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Activating lithium storage in 2D CaSi_(2) anode via enhancing pseudocapacitive properties with oxygen modification engineering

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Nano Research 2025年第4期18卷 199-206页

作者： Yongzheng Zhang Lu Sun Kailin Yang Youwang Ye Liang Zhan Qi Wei Jianan Gu Institute of Energy Power Innovation North China Electric Power UniversityBeijing 100096China State Key Laboratory of Chemical Engineering East China University of Science and TechnologyShanghai 200237China State Key Laboratory of Mesoscience and Engineering Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China Aviation Key Laboratory of Science and Technology on Advanced Surface Engineering AVIC Manufacturing Technology InstituteBeijing 100024China

Silicon(Si)has emerged as a promising anode material for lithium-ion batteries(LIBs)due to its extremely high theoretical capacity of 4200 mAh·g^(-1).However,its practical application is limited by several critical challenges,including severe volume expansion and poor electrical ***,we employ a two-dimensional(2D)oxygen modification engineering approach to fabricate 2D oxygen-functionalized CaSi_(2)(CaSi_(2)O_(x))*** the preparation of 2D CaSi_(2) layers,O atoms are gradually incorporated onto their *** resulting 2D CaSi_(2)O_(x) layers have a thickness of 3-5 nm,closely matching the theoretical thickness of 6-10 *** used as lithium anodes,the 2D CaSi_(2)O_(x) layers exhibit exceptional electrochemical performance,maintaining stability over 3000 cycles at an ultrahigh current density of 30 A·g^(-1).By tailoring the surface properties,their pseudocapacitive charge storage mechanism is significantly enhanced,effectively overcoming the intrinsic limitations of traditional Si *** study highlights the promise of 2D surface engineering in the development of advanced materials for next-generation LIBs.

关键词： two-dimensional(2D)CaSi_(2)O_(x) Si anode volume change pseudocapacitive surface modification lithium storage

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Enhanced room temperature CO2 photoreduction on gas-solid interfaces using nanocrystals integrated with ZIF-8 wrapping design

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材料科学技术（英文版） 2025年第6期209卷 55-63页

作者： Xiaoxiong Hou Zhuangzhuang Ma Zhilei Zhang Xiaotong Gao Hongqiang Wang Lichao Jia Key Laboratory of Applied Surface and Colloid Chemistry Shaanxi Key Laboratory for Advanced Energy DevicesShaanxi Engineering Lab for Advanced Energy TechnologySchool of Materials Science and EngineeringNational Ministry of EducationShaanxi Normal UniversityXi'an 710119China Beijing National Laboratory for Molecular Sciences Key Laboratory of Organic SolidsInstitute of ChemistryChinese Academy of SciencesBeijing 100190China University of the Chinese Academy of Sciences Beijing 100049China State Key Laboratory of Solidification Processing Center for Nano Energy MaterialsSchool of Materials Science and EngineeringNorthwestern Polytechnical University and Shaanxi Joint Laboratory of GrapheneXi'an 710072China

Composites derived from metal-organic frameworks(MOFs)show promise as catalysts for the photocat-alytic reduction of ***,their potential is hindered by constraints such as limited light absorp-tion and sluggish electron transfer and separation,impacting the overall efficiency of the photocatalytic *** this study,TiO2 nanocrystals,modified with Ptx+,underwent laser etching were encapsulated within the traditional MOF-ZIF-8 *** enhanced the adsorption capabilities for CO2 reactants and solar light,while also facilitating directed electron transfer and the separation of photogenerated *** finely-tuned catalyst demonstrates impressive CH4 selectivity at 9.5％,with yields of 250.24 μmol g-1 h-1 for CO and 25.43 μmol g-1 h-1 for CH4,utilizing water as a hole trap and H+*** study demonstrates the viability of achieving characteristics related to the separation of photogen-erated charges in TiO2 nanocrystals through laser etching and MOF composite *** offers novel perspectives for designing MOF-based catalysts with enhanced performance in artificial photosynthesis.

关键词： CO2 photoreduction Nanocrystals TiO2 ZIF-8 Wrapping structure

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A donor-acceptor conjugated bipolar polymer with multielectron redox sites for long-cycle-life and high-rate aqueous zinc dual-ion batteries

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Journal of energy Chemistry 2025年第3期102卷 144-150页

作者： Lian-Wei Luo Siteng Zhu Wen Yan Ma Dan Li Chong Zhang Jia-Xing Jiang Key Laboratory of Optoelectronic Chemical Materials and Devices(Ministry of Education) School of Optoelectronic Materials&TechnologyJianghan UniversityWuhan 430056HubeiChina Key Laboratory for Macromolecular Science of Shaanxi Province Shaanxi Engineering Laboratory for Advanced Energy TechnologySchool of Materials Science and EngineeringShaanxi Normal UniversityXi'an 710062ShaanxiChina

Aqueous zinc-ion batteries(AZIBs)have hugely latent advantages in large-scale energy storage due to its innate safety,reasonable price,and ***,most AZIB cathode materials suffer from short cycling life and poor rate ***,a bipolar donor-acceptor(D-A)conjugated microporous polymer(PTZ-BDTB),consisting of electron-withdrawing benzo[1,2-b:4,5-b']dithiophene-4,8-dio ne(BDTB)units and electron-donating phenothiazine(PTZ)units,is developed as the cathode material of aqueous zinc dual-ion batteries(AZDIBs).The D-A type structure design could reduce the band gap,thus promoting electron transfer in the polymer ***,the PTZ-BDTB cathode in a30 mol/kg(m)ZnCl_(2)water-in-salt electrolyte exhibits a high reversible capacity of 202 mA h g^(-1)at0.05 A g^(-1)with excellent rate performance(109 mA h g^(-1)at 15 A g^(-1)),which is far superior to its counterpart polymers PPTZ and ***,PTZ-BDTB shows ultra-stable cycle performance with capacity retention ratios of 76.2%after 460 cycles at 0.05 A g^(-1)and 96%after 27000 cycles at 5 A g^(-1).PTZBDTB also exhibits a low self-discharge ability with capacity retention about 76.4%after resting the battery for 28 *** results demonstrate that D-A type structural design is a promising strategy for constructing high performance cathode materials for AZDIBs.

关键词： Conjugated microporous polymer Donor-acceptor structure Bipolar organic cathode material Aqueous zinc dual-ion batteries

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Methanolysis of ammonia borane catalyzed by NiO-CuO heterostructured nanosheets:cooperation of visible light and oxygen vacancy

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Rare Metals 2025年第1期44卷 389-403页

作者： You-Xiang Shao Yuan-Zhong Li Xue-Qi Lian Xiao-Ting Che Qian-Yi Li Yu-Fa Feng Hui-Ze Wang Jin-Yun Liao Quan-Bing Liu Hao Li School of Chemistry and Materials Engineering Huizhou UniversityHuizhou 516007China Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology Changzhou UniversityChangzhou 213164China Guangzhou Key Laboratory of Clean Transportation Energy Chemistry School of Chemical Engineering and Light IndustryGuangdong University of TechnologyGuangzhou 510006China

Developing cost-effective and high-activity catalysts for the methanolysis of ammonia borane(AB)has attracted great attention in the field of hydrogen energy *** the modification of the electronic structure of the catalysts,external factors such as visible light irradiation can improve the efficiency of hydrogen production as *** the present study,a Z-scheme heterostructured VO-Cu_(0.5)Ni_(0.5)O catalysts were constructed by introducing a plenteous phase interface and oxygen vacancy(Vo).The catalytic activity of as-prepared VO-Cu_(0.5)Ni_(0.5)O toward AB methanolysis has been improved dramatically with the assistance of visible light *** turnover frequency(TOF)under visible light irradiation was measured to be 29_(mol)H_(2)·mol_(cat.)^(-1)·min^(-1),which is 1.4 times larger than the TOF in the absence of visible *** characterization experiments and density functional theory(DFT)calculations were conducted to unveil the causation of enhanced catalytic *** results demonstrated that the enhancement of the catalytic activity of VO-Cu_(0.5)Ni_(0.5)O originated from the electronic structure modification induced by the formation of heterojunctions,the introduction of oxygen vacancies,and the assistance of visible light *** formation of heterojunction and the introduction of oxygen vacancies provoked the upshift of the d-band center;while the visible light irradiation induced the photogenerated electrons to transfer from Cu to Ni sites at the *** electron structure modulation is beneficial for the construction of abundant active sites,thereby enhancing the adsorption of methanol on the Ni sites,which is considered as the rate-determine step for the methanolysis of *** strong interaction between Ni and O weakened the O-H bond of methanol,accelerating the methanolysis of *** results demonstrate the utilization of combined heterojunction,oxygen vacancy,and visible light to explore highly active

关键词： Ammonia borane Methanolysis Heterojunction Oxygen vacancy Density functional theory(DFT)calculation

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Al-F co-doping towards enhanced electrolyte-electrodes interface properties for halide and sulfide solid electrolytes

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Chinese Chemical Letters 2025年第1期36卷 610-617页

作者： Han Yan Jingming Yao Zhangran Ye Qiaoquan Lin Ziqi Zhang Shulin Li Dawei Song Zhenyu Wang Chuang Yu Long Zhang College of Physics and Energy Fujian Normal UniversityFuzhou 350117China Clean Nano Energy Center State Key Laboratory of Metastable Materials Science and TechnologyYanshan UniversityQinhuangdao 066004China Tianjin Key Laboratory for Photoelectric Materials and Devices School of Materials Science and EngineeringTianjin University of TechnologyTianjin 300384China Guilin Electrical Equipment Scientific Research Institute Co. Ltd.Guilin 541004China State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan 430000China

All-solid-state Li batteries(ASSLBs)using solid electrolytes(SEs)have gained significant attention in recent years considering the safety issue and their high energy *** these advantages,the commercialization of ASSLBs still faces challenges regarding the electrolyte/electrodes interfaces and growth of Li *** doping is an effective and direct method to enhance the performance of ***,we report an Al-F co-doping strategy to improve the overall properties including ion conductivity,high voltage stability,and cathode and anode ***,the Al-F co-doping enables the formation of a thin Li-Al alloy layer and fluoride interphases,thereby constructing a relatively stable interface and promoting uniform Li *** similar merits of Al-F co-doping are also revealed in the Li-argyrodite *** assembled with these optimized electrolytes gain good electrochemical performance,demonstrating the universality of Al-F co-doping towards advanced SEs.

关键词： Solid electrolytes Li halides Li_(2)ZrCl_(6) Li argyrodites Fluorine doping

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Structure-phase transformation of bismuth oxide to BiOCl/Bi_(24)O_(31)Cl_(10)shoulder-by-shoulder heterojunctions for efficient photocatalytic removal of antibiotic

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Journal of Environmental Sciences 2025年第3期149卷 149-163页

作者： Man Yang Zhenzhen Shi Shaodong Sun Bian Yang Jie Cui Jianing Li Daqin Yun Nian Lei Engineering Research Center of Conducting Materials and Composite Technology Ministry of EducationShaanxi Engineering Research Center of Metal-Based Heterogeneous Materials and Advanced Manufacturing TechnologyShaanxi Province Key Laboratory for Electrical Materials and Infiltration TechnologySchool of Materials Science and EngineeringXi’an University of TechnologyXi’an 710048China College of Energy Xiamen UniversityXiamen 361005China Beijing Key Laboratory of Ionic Liquids Clean Process Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China

Developing heterojunction photocatalyst with well-matched interfaces andmultiple charge transfer paths is vital to boost carrier separation efficiency for photocatalytic antibiotics removal,but still remains a great *** present work,a new strategy of chloride anion intercalation in Bi_(2)O_(3)via one-pot hydrothermal process is *** as-prepared Ta-BiOCl/Bi_(24)O_(31)Cl_(10)(TBB)heterojunctions are featured with Ta-Bi_(24)O_(31)Cl_(10)and Ta-BiOCl lined shoulder-by-shouleder via semi-coherent *** this TBB heterojunctions,the well-matched semi-coherent interfaces and shoulder-by-shoulder structures provide fast electron transfer andmultiple transfer paths,respectively,leading to enhanced visible light response and improved photogenerated charge ***,a type-II heterojunction for photocharge separation has been obtained,in which photogenerated electrons are drove from the CB(conduction band)of Ta-Bi_(24)O_(31)Cl_(10)to the both of bilateral empty CB of Ta-BiOCl and gathered on the CB of Ta-BiOCl,while the photogenerated holes are left on the VB(valence band)of Ta-Bi_(24)O_(31)Cl_(10),effectively hindering the recombination of photogenerated electron-hole ***,the separated electrons can effectively activate dissolved oxygen for the generation of reactive oxygen species(·O_(2)^(−)).Such TBB heterojunctions exhibit remarkably superior photocatalytic degradation activity for tetracycline hydrochloride(TCH)solution to Bi_(2)O_(3),Ta-BiOCl and Ta-Bi_(24)O_(31)Cl_(10).This work not only proposes a Ta-BiOCl/Bi_(24)O_(31)Cl_(10)shoulder-by-shoulder micro-ribbon architectures with semi-coherent interfaces and successive type-Ⅱheterojunction for highly efficient photocatalytic activity,but offers a new insight into the design of highly efficient heterojunction through phasestructure synergistic transformation strategy.

关键词： Heterojunction Bismuth oxide Charge separation/transfer Photocatalytic degradation Catalytic mechanism

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Adsorption removal of mercury from flue gas by metal selenide:A review

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Journal of Environmental Sciences 2025年第2期148卷 420-436页

作者： Yang Zheng Guoliang Li Yi Xing Wenqing Xu Tao Yue School of Energy and Environmental Engineering University of Science and Technology BeijingBeijing 100083China State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China CAS Key Laboratory of Green Process and Engineering Institute of Process EngineeringInnovation Academy for Green ManufactureChinese Academy of SciencesBeijing 100190China

Mercury(Hg)pollution has been a global concern in recent decades,posing a significant threat to entire ecosystems and human health due to its cumulative toxicity,persistence,and transport in the *** intense interaction between mercury and selenium has opened up a new field for studying mercury removal from industrial flue gas *** the advantages of good Hg^(0) capture performance and lowsecondary pollution of the mineral selenium compounds,the most noteworthy is the relatively low regeneration temperature,allowing adsorbent regeneration with low energy consumption,thus reducing the utilization cost and enabling recovery of mercury *** paper reviews the recent progress of mineral selenium compounds in flue gas mercury removal,introduces in detail the different types ofmineral selenium compounds studied in the field ofmercury removal,reviews the adsorption performance of various mineral selenium compounds adsorbents on mercury and the influence of flue gas components,such as reaction temperature,air velocity,and other factors,and summarizes the adsorption mechanism of different fugitive forms of selenium *** on the current research progress,future studies should focus on the economic performance and the performance of different carriers and sizes of adsorbents for the removal of Hg^(0) and the correlation between the gas-particle flow characteristics and gas phase mass transfer with the performance of Hg^(0) removal in practical industrial *** addition,it remains a challenge to distinguish the oxidation and adsorption of Hg^(0) quantitatively.

关键词： Non-conventional pollutants Adsorbents Metal selenides Flue gas Mercury removal

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Enhancing Flexibility of Virtual Power Plants Considering Reconfiguration of District Heating Network

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CSEE Journal of Power and energy Systems 2025年第2期11卷 826-837页

作者： Peinan Fan Yixun Xue Haotian Zhao Xinyue Chang Jia Su Ke Wang Hongbin Sun College of Electrical and Power Engineering Taiyuan University of TechnologyEnergy Internet Key Laboratory of Shanxi Provinceand also with Key Laboratory of Cleaner Intelligent Control on Coal&ElectricityMinistry of EducationTaiyuan 030024China Department of Electrical Engineering Tsinghua UniversityBeijing 100084China

Large-scale renewable energy penetration desires higher flexibility in the power *** heat and power virtual power plants(CUP-VPPs)provide an economic-effective method to improve the power system flexibility by aggregating the distributed resources of an electric-thermal coupling *** topology can be optimally reconfigured in a power distribution system by operating tie and segment ***,the heat flow profile can be redistributed in the district heating system(DHS)with valve switching and provide notable flexibility for CHP-VPPs *** address this issue,an aggregation model for the CHP-VPP is proposed to trade in typical day-ahead energy and reserve electricity markets,which is formulated as an adjustable robust optimization(ARO)problem to assure the realizability of all dispatch *** energy flow model is introduced in DHS formulation to make the model *** to the binary switching variables in the second stage of the proposed ARO problem,classical Karush-Kuhn-Tucker-based algorithms cannot be adopted directly and a nested column-and-constraint generation solution strategy is *** studies based on an actual CHP-VPP certify the validity of the proposed model and algorithm.

关键词： Adjustable robust optimization DHS reconfiguration electric-thermal coupling system virtual power plants

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Enhancing solid-state lithium metal battery performance via indium-based modification of electrolytes and lithium metal surfaces:mechanistic insights and optimization

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Science China Chemistry 2025年第3期68卷 1144-1158页

作者： Zhongkai Wu Chen Liu Ziling Jiang Lin Li Siwu Li Chaochao Wei Qiyue Luo Xia Chen Long Zhang Shijie Cheng Chuang Yu State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan 430074China School of Chemistry and Chemical Engineering Huazhong University of Science and TechnologyWuhan 430074China Interdisciplinary Research Center of Smart Sensors Academy of Advanced Interdisciplinary ResearchXidian UniversityXi’an 710126China College of Physics and Energy Fujian Normal UniversityFuzhou 350117China

Argyrodite-based solid-state lithium metal batteries exhibit significant potential as next-generation energy storage ***,their practical applications are constrained by the intrinsic poor stability of argyrodite towards Li metal and exposure to air/***,an indium-involved modification strategy is employed to address these *** optimized doping yields a high Li-ion conductivity of 7.5 mS cm^(-1)for Li_(5.54)In_(0.02)PS_(4.47)O_(0.03)Cl_(1.5)electrolyte,accompanied by enhanced endurance against air/moisture and bare Li *** retains 92.0%of its original conductivity after exposure to air at a low dew point of-60℃in dry ***,a composite layer comprising Li-In alloy and Li F phases is generated on the surface of lithium metal anode via the reaction between InF_(3)and molten *** layer effectively mitigates Li dendrite growth by creating a physical barrier from the robust LiF phase,while the Li-In alloy induces uniform Li-ion deposition and accelerates Li transport dynamics across the interphase between the solid electrolyte/Li ***,the In-doped electrolyte facilitates the in-situ generation of Li-In alloy within its voids,reducing local current density and further inhibiting lithium dendrite ***,the combination of the Li_(5.54)In_(0.02)PS_(4.47)O_(0.03)Cl_(1.5)electrolyte and the InF_(3)@Li anode provides exceptional electrochemical performances in both symmetric cells and solid-state lithium metal batteries across different operating ***,the LiNbO_(3)@LiNi_(0.7)Co_(0.2)Mn_(0.1)O_(2)/Li_(5.54)In_(0.02)PS_(4.47)O_(0.03)Cl_(1.5)/InF_(3)@Li cell delivers a high discharge capacity of 167.8 mAh g^(-1)at 0.5 C under 25℃and retains 80.0%of its initial value after 400 *** work offers a viable strategy for designing functional interfaces with enhanced stability for sulfide-based solid-state lithium batteries.

关键词： Li_(5.5)PS_(4.5)Cl_(1.5)solid electrolyte In_(2)O_(3)dual-doping InF_(3)surface-modification chemical/electrochemical stability electrochemical performance

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Deliberate design of MOF-based pre-catalyst rationalizing the structural reconstruction toward efficient oxygen evolution reaction

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Science China Chemistry 2025年第6期68卷 2388-2398页

作者： Yunhui Chen Meng Tian Zhongqi Zhang Guangzhao Wang Yan Guo Jing Wu Dawei Qi Zhenhua Yan Xiangyu Liu Xi Liu State Key Laboratory of High-efficiency Coal Utilization and Green Chemical Engineering College of Chemistry and Chemical EngineeringNingxia University Key Laboratory of Extraordinary Bond Engineering and Advanced Materials Technology of Chongqing School of Electronic Information Engineering Yangtze Normal University Frontiers Science Center for New Organic Matter Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education) State Key Laboratory of Advanced Chemical Power Sources College of Chemistry Nankai University School of Chemistry and Chemical Engineering In-situ Center for Physical Sciences Frontiers Science Center for Transformative MoleculesShanghai Jiao Tong University

Metal-organic frameworks（MOFs）, that have emerged as promising electrocatalysts in oxygen evolution reaction（OER）,usually undergo structural reconstruction to form metal hydroxides as active sites. However, it remains a great challenge to design and synthesize ideal MOF-based pre-catalysts for properly cognizing and utilizing the reconstruction process toward efficient OER activity. Herein, the well-defined MOF-808 is post-modified by 2-hydroxyphosphonoacetic acid（HPAA） to form a micro-adsorber that enables to capture of metal ions effectively. Fe3+and Ni2+ions are synergistically anchored into the microadsorber, developing a Fe/Ni-containing pre-catalyst that can be dynamically electrooxidized to be an active and stable dual-site electrocatalyst denoted by R-MOF-HPAA@Fe Ni with abundant metal sites. As a result, R-MOF-HPAA@Fe Ni exhibits an excellent OER performance with a low overpotential of 272 m V and Tafel slope of 35.9 m V dec-1, as well as long-term stability over 300 h at 10 m A cm-2. Experiments and theoretical calculations suggest the resulting catalyst mainly follows a lattice oxygen mechanism（LOM） of dual-metal-site mechanism（DMSM）. Owing to the chelating role of HPAA, the post-synthesized MOFHPAA behaves as a trap to uniformly and firmly adhere Fe3+and Ni2+ions, leading to a functionalized MOF-based pre-catalyst which can be structurally evolved into atomic level-distributed OER electrocatalysts.

关键词： metal-organic frameworks functionalization electrochemical reconstruction electrocatalyst oxygen evolution reaction

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