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Structure-performance relationship between denitration performance and catalytic interface morphologies of MnCeO_(x)/P84 catalytic filters

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Journal of Rare Earths 2025年第3期43卷 516-525,I0004页

作者： Bo Yang Yujie Lei Maosen Ni Liuying Wang Qiong Huang Mindong Chen Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment Technology(CICAEET) Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution ControlSchool of Environmental Science and EngineeringNanjing University of Information Science&TechnologyNanjing210044China

MnCeO_(x)/P84 catalytic filters with spherical,flower-like,cubic and rod-like catalytic interfaces were synthesized respectively,and their catalytic activities in the NH_(3)-SCR reaction were *** MnCeO_(x)/P84 catalytic filter with spherical catalytic interfaces(recorded as S-MnCeO_(x)/P84)exhibits the best catalytic denitration *** NO_(x)removal efficiency of S-MnCeO_(x)/P84 reaches the highest value of 98.6%at 160℃when the catalyst loading is 100 g/m^(2).At the same time,S-MnCeO_(x)/P84 exhibits good SO_(2)resistance and stability,achieving a NO_(x)removal rate of 83%at 190℃with 30 ppm SO_(2).The characterization results illustrate that the MnCeO_x active component in S-MnCeO_(x)/P84 is present in weak crystalline states,tightly wrapped around the surface of the filter fiber,and uniformly dispersed,and the mesopore is the main pore structure of the S-MnCeO_(x)/P84,which can provide a channel for the catalytic reaction to *** the same time,transmission electron microscopy(TEM)characterization shows that y-MnO_(2)is the main form of MnO_(2)in the S-MnCeO_(x)/*** analysis of H_(2)temperature programmed reduction(H_(2)-TPR).NH_(3)temperature programmed desorption(NH_(3)-TPD)and in-situ diffuse reflectance infrared spectra(DRIFTS)show that S-MnCeO_(x)/P84 has good redox ability at 100-200℃and has abundant Lewis acid sites and Bronsteds acid sites,which provides an important guarantee for its superior low-temperature NH_(3)-SCR denitration performance.

关键词： Catalytic filter Nitrogen oxides(NO_x) Denitration Catalytic interface Rare earths

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Variations in summertime ozone in Nanjing between 2015 and 2020:roles of meteorology,radical chain length and ozone production efficiency

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Frontiers of environmental Science & Engineering 2024年第11期18卷 85-96页

作者： Lin Li Jingyi Li Momei Qin Xiaodong Xie Jianlin Hu Yuqiang Zhang Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologyNanjing University of Information Science&TechnologyNanjing 210044China Environment Research Institute Shandong UniversityQingdao 266237China

Changes in ozone(O_(3))can be evaluated to inform policy effectiveness and develop reasonable emissions reduction *** study investigated the causes of summertime maximum daily 8-h average(MDA8)O_(3) variation between 2015 and 2020 in Nanjing,China,a megacity in the Yangtze River Delta(YRD)region,from the perspective of meteorological conditions and anthropogenic emissions of O_(3) precursors(VOCs and NO_(x)).Compared with 2015,the observed MDA8 O_(3) decreased by 19.1μg/m^(3) in August *** indirect and indirect impacts of meteorological conditions contributed 44%of the decline,with temperature,relative humidity,and wind playing important roles in the O_(3) *** O_(3) drop by 10.7μg/m^(3)(56%of the total decrease)may have been due to the decreases in anthropogenic emissions of VOCs and NO_(x) by 7.8%and 11.7%,*** longer hydroxyl(OH)radical chain length and higher ozone production efficiency(OPE)indicated that the reduction of anthropogenic emissions accelerated the RO_(x)(RO_(x)=OH+HO_(2)+RO_(2))and NO_(x) cycles in O_(3) production,making O_(3) more sensitive to NO_(x).This corresponded to the O_(3) formation shifting from a VOC-limited regime in 2015 to a transition regime in 2020 and O_(3) decrease with anthropogenic emission ***,the joint control of O_(3) precursor emissions can effectively mitigate O_(3) pollution in Nanjing.

关键词： Ozone Meteorological condition Anthropogenic emission OH radical chain length OPE

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Effectiveness of Precursor Emission Reductions for the control of Summertime Ozone and PM2.5 in the Beijing–Tianjin–Hebei Region under Different Meteorological Conditions

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Advances in atmospheric Sciences 2025年第4期42卷 653-669页

作者： Jing QIAN Hong LIAO Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and EngineeringNanjing University of Information Science&TechnologyNanjing 210044JiangsuChina

We used observed concentrations of air pollutants,reanalyzed meteorological parameters,and results from the Goddard Earth Observing System Chemical Transport Model to examine the relationships between concentrations of maximum daily 8-h average ozone(MDA8 O_(3)),PM_(2.5)(particulate matter with diameter of 2.5μm or less),and PM_(2.5)components and 2-m temperature(T2)or relative humidity(RH),as well as the effectiveness of precursor emission reductions on the control of O_(3) and PM_(2.5) in Beijing–Tianjin–Hebei(BTH)under different summertime temperature and humidity *** observed(simulated)MDA8 O_(3) and PM_(2.5) concentrations increased as T2 went up,with linear trends of 4.8(3.2)ppb℃^(−1) and 1.9(1.5)μg m^(−3)℃^(−1),*** results showed that the decreases in MDA8 O_(3) from precursor emission reductions were more sensitive to T2 than to *** a larger proportion of volatile organic compound(VOC)emissions at higher T2 was more effective for the control of summertime O_(3) in *** the control of summertime PM_(2.5) in BTH,reducing nitrogen oxides(NOx)combined with a small proportion of VOCs was the best *** magnitude of reduction in PM_(2.5) from reducing precursor emissions was more sensitive to RH than to T2,with the best efficiency at high *** from this study are helpful for formulating effective policies to tackle O_(3) and PM_(2.5) pollution in BTH.

关键词： ozone PM_(2.5) emission reductions meteorological conditions

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Recent progress in carbene-catalyzed fluoroalkylation

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Science China Chemistry 2024年第8期67卷 2448-2460页

作者： Bei Zhang Xuan Zhang Jian Wang Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and EngineeringNanjing University of Information Science and TechnologyNanjing 210044China School of Pharmaceutical Sciences Tsinghua UniversityBeijing 100084China

The fluoroalkyl fragment plays a vital role in various fields such as pharmaceuticals and materials science, and has a significant impact on human life not only on the present but also in the future. The insertion of fluoroalkyl groups into the chemical skeletons can cause considerable alternations in the chemical, physical and biological properties of molecules, which has attracted numerous scientists from different fields. This review focuses on N-heterocyclic carbene(NHC)-catalyzed fluoroalkylation reactions, providing a detailed analysis and summary of the achievements in the past two decades. Many successful examples clearly indicate that NHCs can catalyze the tranformation of fluoroalkylation reagents with various electronic characteristics, whether electrophilic, nucleophilic, or radical precursors. Herein, the fluoroalkylation reactions are classified based on different catalytic modes of NHCs: Lewis base catalysis, Umploung catalysis, radical catalysis and others. Meanwhile, by refining and systematically studying the contribution of NHC catalysis in fluoroalkylation reactions, this review is expected to provide valuable insights and enlightenment for related fields.

关键词： N-heterocyclic carbene fluoroalkylation radical catalysis

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Low-temperature NH_(3) abatement via selective oxidation over a supported copper catalyst with high Cu^(+) abundance

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Journal of environmental Sciences 2024年第9期143卷 12-22页

作者： Zhiming Yang Lin Peng Leneng Yang Mingli Fu Daiqi Ye Peirong Chen Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control National Engineering Laboratory for VOCs Pollution Control Technology and EquipmentSchool of Environment and EnergySouth China University of TechnologyGuangzhou 510006China Guangdong Chengyi Environmental Technology Corp. Shaoguan 512158China

Selective catalytic NH_(3)-to-N_(2) oxidation(NH_(3)-SCO)is highly promising for abating NH_(3) emissions slipped from stationary flue gas after-treatment *** practical application,however,is limited by the non-availability of low-cost catalysts with high activity and N_(2) ***,using defect-rich nitrogen-doped carbon nanotubes(NCNT-AW)as the support,we developed a highly active and durable copper-based NH_(3)-SCO catalyst with a high abundance of cuprous(Cu^(+))*** obtained Cu/NCNT-AW catalyst demonstrated outstanding activity with a T_(50)(*** temperature to reach 50% NH_(3) conversion)of 174℃ in the NH_(3)-SCO reaction,which outperformed not only the Cu catalyst supported on N-free O-functionalized CNTs(OCNTs)or NCNT with less surface defects,but also those most active Cu catalysts in open *** kinetics measurements and temperature-programmed surface reactions using NH_(3)as a probe molecule revealed that the NH_(3)-SCO reaction on Cu/NCNT-AW follows an internal selective catalytic reaction(i-SCR)route involving nitric oxide(NO)as a key *** to mechanistic investigations by X-ray photoelectron spectroscopy,Raman spectroscopy,and X-ray absorption spectroscopy,the superior NH_(3)-SCO performance of Cu/NCNT-AW originated from a synergy of surface defects and ***,surface defects promoted the anchoring of Cu O nanoparticles on N-containing sites and,thereby,enabled efficient electron transfer from N to Cu O,increasing significantly the fraction of SCR-active Cu^(+)sites in the *** study puts forward a new idea for manipulating and utilizing the interplay of defects and N-dopants on carbon surfaces to fabricate Cu^(+)-rich Cu catalysts for efficient abatement of slip NH_(3)emissions via selective oxidation.

关键词： NH_(3)-SCO XANES Localized etching N-doping N_(2) selectivity i-SCR

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Effect of industrial alkene ozonolysis on atmospheric H_(2)SO_(4)formation

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Journal of environmental Sciences 2025年第4期150卷 466-476页

作者： Xing Wang Xiaowen Shi Youling Jiang Yan Ma Jun Zheng School of Environmental Science and Engineering Nanjing University of Information Science and TechnologyNanjing 210044China Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control Nanjing 210044China Jiangsu Provincial Academy of Environmental Sciences Nanjing 210036China

This study has employed the master chemical mechanism(MCM)to investigate the influence of the ozone oxidation pathways in the atmospheric formation of H_(2)SO_(4)from shortchain olefins in industrialized ***-situ H_(2)SO_(4)formation data were obtained using a high-resolution chemical ionization time-of-flight mass spectrometer,and the simulated H_(2)SO_(4)concentrations calculated using updated parameters for the MCM model exhibited good agreementwith *** the simulation analysis of different reaction pathways involved in H_(2)SO_(4)formation,hydroxyl radicals were found to dominate H_(2)SO_(4)production during the daytime,while olefin ozone oxidation contributed up to 65%of total H_(2)SO_(4)production during the night-time.A sensitivity analysis of the H_(2)SO_(4)production parameters has revealed a high sensitivity to changes in sulfur dioxide,and a relatively high sensitivity to olefins with fast ozonolysis reaction rates and bimolecular reaction rates of resulting stabilized Criegee Intermediates.A high relative humidity promotes daytime H_(2)SO_(4)formation,but has an inhibiting effect during the night-time due to the different dominant reaction pathways.

关键词： Gaseous sulfuric acid Alkene ozonation reaction MCM model Sensitivity analysis

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The reconstruction of equal-mole bimetal organic framework to heterostructure for effective oxygen evolution reaction

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Journal of Materials Science & Technology 2024年第36期203卷 118-125页

作者： Jinxia Yang Zhaoxia Hu Youlei Feng Zehua Zou Xiaoping Chen Qingxiang Wang Fujian Provincial Key Laboratory of Modern Analytical Science and Separation Technology Fujian Provincial Key Laboratory of Pollution Monitoring and ControlCollege of ChemistryChemical Engineering and EnvironmentMinnan Normal UniversityZhangzhou363000China

Oxygen evolution reaction(OER)is one of the most important issues for hydrogen production from water *** the OER process,electrochemical reconstruction is widely observed for the majority of electrocatalysts,which is strongly related to the formation and evolution of real active ***,bimetal metal-organic framework(MOF)with an equal ratio of Co and Fe sites is screened to exhibit the superior OER *** obvious reconstruction is observed to transform single MOF phase into the heterostructure composed of active CoOOH and ***,the generation of Co^(3+)species is more reliant on the blessing of electricity and electrolyte than that of Fe3+*** a result,the optimal electrocatalyst shows the overpotential of 267 mV at 10 mA/cm^(2)and ultra-low Tafel slope of 24.7 mV/dec with a stable OER performance.

关键词： Oxygen evolution reaction Metal-organic frameworks Reconstruction Heterostructure

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Implications of the extremely hot summer of 2022 on urban ozone control in China

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atmospheric and Oceanic Science Letters 2024年第6期17卷 3-7页

作者： Wenhao Qiao Ke Li Zhenjiang Yang Lei Chen Hong Liao Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and EngineeringNanjing University of Information Science and TechnologyNanjingChina

Frequent occurrences of extreme heat are causing severe ozone pollution over *** study examined the driving factors of urban ozone pollution in China during the extremely hot summer of 2022 and the impact of emission control strategies using surface measurements and the GEOS-Chem *** results show that ozone pollution was extremely severe in summer 2022,with a significant rebound by 12-15 ppbv in the North China Plain(NCP),Yangtze River Delta(YRD),and Sichuan basin(SCB),compared to *** over the NCP,the MDA8(maximum daily 8-hourly average)ozone exceeded 160 ppbv,and the number of ozone exceedances was over 42 *** on an IPR(integrated process rate)analysis,the authors found that the net chemical production was the dominant factor contributing to the strong ozone increase in summer *** example,in June over the NCP,the net chemical production resulted in an increase by 3.08 Gg d^(−1)(∼270%)in ozone mass *** simulations showed that both NO_(x)(nitrogen oxides)and VOC(volatile organic compound)reductions were important over the NCP,and NO_(x)reductions were more important than VOCs over southern *** keep the ozone of 2022 at the same level as 2021,a joint reduction of NO_(x)and VOCs by at least 50%-60%would have been *** study highlights the urgency to develop effective ozone management since extreme heat will become more frequent.

关键词： Ozone pollution Extreme heat Emission controls Joint reductions China

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Climatic drivers of the Canadian wildfire episode in 2023

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atmospheric and Oceanic Science Letters 2024年第4期17卷 23-28页

作者： Yihan Hu Xu Yue Chenguang Tian Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and EngineeringNanjing University of Information Science&Technology(NUIST)NanjingChina

2023年5月加拿大发生极端野火事件并持续4个月时间.野火污染物排放对当地和下风向的空气质量造成了严重影响.本文对驱动此次野火事件的气象因子和相关大尺度环流进行了探究.研究表明,此次极端野火排放的二氧化碳相较往年同期增长了0.37G... 详细信息

2023年5月加拿大发生极端野火事件并持续4个月时间.野火污染物排放对当地和下风向的空气质量造成了严重影响.本文对驱动此次野火事件的气象因子和相关大尺度环流进行了探究.研究表明,此次极端野火排放的二氧化碳相较往年同期增长了0.37Gt (527.1%).受罗斯贝波频散影响,同期加拿大中西部区域出现持续的位势高度正异常,促进气流下沉并引发局地高温,中西部区域5-6月最高温平均上升8.11℃,部分区域甚至超过10℃,导致野火排放的显著增长.受有利地形和泛北极地区快速增暖的影响,预期未来加拿大中西部发生极端野火的概率可能会显著上升.

关键词：野火气候变化遥相关极端天气碳排放

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Exploring formation mechanism and source attribution of ozone during the 2019 Wuhan Military World Games:Implications for ozone control strategies

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Journal of environmental Sciences 2024年第2期136卷 400-411页

作者： Lei Zhang Lili Wang Runyu Wang Nan Chen Yuan Yang Ke Li Jie Sun Dan Yao Yuesi Wang Minghui Tao Yang Sun Institute of Atmospheric Physics Chinese Academy of SciencesBeijing 100029China University of the Chinese Academy of Sciences Beijing 100049China Hubei Ecological Environment Monitoring Center Station Wuhan 430072China Guizhou Research and Designing Institute of Environmental Sciences Guizhou Academy of Environmental Science and DesignGuiyang 550081China Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and EngineeringNanjing University of Information Science and TechnologyNanjing 210044China School of Environment Key Laboratory for Yellow River and Huai River Water Environment and Pollution ControlMinistry of EducationHenan Normal UniversityXinxiang 453007China Key Laboratory of Regional Ecology and Environmental Change School of Geography and Information EngineeringChina University of GeosciencesWuhan 430074China

A series of emission reduction measures were conducted in Wuhan,Central China,to ensure good air quality during the 7th Military World Games(MWG)in October *** better understand the implications for ozone(O_(3))pollution control strategies,we applied integrated analysis approaches based on the de-weathered statistical model,parameterization methods,chemical box model,and positive matrix factorization *** the MWG,concentrations of O_(3),NO_x,and volatile organic compound(VOCs),OFP(O_(3)formation potential),L_(OH)(OH radical loss rate)were 83μg/m^(3),43μg/m^(3),26 ppbv,188μg/m^(3),and 3.9 s^(-1),respectively,which were 26%,18%,3%,15%,and 13%lower than pre-MWG values and 6%,39%,30%,33%,and 50%lower than post-MWG values,*** removing meteorological influence,O_(3)and its precursors during the MWG decreased largely compared with post-MWG values,and only O_(3),NO_(2),and oxygenated VOCs(OVOCs)declined compared with pre-MWG values,which revealed the emission reduction measures during the MWG played an important role for O_(3)*** six VOCs sources,the mass contributions of biomass burning and solvents usage during the MWG decreased largely compared with pre-MWG values.O_(3)production was sensitive to VOCs and the key species were aromatics,OVOCs,and alkenes,which originated mainly from solvents usage,biomass burning,industrial-related combustion,and vehicle *** O_(3)concentration during the strict control was mainly caused by OVOCs reduction due to biomass burning ***,the O_(3)abatement strategies of Wuhan should be focused on the mitigation of high-reactivity VOCs.

关键词： VOCs Ozone Wuhan Military World Games Source apportionment Relative incremental reactivity Random forest

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