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Molecular Tailoring Based on Forster Resonance Energy Transfer for Initiating Two-Photon Theranostics with Amplified Reactive Oxygen Species

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Analytical Chemistry 2022年第40期94卷 14029-14037页

作者： Wang, Junjun Li, Jinsong Yu, Zhipeng Zhu, Xiaojiao Yu, Jianhua Wu, Zhichao Wang, Sen Zhou, Hongping School of Chemistry and Chemical Engineering Institute of Physical Science and Information Technology Anhui University Key Lab. of Struct. and Funct. Reg. of Hybrid Materials (Anhui University) Ministry of Education Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials of Anhui Province Hefei 230601 China

The fabrication of multifunctional photosensitizers (PSs) with abundant Type I/II ROS for efficient theranostics in the "therapeutic window"(700-900 nm) is an appealing yet significantly challenging task. We herein report a molecular tailoring strategy based on intramolecular two-photon Forster Resonance Energy Transfer (TP-FRET) to obtain a novel theranostic agent (Lyso-FRET), featuring the amplified advantage of energy donor (NH) and acceptor (COOH), because of the reuse of fluorescence energy with high efficiency of FRET (∼83%). Importantly, under the excitation by the near-infrared (840 nm) window, Lyso-FRET can not only penetrate the deeper tissue with a higher resolution for fluorescence imaging due to the nonlinear optical (NLO) nature, but also generate more Type I (superoxide anion) and Type II (singlet oxygen) reactive oxygen species for hypoxic PDT. Moreover, Lyso-FRET targeting lysosomes further promotes the effect of treatment. The experiments in vitro and in vivo also verify that the developed TP-FRET PS is conducive to treating deep hypoxic tumors. This strategy provides new and significant insights into the design and fabrication of advanced multifunctional PSs. © 2022 American Chemical Society.

关键词： Cells Fluorescence Fluorescence imaging Fluorescence resonance energy transfer Irradiation

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Low-altitude Friendly-Jamming for Satellite-Maritime Communications via Generative AI-enabled Deep Reinforcement Learning

arXiv

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arXiv 2025年

作者： Huang, Jiawei Wang, Aimin Sun, Geng Li, Jiahui Wang, Jiacheng Niyato, Dusit Leung, Victor C.M. College of Computer Science and Technology Jilin University Changchun130012 China Key Laboratory of Symbolic Computation and Knowledge Engineering of Ministry of Education Jilin University Changchun130012 China College of Computer Science and Technology Key Laboratory of Symbolic Computation and Knowledge Engineering of Ministry of Education Jilin University Changchun130012 China College of Computing and Data Science Nanyang Technological University Singapore639798 Singapore Artificial Intelligence Research Institute Shenzhen MSU-BIT University Shenzhen518115 China College of Computer Science and Software Engineering Shenzhen University Shenzhen518060 China Department of Electrical and Computer Engineering The University of British Columbia VancouverV6T 1Z4 Canada

Low Earth Orbit (LEO) satellites can be used to assist maritime wireless communications for data transmission across wide-ranging areas. However, extensive coverage of LEO satellites, combined with openness of channels, can cause the communication process to suffer from security risks. This paper presents a low-altitude friendly-jamming LEO satellite-maritime communication system enabled by a unmanned aerial vehicle (UAV) to ensure data security at the physical layer. Since such a system requires trade-off policies that balance the secrecy rate and energy consumption of the UAV to meet evolving scenario demands, we formulate a secure satellite-maritime communication multi-objective optimization problem (SSMCMOP). In order to solve the dynamic and long-term optimization problem, we reformulate it into a Markov decision process. We then propose a transformer-enhanced soft actor critic (TransSAC) algorithm, which is a generative artificial intelligence-enable deep reinforcement learning approach to solve the reformulated problem, so that capturing global dependencies and diversely exploring weights. Simulation results demonstrate that the TransSAC outperforms various baselines, and achieves an optimal secrecy rate while effectively minimizing the energy consumption of the UAV. Moreover, the results find more suitable constraint values for the system. Copyright © 2025, The Authors. All rights reserved.

关键词： Multiobjective optimization

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Effects of Back-Reflectors on a-Si: H Solar Cells 7

Effects of Back-Reflectors on a-Si: H Solar Cells

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2021 7th International Forum on Manufacturing Technology and engineering Materials, IFEMMT 2021

作者： Hu, Zhihua Aierken, Abuduwayiti Diao, Hongwei Key Lab. of Advanced Technology and Preparation for Renewable Energy Materials State Ministry of Education Yunnan Key Lab. of Rural Energy Engineering School of Energy and Environmental Sciences Yunnan Normal University Kunming Yunnan China Institute of Electrical Engineering Chinese Academic of Sciences Beijing China

ZAO (ZnO: Al)/Al and ITO/Ag complex back-reflectors were successfully applied to substrate nip and superstrate pin amorphous silicon solar cells respectively. As a result, the short circuit current (Isc) for a cell with a complex back-reflector increases significantly as compared with a cell without a complex back-reflector. For a superstrate pin cell prepared on SnO2 coated glass, the short-circuit current even increases up to 30%. © Published under licence by IOP Publishing Ltd.

关键词： Zinc oxide

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Hierarchical Multi-Granular Decision Networks for Hierarchical Classification

SSRN

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SSRN 2024年

作者： Liu, Haoyang Hu, Xue gang Bai, Shengxing Lin, Yaojin Key Laboratory of Knowledge Engineering with Big Data Hefei University of Technology Ministry of Education China School of Computer Science and Information Engineering Hefei University of Technology Anhui Hefei230009 China Anhui Province Key Laboratory of Industry Safety and Emergency Technology Anhui Hefei230009 China School of Computer Science Minnan Normal University Fujian Zhangzhou363000 China Key Laboratory of Data Science and Intelligence Application Minnan Normal University Fujian Zhangzhou363000 China

Hierarchical classification learning is an effective means of solving large-scale classification problems, which models classification problems at different levels of granularity according to a hierarchical structure. In hierarchical classification tasks, classification results at different levels of granularity are mutually beneficial, where coarse-grained results can reduce the number of fine-grained candidate categories, and fine-grained results can provide a basis for coarse-grained classification. However, for the final decision, the contribution of the granularity levels in the different hierarchies is different and unknown. Feedback from different granularity levels should be flexibly integrated. In addition, errors in hierarchical classification are not equivalent, and some errors can have serious results for practical applications. In order to address the above challenges, we propose a new hierarchical network to integrate multi-granularity knowledge for decision making. On the one hand, the network computes the decision scores of instances at each granularity level and learns a set of weights to combine all scores. Based on the learnable weights, the model can effectively utilize the multi-granularity classification results to obtain the final decision. On the other hand, we design local and global classification losses to guide model optimization, which allows the model to gain a hierarchical perspective and the ability to understand the degree of hierarchical misclassification. As a result, the extent to which the method results in misclassification consequences is limited. Experimental results on five benchmark datasets show that our method arises as a state-of-the-art hierarchical classification method. © 2024, The Authors. All rights reserved.

关键词： Deep neural networks

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An End-to-End data-Adaptive Pancreas Segmentation System with an Image Quality Control Toolbox

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Journal of Healthcare engineering 2023年第1期2023卷

作者： Zhu, Yan Hu, Peijun Li, Xiang Tian, Yu Bai, Xueli Liang, Tingbo Li, Jingsong Engineering Research Center of EMR and Intelligent Expert System Ministry of Education Key Laboratory for Biomedical Engineering of Ministry of Education College of Biomedical Engineering and Instrument Science Zhejiang University Hangzhou310027 China Research Center for Healthcare Data Science Zhejiang Lab Hangzhou311100 China Department of Hepatobiliary and Pancreatic Surgery The First Affiliated Hospital Zhejiang University School of Medicine Hangzhou310006 China Zhejiang Provincial Key Laboratory of Pancreatic Disease Hangzhou310006 China

With the development of radiology and computer technology, diagnosis by medical imaging is heading toward precision and automation. Due to complex anatomy around the pancreatic tissue and high demands for clinical experience, the assisted pancreas segmentation system will greatly promote clinical efficiency. However, the existing segmentation model suffers from poor generalization among images from multiple hospitals. In this paper, we propose an end-to-end data-adaptive pancreas segmentation system to tackle the problems of lack of annotations and model generalizability. The system employs adversarial learning to transfer features from lab.led domains to unlab.led domains, seeking a dynamic balance between domain discrimination and unsupervised segmentation. The image quality control toolbox is embedded in the system, which standardizes image quality in terms of intensity, field of view, and so on, to decrease heterogeneity among image domains. In addition, the system implements a data-adaptive process end-to-end without complex operations by doctors. The experiments are conducted on an annotated public dataset and an unannotated in-hospital dataset. The results indicate that after data adaptation, the segmentation performance measured by the dice similarity coefficient on unlab.led images improves from 58.79% to 75.43%, with a gain of 16.64%. Furthermore, the system preserves quantitatively structured information such as the pancreas' size and volume, as well as objective and accurate visualized images, which assists clinicians in diagnosing and formulating treatment plans in a timely and accurate manner. © 2023 Yan Zhu et al.

关键词： Image quality

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Visible Thermal Person Re-Identification Via Multi-Branch Modality Residual Complementary Learning

SSRN

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SSRN 2024年

作者： Chen, Long Sun, Rui Yu, Yiheng Du, Yun Zhang, Xudong Key Laboratory of Knowledge Engineering with Big Data Ministry of Education School of Computer and Information Anhui Province Key Laboratory of Industry Safety and Emergency Technology Hefei University of Technology Hefei230009 China The School of Computer and Information Anhui Province Key Laboratory of Industry Safety and Emergency Technology Hefei University of Technology Hefei230009 China

Visible-thermal Person Re-identification (VT Re-ID) is a challenging task in all-weather surveillance system. Existing methods focus on extracting the modality-shared features, ignoring the discriminative inter-modality complementary features. To tackle this issue, we propose the multi-branch modality residual complementary learning method consisting of modality residual complementary learning (MRCL) module and multi-branch feature learning (MBFL) module. The MRCL module can be easily integrated into existing CNN and Transformer baselines and drive the network to focus on both intra-modality and inter-modality information simultaneously. On one hand, we adopt the basic two-stream network to obtain the intra-modality features, on the other hand, we feed the residual image acquired by cross-modality correlation saliency erasing operation to another two-stream network to capture the inter-modality complementary features. Moreover, we employ the MBFL module to capture local spatial features and local channel features and integrate them with global features to increase the discriminability and robustness of the ultimate representations for handling intra-modality variations. The extensive experiments on RegDB and SYSU-MM01 datasets demonstrate the superiority of our proposed method compared with state-of-the-art methods. © 2024, The Authors. All rights reserved.

关键词： Learning systems

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Dual UAV Cluster-Assisted Maritime Physical Layer Secure Communications via Collab.rative Beamforming

arXiv

引用

arXiv 2024年

作者： Huang, Jiawei Wang, Aimin Sun, Geng Li, Jiahui Wang, Jiacheng Du, Hongyang Niyato, Dusit College of Computer Science and Technology Jilin University Changchun130012 China Key Laboratory of Symbolic Computation and Knowledge Engineering of Ministry of Education Jilin University Changchun130012 China College of Computing and Data Science Nanyang Technological University Singapore639798 Singapore Department of Electrical and Electronic Engineering Hong Kong University 999077 Hong Kong

Unmanned aerial vehicles (UAVs) can be utilized as relay platforms to assist maritime wireless communications. However, complex channels and multipath effects at sea can adversely affect the quality of UAV transmitted signals. Collab.rative beamforming (CB) can enhance the signal strength and range to assist the UAV relay for remote maritime communications. However, due to the open nature of UAV channels, security issue requires special consideration. This paper proposes a dual UAV cluster-assisted system via CB to achieve physical layer security in maritime wireless communications. Specifically, one UAV cluster forms a maritime UAV-enabled virtual antenna array (MUVAA) relay to forward data signals to the remote legitimate vessel, and the other UAV cluster forms an MUVAA jammer to send jamming signals to the remote eavesdropper. In this system, we formulate a secure and energy-efficient maritime communication multi-objective optimization problem (SEMCMOP) to maximize the signal-to-interference-plus-noise ratio (SINR) of the legitimate vessel, minimize the SINR of the eavesdropping vessel and minimize the total flight energy consumption of UAVs. Since the SEMCMOP is an NP-hard and large-scale optimization problem, we propose an improved swarm intelligence optimization algorithm with chaotic solution initialization and hybrid solution update strategies to solve the problem. Simulation results indicate that the proposed algorithm outperforms other comparison algorithms, and it can achieve more efficient signal transmission by using the CB-based method. Copyright © 2024, The Authors. All rights reserved.

关键词： Multiobjective optimization

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Hierarchical Alignment-enhanced Adaptive Grounding Network for Generalized Referring Expression Comprehension 39

Hierarchical Alignment-enhanced Adaptive Grounding Network f...

引用

39th Annual AAAI Conference on Artificial Intelligence, AAAI 2025

作者： Wang, Yaxian Ding, Henghui He, Shuting Jiang, Xudong Wei, Bifan Liu, Jun School of Computer Science and Technology Xi'an Jiaotong University China Ministry of Education Key Laboratory of Intelligent Networks and Network Security Xi'an Jiaotong University China Institute of Big Data Fudan University China Shanghai University of Finance and Economics China Nanyang Technological University Singapore School of Continuing Education Xi'an Jiaotong University China Shaanxi Province Key Laboratory of Big Data Knowledge Engineering Xi'an Jiaotong University China

ISBN: (纸本)157735897X

In this work, we address the challenging task of Generalized Referring Expression Comprehension (GREC). Compared to the classic Referring Expression Comprehension (REC) that focuses on single-target expressions, GREC extends the scope to a more practical setting by further encompassing no-target and multi-target expressions. Existing REC methods face challenges in handling the complex cases encountered in GREC, primarily due to their fixed output and limitations in multi-modal representations. To address these issues, we propose a Hierarchical Alignment-enhanced Adaptive Grounding Network (HieA2G) for GREC, which can flexibly deal with various types of referring expressions. First, a Hierarchical Multi-modal Semantic Alignment (HMSA) module is proposed to incorporate three levels of alignments, including word-object, phrase-object, and text-image alignment. It enables hierarchical cross-modal interactions across multiple levels to achieve comprehensive and robust multi-modal understanding, greatly enhancing grounding ability for complex cases. Then, to address the varying number of target objects in GREC, we introduce an Adaptive Grounding Counter (AGC) to dynamically determine the number of output targets. Additionally, an auxiliary contrastive loss is employed in AGC to enhance object-counting ability by pulling in multi-modal features with the same counting and pushing away those with different counting. Extensive experimental results show that HieA2G achieves new state-of-the-art performance on the challenging GREC task and also the other 4 tasks, including REC, Phrase Grounding, Referring Expression Segmentation (RES), and Generalized Referring Expression Segmentation (GRES), demonstrating the remarkable superiority and generalizability of the proposed HieA2G. Copyright © 2025, Association for the Advancement of Artificial Intelligence (***). All rights reserved.

关键词： Modal analysis

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Size-Invariance Matters: Rethinking Metrics and Losses for Imbalanced Multi-object Salient Object Detection 41

Size-Invariance Matters: Rethinking Metrics and Losses for I...

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41st International Conference on Machine Learning, ICML 2024

作者： Li, Feiran Xu, Qianqian Bao, Shilong Yang, Zhiyong Cong, Runmin Cao, Xiaochun Huang, Qingming Institute of Information Engineering Chinese Academy of Sciences Beijing China School of Cyber Security University of Chinese Academy of Sciences Beijing China Key Laboratory of Intelligent Information Processing Institute of Computing Technology Chinese Academy of Sciences Beijing China School of Computer Science and Technology University of Chinese Academy of Sciences Beijing China Institute of Information Science Beijing Jiaotong University Beijing China School of Control Science and Engineering Shandong University Jinan China Key Laboratory of Machine Intelligence and System Control Ministry of Education Jinan China School of Cyber Science and Tech. Sun Yat-sen University Shenzhen Campus China Key Laboratory of Big Data Mining and Knowledge Management Chinese Academy of Sciences Beijing China

This paper explores the size-invariance of evaluation metrics in Salient Object Detection (SOD), especially when multiple targets of diverse sizes co-exist in the same image. We observe that current metrics are size-sensitive, where larger objects are focused, and smaller ones tend to be ignored. We argue that the evaluation should be size-invariant because bias based on size is unjustified without additional semantic information. In pursuit of this, we propose a generic approach that evaluates each salient object separately and then combines the results, effectively alleviating the imbalance. We further develop an optimization framework tailored to this goal, achieving considerable improvements in detecting objects of different sizes. Theoretically, we provide evidence supporting the validity of our new metrics and present the generalization analysis of SOD. Extensive experiments demonstrate the effectiveness of our method. The code is availab.e at https://***/Ferry-Li/SI-SOD. Copyright 2024 by the author(s)

关键词： Object detection

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Hierarchical Alignment-enhanced Adaptive Grounding Network for Generalized Referring Expression Comprehension

arXiv

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arXiv 2025年

In this work, we address the challenging task of Generalized Referring Expression Comprehension (GREC). Compared to the classic Referring Expression Comprehension (REC) that focuses on single-target expressions, GREC extends the scope to a more practical setting by further encompassing notarget and multi-target expressions. Existing REC methods face challenges in handling the complex cases encountered in GREC, primarily due to their fixed output and limitations in multi-modal representations. To address these issues, we propose a Hierarchical Alignment-enhanced Adaptive Grounding Network (HieA2G) for GREC, which can flexibly deal with various types of referring expressions. First, a Hierarchical Multi-modal Semantic Alignment (HMSA) module is proposed to incorporate three levels of alignments, including word-object, phrase-object, and text-image alignment. It enables hierarchical cross-modal interactions across multiple levels to achieve comprehensive and robust multi-modal understanding, greatly enhancing grounding ability for complex cases. Then, to address the varying number of target objects in GREC, we introduce an Adaptive Grounding Counter (AGC) to dynamically determine the number of output targets. Additionally, an auxiliary contrastive loss is employed in AGC to enhance object-counting ability by pulling in multi-modal features with the same counting and pushing away those with different counting. Extensive experimental results show that HieA2G achieves new state-of-the-art performance on the challenging GREC task and also the other 4 tasks, including REC, Phrase Grounding, Referring Expression Segmentation (RES), and Generalized Referring Expression Segmentation (GRES), demonstrating the remarkable superiority and generalizability of the proposed HieA2G. Copyright © 2025, The Authors. All rights reserved.

关键词： Electric grounding

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