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Calcium-magnesium-alumina-silicate(CMAS)resistant high entropy ceramic(Y_(0.2)Gd_(0.2)Er_(0.2)Yb_(0.2)Lu_(0.2))_(2)Zr_(2)O_(7) for thermal barrier coatings

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Journal of materials science & Technology 2022年第12期107卷 259-265页

作者： Shuxiang Deng Gang He Zengchao Yang Jingxia Wang Jiangtao Li Lei Jiang Key Laboratory of Cryogenics Technical Institute of Physics and ChemistryChinese Academy of SciencesBeijing 100190China Center of Materials Science and Optoelectronics Engineering University of the Chinese Academy of SciencesBeijing 100049China Key Laboratory of Bio-Inspired Materials and Interface Sciences Technical Institute of Physics and ChemistryChinese Academy of SciencesBeijing 100190China

A novel high-entropy material,(Y_(0.2)Gd_(0.2)Er_(0.2)Yb_(0.2)Lu_(0.2))_(2)Zr_(2)O_(7)was successfully synthesized by the solid state reaction method and spark plasma sintering,and investigated as a promising thermal barrier coating ***-earth elements were distributed homogeneously in the pyrochlore *** was found that the prepared high-entropy ceramic maintains pyrochlore structure at the temperature up to 1600℃,and it possesses a similar thermal expansion coefficient(10.2×10^(−6)K^(−1) at 25-900℃)to that of YSZ,low thermal conductivity(<0.9 W m^(-1)K^(−1) at 100-1000℃)and good CMAS resistance(infiltration depth is 22μm after annealed at 1300℃for 24 h).The corrosion process was investigated,and RE elements distributing homogeneously in(Y_(0.2)Gd_(0.2)Er_(0.2)Yb_(0.2)Lu_(0.2))_(2)Zr_(2)O_(7)show different diffusion rates in ***^(3+) with a larger radius(closer to Ca^(2+))is easier to react with CMAS to form an apatite phase.

关键词： High-entropy ceramic Pyrochlore structure Thermal barrier coating material CMAS resistance

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Pd Ensemble Sites Tuned Local Environment of Cu Catalysts for Matching Propyne Semi-Hydrogenation

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Angewandte Chemie 2025年

作者： Kelin Yan Dr. Xiaohu Ge Dr. Yueqiang Cao Qiang Yuwen Prof. Jing Zhang Prof. Sheng Dai Prof. Gang Qian Prof. De Chen Prof. Xinggui Zhou Prof. Weikang Yuan Prof. Xuezhi Duan State Key Laboratory of Chemical Engineering School of Chemical Engineering East China University of Science and Technology Shanghai 200237 China Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering Feringa Nobel Prize Scientist Joint Research Centre School of Chemistry and Molecular Engineering East China University of Science and Technology Shanghai 200237 China Department of Chemical Engineering Norwegian University of Science and Technology Trondheim 7491 Norway

Tailoring local environments of active sites to match targeted configuration of key species is significant for controlling reaction pathways in selective hydrogenations. Herein, differently typed Pd sites are introduced onto Cu catalysts to tune the local environment of Cu sites for controlling the configuration of semi-hydrogenation pathway of propyne hydrogenation used in production of polymer-grade propylene. Detailed structure characterizations demonstrate the controllable construction of Pd single-atom and Pd ensemble sites modified Cu surfaces and PdCu alloy via fine tuning the Pd/Cu ratios. Catalytic tests, kinetics analysis, and temperature-programmed experiments demonstrate that the presence of Pd ensemble sites on Cu surface directly catalyzes the hydrogenation of propyne that occurs on the Cu sites in other cases, and enables a facile activation for hydrogen and simultaneously promotes the desorption of propylene against its hydrogenation. Accordingly, the selectivity to target propylene is up to 95.3% at the full conversion of propyne on the corresponding Pd 0.1 Cu catalyst. In contrast, the C─C coupling pathway is quite facile on the Cu surface tuned by single-atom Pd sites, which is similar to that on the pristine Cu sites on the Cu catalyst, and the well-defined Pd─Cu coordination on PdCu alloy catalyst leads to facile over-hydrogenation process.

关键词： Configuration Ensemble sites Local environment Propyne semi-hydrogenation Reaction pathway

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Bio-based and Biodegradable Electrospun Fibers Composed of Poly(L-lactide) and Polyamide 4

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Chinese Journal of Polymer science 2020年第1期38卷 53-62,I0006页

作者： Tao Chen Guo-Cheng Zhong Yuan-Ting Zhang Li-Ming Zhao Yong-Jun Qiu School of Materials Science and Engineering East China University of Science and TechnologyShanghai 200237China Key Laboratory of Bio-based Material Engineering of China National Light Industry Council Shanghai200237China Shanghai Key Laboratory of Advanced Polymeric Materials Shanghai200237China School of Biotechnology East China University of Science and TechnologyShanghai200237China

Novel bio-based and biodegradable block copolymers were synthesized by "click" reaction between poly(L-lactide)(PLLA) and polyamide 4(PA4). Upon tuning the molar mass of PLLA block, the properties of copolymers and electrospun ultrafine fibers were investigated and compared with those of PLLA and PA4 blends. PLLA and PA4 were found incompatible and formed individual crystalline regions, along with reciprocal inhibition in crystallization. Electrospun fibers were highly hydrophobic, even if hydrophilic PA4 was the rich component. The crystallinity of either PLLA or PA4 decreased after electrospinning and PLLA-rich as-spun fibers were almost amorphous. Immersion tests proved that fibers of block copolymers were relatively homogeneous with micro-phase separation between PLLA and PA4. The fibrous structures of copolymers were different from those of the fibers electrospun from blends, for which sheath-core structure induced by macro-phase separation between homopolymers of PLLA and PA4 was confirmed by TEM, EDS, and XPS.

关键词： Poly(L-lactide) Polyamide 4 "Click"reaction Electrospinning Fiber

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Discovery of carbon-based strongest and hardest amorphous material

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National science Review 2022年第1期9卷 25-35页

作者： Shuangshuang Zhang Zihe Li Kun Luo Julong He Yufei Gao Alexander V.Soldatov Vicente Benavides Kaiyuan Shi Anmin Nie Bin Zhang Wentao Hu Mengdong Ma Yong Liu Bin Wen Guoying Gao Bing Liu Yang Zhang Yu Shu Dongli Yu Xiang-Feng Zhou Zhisheng Zhao Bo Xu Lei Su Guoqiang Yang Olga P.Chernogorova Yongjun Tian Center for High Pressure Science (CHiPS) State Key Laboratory of Metastable Materials Science and Technology Yanshan University Key Laboratory for Microstructural Material Physics of Hebei Province School of Science Yanshan University Department of Engineering Sciences and Mathematics Lule a University of Technology Department of Physics Harvard University Center for High Pressure Science and Technology Advanced Research Department of Materials Science Saarland University Key Laboratory of Photochemistry Institute of Chemistry University of Chinese Academy of Sciences Baikov Institute of Metallurgy and Materials Science Russian Academy of Sciences

Carbon is one of the most fascinating elements due to its structurally diverse allo tropic forms stemming from its bonding varieties(sp,sp~2 and sp~3).Exploring new forms of carbon has been the eternal theme of scientific ***,we report on amorphous(AM) carbon materials with a high fraction of sp~3 bonding recovered from compression of fullerene C60 under high pressure and high temperature,previously *** of photoluminescence and absorption spectra demonstrates that they are semiconducting with a bandgap range of 1.5-2.2 eV,comparable to that of widely used AM *** mechanical tests demonstrate that synthesized AM-Ⅲ carbon is the hardest and strongest AM material known to date,and can scratch diamond crystal and approach its *** produced AM carbon materials combine outstanding mechanical and electronic properties,and may potentially be used in photovoltaic applications that require ultrahigh strength and wear resistance.

关键词： amorphous carbon ultrahard ultrastrong semiconductor phase transition

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interface Modification of TiO_(2)Electron Transport Layer with PbCl_(2)for Perovskiote Solar Cells with Carbon Electrode

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Tsinghua science and Technology 2022年第4期27卷 741-750页

作者： Abolfazl Amraeinia Yuhua Zuo Jun Zheng Zhi Liu Guangze Zhang Liping Luo Buwen Cheng Xiaoping Zou Chunbo Li Key Laboratory on Integrated Optoelectronics Institute of SemiconductorChinese Academy of SciencesBeijing 100083China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China Beijing Advanced Innovation Center for Materials Genome Engineering Beijing Key Laboratory for SensorMOE Key Laboratory for Modern Measurement and Control TechnologyBeijing Information Science and Technology UniversityBeijing 100101China School of Science Minzu University of ChinaBeijing 100081China

Perovskite Solar Cells(PSCs)have attracted considerable attention because of their unique features and high ***,the stability of perovskite solar cells remains to be *** this study,we modified the TiO_(2)Electron Transport Layer(ETL)interface with PbCl_(2).The efficiency of the perovskite solar cells with carbon electrodes increased from 11.28%to 13.34%,and their stability obviously *** addition of PbCl_(2)had no effect on the morphology,crystal structure,and absorption property of the perovskite absorber ***,it affected the band energy level alignment of the solar cells and accelerated the electron extraction and transfer at the interface between the perovskite layer and the ETL,thus enhancing the overall photovoltaic *** interfacial modification of ETL with PbCl_(2)is a promising way for the potential commercialization of low-cost carbon electrode-based perovskite solar cells.

关键词： Perovskite Solar Cell(PSC) Electron Transport Layer(ETL) electron and hole recombination modification stability

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Ti_(3)C_(2)T_(x) MXene in-situ transformed Li_(2)TiO_(3) interface layer enabling 4.5 V-LiCoO_(2)/sulfide all-solid-state lithium batteries with superior rate capability and cyclability

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Chinese Chemical Letters 2024年第6期35卷 195-200页

作者： Yaping Wang Pengcheng Yuan Zeyuan Xu Xiong-Xiong Liu Shengfa Feng Mufan Cao Chen Cao Xiaoqiang Wang Long Pan Zheng-Ming Sun Key Laboratory of Advanced Metallic Materials of Jiangsu Province School of Materials Science and EngineeringSoutheast UniversityNanjing 211189China CALB Technology Co. Ltd.Changzhou 213200China

All-solid-state lithium batteries(ASSLBs)based on sulfide electrolytes promise next-generation energy storage with high energy density and ***,the sulfide electrolytes suffer from phase instability and sluggish interfacial charge transport when pairing with layered oxide cathodes at high ***,a simple and efficient strategy is proposed using two-dimensional Ti_(3)C_(2)T_(x)MXene as starting material to in-situ construct a 15 nm Li_(2)TiO_(3) layer on a typical oxide cathode,LiCoO_(2).The in-situ transformation of Ti_(3)C_(2)T_(x)into Li_(2)TiO_(3) layer occurs at a low temperature of 500℃,avoiding the phase deterioration of LiCoO_(2).The thin Li_(2)TiO_(3) layer is Li^(+)conducting and electrochemically stable,thereby preventing the interfacial decomposition of sulfide electrolytes induced by LiCoO_(2) at high voltages and facilitating Li+transport at the ***,Li_(2)TiO_(3) can stabilize the layer structure of LiCoO_(2) at high ***,the sulfide-based ASSLB using LiCoO_(2)@Li_(2)TiO_(3) cathode can operate stably at a high voltage of up to 4.5 V(***+/Li),delivering an outstanding initial specific discharge capacity of 138.8 m Ah/g with a high capacity retention of 86.2% after 100 cycles at 0.2 *** in-situ transformation strategy may also apply to other MXenes,offering a general approach for constructing other advanced lithiated coatings for oxide cathodes.

关键词： Solid sulfide electrolyte Oxide cathode MXene In-situ transformation Li_(2)TiO_(3) interfacial layer

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Self-sensing tribological coating with phosphor particles for wear indicator

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Rare Metals 2023年第7期42卷 2462-2469页

作者： Ling He Xue-Yan Wu Wen-Sheng Li Mi-Na Zhang Shu-Jie Liu State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals Lanzhou University of TechnologyLanzhou730050China School of Materials Science and Engineering Lanzhou University of TechnologyLanzhou730050China

Monitoring of coating health was achieved by embedding sensor materials(MAl_(2)O_(4):Eu^(2+),Dy^(3+),M=Sr,Ba)in tribological *** the luminescence disappears under ultraviolet(UV)light,it means that the functional coating is worn out and that recoating is *** this work,four types of alloy(Cu-14Al-X,Cu,Cu-Al,Al)composite coatings were investigated by vacuum pres sure-as sis ted sintering *** composite coatings with different copper-aluminium alloy matrixes were compared by phase composition,microstructure,luminescence properties and tribological *** results indicate that the Cu-14Al-X matrix composite coating shows not only good resistance to wear but also exhibits strong green light emitting under ultraviolet(UV)*** is the best wear-resistant self-sensitive coating which has potential industrial *** the coating wore or broke,the emitting intensity will decrease or disappear.

关键词： Copper-aluminium alloy coatings Luminescent powders Wear indicator Luminescent spectroscopy Tribology

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Effects of Adsorption of Albumin and Gamma-Globulin on the Tribological Performance of a Diamond-Like Carbon Film

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Journal of Wuhan University of Technology(materials science) 2019年第5期34卷 1103-1108页

作者： WU Bingjie LENG Yongxiang Key Laboratory for Advanced Technologies of Materials Ministry of EducationSchool of Materials Science and EngineeringSouthwest Jiaotong UniversityChengdu 610031China Quantum Materials Research Center School of Physics and Electronic EngineeringZhengzhou Normal UniversityZhengzhou 450044China

The effects of surface adsorption of bovine serum albumin(BSA) and human gamma-globulin(HGG) on the tribological performance of a DLC film were investigated using a quartz crystal microbalance with dissipation(QCM-D), a ball-on-disk reciprocating tribometer, and a three-electrode electrochemical cell. The results showed that the wear depth in the BSA solution was higher than that in the HGG solution. In the HGG solution, the HGG-adsorbed layer could act as a lubricating layer and protect the DLC film from wear. The wear volume of DLC film in BSA and HGG mixture solution was higher than that in single HGG solution. This may be because the BSA molecules inhibit the formation of HGG adsorbed layer during sliding.

关键词： Diamond like carbon(DLC) Quartz crystal microbalance with dissipation(QCM-D) Adsorbed layer Wear

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Comparison of Microstructure and Residual Stress Between TIG and MAG Welding Using Low Transformation Temperature Welding Filler

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Acta Metallurgica Sinica(English Letters) 2018年第3期31卷 263-272页

作者： Zhong-Yuan Feng Xin-Jie Di Shi-Pin Wu Dong-Po Wang Xiao-Qian Liu School of Materials Science and Engineering Tianjin UniversityNo.135 Yaguan RoadJinnan DistrictTianjin 300350China Tianjin Key Laboratory of Advanced Joining Technology Tianjin 300350 China

A Cr-Ni type of low transformation temperature（LTT）welding filler was devised in the present *** LTT weld microstructures of the tungsten inert gas（TIG）and metal active gas（MAG）weldings were investigated by using electron-backscattered diffraction and orientation imaging *** results showed that the LTT weld microstructures prepared by TIG and MAG weldings were primarily martensite with 17.5% and 8.0% retained austenite,*** LTT weld metal using TIG welding had larger grain size than using *** addition,based on the Taylor factor calculation,the weld metal using MAG welding was more competent in repressing fatigue crack ***,the high angle and coincidence site lattice grain boundaries were dominant in the LTT weld metal using MAG ***,the hardness of the LTT weld metal using MAG welding was higher than that of using *** on heat input and phase transformation,finite element method was applied to analyzing the tensile residual stress（RS）reduction in welded joints prepared by both conventional and LTT welding fillers,*** corresponding outcome confirmed that the LTT weld metal using MAG welding was more beneficial to tensile RS reduction.

关键词： Martensitic transformation Taylor factor Grain boundaries Residual stress

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A Study of Nano materials and Their Reactions in Liquid Using in situ Wet Cell TEM Technology

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Chinese Journal of Chemistry 2012年第12期30卷 2839-2843页

作者： Chen Xin Zhou Lihui Wang Ping Zhao Chongjun Miao Xiaoli Key Laboratory for Ultrafine Materials of Min&try of Education and Shanghai Key Laboratory of Advanced Polymeric Materials School of Materials Science and Engineering East China University of Science and Technology Shanghai 200237 China Department of Materials Science andEngineering University of Illinois at Urbana-Champaign Urbana IL 61801 USA East China University of Science and Technology Shanghai 200237 China State Key Laboratory of Bioreactor Engineering Biomedical Nanotechnology Center East China University of Science and Technology Shanghai 200237 China

Several nano material and reaction systems were in situ monitored with an electrochemical TEM wet cell set up. In a 1 g/L sliver particle aqueous solution, the particles were observed to be ca. 10 nm sized, in both discrete particle and nano cluster forms. The silver particles were attached to the 50 nm-thick Si3N4 windows of the wet cell and could not move freely in the liquid. With a SIC14 liquid loaded in the wet cell, silicon nano materials were controllably grown on the wet cell windows by means of a liquid phase electron beam induced deposition （EBID） method. The deposited nano dots were nicely round-shaped, and demonstrated a power law growth dependency on beam exposure time in a log-log plot. In a NiCI2 solution/Ni system, both electrochemical deposition and dissolution of the nickel nano films were observed while applying electric biases on to the nickel electrodes in the wet cell. Instead of extensional growth on existing crystals, interestingly, it is more commonly observed that new nickel nano particles grow out in front of the existing film first and then merged into the film. The wet cell set up is demonstrated to be a versatile tool for nano liquid system research.

关键词： in situ TEM nano material electrochemical reaction electron beam induced deposition semiconductor

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