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Ru-Ni alloy nanosheets as tandem catalysts for electrochemical reduction of nitrate to ammonia

Nano Research 2024年第6期17卷 4815-4824页

作者： Xingchao You Jiawei Xu Zechao Zhuang Junkai Xia Suwen Wang Haiyan Wei Yongfu Li Yanjiang Cai Hai Xiang Bing Yu State Key Laboratory of Subtropical Silviculture Zhejiang A&F UniversityHangzhou 311300China Ecological-Environment&Health College(EEHC) Zhejiang A&F UniversityHangzhou 311300China Jiangsu Key Laboratory of Numerical Simulation of Large Scale Complex Systems and School of Chemistry and Materials Science Nanjing Normal UniversityNanjing 210023China Department of Chemistry Tsinghua UniversityBeijing 100084China Department of Chemical Engineering Columbia UniversityNew YorkNY 10027USA

Developing electrocatalysts that exhibit both high activity and ammonia selectivity for nitrate reduction is a significant and demanding challenge,primarily due to the complex nature of the multiple-electron reduction process *** encouraging approach involves coupling highly active precious metals with transition metals to enhance catalytic performance through ***,we report a ruthenium-nickel alloy catalyst with nanosheets(Ru-Ni NSs)structure that achieves a remarkable ammonia Faradaic efficiency of approximately 95.93%,alongside a yield rate of up to 6.11 g·h^(−1)·cm^(−2).Moreover,the prepared Ru-Ni NSs exhibit exceptional stability during continuous nitrate reduction in a flow reactor for 100 h,maintaining a Faradaic efficiency of approximately 90%and an ammonia yield of 37.4 mg·L^(−1)·h^(−1)using 0.05 M nitrate alkaline *** studies reveal that the catalytic process follows a two-step pathway,in which HONO serves as a migration *** presence of a partially oxidized Ru(002)surface enhances the adsorption of nitrate and facilitates the release of the migration intermediate by adjusting the strength of the electrostatic and covalent interactions between the adsorbate and the surface,*** the other hand,the Ni(111)surface promotes the utilization of the migration intermediate and requires less energy for NH_(3)*** tandem process contributes to a high catalytic activity of Ru-Ni NSs towards nitrate reduction.

关键词： alloy catalyst nitrate reduction ammonia synthesis Faradaic efficiency

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Chlorine-induced mixed valence of CuO_(x)/C to promote the electroreduction of carbon dioxide to ethylene

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Nano Research 2023年第7期16卷 8827-8835页

作者： Xin Wang Ming Miao Bowen Tang Haotian Duan Fulong Zhu Huigang Zhang Xian Zhang Wen-jin Yin Yongzhu Fu College of Chemistry Zhengzhou UniversityZhengzhou 450001China School of Physics and Electronic Science Hunan University of Science and TechnologyXiangtan 411201China State Key Laboratory of Multiphase Complex Systems Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China Qian Xuesen Laboratory of Space Technology China Academy of Space TechnologyBeijing 100094China

Electrochemical conversion of CO_(2)(CO_(2)RR)into high-value fuel is identified as one of the promising approaches to achieve carbon *** synthesis of high-efficiency CO_(2)reduction electrocatalysts with high C_(2):C_(1) selectivity remains a field of intense *** studies have shown that the presence of Cu(I)is beneficial for the reduction of CO_(2)into C_(2)***,the stable presence of Cu(I)remains controversial,especially in the negative potential *** we report a simple and easily scalable catalyst precursor Cu_(2)(OH)_(3)Cl/C,which automatically forms in-situ chlorine-doped Cu/Cu_(2)O heterointerface during *** catalyst not only exhibits a Faradaic efficiency of 33.03%but also provides a long-term stability of Cu^(+),gaining a stable electrolysis of 11 h,with an ethylene/methane ratio over *** experimental results and mechanistic studies confirm that the presence of Cl^(-)inhibits the reduction of Cu^(+),inducing the formation of Cu^(0)/Cu^(+),and reduces the reaction energy of the intermediate ^(*)CO dimerization,thereby facilitating the formation of C_(2)*** work provides a feasible way to synthesize copper ions with long-term and stable positive charge in CO_(2)RR and expands a new way to synthesize ethylene industrial products in the future.

关键词： basic copper chloride chlorine dopant mixed-phase catalysts CO_(2)reduction reaction ethylene

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Advanced Nonflammable Localized High-Concentration Electrolyte For High Energy Density Lithium Battery

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Energy & Environmental Materials 2022年第4期5卷 1294-1302页

作者： Mengmin Jia Chi Zhang Yawei Guo Linshan Peng Xiaoyan Zhang Weiwei Qian Lan Zhang Suojiang Zhang CAS Key Laboratory of Green Process and Engineering State Key Laboratory of Multiphase Complex SystemsInstitute of Process EngineeringBeijing Key Laboratory of Ionic Liquids Clean ProcessChinese Academy of SciencesBeijing 100190China School of Chemical Engineering University of Chinese Academy of SciencesBeijing 100049China School of Chemical Engineering Zhengzhou UniversityZhengzhou 450001China School of Chemical Engineering and Technology Xi’an Jiaotong UniversityXi’an 710049China Langfang Institute of Process Engineering Chinese Academy of SciencesHebei 065001China

The key to realize long-life high energy density lithium batteries is to exploit functional electrolytes capable of stabilizing both high voltage cathode and lithium *** emergence of localized high-concentration electrolytes(LHCEs)shows great promise for ameliorating the above-mentioned interfacial *** this work,a lithium difluoro(oxalate)borate(LiDFOB)based nonflammable dual-anion LHCE is designed and *** in the mixture of trimethyl phosphate(TMP)/1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropylether(D_(2)),the continuously consumption of LiDFOB is suppressed by simply introducing lithium nitrate(LiNO_(3)).Meantime,as most of the TMP molecular are coordinated with Li^(+),the electrolyte does not show incompatibility issue between neither metal lithium nor graphite ***,it demonstrates excellent capability in stabilizing the interface of Ni-rich cathode and regulating lithium deposition *** Li||LiNi_(0.87)Co_(0.08)Mn_(0.05)O_(2)(NCM87)batteries exhibit high capacity retention of more than 90%after 200 cycles even under the high cutoff voltage of 4.5 V,1 C *** study offers a prospective method to develop safe electrolytes suitable for high voltage applications,thus providing higher energy densities.

关键词： dual-anion lithium metal battery localized high-concentration electrolyte nonflammable phosphate

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A policy gradient algorithm integrating long and short-term rewards for soft continuum arm control

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Science China(Technological Sciences) 2022年第10期65卷 2409-2419页

作者： DONG Xiang ZHANG Jing CHENG Long XU WenJun SU Hang MEI Tao School of Electrical Engineering and Automation Anhui UniversityHefei 230601China State Key Laboratory for Control and Management of Complex Systems Institute of AutomationChinese Academy of SciencesBeijing 100190China Robotics Research Center Peng Cheng LaboratoryShenzhen 518055China

The soft continuum arm has extensive application in industrial production and human life due to its superior safety and flexibility. Reinforcement learning is a powerful technique for solving soft arm continuous control problems, which can learn an effective control policy with an unknown system model. However, it is often affected by the high sample complexity and requires huge amounts of data to train, which limits its effectiveness in soft arm control. An improved policy gradient method, policy gradient integrating long and short-term rewards denoted as PGLS, is proposed in this paper to overcome this issue. The shortterm rewards provide more dynamic-aware exploration directions for policy learning and improve the exploration efficiency of the algorithm. PGLS can be integrated into current policy gradient algorithms, such as deep deterministic policy gradient(DDPG). The overall control framework is realized and demonstrated in a dynamics simulation environment. Simulation results show that this approach can effectively control the soft arm to reach and track the targets. Compared with DDPG and other model-free reinforcement learning algorithms, the proposed PGLS algorithm has a great improvement in convergence speed and performance. In addition, a fluid-driven soft manipulator is designed and fabricated in this paper, which can verify the proposed PGLS algorithm in real experiments in the future.

关键词： soft arm control Cosserat rod deep reinforcement learning policy gradient algorithm high sample complexity

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Deep Semantic and Attentive Network for Unsupervised Video Summarization

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ACM Transactions on Multimedia Computing, Communications and Applications 2022年第2期18卷 1-21页

作者： Zhong, Sheng-Hua Lin, Jingxu Lu, Jianglin Fares, Ahmed Ren, Tongwei College of Computer Science and Software Engineering Shenzhen University Shenzhen518060 China Department of Electrical Engineering Computer Systems Engineering Program Faculty of Engineering at Shoubra Benha University Cairo Egypt State Key Laboratory for Novel Software Technology Nanjing University Nanjing210023 China

With the rapid growth of video data, video summarization is a promising approach to shorten a lengthy video into a compact version. Although supervised summarization approaches have achieved state-of-the-art performance, they require frame-level annotated labels. Such an annotation process is time-consuming and tedious. In this article, we propose a novel deep summarization framework named Deep Semantic and Attentive Network for Video Summarization (DSAVS) that can select the most semantically representative summary by minimizing the distance between video representation and text representation without any frame-level labels. Another challenge associated with video summarization tasks mainly originates from the difficulty of considering temporal information over a long time. Long Short-Term Memory (LSTM) performs well for temporal dependencies modeling but does not work well with long video clips. Therefore, we introduce a self-attention mechanism into our summarization framework to capture the long-range temporal dependencies among the frames. Extensive experiments on two popular benchmark datasets, i.e., SumMe and TVSum, show that our proposed framework outperforms other state-of-the-art unsupervised approaches and even most supervised methods. © 2022 Association for Computing Machinery.

关键词： Semantics

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Few-shot Pose-free View Synthesis with 3D Gaussian Splatting

Few-shot Pose-free View Synthesis with 3D Gaussian Splatting

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2024 China Automation Congress, CAC 2024

作者： Huang, Yuan Xu, Chi School of Automation China University of Geosciences Hubei Key Laboratory of Advanced Control and Intelligent Automation for Complex Systems Engineering Research Center of Intelligent Technology for Geo-Exploration Ministry of Education Wuhan China

ISBN: (纸本)9798350368604

Recent advancements in Novel View Synthesis using neural radiance fields and 3D Gaussian splatting have demonstrated promising results. However, these methods conventionally rely on accurate initial poses and point clouds from the model of structure from motion, which poses challenges in sparse input views. To addressing these drawbacks, we introduces an novel method for view synthesis based on 3D Gaussian splatting. Our approach operates on sparse input views without the prerequisite of pose priors, achieving reconstruction and real-time rendering of novel perspectives. For the deficiency of camera poses and point cloud, we employ an end-to-end deep learning model to recover the 3D structure from a few of 2D images to initialize the 3D Gaussian point cloud. In addressing the issue with few-shot, we utilize the differentiable rasterization module to render depth map and apply regulation on it. Additionally, we incorporate supervision between input views by interpolating to generate novel perspectives during training. Experimental results demonstrate that our proposed method significantly enhances the capabilities of 3D Gaussian splatting for novel view synthesis in sparse views and without the necessity of camera pose priors. © 2024 IEEE.

关键词： 3D reconstruction

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Excellent Antibacterial Performance of ROS-mediated Cu-doped ZIF-8 and the Mechanism of ROS Generation 18

Excellent Antibacterial Performance of ROS-mediated Cu-doped...

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18th International Conference on Indoor Air Quality and Climate, INDOOR AIR 2024

作者： Chen, Yunfa Zhang, Jingkun Ding, Yan Yin, Hang State Key Laboratory of Multiphase Complex Systems Institute of Process Engineering Chinese Academy of Sciences Beijing China Vehicle Emission Control Center Chinese Research Academy of Environmental Sciences Beijing China

ISBN: (纸本)9798331306816

Nowadays, it is necessary to explore efficient antibacterial materials to complement or substitute the conventional antibiotic, to cope with the ever-growing bacterial contamination. Here, a series of Cu-doped ZIF-8 materials are prepared and adopted for disinfection against typical bacteria E. coli and S. aureus in dark. The results show that 5-7 log efficiency can be achieved at a dosage of 15-30 mg mL-1 of 1.35 atomic % Cu doped ZIF-8, and this concentration is also safe as verified by cytotoxicity test. Mechanism investigation shows that Cu(II) is reduced to Cu(I), which would contribute to the effective electron transfer for the reactive oxygen species generation. And these reactive oxygen species would cause oxidative stress and membrane damage on bacteria cells. All these results show the promise of Cu-doped ZIF-8 in the antibacterial applications especially in the environments without any energy input. © 2024 18th Conference of the International Society of Indoor Air Quality and Climate, INDOOR AIR 2024 - Conference Program and Proceedings. All rights reserved.

关键词： Reactive oxygen species

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Forming Circle Formations of Multi-agent systems Under Actuator Faults 5th

Forming Circle Formations of Multi-agent Systems Under Actu...

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5th Chinese Conference on Swarm Intelligence and Cooperative Control, CCSICC 2021

作者： Liu, Jiajun Ru, Xinfeng Xia, Weiguo Wang, Chen China National Aeronautical Radio Electronic Research Institute and National Key Laboratory of Science and Technology on Avionics System Integration Shanghai China Key Laboratory of Intelligent Control and Optimization for Industrial Equipment of Ministry of Education and School of Control Science and Engineering Dalian University of Technology Dalian China National Engineering Research Center of Software Engineering and the State Key Laboratory of Turbulence and Complex Systems Intelligent Biomimetic Design Lab College of Engineering Peking University Beijing China

ISBN: (纸本)9789811939976

A distributed fault-tolerant formation control law is designed in this paper for multi-agent systems under external disturbances and actuator faults including time-varying loss of effectiveness faults. The initial position of each agent is already on a circle and the control purpose is to form a desired formation on this circle. Based on this local information, a distributed adaptive formation control law is designed by employing the congelation of variables method to deal with time-varying actuator faults. Finally, a simulation example is given to verify the effectiveness of the adaptive fault-tolerant control design method. © 2023, The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd.

关键词： Multi agent systems

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A Unified Information Diffusion Prediction Model Based on Multi-task Learning 9th

A Unified Information Diffusion Prediction Model Based on M...

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19th International Conference on Advanced Data Mining and Applications, ADMA 2023

作者： Shang, Yingdan Zhou, Bin Zeng, Xiang Chen, Kai College of Computer Science and Technology National University of Defense Technology Changsha China Key Lab of Software Engineering for Complex Systems School of Computer National University of Defense Technology Changsha China

ISBN: (纸本)9783031466731

The prediction of online information diffusion trends on social networks is crucial for understanding people’s interests and concerns, and has many real-world applications in fields such as business, politics and social security. Existing research on information diffusion prediction has predominantly focused on either macro level prediction of the future popularity of online information or micro level user activation prediction. However, information diffusion prediction on micro or macro level only may lead to one-sided prediction results, and there is a lack of research on implementing micro and macro level diffusion prediction tasks at the same time. Since micro and macro level diffusion prediction tasks are related to each other, we propose a unified information diffusion model which can jointly predicting the micro level user activation probability and macro level information popularity based on multi-task learning framework. We utilize graph neural network to learn user representation from both the information cascades and social network structure. Comparing with micro and macro level baseline methods separately, the prediction results of our proposed model outperform all baseline methods and proves the effectiveness of the proposed method. © The Author(s), under exclusive license to Springer Nature Switzerland AG 2023.

关键词： Forecasting

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Hierarchically microporous membranes for highly energy-efficient gas separations

Industrial Chemistry & Materials

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Industrial Chemistry & Materials 2023年第3期1卷 376-387页

作者： Shuangjiang Luo Tianliang Han Can Wang Ying Sun Hongjun Zhang Ruilan Guo Suojiang Zhang CAS Key Laboratory of Green Process and Engineering State Key Laboratory of Multiphase Complex SystemsBeijing Key Laboratory of Ionic Liquids Clean ProcessInstitute of Process EngineeringChinese Academy of Sciences(CAS)Beijing 100190China State Key Laboratory of Particle Detection and Electronics University of Science and Technology of ChinaHefei 230026China Department of Chemical and Biomolecular Engineering University of Notre DameNotre DameIN 46556USA Longzihu New Energy Laboratory Zhengzhou 450000China Henan University Jinming RoadKaifeng475004China

The implementation of synthetic polymer membranes in gas separations,ranging from natural gas sweetening,hydrogen separation,helium recovery,carbon capture,oxygen/nitrogen enrichment,etc.,has stimulated the vigorous development of high-performance membrane ***,size-sieving types of synthetic polymer membranes are frequently subject to a trade-off between permeability and selectivity,primarily due to the lack of ability to boost fractional free volume while simultaneously controlling the micropore size ***,we review recent research progress on microporosity manipulation in high-free-volume polymeric gas separation membranes and their gas separation performance,with an emphasis on membranes with hourglass-shaped or bimodally distributed ***-of-the-art strategies to construct tailorable and hierarchically microporous structures,microporosity characterization,and microcavity architecture that govern gas separation performance are systematically summarized.

关键词： Gas separation membranes Hierarchical microporosity Micropore size distribution Configurational free volume Solution-diffusion mechanism

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