Understanding of reaction and structural property of diuranium(Ⅲ) complexes of a single ligand is essential to advancing their experimental synthesis and exploring promising applications in small molecule activatio...
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Understanding of reaction and structural property of diuranium(Ⅲ) complexes of a single ligand is essential to advancing their experimental synthesis and exploring promising applications in small molecule activation *** examined a series of diuranium(Ⅲ) complexes building on the reaction of[UI(THF)]and octadentate polypyrrolic ligands(HL and HL).At the relativistic density functional theory level,11.2 kcal/mol energy is required to form the Pacman-like[(UI)(μ-I)(L)](1) in THF solution,while only 0.5 kcal/mol for its non-classic Pacman isomer *** agree with their analogues that have been experimentally proposed.A variety of chemical modification has been made for *** addition of one THF solvent or one iodine ion raises reaction energy by 6.8~14.5 kcal/mol,while two or more are significantly *** energies of 1.4 and 7.4kcal/mol are required when varying bridged atom(from the iodine of 1 into the THF of 2[(UI)(μ-THF)(L)]) and lengthening ligand linker size(from ortho-phenylene of HL of 1 into anthracene of HL of 3[(UI)(μ-I)(L)]),*** diuranium(Ⅲ) complexes were optimized to be energetically *** U-U distances of 4.13 and 4.08 A were calculated for 1 and 2,respectively,compared with the long one of 5.90 A for 3.
Upon deposition of laser irradiation on sealing surface, energy build-up heats up the structural radiation area, significantly and rapidly changing the mechanical properties of the materials in the irradiated area. Co...
Upon deposition of laser irradiation on sealing surface, energy build-up heats up the structural radiation area, significantly and rapidly changing the mechanical properties of the materials in the irradiated area. Consequently, the change of material properties leads to the liquidation of the radiated surfaces which is responsible for the binding efficacy of EVA glue. It is therefore important to investigate the temperature field during the transient sealing period. In our study we demonstrate a method of temperature field investigation by finite element analysis using Ansys software. Three-dimensional finite element simulation is employed to investigate the temperature fields and heat flux in a 0.2mm-thick adhesive layer on surface of a sealing edge with total thickness of 0.5mm x 22mm width. The laser beam was emitted by a device with laser power of 3kw, scanning speed 100mm/s, 980nm wavelength, induced temperature ranging from 100°C to 160°C. Results proved optimal temperature of 135°C, inducing total heat flux of 8731.8 w/m2 which is suitable for melting adhesive for optimized binding efficacy. Our study introduced the optimal temperature, heat flux generated by the laser beam yet retaining performance of adhesive, as well as ascertaining binding efficacy and durable linkage between EVA glue and surface of wooden boards.
China has become a leading powerhouse in global research *** boom of scientific and technical papers published by Chinese researchers in terms of both quantity and quality has been well ***,concerns have been raised o...
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China has become a leading powerhouse in global research *** boom of scientific and technical papers published by Chinese researchers in terms of both quantity and quality has been well ***,concerns have been raised on current publication drives.
China is a significant atmospheric carbon dioxide *** of agricultural waste in China is also a problematic issue,raising environmental and carbon-emission-related ***,the coal-dependent economy is accompanied by the f...
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China is a significant atmospheric carbon dioxide *** of agricultural waste in China is also a problematic issue,raising environmental and carbon-emission-related ***,the coal-dependent economy is accompanied by the formation of large coal mine goaf areas,particularly in Shanxi *** this context,the idea of filling crop residues into the coal mine goafs is *** concept addresses multi-functions:(1)carbon sequestration,(2)an alternative disposal method of crop residue in rural areas,and(3)coal mine goaf remedy.
Ni-Fe-P ternary alloy coating was deposited on triplochiton sclexcylon veneers by electroless plating to prepare a magnetic,corrosion-resistant and electromagnetic shielding wood-based *** effects of solution pH and p...
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Ni-Fe-P ternary alloy coating was deposited on triplochiton sclexcylon veneers by electroless plating to prepare a magnetic,corrosion-resistant and electromagnetic shielding wood-based *** effects of solution pH and plating temperature on the deposition rate,surface resistivity,chemical composition and crystal structure of the coatings were *** surface morphologies were observed by using scanning electron microscope(SEM)and the chemical composition of the coatings were analyzed by energy dispersive spectrometer(EDS)and X-ray photoelectron spectroscopy(XPS).The magnetism and corrosion resistance were measured by vibrating sample magnetometer and potentiodynamic corrosion *** results show that the deposition rate increases with pH value increasing from 8.6 to 9.2 and temperature increasing from 70 ℃ to 90 ℃.The coatings obtained at experimental condition are all *** coating is mainly consisted of Ni0,Fe0 and P0,but the surface was polluted by the component of the plating *** coatings are uniform,continuous and compact,and the special structure of wood is still seen *** veneer-based composite exhibits higher corrosion resistance and *** ESE value reaches 40-60 dB in frequencies from 9 kHz to 1.5 *** work provided a new pathway for producing multifunctional wood-based composite.
The curing behavior of lignin-based phenol-formaldehyde (LPF) resin with different contents of nano-crystalline cellulose (NCC) was studied by differential scanning calorimetry (DSC) at different heating rates (5, 10 ...
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The curing behavior of lignin-based phenol-formaldehyde (LPF) resin with different contents of nano-crystalline cellulose (NCC) was studied by differential scanning calorimetry (DSC) at different heating rates (5, 10 and 20°C/min) and the bonding property was evaluated by the wet shear strength and wood failure of two-ply plywood panels after soaking in water (48 hours at room temperature and followed by 1-hour boiling). The test results indicated that the NCC content had little influence on the peak temperature, activation energy and the total heat of reaction of LPF resin at 5 and 10°C/min. But at 20°C/min, LPF0.00% (LPF resin without NCC) showed the highest total heat of reaction, while LPF0.25% (LPF resin containing 0.25% NCC content) and LPF0.50% (LPF resin containing 0.50% NCC content) gave the lowest value. The wet shear strength was affected by the NCC content to a certain extent. With regard to the results of one-way analysis of variance, the bonding quality could be improved by NCC and the optimum NCC content ranged from 0.25% to 0.50%. The wood failure was also affected by the NCC content, but the trend with respect to NCC content was not clear.
Mechanical models were often used to describe and predict synthetic fibre reinforced thermosetting polymers. However, natural fibre reinforced thermoplastic polymers were less mentioned. In this paper, the application...
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