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Solid–Liquid Interfacial Coordination Chemistry Enables High-Capacity Ammonium Storage in Amorphous Manganese Phosphate

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Angewandte Chemie 2022年第37期134卷

作者： Duo Yang Prof. Yu Song Ming-Yue Zhang Zengming Qin Jie Liu Prof. Xiao-Xia Liu Department of Chemistry Northeastern University 3-11 Wenhua Road Heping district Shenyang 110819 China School of Resources and Civil Engineering Northeastern University 3-11 Wenhua Road Heping district Shenyang 110819 China National-local Joint Engineering Research Center of High-efficient Exploitation Technology for Refractory Iron Ore Resources Shenyang 110819 Liaoning China National Frontiers Science Center for Industrial Intelligence and Systems Optimization Northeastern University 3-11 Wenhua Road Heping district Shenyang 110819 China Key Laboratory of Data Analytics and Optimization for Smart Industry Northeastern University) Ministry of Education China 3-11 Wenhua Road Heping district Shenyang 110819 China

Ammonium (NH 4 + ) ion as charge carrier is attracting attention in aqueous batteries. Yet, most NH 4 + host materials are still limited by the relatively low capacities. Here, we fabricated a manganese phosphate (MP-20) for NH 4 + ion storage. MP-20 displays a high capacity of 299.6 mAh g −1 at 1 A g −1 in ammonium acetate (NH 4 Ac) electrolyte, outperforming other reported NH 4 + host materials. Spectroscopy studies suggest a new NH 4 + /H + co-insertion mechanism. We surprisingly discover that the NH 4 Ac electrolyte plays an important role in improving the charge storage capability of the materials. Experimental and computational results indicate acetate ions can form coordination bonds with the Mn atoms, tailoring the electronic structure of the Mn atoms and the surrounding O atoms, and therefore facilitating the NH 4 + storage process. Our findings provide a new NH 4 + host material and propose the important role of the electrolyte-electrode coordination effect in aqueous ammonium batteries.

关键词： Aqueous Ammonium-Ion Batteries Charge Storage Mechanism Coordination Electrochemical Deposition Manganese Phosphate

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Distinguishing Protein Chemical Topologies Using Supercharging Ion Mobility Spectrometry-Mass Spectrometry

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Angewandte Chemie 2023年第51期135卷

作者： Jiyeon Lee Dahye Im Yajie Liu Jing Fang Xibao Tian Minsu Kim Prof. Wen-Bin Zhang Prof. Jongcheol Seo Department of Chemistry Pohang University of Science and Technology (POSTECH) 77 Cheongam-ro Nam-gu Pohang 37673 Gyeonsangbuk-do (Republic of Korea Contribution: Data curation (lead) Formal analysis (equal) Visualization (lead) Writing - original draft (lead) Writing - review & editing (supporting) Contribution: Data curation (supporting) Formal analysis (equal) Visualization (supporting) Writing - original draft (supporting) Writing - review & editing (supporting) Beijing National Laboratory for Molecular Sciences Key Laboratory of Polymer Chemistry & Physics of Ministry of Education Center for Soft Matter Science and Engineering College of Chemistry and Molecular Engineering Peking University Beijing 100871 P. R. China Contribution: Resources (equal) Contribution: Data curation (supporting) Validation (supporting) Contribution: Conceptualization (equal) Funding acquisition (equal) Investigation (equal) Project administration (supporting) Writing - review & editing (equal) Contribution: Conceptualization (equal) Funding acquisition (equal) Investigation (lead) Project administration (lead) Validation (lead) Writing - review & editing (lead)

A technique combining ion mobility spectrometry-mass spectrometry (IMS-MS) and supercharging electrospray ionization (ESI) has been demonstrated to differentiate protein chemical topology effectively. Incorporating as many charges as possible into proteins via supercharging ESI allows the protein chains to be largely unfolded and stretched, revealing their hidden chemical topology. Different chemical topologies result in differing geometrical sizes of the unfolded proteins due to constraints in torsional rotations in cyclic domains. By introducing new topological indices, such as the chain-length-normalized collision cross-section (CCS) and the maximum charge state ( z M ) in the extensively unfolded state, we were able to successfully differentiate various protein chemical topologies, including linear chains, ring-containing topologies (lasso, tadpole, multicyclics, etc.), and mechanically interlocked rings, like catenanes.

关键词： Mass Spectrometry Protein engineering Proteins

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Managing Multiple Halide-Related Defects for Efficient and Stable Inorganic Perovskite Solar Cells

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Angewandte Chemie 2023年第30期135卷

作者： Zhiteng Wang Prof. Qingwen Tian Hao Zhang Prof. Huidong Xie Yachao Du Lei Liu Xiaolong Feng Adel Najar Xiaodong Ren Prof. Shengzhong (Frank) Liu Key Laboratory of Applied Surface and Colloid Chemistry Ministry of Education Shaanxi Key Laboratory for Advanced Energy Devices Shaanxi Engineering Lab for Advanced Energy Technology School of Materials Science and Engineering Shaanxi Normal University Xi'an 710119 P. R. China Contribution: Conceptualization (lead) Data curation (lead) Formal analysis (lead) Investigation (lead) Contribution: Conceptualization (lead) Funding acquisition (lead) Project administration (lead) Supervision (lead) Validation (lead) Writing - original draft (lead) Writing - review & editing (lead) Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences Beijing 100049 P. R. China Dalian Institute of Chemical Physics Chinese Academy of Sciences Dalian 116023 P. R. China Contribution: Data curation (supporting) Formal analysis (supporting) Investigation (supporting) School of Chemistry and Chemical Engineering Xi'an University of Architecture and Technology Xi'an 710055 P. R. China Contribution: Formal analysis (supporting) Validation (supporting) Contribution: Data curation (supporting) Formal analysis (supporting) Contribution: Data curation (supporting) Formal analysis (supporting) Methodology (supporting) Resources (supporting) Department of Physics College of Science United Arab Emirates University Al Ain 15551 United Arab Emirates Contribution: Supervision (supporting) Validation (supporting) Writing - review & editing (supporting) Contribution: Data curation (supporting) Formal analysis (supporting) Methodology (supporting) Contribution: Funding acquisition (lead) Project administration (lead) Validation (lead) Writing - review & editing (lead)

Halide-related surface defects on inorganic halide perovskite not only induce charge recombination but also severely limit the long-term stability of perovskite solar cells. Herein, adopting density functional theory calculation, we verify that iodine interstitials (I i ) has a low formation energy similar to that of the iodine vacancy (V I ) and is also readily formed on the surface of all-inorganic perovskite, and it is regarded to function as an electron trap. We screen a specific 2,6-diaminopyridine (2,6-DAPy) passivator, which, with the aid of the combined effects from halogen-N pyridine and coordination bonds, not only successfully eliminates the I i and dissociative I 2 but also passivates the abundant V I . Furthermore, the two symmetric neighboring -NH 2 groups interact with adjacent halides of the octahedral cluster by forming hydrogen bonds, which further promotes the adsorption of 2,6-DAPy molecules onto the perovskite surface. Such synergetic effects can significantly passivate harmful iodine-related defects and undercoordinated Pb 2+ , prolong carrier lifetimes and facilitate the interfacial hole transfer. Consequently, these merits enhance the power-conversion efficiency (PCE) from 19.6 % to 21.8 %, the highest value for this type of solar cells, just as importantly, the 2,6-DAPy-treated CsPbI 3− x Br x films show better environmental stability.

关键词： All-Inorganic Perovskite CsPbI3−xBrx Defect Passivation Iodine-Related Defects Solar Cells

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Dual-Network Structured Hydrogel Electrolytes Engaged Solid-State Rechargeable Zn-Air/Iodide Hybrid Batteries

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Angewandte Chemie 2022年第44期134卷

作者： Qingqing Liu Chenfeng Xia Chaohui He Wei Guo Zi Ping Wu Zhen Li Qiang Zhao Bao Yu Xia Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education) Hubei Key Laboratory of Material Chemistry and Service Failure School of Chemistry and Chemical Engineering Huazhong University of Science and Technology (HUST) 1037 Luoyu Rd Wuhan 430074 PR China Contribution: Conceptualization (lead) Data curation (lead) Investigation (lead) Validation (lead) Visualization (lead) Writing - original draft (lead) Writing - review & editing (equal) Contribution: Investigation (equal) Methodology (supporting) Validation (equal) Writing - original draft (equal) Contribution: Methodology (equal) Validation (equal) Contribution: Project administration (equal) Supervision (equal) Visualization (equal) School of Materials Science and Engineering Jiangxi University of Science and Technology (JXUST) Ganzhou 341000 PR China Contribution: Funding acquisition (equal) Project administration (equal) Resources (supporting) State Key Laboratory of Material Processing and Die & Mold Technology School of Materials Science and Engineering Huazhong University of Science and Technology 1037 Luoyu Rd Wuhan 430074 PR China Contribution: Resources (supporting) Validation (supporting) Writing - review & editing (supporting) Contribution: Data curation (supporting) Resources (supporting) Validation (supporting) Contribution: Conceptualization (lead) Project administration (lead) Supervision (lead) Writing - original draft (equal) Writing - review & editing (equal)

As a key component of batteries, the electrolyte determines the ion transport and interface chemistry of the cathode and anode. In this work, we develop a dual-network structured hydrogel electrolyte composed of polyacrylamide (PAM), sodium alginate (SA) and potassium iodide (KI) for solid-state zinc-air/iodide hybrid batteries. The assembled hybrid battery shows excellent renewability and a long cycling life of 110 h with a high energy efficiency of 80 %. The ion-crosslinked dual-network structure endows the material with improved mechanical strength and increased ionic conductivity. More importantly, the introduction of iodine species not only offers more favorable cathodic kinetics of iodide/iodate redox than oxygen electrocatalysis but also regulates the solvation structure of zinc ions to ensure better interface stability. This work provides significant concepts for developing novel solid-state electrolytes to realize high-performance energy devices and technologies.

关键词： Hydrogel Electrolyte Iodide/Iodate Redox Oxygen Electrocatalysis Solid-State Battery Solvation Effect

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Electron Acceptor Molecule Doping Induced π–π Interaction to Promote Charge Transport Kinetics for Efficient and Stable 2D/3D Perovskite Solar Cells

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Angewandte Chemie 2023年第26期135卷

作者： Lian Wang Bohong Chang Hui Li Yutong Wu Luyuan Zhang Longwei Yin Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials Ministry of Education School of Materials Science and Engineering Shandong University 250061 Jinan P. R.China Contribution: Conceptualization (lead) Data curation (lead) Formal analysis (lead) Investigation (lead) Methodology (lead) Writing - original draft (lead) Contribution: Data curation (supporting) Investigation (supporting) Methodology (supporting) Writing - original draft (supporting) Contribution: Formal analysis (supporting) Investigation (supporting) Methodology (supporting) Writing - original draft (supporting) Contribution: Conceptualization (supporting) Methodology (supporting) Writing - original draft (supporting) Contribution: Formal analysis (supporting) Investigation (supporting) Writing - original draft (supporting) Contribution: Conceptualization (lead) Data curation (lead) Funding acquisition (lead) Investigation (lead) Methodology (lead) Writing - original draft (lead)

Although the incorporation of 2D perovskite into 3D perovskite can greatly enhance intrinsic stability, power conversion efficiency (PCE) of 2D/3D perovskite is still inferior to its 3D counterpart due to poor carrier transport kinetics resulted from the quantum and dielectric confinement of 2D component. To overcome this issue, the electron acceptor molecule 1,2,4,5-tetracyanobenzene (TCNB) was introduced to trigger intermolecular π–π interaction in 2D perovskite along with the electronic doping of 2D/3D perovskite to improve charge transfer efficiency. By virtue of high electron affinity, TCNB can undergo electron transfer reaction and subsequently establish π–π interaction with 1-naphthalenemethylammonium (NMA) cations, greatly strengthening lattice rigidity and reducing exciton binding energy. Transmission electron microscopy results demonstrate that 2D phases are mainly distributed at grain boundaries, reducing defect density and weakening nonradiative recombination. Meanwhile, the p-type doping of perovskite by TCNB optimizes energy level alignment at perovskite/hole transport layer interface. Consequently, PCE of champion device is significantly boosted to 24.01 %. The unencapsulated device retains an initial efficiency close to 94 % after exposure to ambient environment for over 1000 h. This work paves a novel path for designing new mixed-dimensional perovskite solar cells with high PCE and superior stability.

关键词： 2D/3D Perovskite Charge Transport Electron Acceptor Molecule Solar Cells π–π Interaction

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Virus Detection: Nanopore Targeted Sequencing for the Accurate and Comprehensive Detection of SARS-CoV-2 and Other Respiratory Viruses (Small 32/2020)

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Small 2020年第32期16卷

作者： Ming Wang Aisi Fu Ben Hu Yongqing Tong Ran Liu Zhen Liu Jiashuang Gu Bin Xiang Jianghao Liu Wen Jiang Gaigai Shen Wanxu Zhao Dong Men Zixin Deng Lilei Yu Wu Wei Yan Li Tiangang Liu Department of Clinical Laboratory Renmin Hospital of Wuhan University Wuhan 430060 China Key Laboratory of Combinatorial Biosynthesis and Drug Discovery Ministry of Education and Wuhan University School of Pharmaceutical Sciences Wuhan 430071 China CAS Key Laboratory of Computational Biology CAS-MPG Partner Institute for Computational Biology Shanghai Institute of Nutrition and Health University of Chinese Academy of Sciences Chinese Academy of Sciences Shanghai 200031 China Wuhan Dgensee Clinical Laboratory Co. Ltd. Wuhan 430075 China Wuhan Institute of Virology Chinese Academy of Sciences Wuhan 430071 China Department of Internal Medicine Renmin Hospital of Wuhan University Wuhan 430060 China Center for Biomedical Informatics Shanghai Engineering Research Center for Big Data in Pediatric Precision Medicine Shanghai Children's Hospital Shanghai Jiao Tong University Shanghai 200040 China

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Bidirectional Tandem Electrocatalysis Manipulated Sulfur Speciation Pathway for High-Capacity and Stable Na-S Battery

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Angewandte Chemie 2022年第6期135卷

作者： Hong Zhang Bin Song Weiwei Zhang Bowen An Lin Fu Songtao Lu Yingwen Cheng Qianwang Chen Ke Lu Institutes of Physical Science and Information Technology School of Materials Science and Engineering Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education Anhui University Hefei Anhui 230601 China Hefei National Laboratory for Physical Sciences at the Microscale University of Science and Technology of China Hefei Anhui 230026 China Contribution: Conceptualization (equal) Writing - original draft (equal) Institute of Functional Nano & Soft Materials (FUNSOM) Soochow University Suzhou Jiangsu 215123 China Contribution: Data curation (supporting) Formal analysis (supporting) Writing - original draft (supporting) School of Chemistry and Chemical Engineering Qufu Normal University Qufu Shandong 273165 China School of Chemistry and Chemical Engineering Harbin Institute of Technology Harbin Heilongjiang 150001 China Contribution: Data curation (supporting) Investigation (supporting) Department of Chemistry and Biochemistry Northern Illinois University DeKalb IL 60115 USA Contribution: Formal analysis (supporting) School of Chemistry and Chemical Engineering Guizhou University Guiyang Guizhou 550025 China Contribution: Formal analysis (supporting) Writing - review & editing (supporting) Contribution: Data curation (supporting) Investigation (supporting) Writing - review & editing (supporting) Contribution: Writing - review & editing (equal) Contribution: Conceptualization (lead) Formal analysis (lead) Writing - original draft (lead) Writing - review & editing (lead)

The sluggish polysulfide redox kinetics and the uncontrollable sulfur speciation pathway, leading to serious shuttling effect and high activation barrier associated with sulfur cathode. We describe here the use of core–shell structured composite matrixes containing abundant catalytic sites for nearly fully reversible cycling of sulfur cathodes for Na-S batteries. The bidirectional tandem electrocatalysis provide successive reversible conversion of both long- and short-chain polysulfides, whereas Fe 2 O 3 accelerates Na 2 S 8 /Na 2 S 6 to Na 2 S 4 conversion and the redox-active Fe(CN) 6 4− -doped polypyrrole shell catalyzes Na 2 S 4 reduction to Na 2 S. The electrochemically reactive Na 2 S can be readily charged back to sulfur with minimal overpotential. Simultaneously, stable cycling of Na-S pouch cell with a high reversible capacity of 696 mAh g −1 is also demonstrated. The bidirectional confined tandem catalysis renders the manipulation of sulfur redox electrochemistry for practical Na-S cells.

关键词： Bidirectional Catalysts Confined Catalysis Na-S Battery Polysulfide Manipulation

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Intramolecular Chloro–Sulfur Interaction and Asymmetric Side-Chain Isomerization to Balance Crystallinity and Miscibility in All-Small-Molecule Solar Cells

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Angewandte Chemie 2022年第33期134卷

作者： Dr. Wei Gao Mengyun Jiang Ziang Wu Dr. Baobing Fan Dr. Wenlin Jiang Prof. Ning Cai Prof. Hua Xie Dr. Francis R. Lin Prof. Jingdong Luo Prof. Qiaoshi An Prof. Han Young Woo Prof. Alex K.-Y. Jen Department of Materials Science and Engineering City University of Hong Kong Kowloon 999077 Hong Kong Hong Kong Hong Kong Institute for Clean Energy City University of Hong Kong Kowloon 999077 Hong Kong Hong Kong Contribution: Data curation (lead) Methodology (lead) Writing - original draft (lead) Key Laboratory of Cluster Science of Ministry of Education Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials School of Chemistry and Chemical Engineering Beijing Institute of Technology Beijing 100081 China Contribution: Investigation (supporting) Department of Chemistry College of Science Korea University Seoul 136-713 Republic of Korea School of Chemical Engineering and Light Industry Guangdong University of Technology Guangzhou 510006 China School of Water Resources and Hydropower Wuhan University Wuhan 430072 China Department of Chemistry City University of Hong Kong Kowloon 999077 Hong Kong Hong Kong Contribution: Writing - review & editing (supporting) Contribution: Investigation (supporting) Methodology (supporting) Department of Materials Science and Engineering University of Washington Seattle WA 98195-2120 USA Contribution: Funding acquisition (lead) Supervision (lead) Writing - review & editing (lead)

Intramolecular Cl−S non-covalent interaction is introduced to modify molecular backbone of a benzodithiophene terthiophene rhodamine (BTR) benchmark structure, helping planarize and rigidify the molecular framework for improving charge transport. Theoretical simulations and temperature-variable NMR experiments clearly validate the existence of Cl−S non-covalent interaction in two designed chlorinated donors and explain its important role in enhancing planarity and rigidity of the molecules for enhancing their crystallinity. The asymmetric isomerization of side-chains further optimizes the molecular orientation and surface energy to strike a balance between its crystallinity and miscibility. This carefully manipulated molecular design helps result in increased carrier mobility and suppressed charge recombination to obtain simultaneously enhanced short-circuit current ( J sc ) and fill factor (FF) and a very high efficiency of 15.73 % in binary all-small-molecule organic solar cells.

关键词： Crystallinity Intramolecular Interaction Miscibility Small Molecule Donors Solar Cells

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Monodisperse Adducts-Induced Homogeneous Nucleation Towards High-Quality Tin-Based Perovskite Film

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Angewandte Chemie 2023年第33期135卷

作者： Huan Rao Yang Su Gengling Liu Hongbo Zhou Jia Yang Wangping Sheng Yang Zhong Prof. Licheng Tan Prof. Yiwang Chen College of Chemistry and Chemical Engineering/Institute of Polymers and Energy Chemistry (IPEC)/Jiangxi Provincial Key Laboratory of New Energy Chemistry Nanchang University 999 Xuefu Avenue Nanchang 330031 China Contribution: Investigation (lead) Methodology (lead) Writing - original draft (lead) Contribution: Investigation (equal) Methodology (equal) Writing - original draft (equal) Key Laboratory of Bioinorganic and Synthetic Chemistry (MoE) Lehn Institute of Functional Materials School of Chemistry Sun Yat-sen University Guangzhou 510006 China Contribution: Data curation (equal) Contribution: Software (equal) Contribution: Writing - review & editing (equal) Contribution: Resources (equal) Contribution: Investigation (equal) Peking University Yangtze Delta Institute of Optoelectronics 60 Chongzhou Avenue Nantong 226010 China Contribution: Resources (equal) Writing - review & editing (equal) National Engineering Research Center for Carbohydrate Synthesis/Key Laboratory of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education Jiangxi Normal University 99 Ziyang Avenue Nanchang 330022 China Contribution: Funding acquisition (lead) Methodology (equal)

The classic solvent system can't sufficiently separate one-dimensional edge-sharing SnI 2 crystals in solution, which severely restricts the fabrication of high-quality tin-based perovskite film. Herein, a strong Lewis base (hexamethylphosphoramide, HMPA) has been introduced to coordinate Sn 2+ to modulate solvation behaviours on perovskite precursor and regulate crystallization kinetics. The large molecular volume of HMPA and stronger bind energy of SnI 2 ⋅ 2HMPA (−0.595 eV vs −0.118 eV for SnI 2 ⋅ 2DMSO) change the solvation structure of SnI 2 from edge-sharing cluster to monodisperse adduct, which contributes to uniform nucleation sites and prolongs crystal growth process. Delightfully, a fully-covered perovskite film is formed on the large-area substrate and tin-based perovskite solar cells processed with HMPA exhibit an excellent efficiency of 13.46 %. This research provides novel insights and directions for the solution preparation of smooth and uniform large-area tin-based perovskite film.

关键词： Monodisperse Adduct Uniform Nucleation Crystallization Tin-Based Perovskite Solar Cells

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A Molybdenum Disulfide Nanozyme with Charge-Enhanced Activity for Ultrasound-Mediated Cascade-Catalytic Tumor Ferroptosis

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Angewandte Chemie 2022年第11期135卷

作者： Longwei Wang Xiaodi Zhang Zhen You Zhongwei Yang Dr. Mengyu Guo Jiawei Guo He Liu Xiaoyu Zhang Zhuo Wang Prof. Aizhu Wang Prof. Yawei Lv Dr. Jian Zhang Prof. Xin Yu Prof. Jing Liu Prof. Chunying Chen CAS Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety & CAS Center for Excellence in Nanoscience National Center for Nanoscience and Technology of China University of Chinese Academy of Science Beijing 100190 China Key Laboratory of Resource Biology and Biotechnology in Western China Ministry of Education School of Medicine Northwest University Xi'an 710069 China Contribution: Data curation (lead) Formal analysis (lead) Investigation (lead) Methodology (lead) Institute for Advanced Interdisciplinary Research School of Chemistry and Chemical Engineering University of Jinan Jinan 250022 China Contribution: Data curation (equal) Contribution: Investigation (equal) Methodology (equal) Contribution: Formal analysis (supporting) Contribution: Methodology (supporting) Contribution: Investigation (supporting) Contribution: Formal analysis (supporting) Software (lead) School of Physics and Electronics Hunan University Changsha 410082 China Contribution: Software (lead) Department of Biology and Biological Engineering Chalmers University of Technology Kemivägen 10 41296 Göteborg Sweden Contribution: Data curation (lead) Formal analysis (lead) Writing - original draft (lead) Contribution: Data curation (lead) Formal analysis (lead) Funding acquisition (equal) Writing - original draft (equal) Writing - review & editing (lead) Contribution: Conceptualization (lead) Funding acquisition (lead) Writing - review & editing (lead)

The deficient catalytic activity of nanozymes and insufficient endogenous H 2 O 2 in the tumor microenvironment (TME) are major obstacles for nanozyme-mediated catalytic tumor therapy. Since electron transfer is the basic essence of catalysis-mediated redox reactions, we explored the contributing factors of enzymatic activity based on positive and negative charges, which are experimentally and theoretically demonstrated to enhance the peroxidase (POD)-like activity of a MoS 2 nanozyme. Hence, an acidic tumor microenvironment-responsive and ultrasound-mediated cascade nanocatalyst (BTO/MoS 2 @CA) is presented that is made from few-layer MoS 2 nanosheets grown on the surface of piezoelectric tetragonal barium titanate (T-BTO) and modified with pH-responsive cinnamaldehyde (CA). The integration of pH-responsive CA-mediated H 2 O 2 self-supply, ultrasound-mediated charge-enhanced enzymatic activity, and glutathione (GSH) depletion enables out-of-balance redox homeostasis, leading to effective tumor ferroptosis with minimal side effects.

关键词： Ferroptosis Nanozymes Reactive Oxygen Species Tumor Therapy

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