** using advanced techniques,e.g.,extended X-ray absorption fine structure and high-angle annular dark-field scanning transmission electron microscopy,NiV-LDHs films with 2.6 nm could expose larger specific surface *** benzaldehyde as a model,high current density of 200 mA cm^(-2)at 1.8 V ***,81.1% conversion,77.6% yield of benzoic acid and 90.8% Faradaic efficiency were reached,which was superior to most of previous *** DFT analysis was well matched with experimental findings and documented that NiV-LDHs had high adsorption capacity for the aldehydes to suppress the side reaction,and the aldehydes were oxidized by the electrophilic hydroxyl radicals formed on *** findings offer a universal strategy for the robust upgrading of diverse biomass-derived platform chemicals.

关键词： NiV-LDHs Films Hydroxyl radicals Electrocatalytic oxidation Biomass-derived aldehydes

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