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Effect of Ca Micro-Alloying on the Microstructure and Anti-Corrosion Property of Mg0.5Zn0.2Ge Alloy

Acta Metallurgica Sinica(English Letters) 2024年第7期37卷 1147-1160页

作者： Bishan Cheng Depeng Li Baikang Xing Ruiqing Hou Pingli Jiang Shijie Zhu Shaokang Guan School of Materials Science and Engineering and Henan Key Laboratory of Advanced Magnesium Alloys Zhengzhou UniversityZhengzhou450001China Center of Advanced Analysis and Gene Sequencing Zhengzhou UniversityZhengzhou450001China Key Laboratory of Materials Processing and Mold Technology Ministry of EducationZhengzhou450002China

Magnesium and its alloys have attracting rising attention as one of biodegradable metallic ***,the rapid corrosion and severe localized corrosion still hinder their extensive applications in *** this study,micro-alloying of Ca(≤0.1 wt%)into Mg0.5Zn0.2Ge alloy developed in our previous work was explored to further enhance the corrosion resistance and alleviate the localized corrosion of the *** results reveal that the addition of Ca leads to the transformation of the cathodic Mg_(2)Ge phase in Mg0.5Zn0.2Ca alloy into anodic MgCaGe phase in Ca-containing alloys,thereby changing the galvanic couples in alloys during *** preferential dissolution of MgCaGe phase promotes the participation of Ca and Ge into the formation of corrosion products,resulting in the enrichment of Ca and Ge in the outmost of corrosion product layer,which stabilizes and passivates the corrosion product layer on Mg alloy ***,the enrichment of Zn at the corrosion interface seems to further hinder the corrosion of Mg *** of these factors confer a slower and more uniform corrosion on Mg0.5Zn0.2GexCa(x<0.1 wt%)alloy,which provides favorable candidates for the further processing to gain suitable biodegradable Mg alloys.

关键词： Magnesium alloy Micro-alloying Calcium Corrosion resistance

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Atomistic study of inverse size effect induced by interfacial plasticity in pearlitic multi-principal element alloy

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Rare Metals 2024年第7期43卷 3341-3355页

作者： Chen Yang Qiao-Sheng Xia Cun-Hong Yin Dong-Peng Hua College of Mechanical Engineering Guizhou UniversityGuiyang 550025China Key Laboratory of Advanced Manufacturing Technology Ministry of EducationGuizhou UniversityGuiyang 550025China State Key Laboratory of Solidification Processing Center of Advanced Lubrication and Seal MaterialsNorthwestern Polytechnical UniversityXi'an 710072China

Owing to the fine nano-laminated structure,the pearlitic multi-principal element alloy(PMPEA) exhibits excellent mechanical and tribological ***,the incomplete understanding of the size effect of its lamella thickness and the unclear understanding of the plasticity-interface interaction mechanism limit further optimization of *** this study,the FeCoNi/Ni_3Ti interface-mediated plastic deformation behavior in PMPEA and the variation of mechanical and tribological properties with lamella thickness within the nanoscale range using molecular dynamics(MD) simulation were *** results indicate that the mechanical and tribological properties of the PMPEA with lamella thicknesses below 10 nm have a significant inverse size effect,i.e.,the smaller the lamella thickness,the weaker the *** is because the plastic carrier-interface interaction mechanism changes from a strengthening mechanism that hinders dislocations to a weakening mechanism that promotes dislocations with the decreases in the lamella thickness,and the weakening effect becomes more pronounced as the lamella thickness decreases and the number of interfaces *** particular,the deformation behavior of Ni_3Ti lamellae changes from crystal-like to amorphous-like with decreasing ***,in the sample with larger lamella thickness,the occurrence of hierarchical slips in the body-centered cubic(BCC) phase due to the multiprincipal elements effect can better alleviate the stress concentration caused by the dislocation accumulation at the interface,so that the phase interface exhibits outstanding load-bearing *** the dislocation pattern in BCC phase shows a firm high-density cell,which makes the substrate exhibit a stable tribological response.

关键词： Multi-principal element alloy Nano-laminated structure Molecular dynamics simulation Nanoindentation and nanoscratch

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Optimizing large optical contrast in Ge-Se-Te films via high-throughput method

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Progress in Natural Science:materials International 2025年第1期35卷 222-228页

作者： Qiqi Chen Guoxiang Wang Zijun Liu Yixiao Gao Chenjie Gu Tiefeng Xu Xiang Shen Yimin Chen Laboratory of Infrared Material and Devices & Key Laboratory of Photoelectric Materials and Devices of Zhejiang Province Advanced Technology Research InstituteNingbo University Department of Microelectronic Science and Engineering School of Physical Science and Technology Ningbo University Ningbo Solartrum Co.Ltd.

Chalcogenide phase-change materials（PCMs） have attracted great attentions due to their potential applications in reconfigurable photonic devices. The Ge2Sb2Te5and GeTe PCMs exhibit significant difference in refractive index（Δn） between amorphous and crystalline states, but they suffer from high optical loss. The binary Sb2S3and Sb2Se3PCMs, however, show low optical loss but small Δn. This encourages us to develop the novel materials,which are desired to combine large Δn and low optical loss. Instead of traditional trial-and-error screening method, we here used an efficient high-throughput method to optimize the PCMs' candidates for reconfigurable photonic devices in Ge-Se-Te chalcogenides. The crystallization temperature and difference in optical bandgap were detected, and then the component of Ge25Se7Te68, which also exhibits ultralow optical loss of 1.2 × 10-6（in amorphous state） and large Δn of 1.32 at 1550 nm, was optimized. This Te-rich Ge-Se-Te film can be a candidate for the applications of programmable reconfigurable photonic circuits.

关键词： Chalcogenide phase-change films High-throughput Reconfigurable photonics Refractive index

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Accelerated water harvesting from vapor via a bio-inspired hydrogel pattern

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National Science Review 2024年第3期11卷 48-49页

作者： Lianbin Zhang Peng Wang State Key Laboratory of Material Processing and Die&Mould Technology Key Laboratory of Materials Chemistry for Energy Conversion and Storage of Ministry of Education School of Chemistry and Chemical Engineering Huazhong University of Science and Technology(HUST) School of Environmental Science and Engineering Sun Yat-sen University

Water and energy sustainability are integral parts of resource sustainability of the world. Due to water molecules' superior capability of serving as both hydrogenbond donor and acceptor, phase change of water, especially between liquid and vapor, underpins global water cycles,facilitates energy transformation and transfer, and thus helps shape the unique local weather and global climate patterns.

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Effect of Ti and Ta content on the oxidation resistance of Co-Ni-based superalloys

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International Journal of Minerals,Metallurgy and materials 2024年第2期31卷 351-361页

作者： Yuheng Zhang Zixin Li Yunwei Gui Huadong Fu Jianxin Xie Beijing Advanced Innovation Center for Materials Genome Engineering University of Science and Technology BeijingBeijing 100083China Institute of Materials Intelligent Technology Liaoning Academy of MaterialsShenyang 110004China Key Laboratory for Advanced Materials Processing(MOE) University of Science and Technology BeijingBeijing 100083China Beijing Laboratory of Metallic Materials and Processing for Modern Transportation University of Science and Technology BeijingBeijing 100083China

Co-Ni-based superalloys are known for their capability to function at elevated temperatures and superior hot corrosion and thermal fatigue ***,these alloys show potential as crucial high-temperature structural materials for aeroengine and gas turbine hot-end *** previous work elucidated the influence of Ti and Ta on the high-temperature mechanical properties of ***,the intricate interaction among elements considerably affects the oxidation resistance of *** this paper,Co-35Ni-10Al-2W-5Cr-2Mo-1Nb-xTi-(5−x)Ta alloys(x=1,2,3,4)with varying Ti and Ta contents were designed and compounded,and their oxidation resistance was investigated at the temperature range from 800 to 1000℃.After oxidation at three test conditions,namely,800℃for 200 h,900℃for 200 h,and 1000℃for 50 h,the main structure of the oxide layer of the alloy consisted of spinel,Cr_(2)O_(3),and Al_(2)O_(3)from outside to *** consisting of Ta,W,and Mo formed below the Cr_(2)O_(3)*** interaction of Ti and Ta imparted the highest oxidation resistance to 3Ti2Ta ***,an excessive amount of Ti or Ta resulted in an adverse effect on the oxidation resistance of the *** study reports the volatilization of W and Mo oxides during the oxidation process of Co-Ni-based cast superalloys with a high Al content for the first time and explains the formation mechanism of holes in the oxide *** results provide a basis for gaining insights into the effects of the interaction of alloying elements on the oxidation resistance of the alloys they form.

关键词： Co-Ni-based superalloys high-temperature oxidation Ti and Ta elements formation mechanism of holes

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Facile and effective synthesis strategy for terbium-doped hydroxyapatite toward photoelectric devices and flexible functional fibers

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Rare Metals 2024年第4期43卷 1713-1723页

作者： Xiao-Dong Zhang Kun Nie Zi-Yao Hu Ran-Ran Zhou Xiu-Qiang Duan Wu-Bin Dai Song-Song Nie Song-Jun Yao Luo-Xin Wang Le-Fu Mei Hua Wang Yi-Yi Yao Xiao-Xue Ma Hubei Key Laboratory for New Textile Materials and Applications and State Key Laboratory of New Textile Materials and Advanced Processing Technology School of Materials Science and EngineeringWuhan Textile UniversityWuhan430200China Key Laboratory of Testing and Tracing of Rare Earth Products for State Market Regulation Jiangxi University of Science and TechnologyGanzhou341000China Hubei Key Laboratory of Plasma Chemistry and Advanced Materials and Key Laboratory of Green Chemical Engineering Process of Ministry of Education Wuhan Institute of TechnologyWuhan430205China

As a material with good biocompatibility,hydroxyapatite(HAP)can have optical properties after doping with various rare earth *** a biocompatible fluorescent material,doped HAP could have broad applications in biological probes,drug delivery,optoelectronic materials,fluorescence anti-counterfeiting,and other *** this paper,we put forward the preparation of HAP doped with terbium(Ⅲ)ions(Tb^(3+))by hydrothermal *** controlling the Tb^(3+)doping content in reaction and the reaction time,the changes in HAP's structure,morphology,and luminescence properties under different conditions were *** the doping amount of Tb^(3+)reached an optimal value,the dipole-quadrupole would occur and the concentration would be *** control experiment showed that the optimal Tb3+content was 7.5×10^(-5)mol,which showed the best fluorescence ***,a non-luminous material,was rarely used in the field of fluorescent anti-counterfeiting and photoelectric *** proposed to prepare a luminescent aramid/polyphenylene sulfide(ACFs/PPS)fiber paper and a new light-emitting diode(LED)using the Tb-doped HAP *** composite sample exhibited an excellent stability and fluorescence performance,which also demonstrated a possibility of HAP applications in anticounterfeiting and *** introduction of Tb3+dopant HAP was done to give HAP optical properties and broaden the application range of HAP.

关键词： Hydroxyapatite Rare earth luminescence Photoelectric device Aramid Polyphenylene sulfide fiber paper Luminescent fiber

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Enhanced preparation of dendritic metallic vanadium in recyclable NaCl-KCl-VCl_(2) molten salt by V_(2)CO electrolysis

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Rare Metals 2024年第8期43卷 3961-3973页

作者： Jia-Liang An Ming-Yong Wang Yong-Zheng Jia Jin-Tao Zhang Bao-Yan Feng Shu-Qiang Jiao State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China College of Material Science and Engineering Hebei Province Laboratory of Inorganic Nonmetallic MaterialsNorth China University of Science and TechnologyTangshan 063210China

A promising method for the preparation of pure metallic vanadium via V_(2)CO anode electrolysis was proposed and *** simple and controllable synthesis of a molten chloride salt containing VCl_(2) by an insitu reaction between VCl_(3) and metallic vanadium was verified through thermodynamic analysis and ***-KCl-VCl_(2) molten salt exhibited excellent recycling performance and could be repetitively used to prepare metallic vanadium by V_(2)CO *** V^(2+) ions remained in the molten salt after *** electrolysis conditions,such as the cathode diameter,current density,V^(2+) ion concentration,and temperature,were optimised to maximise the current *** was also simulated to reveal the regulatory *** highest current efficiency was 85%.The purity of metallic vanadium was up to 99.8%.In this study,an easy and efficient preparation of pure metallic vanadium was achieved.

关键词： V_(2)CO Metallic vanadium Current efficiency Molten salt electrolysis

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Exploring photogenerated charge carrier transfer in semiconductor/metal junctions using Kelvin probe force microscopy

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Journal of materials Science & technology 2024年第6期173卷 11-19页

作者： Chuanbiao Bie Zheng Meng Bowen He Bei Cheng Gang Liu Bicheng Zhu Laboratory of Solar Fuel Faculty of Materials Science and ChemistryChina University of GeosciencesWuhan 430078China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China CAS Key Laboratory of Standardization and Measurement for Nanotechnology National Center for Nanoscience and TechnologyBeijing 100190China

Semiconductor/metal junctions are widely discussed in ***,there is a notable scarcity of systematic studies focusing on photogenerated charge carrier transfer in such ***,CdS/Pt,CdS/Au,and CdS/Ag are synthesized to serve as model systems for investigating the charge carrier transfer in semiconductor/metal *** probe force microscopy is employed to visualize the transfer of photogenerated carriers in these *** results show that the electron transfer behavior under illumination is related to the conduction band position of CdS and the Fermi level position of the ***,Schottky junctions hinder the transfer of photogenerated electrons from CdS to Pt and Au,whereas ohmic contacts facilitate the transfer of photogenerated electrons from CdS to *** work provides novel insights into the mechanisms governing the transfer of photogenerated carriers in semiconductor/metal junctions.

关键词： Kelvin probe force microscopy Surface potential Work function Contact potential difference Charge carrier transfer

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Enhancing thermoelectric performance in P-type Mg_(3)Sb_(2)-based Zintls through optimization of band gap structure and nanostructuring

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Journal of materials Science & technology 2024年第3期170卷 25-32页

作者： Yi-bo Zhang Ji-Sheng Liang Chengyan Liu Qi Zhou Zhe Xu Hong-bo Chen Fu-cong Li Ying Peng Lei Miao Guangxi Key Laboratory of Information Material Engineering Research Center of Electronic Information Materials and DevicesMinistry of EducationSchool of Material Science and EngineeringGuilin University of Electronic TechnologyGuilin 541004China Guangxi Key Laboratory for Relativity Astrophysics Center on Nanoenergy ResearchGuangxi Key Laboratory of Processing for Nonferrous Metal and Featured MaterialsSchool of Physical Science&TechnologyGuangxi UniversityNanning 530004China Guangxi Key Laboratory of Precision Navigation Technology and Application Guilin University of Electronic TechnologySchool of Information and CommunicationGuilin 541004China

P-type Mg_(3)Sb_(2)-based Zintls have attracted considerable interest in the thermoelectric(TE)field due to their environmental friendliness and low ***,compared to their n-type counterparts,they show relatively low TE performance,limiting their application in TE *** this work,we simultaneously introduce Bi alloying at Sb sites and Ag doping at Mg sites into the Mg_(3)Sb_(2)to coopera-tively optimize the electrical and thermal properties for the first time,acquiring the highest ZT value of∼0.85 at 723 K and a high average ZT of 0.39 in the temperature range of 323-723 K in sample Mg_(2.94)Ag_(0.06)Sb_(1.9)Bi_(0.1).The first-principle calculations show that the codoping of Ag and Bi can shift the Fermi level into the valence band and narrow the band gap,resulting in the increased carrier concentration from 3.50×10^(17)cm^(-3)in the reference Mg 3 Sb 0.9 Bi 0.1 to∼7.88×10^(19)cm^(-3)in sample Mg 2.94 Ag 0.06 Sb 0.9 Bi *** a result,a remarkable power factor of∼778.9μW m^(-1)K^(-2)at 723 K is achieved in sample Mg 2.94 Ag 0.06 Sb 0.9 Bi ***,a low lattice thermal conductivity of∼0.48 W m^(-1)K^(-1)at 723 K is also obtained with the help of phonon scattering at the distorted lattice,point defects,and nano-precipitates in sample Mg 2.94 Ag 0.06 Sb 0.9 Bi *** synergistic effect of using the multi-element co-doping/-alloying to optimize electrical properties in Mg_(3)Sb_(2)holds promise for further improving the TE performance of Zintl phase materials or even others.

关键词： Thermoelectric materials Band engineering Nanostructuring P-type Mg_(3)Sb_(2) Ag and Bi Co-doping

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Grain-refining fabrication of nanocrystalline(La_(0.2)Nd_(0.2)Sm_(0.2)Gd_(0.2)Eu_(0.2))_(2)Zr_(2)O_(7)high-entropy ceramics by ultra-high pressure sintering

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Journal of materials Science & technology 2023年第36期167卷 205-212页

作者： Zhangtian Wu Wei Ji Jinyong Zhang Yanan Yuan Ji Zou Weimin Wang Zhengyi Fu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Hubei Longzhong Laboratory Wuhan University of Technology Xiangyang Demonstration ZoneXiangyang 441000China

As an important A_(2)B_(2)O_(7)-type ceramic,(La_(0.2)Nd_(0.2)Sm_(0.2)Gd_(0.2)Eu_(0.2))_(2)Zr_(2)O_(7)high-entropy pyrochlore pos-sesses promising properties such as high melting point,high chemical durability,and low thermal ***,the low sintering ability limits its application in thermal barrier coating and radioactive waste *** usually needs long-term high-temperature soaking to achieve full density,but with inevitable grain *** this work,dense and grain-refined nanocrystalline(La_(0.2)Nd_(0.2)Sm_(0.2)Gd_(0.2)Eu_(0.2))_(2)Zr_(2)O_(7)ceramics were prepared with ultra-high pressure sintering(UHPS)method under 10 GPa at a low temperature of 800℃.The densification behavior,microstructure evo-lution,and properties of the UHPS-ed samples were then *** grain size of as-prepared(La_(0.2)Nd_(0.2)Sm_(0.2)Gd_(0.2)Eu_(0.2))_(2)Zr_(2)O_(7)ceramic was only 151 nm,which is 40%smaller than that of raw *** addition,it exhibited advantageous properties including both high hardness and aqueous *** deformation under ultra-high pressure was believed as the dominant densification mechanism responsible for grain refinement and property improvement.

关键词： High-entropy ceramics Ultra-high pressure sintering Grain refining Nanocrystalline Plastic deformation

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