An Al2O3 dispersion strengthened(ADS)alloy with an ultra-high softening temperature of∼1200 K was fabricated by the in-situ internal oxidation and reduction *** evolution of the nanometer Al2O3 particles,grain size,a...
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An Al2O3 dispersion strengthened(ADS)alloy with an ultra-high softening temperature of∼1200 K was fabricated by the in-situ internal oxidation and reduction *** evolution of the nanometer Al2O3 particles,grain size,and consequently the softening behavior of this ADS alloy,were investigated by conducting the annealing treatments in the range from 673 K to 1273 K for 60 *** refined nanometer Al2O3 particles were found to be highly stable at elevated temperatures,leading to the high dislocation density and grain boundary stability of the *** average grain size was found to increase extremely slowly from∼0.60μm to∼0.74μm with increasing annealing temperatures from 773 K to 1273 K.A criterion for grain boundaries migration and softening was established based on the competition between grain growth and pinning effect of Al2O3 *** strong pinning effect of Al2O3 particles was found when the grain size was between the lower limit(about 0.4-0.5μm)and upper limit(2.18μm).The occurrence of softening behavior was attributed to the rapid increase of the proportion of grains larger than the upper limit.A modified Hall-Petch relationship was established by introducing the integration of the grain size distribution,which can describe this correlation between softening behavior and the pinning effect of Al2O3 *** current study not only sheds light on the further understanding of the softening mechanism of ADS copper alloy but also provides a useful route for designing copper alloy with high softening resistance.
Half Heusler materials exhibit excellent thermoelectric and mechanical properties,rendering them potential candidates for advanced thermoelectric ***,the developments on interrelated devices are impeded by their inher...
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Half Heusler materials exhibit excellent thermoelectric and mechanical properties,rendering them potential candidates for advanced thermoelectric ***,the developments on interrelated devices are impeded by their inherent brittleness and limited ***,it exists the potential ductility on half Heusler materials with face-centered cubic sub-lattices through the expectation of the occurrence of shear-induced‘catching bonds’which can result in excellent ductility on other face-centered cubic materials.
The wetting behavior of molten Cu on the B_(4)C-xTiB_(2)ceramic composites was investigated in this *** results show that the contact angle of molten Cu alloy on B_(4)C-TiB_(2)ceramic composites is linear with the com...
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The wetting behavior of molten Cu on the B_(4)C-xTiB_(2)ceramic composites was investigated in this *** results show that the contact angle of molten Cu alloy on B_(4)C-TiB_(2)ceramic composites is linear with the composition rate of TiB_(2)or B_(4)C while the temperature is in the range of 1300 to 1350℃,consistent with the expectation of the commonly used theoretical ***,a nonlinear relationship between the contact angle and the composition rate unexpectedly occurred at temperatures ranging from 1400 to 1500℃.The big difference of the contact angles between the molten metal and the components in the composites was found to be the key *** result identifies that the commonly used theoretical method only works at a limited difference of the contact angle of the liquid on the different phases in the composites,and fails at a big difference.
Simultaneously achieving high strength and high electrical conductivity in Cu–Ni–Si alloys pose a significant challenge, which greatly constrains its applications in the electronics industry. This paper offers a new...
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Simultaneously achieving high strength and high electrical conductivity in Cu–Ni–Si alloys pose a significant challenge, which greatly constrains its applications in the electronics industry. This paper offers a new pathway to improve properties, by preparation of nanometer lamellar discontinuous precipitates(DPs) arranged with the approximate same direction through a combination of deformationaging and cold rolling process. The strengthening effect is primarily attributed to nanometer-lamellar DPs strengthening and dislocation strengthening mechanism. The accumulation of dislocations at the interface between nanometer lamellar DPs and matrix during cold deformation process can results in the decrease of dislocation density inside the matrix grains, leading to the acceptably slight reduction of electrical conductivity during cold rolling. The alloy exhibits an electrical conductivity of 45.32%IACS(international annealed copper standard, IACS), a tensile strength of 882.67 MPa, and a yield strength of 811.33 MPa by this method. This study can provide a guidance for the composition and microstructure design of a Cu–Ni–Si alloy in the future, by controlling the morphology and distribution of DPs.
Reducing the hot working temperature and high-temperature deformation resistance of titanium alloy to improve hot rolling and hot extrusion workability of products with thin walls and complex section shapes has always...
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Reducing the hot working temperature and high-temperature deformation resistance of titanium alloy to improve hot rolling and hot extrusion workability of products with thin walls and complex section shapes has always been an important topic in the field of titanium alloy *** paper proposed a strategy of adding Mo and Fe elements to simultaneously reduce the hot working temperature and high-temperature deformation resistance of Ti-6Al-4V *** effects of Mo and Fe contents on the mi-crostructure,β transus temperature(Tp),and high-temperature flow stress(HFS)of Ti-6Al-4V-xMo-xFe(x=0-5)alloys were *** results showed that adding Mo and Fe can substantially reduce the Tp and HFS of the alloy,and greatly improve its room-temperature *** with com-mercial Ti-6Al-4V samples,the T_(β) of Ti-6Al-4V-2Mo-2Fe and Ti-6Al-4V-3Mo-3Fe samples was decreased by 68-98 ℃,and the HFS at 800-900 ℃ was decreased by 37.8%-46.0%.Compared with hot-rolled Ti-6Al-4V samples,the room-temperature tensile strength of hot-rolled Ti-6Al-4V-2Mo-2Fe samples was increased by about 30%,while the elongation hardly *** increased strength was mainly at-tributed to fine grain strengthening and solid solution *** hot workability and room-temperature strength of Ti-6Al-4V alloy can be significantly improved by adding 2-3 wt.%Mo and Fe simultaneously.
The cardiovascular diseases(CVD)continue to be the major threat to global public health over the years,while one of the effective methods to treat CVD is stent *** magnesium(Mg)alloys have great potential applications...
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The cardiovascular diseases(CVD)continue to be the major threat to global public health over the years,while one of the effective methods to treat CVD is stent *** magnesium(Mg)alloys have great potential applications in cardiovascular stents benefit from their excellent biodegradability and ***,excessive degradation rate and the delayed surface endothelialization still limit their further *** this study,we modified a Mg-Zn-Y-Nd alloy(ZE21B)by preparing MgF_(2) as the corrosion resistance layer,the dopamine polymer film(PDA)as the bonding layer,and hyaluronic acid(HA)loaded astaxanthin(ASTA)as an important layer to directing the cardiovascular cells *** electrochemical test results showed that the MgF_(2)/PDA/HA-ASTA coating improved the corrosion resistance of *** cytocompatibility experiments also demonstrated that this novel composite coating also selectively promoted endothelial cells proliferation,inhibited hyperproliferation of smooth muscle cells and adhesion of *** with the HAloaded rapamycin(RAPA)coating,our MgF_(2)/PDA/HA-ASTA coating showed better blood compatibility and cytocompatibility,indicating stronger multi-functions for the ZE21B alloy on cardiovascular application.
The exceptional photoelectric performance and high compatibility of perovskite materials render perovskite solar cells highly promising for extensive development,thus garnering significant *** perovskite solar cells,t...
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The exceptional photoelectric performance and high compatibility of perovskite materials render perovskite solar cells highly promising for extensive development,thus garnering significant *** perovskite solar cells,the hole transport layer plays a crucial *** the commonly employed organic small molecule hole transport material Spiro-OMeTAD,a certain period of oxidation treatment is required to achieve complete transport ***,this posttreatment oxidation processes typically rely on ambient oxidation,which poses challenges in terms of precise control and leads to degradation of the perovskite light absorption *** approach fails to meet the demands for high efficiency and stability in practical ***,the mechanism of ultrafast laser on Spiro-OMeTAD and the reaction process for laser-induced oxidation of it are ***2at Perovskite/Spiro-OMeTAD interface breaks down to produce I2upon ultrafast laser irradiation and I2promote the oxidation *** the laser irradiation oxidation processing,a higher stability of perovskite solar cells is *** work establishes a new approach toward oxidation treatment of Spiro-OMeTAD.
In the process of spraying coating perovskite films,the "coffee ring" effect (CRE) leads to the problem of excessive organic ammonium salt accumulation in local areas that cannot be completely *** introduc...
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In the process of spraying coating perovskite films,the "coffee ring" effect (CRE) leads to the problem of excessive organic ammonium salt accumulation in local areas that cannot be completely *** introduce an in-situ targeted defect-healing strategy by incorporating butylamine formate (BAFa) ionic liquid into the spray *** liquids,due to their long carbon chain structure,tend to target flow towards the CRE region during the droplet evaporation *** coordination between the lone pair electrons in the C=O group of BAFa and Pb2+effectively reduces defects in perovskite and suppresses non-radiative recombination ***,amine ligands,which are repelled to the film surface and grain boundaries,form a thin insulating monolayer in the CRE areas,forcing charge carriers to transport through areas of the perovskite with fewer *** approach enables the crystallization control and defect-heal over the Cs0.19FA0.81PbI3-x-yBrxClyperovskite ***,the champion perovskite solar cell achieved a power conversion efficiency of 22.04%,while mini-modules with an effective area of 64.8 cm2reached a peak power conversion efficiency of 18.35%,demonstrating the significant potential for commercializing large-area perovskite solar cells.
We synthesized BiVO_(4)mesocrystals with ordered assembly structure,and studied the structural order and the relationship between the photodegradation of Rhodamine *** nanoparticles(NPs)were successfully loaded onto M...
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We synthesized BiVO_(4)mesocrystals with ordered assembly structure,and studied the structural order and the relationship between the photodegradation of Rhodamine *** nanoparticles(NPs)were successfully loaded onto Meso-BiVO_(4)by light-assisted induction,and Cd nanoparticles were further selected to be deposited on Au nanoparticles to form Z-scheme photocatalyst Meso-BiVO_(4)-Au-CdS *** try and propose to analyze its ordered assembly structure by XRD for the first *** results show that Meso-BiVO_(4)is a mesocrystal with highly exposed(001)plane and directional assembly *** charge separation efficiency of all samples was studied by PL *** results show that the Z-scheme Meso-BiVO_(4)-Au-CdS can promote the charge separation and obtain the best carrier separation ***,it has the best photocatalytic activity in the experiment of photocatalytic degradation of rhodamine *** main active species in the degradation process were confirmed by free radical trapping experiment,and the degradation mechanism was put forward.
Under the vision of 'carbon peaking and carbon neutrality',the global energy system is facing a deep *** a clean energy with the potential to achieve zero carbon emissions,hydrogen energy will undoubtedly play...
Under the vision of 'carbon peaking and carbon neutrality',the global energy system is facing a deep *** a clean energy with the potential to achieve zero carbon emissions,hydrogen energy will undoubtedly play an important ***-energy-driven photo catalytic reactions can decompose water to produce hydrogen and reduce carbon dioxide to produce solar fuels.
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