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Enhanced ethanol sensing performance of N-doped ZnO derived from ZIF-8

Chinese Chemical Letters 2023年第2期34卷 317-321页

作者： Huifen Fu Ziyue Feng Shan-Shan Liu Peng Wang Chen Zhao Chong-Chen Wang Beijing Key Laboratory of Functional Materials for Building Structure and Environment Remediation/Beijing Energy Conservation and Sustainable Urban and Rural Development Provincial and Ministry Co-construction Collaboration Innovation Center Beijing University of Civil Engineering and ArchitectureBeijing 100044China

Metal oxides derived from metal-organic framework(MOF) have attracted considerable attention due to its excellent performance and unique structure. Doping is considered as an effective method to improve gas-sensing performance. However, nonmetal doped metal oxides derived from MOF as gas-sensing materials have not been reported. Within this work, N atoms were successfully doped into the lattice of ZnO nanoparticles using ZIF-8 as a self-sacrificial template through a thermal treatment process with the assistant of urea. The obtained N-ZnO exhibited competitive ethanol-sensing performance, in which the response value of N-ZnO-5 to 100 ppm ethanol reached 115 at 190 ℃ with a satisfactory selectivity. It was found that the N-doping in ZnO facilitated the formation of oxygen vacancy that promoted the generation of adsorbed oxygen species to achieve the enhanced gas-sensing performance. Besides, the larger specific surface area resulting from the size reduction during the urea-assisted pyrolysis process can also be responsible for the improving of the ethanol-sensing performance.

关键词： ZIF-8 N-doped ZnO Gas sensor Oxygen vacancy Urea-assisted pyrolysis

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Comparison of life cycle assessment of large-scale biogas projects with different raw materials in China

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International Journal of agricultural and Biological engineering 2024年第2期17卷 268-279页

作者： Jiazheng Sun Youpei Qu Xiaoyi Lyu Xinjie Ding Xinying Miao Mukesh Kumar Awasthi Jingbo Qu School of Energy and Environment City University of Hong KongHong Kong 999077China College of Engineering Northeast Agricultural UniversityHarbin 150030China Key Laboratory of Agricultural Renewable Resources Utilization Technology and Equipment in Cold Areas of Heilongjiang Province Harbin 150030China College of Natural Resources and Environment Northwest A&F UniversityYangling 712100Shaanxi China

The anaerobic digestion(AD)disposal of stover and cattle manure is of great significance to the development of low-carbon economy and green energy in China,but it will also have an impact on the environment,and the degree of influence is different for various raw *** this study,life cycle assessment(LCA)methods were applied to analyze and compare the impact of corn stovers biogas projects(CSBP)and dairy manure biogas projects(DMBP)on the environment during the whole operation *** results of inventory analysis were evaluated by ReCiPe2016 Hierarchy(H)mid-point(problem-oriented)and end-point(destruction-oriented)method,*** results showed that the net energy efficiency of CSBP was higher(763.903 kW·h/FU)and the greenhouse gas(GHG)emission reduction of DMBP was more(5541.418 kg CO_(2)-eq/FU).The anaerobic digestion(AD)units have the greatest environmental impacts,and human carcinogenic toxicity is the largest environmental impact category(1.16-1.43 PE).The key to reducing environmental impact is reducing the input of chemical substances and the waste of electric *** CSBP and DMBP have a favorable impact on ecosystem quality and resources,and CSBP is more beneficial to the environment(-10.297 Pt).Co-digestion is an important measure to reduce the environmental damage from biogas *** research results provide theoretical support for the selection of raw materials for large-scale biogas projects in China,provide technical basis for reducing the impact of actual operation on the environment,and promote the resource utilization of agricultural waste and carbon dioxide emission reduction and sequestration.

关键词： life cycle assessment environmental impact assessment large-scale biogas projects bioenergy carbon dioxide emission reduction

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Effect of PyC Interface Thickness on the Heat-stability of Cansas-ⅡSiC_(f)/SiC Composites

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Journal of Wuhan University of Technology(Materials Science) 2023年第4期38卷 725-734页

作者：韩笑于国强张盛 SHI Jian GAO Xiguang SONG Yingdong WANG Fang Key Laboratory of Aero-Engine Thermal Environment and Structure Ministry of Industry and Information TechnologyCollege of Energy and Power EngineeringNanjing University of Aeronautics and AstronauticsNanjing210016China College of Chemical Engineering Nanjing Forestry UniversityNanjing210016China Jiangsu Province Key Laboratory of Aerospace Power System College of Energy and Power EngineeringNanjing University of Aeronautics and AstronauticsNanjing210016China State Key Laboratory of Mechanics and Control of Mechanical Structures Nanjing University of Aeronautics and AstronauticsNanjing210016China AECC Sichuan Gas Turbine Establishment Chengdu610500China

The effect of the pyrolytic carbon(PyC)interface thickness on the heat-stability of CansasⅡSiC_(f)/SiC composites under Ar up to 1500℃was studied in *** the heat treatment at 1500℃for 50 h,the interface bonding strength of the thin interface(about 200 nm)decreases from 74.4 to 20.1 MPa(73.0%),while that of the thick interface(about 2μm)declines from 7.3 to 3.2 MPa(52.7%).At the same time,the decline fraction of strength of the composites with the thin interface is 12.1%,less than that with the thick interface(42.0%).The fiber strength also decreases after heat treatment,which may be due to the significant growth ofβ-SiC grains and critical *** different heat-stability of the interface with the thin and thick thickness might be related to the inconsistency of the degree of the graphitization of *** with the composites with the thick interface,the composites with the thin interface remained higher tensile strength after heat treatment due to the better interface bonding *** interface with strong bonding strength could protect the fiber by postponing the decomposition of amorphous phases SiC_(x)O_(y) and hindering the generation of fiber defects.

关键词： SiC_(f)/SiC mini-composites heat-stability interface thickness mechanical properties microstructure

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Photocatalytic Cr(Ⅵ)reduction over MIL-88A(Fe)on polyurethane sponge: From batch to continuous-flow operation

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Chinese Chemical Letters 2023年第7期34卷 236-239页

作者： Xiao-Hong Yi Ya Gao Chong-Chen Wang Yu-Hang Li Hong-Yu Chu Peng Wang Beijing Key Laboratory of Functional Materials for Building Structure and Environment Remediation School of Environment and Energy Engineering.Beijing University of Civil Engineering and ArchitectureBeijing 100044China Beijing Energy Conservation&Sustainable Urban and Rural Development Provincial and Ministry Co-construction Collaboration Innovation Center Beijing University of Civil Engineering and ArchitectureBeijing100044China

MIL-88A(Fe)@sponge(MS) was synthesized by a dip-coating method, which displayed efficient photocatalytic Cr(Ⅵ) reduction efficiency under both low power LED UV light and real solar light irradiation. It was observed that MS(0.2 g/L) could remove 100% Cr(Ⅵ)(10 mg/L) by adding 0.4 mmol/L tartaric acid(TA) without adjusting pH(pH 5.05) within 6.0 min and 3.0 min under UV light and real solar light irradiation, respectively. Besides, the photo-induced e-and radicals(O_(2)^(·-) and CO_(2)^(·-)) were found to play the momentous roles in the MS/TA/UVL/Cr(Ⅵ) system by the scavenger experiments and electron spin resonance(ESR) tests. MS was also filled into a fixed-bed reactor to test the possibility of long-term Cr(Ⅵ)reduction operation in TA/UVL system. As expected, the results revealed that MS could still maintain 100% activity up to 60 h. These results demonstrated that MIL-88A(Fe) might be the potentially efficient catalyst for large-scale wastewater treatment in the near future.

关键词： MIL-88A(Fe) Polyurethane sponge Cr(Ⅵ)reduction Tartaric acid Continuous operation

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In situ observation of the phase transformation kinetics of bismuth during shock release

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Chinese Physics B 2024年第4期33卷 586-592页

作者：李江涛王倩男徐亮柳雷张航 Sota Takagi Kouhei Ichiyanagi Ryo Fukaya Shunsuke Nozawa 胡建波 Laboratory for Shock Wave and Detonation Physics Research Institute of Fluid PhysicsChina Academy of Engineering PhysicsMianyang 621900China State Key Laboratory for Environment-Friendly Energy Materials Southwest University of Science and TechnologyMianyang 621010China Japan Society for the Promotion of Science Tokyo102-0083Japan Institute of Materials Structure Science High Energy Accelerator Research OrganizationIbaraki305-8572Japan

A time-resolved x-ray diffraction technique is employed to monitor the structural transformation of laser-shocked *** reveal a retarded transformation from the shock-induced Bi-Ⅴphase to a metastable Bi-Ⅳphase during the shock release,instead of the thermodynamically stable Bi-Ⅲ*** emergence of the metastable Bi-Ⅳphase is understood by the competitive interplay between two transformation pathways towards the Bi-Ⅳand Bi-Ⅲ,*** former is more rapid than the latter because the Bi-Ⅴto B-Ⅳtransformation is driven by interaction between the closest atoms while the Bi-Ⅴto B-Ⅲtransformation requires interaction between the second-closest *** nucleation time for the Bi-Ⅴto Bi-Ⅳtransformation is determined to be 5.1±0.9 ns according to a classical nucleation *** observation demonstrates the importance of the formation of the transient metastable phases,which can change the phase transformation pathway in a dynamic process.

关键词： phase transformation time-resolved x-ray diffraction(XRD) bismuth metastable phase nonequilibrium phase diagram

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Reproductive toxicity of enrofloxacin in Caenorhabditis elegans involves oxidative stress-induced cell apoptosis

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Journal of environmental Sciences 2023年第5期127卷 726-737页

作者： Jiahao Huang Lizi Liao Guowei Wang Zhongkun Du Zhengxing Wu Key Laboratory of Molecular Biophysics Ministry of EducationCollege of Life Science and TechnologyHuazhong University of Science and TechnologyWuhan 430074China School of Environmental Ecology and Biological Engineering Wuhan Institute of TechnologyWuhan 430205China Key Laboratory of Green Chemical Engineering Process of Ministry of Education Wuhan 430205China College of Resources and Environment Shandong Agricultural UniversityTaian 271018China

Fluoroquinolone antibiotics(FQs)that persist and bioaccumulate in the environment have aroused people’s great ***,we studied the adverse effects of FQs in soil animals of Caenorhabditis elegans via food-chronically *** result shows *** exposed to FQs exhibited reproductive toxicity with small-brood size and low-egg *** study the underlying mechanism,we conduct a deep investigation of enrofloxacin(ENR),one of the most frequently detected FQs,on nematodes which is one of commonly used animal indicator of soil *** concentration-effect curves simulated by the Hill model showed that the half effect concentrations(EC50)of ENR were(494.3±272.9)μmol/kg and(107.4±30.9)μmol/kg for the brood size and the hatchability,*** gene expression between the control and the ENR-exposure group enriched with the oxidative stress and cell apoptosis *** results together with the enzyme activity in oxidative stress and the cell corpses suggested that ENR-induced reproductive toxicity was related to germ cell apoptosis under oxidative *** risk quotients of some soil and livestock samples were calculated based on the threshold value of EC10 for the egg hatchability(2.65μmol/kg).The results indicated that there was possible reproductive toxicity on the nematodes in certain agricultural soils for the *** study suggested that chronic exposure to FQs at certain levels in environment would induce reproductive toxicity to the nematodes and might reduce the soil sustainability,alarming the environment risks of antibiotics abuse.

关键词： environmental toxicity Nematodes Chronic exposure Oxidative stress response Germ cell apoptosis

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Optimal red:blue ratio of full spectrum LEDs for hydroponic pakchoi cultivation in plant factory

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International Journal of agricultural and Biological engineering 2022年第3期15卷 72-77页

作者： Yunong Li Nan Liu Fang Ji Dongxian He Key Lab.Agricultural Engineering in Structure and Environment of Ministry of Agriculture and Rural Affairs College of Water Resources and Civil EngineeringChina Agricultural UniversityBeijing 100083China Big Herdsman Machinery Co. LtdQingdao 266108ShandongChina

Pakchoi,a popular leafy vegetable in China,is expected to be planted in plant factories with artificial lighting(PFALs).In order to examine the effects of different red and blue light ratios(R:B ratio)on growth,photosynthesis,and absorption spectrum of plant leaves,and to analyze the energy use efficiency,the pakchoi(Brassica Chinensis ***)was cultivated hydroponically under white LEDs with R:B ratios of 0.9(L0.9)and 1.8(L1.8),white plus red LEDs with R:B ratios of 2.7(L2.7)and 4.0(L4.0)for 40 d,*** results showed that the leaf length and width were significantly greater in the L0.9 treatment than in other treatments,and the dry weight per plant increased by over 33%when R:B ratio decreased from 4.0 to *** net photosynthesis rates of pakchoi leaves ranged from 9.2 to 9.6μmol/(m2·s)under different lighting conditions,which had no significant *** biggest difference in the spectrum absorptance of pakchoi leaves was expressed in green light waveband,and the highest absorption of plant leaves was under L0.9 and L1.8 *** light energy use efficiency(LUE),photon yield(PY),and energy yield(EY)in L0.9 were over 25%higher than that in the other treatments,while there was no significant difference in the electrical energy use efficiency(EUE).In conclusion,an optimal light quality to cultivate pakchoi in PFALs was the white LEDs with R:B ratio of 0.9,and this finding could provide a promising lighting environment to hydroponic pakchoi yield and energy use efficiency.

关键词： pakchoi R:B ratio yield absorption spectrum energy use efficiency

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Threshold friction velocity influenced by soil particle size within the Columbia Plateau, northwestern United States

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Journal of Arid Land 2024年第8期16卷 1147-1162页

作者： MENG Ruibing MENG Zhongju Brenton SHARRATT ZHANG Jianguo CAI Jiale CHEN Xiaoyan College of Desert Control Science and Engineering Inner Mongolia Agricultural UniversityHohhot 010018China Key Laboratory of Aeolian Physics and Desertification Control Engineering from Inner Mongolia Autonomous Region Inner Mongolia Agricultural UniversityHohhot 010018China Key Laboratory of Desert Ecosystem Conservation and Restoration State Forestry and Grassland Administration of ChinaInner Mongolia Agricultural UniversityHohhot 010018China USDA-Agricultural Research Service Washington State UniversityWashington 99164USA College of Resources and Environment Northwest A&F UniversityYangling 712100China Inner Mongolia Autonomous Region Academy of Social Sciences Hohhot 010010China

Wind erosion is a geomorphic process in arid and semi-arid areas and has substantial implications for regional climate and *** the Columbia Plateau of northwestern United States,the emissions from fine particles of loessial soils often contribute to the exceedance of inhalable particulate matter(PM)with an aerodynamic diameter of 10μm or less(PM10)according to the air quality ***,little is known about the threshold friction velocity(TFV)for particles of different sizes that comprise these *** this study,soil samples of two representative soil types(Warden sandy loam and Ritzville silt loam)collected from the Columbia Plateau were sieved to seven particle size fractions,and an experiment was then conducted to determine the relationship between TFV and particle size *** results revealed that soil particle size significantly affected the initiation of soil movement and TFV;TFV ranged 0.304-0.844 and 0.249-0.739 m/s for different particle size fractions of Ritzville silt loam and Warden sandy loam,***10 and total suspended particulates(TSP)emissions from a bed of 63-90μm soil particles were markedly higher for Warden sandy loam than for Ritzville silt *** with the lower TFV of Warden sandy loam,dust emissions from fine particles(<100μm in diameter)of Warden sandy loam thus may be a main contributor to dust in the region's atmosphere,since the PM10 emissions from the soil erosion surfaces and its ensuing suspension within the atmosphere constitute an essential process of soil erosion in the Columbia *** and implementing strategic land management practices on sandy loam soils is therefore necessary to control dust emissions in the Columbia Plateau.

关键词： particle size threshold friction velocity inhalable particulate matter total suspended particles Warden sandy loam Ritzville silt loam Columbia Plateau

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Elucidating the role of embedding dispersed cobalt sites in nitrogen-doped carbon frameworks in Si-based anodes for stable and superior storage

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Journal of Energy Chemistry 2024年第11期98卷 180-195页

作者： Yueying Chen Ping Li Mianying Huang Chunlei Wu Qianhong Huang Tingyang Xie Xiaoming Lin Akif Zeb Yongbo Wu Zhiguang Xu Yuepeng Cai Joint Laboratory of Energy and Materials Chemistry(South China Normal University-Guangzhou Tianci New Materials Co.Ltd.) Key Laboratory of Theoretical Chemistry of EnvironmentMinistry of EducationSchool of ChemistrySouth China Normal UniversityGuangzhou 510006GuangdongChina Department of Chemistry and Chemical Engineering Jiangxi Normal UniversityNanchang 330022JiangxiChina Guangzhou Huifu Research Institute Co.Ltd Nanxiang San LuGuangzhou 510663GuangdongChina Key Laboratory of Atomic and Subatomic Structure and Quantum Control(Ministry of Education) Guangdong Basic Research Center of Excellence for Structure and Fundamental Interactions of MatterSchool of PhysicsSouth China Normal UniversityGuangzhou 510006GuangdongChina Guangdong Provincial Key Laboratory of Quantum Engineering and Quantum Materials Guangdong-Hong Kong Joint Laboratory of Quantum MatterSouth China Normal UniversityGuangzhou 510006GuangdongChina

Unsatisfactory conductivity and volume effects have hindered the commercial application of siliconbased materials as advanced anode materials for high-performance lithium-ion batteries. Herein, nitrogen doped carbon silicon matrix composite with atomically dispersed Co sites(Si/Co-N-C) is obtained via the design of the frame structure loaded with nano-components and the multi-element hybrid strategy. Co atoms are uniformly fixed to the N-C frame and tightly packed with nanoscale silicon particles as an activation and protection building block. The mechanism of the N-C framework of loaded metal Co in the Si alloying process is revealed by electrochemical kinetic analysis and ex situ characterization ***, the nitrogen-doped Co site activates the intercalation of the outer carbon matrix to supplement the additional capacity. The Co nanoparticles with high conductivity and support enhance the conductivity and structural stability of the composite, accelerating the Li^(+)/Na^(+) diffusion kinetics. Density functional theory(DFT) calculation confirms that the hetero-structure Si/Co-N-C adjusts the electronic structure to obtain good lithium-ion adsorption energy, reduces the Li^(+)/Na^(+) migration energy *** work provides meaningful guidance for the development of high-performance metal/non-metal modified anode materials.

关键词： Co nanoparticles Nitrogen doped carbon Silicon Lithium/sodium storage Metal-organic frameworks(MOFs)

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KCl acts as a flux to assist the growth of sub-millimeter-scale metallic 2D non-layered molybdenum dioxide

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Rare Metals 2025年第1期44卷 404-416页

作者： Li-Ying Deng Qing Zhang Wang-Yang Li Xiao-Yuan Ye Yi-Fan Zhao Shen-Zhong Chen Yu-Lan Wang Xing-Hui Wang Hui-Peng Chen Zhi-Yang Yu Qun Yan Shu-Ying Cheng Tai-Liang Guo Wen-Ping Hu Feng Ding Jie Sun National and Local United Engineering Laboratory of Flat Panel Display Technology College of Physics and Information EngineeringFuzhou UniversityFuzhou350100China Fujian Key Laboratory of Agricultural Information Sensing Technology College of Mechanical and Electrical EngineeringFujian Agriculture and Forestry UniversityFuzhou350002China Key Laboratory of Organic Integrated Circuit Department of ChemistrySchool of ScienceMinistry of Education and Tianjin Key Laboratory of Molecular Optoelectronic SciencesTianjin UniversityTianjin300072China Collaborative Innovation Center of Chemical Science and Engineering(Tianjin) Tianjin300072China College of Physics and Information Engineering Institute of Micro-Nano Devices and Solar CellsFuzhou UniversityFuzhou350108China State Key Laboratory of Photocatalysis on Energy and Environment College of ChemistryFuzhou UniversityFuzhou350116China Faculty of Materials Science and Engineering/Institute of Technology for Carbon Neutrality Shenzhen Institute of Advanced TechnologyChinese Academy of SciencesShenzhen518000China

Two-dimensional(2D)metal oxides(2DMOs),such as MoO_(2),have made impressive strides in recent years,and their applicability in a number of fields such as electronic devices,optoelectronic devices and lasers has been ***,2DMOs present challenges in their synthesis using conventional methods due to their non-van der Waals *** report that KCl acts as a flux to prepare large-area 2DMOs with sub-millimeter *** systematically investigate the effects of temperature,homogeneous time and cooling rate on the products in the flux method,demonstrating that in this reaction a saturated homogenous solution is obtained upon the melting of the salt and ***,the cooling rate was adjusted to regulate the thickness of the target crystals,leading to the precipitation of 2D non-layered material from the supersaturated solution;by applying this method,the highly crystalline non-layered 2D MoO_(2)flakes with so far the largest lateral size of up to sub-millimeter scale(~464μm)were *** studies have revealed that the 2D MoO_(2)features metallic properties,with an excellent sheet resistance as low as 99Ω·square^(-1 )at room temperature,and exhibits a property of charge density wave in the measurement of resistivity as a function of temperature.

关键词： 2D non-layered materials Metallic Metal oxide Thickness modulation Flux method

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