检索结果-内蒙古大学图书馆

Identifying the dynamic behaviors in complete reconstruction of Co-based complex precatalysts during electrocatalytic oxygen evolution

引用

Journal of Energy Chemistry 2025年第1期100卷 226-233页

作者： Jingfang Zhang Danyang Wu Linke Cai Youluan Lu Fanpeng Cheng Lijuan Shi Qun Yi Yao Liu Yi Huang Key Laboratory of Green Chemical Engineering Process of Ministry of Education Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of EducationHubei Key Laboratory of Novel Reactor and Green Chemical TechnologySchool of Chemical Engineering&PharmacyWuhan Institute of TechnologyWuhan 430205HubeiChina Key Laboratory of Pesticide&Chemical Biology of Ministry of Education Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction of Ministry of EducationCollege of ChemistryCentral China Normal UniversityWuhan 430079HubeiChina College of Materials Science and Engineering Fuzhou UniversityFuzhou 350108FujianChina

Transition metal-based nanomaterials have emerged as promising electrocatalysts for oxygen evolution reaction(OER).Considerable research efforts have shown that self-reconstruction occurs on these nanomaterials under operating conditions of OER ***,most of them undergo incomplete reconstruction with limited thickness of reconstruction layer,leading to low component utilization and arduous exploration of real catalytic ***,we identify the dynamic behaviors in complete reconstruction of Co-based complexes during *** hollow phytic acid(PA)cross-linked CoFe-based complex nanoboxes with porous nanowalls are designed because of their good electrolyte penetration and mass transport ability,in favor of the fast and complete reconstruction.A series of experiment characterizations demonstrate that the reconstruction process includes the fast substitution of PA by OH-to form Co(Fe)(OH)xand subsequent potential-driven oxidation to Co(Fe)*** obtained CoFeOOH delivers a low overpotential of 290 mV at a current density of 10 mA cm^(-2)and a long-term *** experiment results together with theory calculations reveal that the Fe incorporation can result in the electron rearrangement of reconstructed CoFeOOH and optimization of their electronic structure,accounting for the enhanced OER *** work provides new insights into complete reconstruction of metal-based complexes during OER and offers guidelines for rational design of high-performance electrocatalysts.

关键词： Complete reconstruction Co-based complex Precatalysts Oxygen evolution reaction

来源：评论

学校读者我要写书评

暂无评论

Time-Varying Formation Tracking control of Heterogeneous Multi-Agent Systems With Intermittent Communications and Directed Switching Networks

引用

IEEE/CAA Journal of Automatica Sinica 2025年第1期12卷 294-296页

作者： Yuhan Wang Zhuping Wang Hao Zhang Huaicheng Yan the Shanghai Research Institute for Intelligent Autonomous Systems Tongji University the National Key Laboratory of Autonomous Intelligent Unmanned Systems the Frontiers Science Center for Intelligent Autonomous System of Ministry of Education the College of Electronic and Information Engineering the Department of Control Science and Engineering Tongji University the Key Laboratory of Advanced Control and Optimization for Chemical Processes of Ministry of Education the School of Information Science and Engineering East China University of Science and Technology

Dear Editor,This letter is concerned with the problem of time-varying formation tracking for heterogeneous multi-agent systems(MASs) under directed switching networks. For this purpose, our first step is to present so... 详细信息

关键词： Switches Topology Observers Formation control Event detection Switched systems Multi-agent systems control theory Autonomous systems Stability

来源：评论

学校读者我要写书评

暂无评论

High concentration of Ti^(3+)in C-TiO_(x)nanosheets boosting efficient photodegradation

引用

Science China(Technological Sciences) 2025年第3期68卷 156-166页

作者： Chongbei WU Xuan LI Haibin WANG Jiaxin TANG Shuai WEI Yuanyuan WU Aobing WANG Jizhou JIANG Hebei Key Laboratory of Man-machine Environmental Thermal Control Technology and Equipment Hebei Vocational University of Technology and EngineeringXingtai054000China School of Materials Science and Engineering Key Laboratory of Green Chemical Engineering Process of Ministry of EducationEngineering Research Center of Phosphorus Resources Development and Utilization of Ministry of EducationWuhan Institute of TechnologyWuhan430205China

Semiconductor photocatalysis holds significant promise for addressing dye-pollution in ***,the efficiency of photocatalytic water purification is constrained by the weak light absorption capacity and low active site distribution of *** a bottom-up approach,carbon-doped TiO_(x)(C-TiO_(x))nanosheets with high concentrations of Ti^(3+)active sites were fabricated by etching the Al element in Ti_(3)Ai C_(2)with H_(2)O_(2).Experimental evidence demonstrates that the optimal C-TiO_(x)nanosheets exhibit high activity for the photocatalytic degradation of methylene blue,achieving a degradation rate of 100%within 50 *** introduction of carbon into the C-TiO_(x)nanosheets induces a red shift in the absorption edge,boosting the migration of photo-generated charge ***,there is a significant correlation between the concentration of Ti^(3+)active sites and the density of oxygen vacancies in the C-TiO_(x)nanosheets,which synergistically influence the photocatalytic degradation performance of MB dye wastewater.

关键词： bottom-up strategies C-TiO_(x)nanosheets high-concentrations Ti^(3+) photocatalytic degradation

来源：评论

学校读者我要写书评

暂无评论

Enhancement of weathered crust elution-deposited rare earth ores leaching process with PQ-10 addition

引用

Journal of Rare Earths 2025年第1期43卷 180-190,I0007页

作者： Aoyang Sha Huifang Yang Zhengyan He Zhigao Xu Chenjie Wu Ming Wu Ru'an Chi Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education Key Laboratory of Resources Conversion and Pollution Control of the State Ethnic Affairs Commission&Hubei Key Laboratory of Catalysis and Materials ScienceCollege of Resources and Environmental ScienceSouth-Central Minzu UniversityWuhan430074China Key Laboratory for Green Chemical Process of Ministry of Education School of Resources&Safety EngineeringWuhan Institute of TechnologyWuhan 430073China

To solve the problems of the long development period,low mass transfer efficiency and high impurity conte nt in the in-situ leaching process of weathe red crust elution-deposited rare earth ores(WCE-DREO),cationic hydroxyethyl cellulose(PQ-10)was composited with conventional leaching agent ammonium sulfate((NH_(4))_(2)SO_(4))to form a novel composite leaching *** effects of PQ-10 concentration,leaching temperature and leaching flow rate of the composite leaching agent on the leaching kinetics and mass transfer processes of rare earth(RE)and aluminum(Al)were *** to the single leaching agent(NH_(4))_(2)SO_(4),the composite leaching agent(2 wt%(NH_(4))_(2)SO_(4)+0.02 wt%PQ-10)can reduce the RE leaching equilibrium time from 465 to 130 min and increase the RE leaching efficiency and decrease the Al leaching *** also facilitates the leaching process of WCE-DREO by increasing the peak concentrations of RE and Al,reducing the theoretical tower plate height(HETP)and improving the leaching mass transfer *** is indicated that PQ-10 can promote the leaching of *** leaching process of the composite leaching system conforms to the diffusion kinetic control *** the PQ-10 concentration is in the range of 0.005 wt%-0.020 wt%,the reaction orders of RE and Al are 0.73 and 0.54,respectively,which shows a positive effect on the leaching velocity;when the PQ-10 concentration is in the range of 0.030 wt%-0.060 wt%,the reaction orders of RE and Al are-1.16 and-0.75,respectively,which show a negative effect on the leaching *** the range of 10-50℃,the apparent activation energies of RE and Al are 15.02 and 17.31 kJ/mol,respectively,and the higher the leaching temperature,the smaller the HETP and the higher the leaching velocity and mass transfer *** increase in leaching flow rate contributes to the increase in the longitudinal diffusion velocity of the leaching agent within WCE-DREO,causing a shorter time for RE

关键词： Cationic hydroxyethyl cellulose Weathered crust elution-deposited rare earthores Leaching Novel compositeagent

来源：评论

学校读者我要写书评

暂无评论

Distributed asynchronous double accelerated optimization for ethylene plant considering delays

引用

Chinese Journal of chemical Engineering 2025年 78卷 245-250页

作者： Wang, Ting Li, Zhongmei Du, Wenli State Key Laboratory of Industrial Control Technology East China University of Science and Technology Shanghai200237 China Key Laboratory of Smart Manufacturing in Energy Chemical Process Ministry of Education East China University of Science and Technology Shanghai200237 China

Considering the complexity of plant-wide optimization for large-scale industries, a distributed optimization framework to solve the profit optimization problem in ethylene whole process is proposed. To tackle the delays arising from the residence time for materials passing through production units during the process with guaranteed constraint satisfaction, an asynchronous distributed parameter projection algorithm with gradient tracking method is introduced. Besides, the heavy ball momentum and Nesterov momentum are incorporated into the proposed algorithm in order to achieve double acceleration properties. The experimental results show that the proposed asynchronous algorithm can achieve a faster convergence compared with the synchronous algorithm. © 2024 chemical Industry and Engineering Society of China (CIESC) and chemical Industry Press Co., Ltd. (CIP)

关键词： optimization algorithms

来源：评论

学校读者我要写书评

暂无评论

Observer-based stabilization for discrete nonlinear semi-Markov jump singularly perturbed models with mode-switching delay

引用

Science China(Information Sciences) 2025年第4期68卷 389-390页

作者： Wenhai QI Runkun LI Ju H.PARK Zheng-Guang WU Huaicheng YAN School of Engineering Qufu Normal University Department of Electrical Engineering Yeungnam University Institute of Cyber-Systems and Control Zhejiang University Key Laboratory of Smart Manufacturing in Energy Chemical Process of Ministry of Education East China University of Science and Technology

Semi-Markov jump systems(S-MJMs) not only characterize hybrid systems but also address the limitations of Markov jump systems(MJMs) [1–3]. Due to their ability to exhibit multi-time-scale features, singularly perturbed models(SPMs) effectively model practical systems influenced by multiple time-scale phenomena [4]. In this study, the observer-based output feedback controller is asynchronous with the original system due to the time delay in the controller mode switching. A nonlinear plant with singularly perturbed parameters(SPPs) is represented using an interval type-2(IT2) fuzzy model [5].

关键词：

来源：评论

学校读者我要写书评

暂无评论

Formation control and path planning of multi-robot systems via large language models

引用

Science China(Information Sciences) 2025年第5期68卷 72-88页

作者： Dong XUE Xuanjie ZHOU Ming WANG Fangzhou LIU Key Laboratory of Smart Manufacturing in Energy Chemical Process Ministry of EducationEast China University of Science and Technology Research Institute of Intelligent Control and Systems School of Astronautics Harbin Institute of Technology

Existing path planning and coordination control methods for multi-robot systems(MRS) typically rely on predefined rules and rudimentary algorithms. However, these methods often struggle to adapt flexibly to complex environments and to adjust motion targets appropriately. To address this challenge, this study presents a large language model(LLM)-assisted framework. By integrating textual descriptions of complex motion constraints, robot information, and local environmental data as inputs, LLMs generate motion objectives and translate them into executable control commands for the robots, thereby achieving coordinated control and path planning. This framework facilitates the generation, maintenance, and reshaping of formations in MRSs during path planning, applicable to both obstacle-free and obstacle-avoidance environments. Simulation results demonstrate that LLM-based control strategies enhance the autonomy, adaptability, flexibility, and robustness of MRS by processing complex information, making intelligent decisions, adapting to environmental changes, and handling disturbances and uncertainties.

关键词： multi-robot systems formation control path planning obstacle avoidance large language models

来源：评论

学校读者我要写书评

暂无评论

Finite-Time Consensus of Second-Order Multiagent Systems with Input Saturation via Hybrid Sliding-Mode control

引用

IEEE Transactions on Automation Science and Engineering 2025年 22卷 14623-14632页

作者： Jiang, Xiaowei Jiao, Ranran Li, Bo Zhang, Xianhe Yan, Huaicheng China University of Geosciences School of Automation Hubei Key Laboratory of Advanced Control and Intelligent Automation of Complex Systems Engineering Research Center of Intelligent Geodetection Technology Ministry of Education Wuhan430074 China Ministry of Education Key Laboratory of System Control and Information Processing Shanghai200240 China Anhui University of Finance and Economics School of Finance Bengbu233030 China Hubei Normal University School of Electrical Engineering and Automation Huangshi435002 China East China University of Science and Technology Key Laboratory of Smart Manufacturing in Energy Chemical Process Ministry of Education Shanghai200237 China

This paper addresses the finite-time consensus (FTC) issue for second-order multi-agent systems (MASs) with nonlinear disturbances. To tackle the challenges posed by increasingly complex communication environments, an innovative integral sliding-mode surface is designed using event-triggered control. Furthermore, the study explores communication constraints between the leader and followers, employing impulsive control to facilitate communication only at specific intervals. A novel hybrid integral sliding-mode control protocol is advanced for the second-order MASs, which effectively eliminates the "Zeno phenomenon" and notably reduces both communication frequency and energy consumption, thereby enhancing overall communication efficiency. Ultimately, the efficacy of the put forward protocol is verified through simulation examples including comparison experiment. © 2004-2012 IEEE.

关键词： Protocols Sliding mode control Event detection Multi-agent systems Costs Training Topology Switches Sufficient conditions Stability analysis

来源：评论

学校读者我要写书评

暂无评论

A Kalman and Fading Memory Co-Filter for Uncertain Systems Based on Self-Perception Mechanism

引用

IEEE Transactions on Automatic control 2025年

作者： Luan, Xiaoli Xue, Wei Zhao, Shunyi Liu, Fei Jiangnan University Key Laboratory of Advanced Process Control for Light Industry Ministry of Education Wuxi214122 China

A co-filter by collaboration of Kalman filter and fading memory filter improves the filter estimation performance for uncertain systems. Specifically, the influence function is utilized to quantify the influence of uncertainty on estimation performance, forming the self-perception mechanism. Then, the co-filter takes the Kalman filter as the robust lower bound and the fading memory filter as the robust upper bound and adjusts the robust parameters based on the self-perception mechanism to form an adaptive robust filter. The advantage of the proposed co-filter is that it resists uncertainty while reducing performance loss. The performance of the adaptive robust filter is analyzed theoretically using the Riccati equation and the Lyapunov equation. Furthermore, one numerical example simulation, one practice-oriented 1-DOF torsion simulation, and one water tank experiment are given as an illustration of the efficiency of the proposed adaptive robust filter. © 1963-2012 IEEE.

关键词： Kalman filters

来源：评论

学校读者我要写书评

暂无评论

Novel titanium vanadate with superior Na^(+) transport kinetics for rapid charging and low-temperature sodium ion batteries

引用

Green Energy & Environment 2025年第2期10卷 374-381页

作者： Dan Lv Liehao Wei Cheng Wang Mingyue Wang Zhongchao Bai Yameng Fan Dongdong Wang Nana Wang Jian Yang Key Laboratory of Advanced Ceramics and Machining Technology(Ministry of Education) School of Materials Science and EngineeringTianjin UniversityTianjin300072China Key Laboratory of Colloid and Interface Chemistry Ministry of EducationSchool of Chemistry and Chemical EngineeringShandong UniversityJinan250100China Tianjin Key Lab of Indoor Air Environmental Quality Control School of Environmental Science and TechnologyTianjin UniversityTianjin300072China Institute for Superconducting and Electronic Materials University of WollongongWollongongAustralia Institute of Energy Materials Science(IEMS) University of Shanghai for Science and Technology516 Jungong RoadShanghai200093China

Sodium-ion batteries(SIBs)hold great promise for large-scale energy storage in the post-lithium-ion battery era due to their high rate performance and long lifespan,although their sluggish Na^(+) transformation kinetics still require *** by the excellent electrochemical performance of titanium-based anode materials,here,we present a novel titanium vanadate@carbon(TVO@C)material as anode for *** TVO@C material is synthesized via a facile coprecipitation method,with the following annealing process in an acetylene *** opened ion channel and the oxygen vacancies within TVO@C facilitate the diffusion of Na^(+) ions,reducing their diffusion ***,an ultrahigh rate of 100 A g^(-1)and long life of 10,000 cycles have been ***,the TVO@C electrode exhibits stable performance,not only at room temperature,but also at temperatures as low as 20 *** TVO@CjjNa_(3)V_(2)(PO_(4))_(3)@C full cells have also achieved stable discharge/charge for 500 *** is believed that this strategy provides new insight into the development of advanced electrodes and provides a new opportunity for constructing novel high rate electrodes.

关键词： Anode High rate Titanium vanadate Sodium ion batteries

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：