检索结果-内蒙古大学图书馆

Mg-doped,carbon-coated,and prelithiated SiO_(x) as anode materials with improved initial Coulombic efficiency for lithium-ion batteries

引用

Carbon Energy 2024年第3期6卷 204-214页

作者： Bin Liu Jie Liu Cheng Zhong Wenbin Hu Key Laboratory of Advanced Ceramics and Machining Technology(Ministry of Education) School of Materials Science and EngineeringTianjin UniversityTianjinChina Tianjin Key Laboratory of Composite and Functional Materials School of Materials Science and EngineeringTianjin UniversityTianjinChina Joint School of National University of Singapore and Tianjin University TianjinChina International Campus of Tianjin University Binhai New CityFuzhouChina

Silicon suboxide(SiO_(x),x≈1)is promising in serving as an anode material for lithium-ion batteries with high capacity,but it has a low initial Coulombic efficiency(ICE)due to the irreversible formation of lithium silicates during the first *** this work,we modify SiO_(x) by solid-phase Mg doping reaction using low-cost Mg powder as a reducing *** show that Mg reduces SiO_(2) in SiO_(x) to Si and forms MgSiO_(3) or Mg_(2)SiO_(4).The MgSiO_(3) or Mg_(2)SiO_(4) are mainly distributed on the surface of SiO_(x),which suppresses the irreversible lithium-ion loss and enhances the ICE of SiO_(x).However,the formation of MgSiO_(3) or Mg_(2)SiO_(4) also sacrifices the capacity of SiO_(x).Therefore,by controlling the reaction process between Mg and SiO_(x),we can tune the phase composition,proportion,and morphology of the Mg-doped SiO_(x) and manipulate the *** obtain samples with a capacity of 1226 mAh g^(–1) and an ICE of 84.12%,which show significant improvement over carbon-coated SiO_(x) without Mg *** the synergistical modification of both Mg doping and prelithiation,the capacity of SiO_(x) is further increased to 1477 mAh g^(–1) with a minimal compromise in the ICE(83.77%).

关键词： initial Coulombic efficiency lithium-ion batteries magnesium doping prelithiation silicon suboxide

来源：评论

学校读者我要写书评

暂无评论

Single-Molecule Confinement Induced Intrinsic Multi-Electron Redox-Activity to Enhance Supercapacitor Performance

引用

Energy & Environmental materials 2023年第4期6卷 227-238页

作者： Su Yang Meiling Wang Yong Zhang Pinyi He Wenhua Cong Chongji Wang Qiankun Yang Xuguang Liu Tian Wang Xianming Zhang Jiadong Zhou College of Materials Science and Engineering Taiyuan University of TechnologyTaiyuan 030024China Key Lab of Advanced Optoelectronic Quantum Architecture and Measurement(Ministry of Education) Beijing Key Lab of Nanophotonics&Ultrafine Optoelectronic Systemsand School of PhysicsBeijing Institute of TechnologyBeijing 100081China School of Materials Science and engineering Central South UniversityChangsha 410083China Department of Chemistry National University of Singapore3 Science Drive 3117543Singapore Key Laboratory of Interface Science and Engineering in Advanced Materials Ministry of Education (Taiyuan University of Technology)Taiyuan 030024China

Aggregation of polyoxometalates(POM)is largely responsible for the reduced performance of POM-based energy-storage *** address this challenge,here,the precise confinement of single Keggin-type POM molecule in a porous carbon(PC)of unimodal super-micropore(micro-PC)is *** precise single-molecule confinement enables sufficient activity center exposure and maximum electron-transfer from micro-PC to POM,which well stabilizes the electron-accepting molecules and thoroughly activates its inherent multi-electron *** particular,the redox-activities and electron-accepting properties of the confined POM molecule are revealed to be super-micropore pore size-dependent by experiment and spectroscopy as well as theoretical ***,the molecularly dispersed POM molecules confined steadily in the“cage”of micro-PC exhibit unprecedented large-negative-potential stability and multiple-peak redox-activity at an ultra-low loading of~11.4 wt%.As a result,the fabricated solid-state supercapacitor achieves a remarkable areal capacitance,ultrahigh energy and power density of 443 mF cm^(-2),0.12 mWh cm^(-2)and 21.1 mW cm^(-2),*** work establishes a novel strategy for the precise confinement of single POM molecule,providing a versatile approach to inducing the intrinsic activity of POMs for advanced energy-storage systems.

关键词： intrinsic redox-activity polyoxometalates single-molecule confinement supercapacitor

来源：评论

学校读者我要写书评

暂无评论

Tunable polarization-drived superior energy storage performance in PbZrO_(3) thin films

引用

Journal of advanced Ceramics 2023年第5期12卷 930-942页

作者： Tiandong Zhang Zhuangzhuang Shi Chao Yin Changhai Zhang Yue Zhang Yongquan Zhang Qingguo Chen Qingguo Chi Key Laboratory of Engineering Dielectrics and Its Application Ministry of EducationHarbin University of Science and TechnologyHarbin 150080China Department of Materials Science and Engineering Korea Advanced Institute of Science and TechnologyDaejeon 305-701Republic of Korea

Antiferroelectric PbZrO_(3)(AFE PZO)films have great potential to be used as the energy storage dielectrics due to the unique electric field(E)-induced phase transition ***,the phase transition process always accompanies a polarization(P)hysteresis effect that induces the large energy loss(Wloss)and lowers the breakdown strength(EBDS),leading to the inferior energy storage density(Wrec)as well as low *** this work,the synergistic strategies by doping smaller ions of Li^(+)–Al^(3+)to substitute Pb2+and lowering the annealing temperature(T)from 700 to 550℃are proposed to change the microstructures and tune the polarization characters of PZO films,except to dramatically improve the energy storage *** prepared Pb_((1−x))(Li_(0.5)Al_(0.5))_(x)ZrO_(3)(P_((1−x))(L_(0.5)A_(0.5))_(x)ZO)films exhibit ferroelectric(FE)-like rather than AFE character once the doping content of Li^(+)–Al^(3+)ions reaches 6 mol%,accompanying a significant improvement of W_(rec) of 49.09 J/cm^(3),but the energy storage efficiency(η)is only 47.94%due to the long-correlation of FE ***,the low-temperature annealing is carried out to reduce the crystalline degree and the P loss.P_(0.94)(L_(0.5)A_(0.5))_(0.06)ZO films annealed at 550℃deliver a linear-like polarization behavior rather than FE-like behavior annealed at 700℃,and the lowered remanent polarization(P_(r))as well as improved E_(BDS)(4814 kV/cm)results in the superior Wrec of 58.7 J/cm^(3) and efficiency of 79.16%,simultaneously possessing excellent frequency and temperature stability and good electric fatigue tolerance.

关键词： lead zirconate ionic pair polarization breakdown strength energy storage

来源：评论

学校读者我要写书评

暂无评论

Ultrafast synthesis of nanocrystalline spinel oxides by Joule-heating method

引用

Chinese Chemical Letters 2024年第11期35卷 517-521页

作者： Wenxuan Yang Long Shang Xiaomeng Liu Sihan Zhang Haixia Li Zhenhua Yan Jun Chen State Key Laboratory of Advanced Chemical Power Sources Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education)Frontiers Science Center for New Organic MatterCollege of ChemistryNankai UniversityTianjin 300071China

Spinel oxides,with the formula AB_(2)O_(4)(A and B represent metal ions)perform superior electrocatalytic characteristic when A and B are transition metals like Co,Fe,Mn,*** researches have been attached to the structure designments while methods are often energy-intensive and ***,we devised a universal strategy to achieve rapid synthesis of nanocrystalline spinel materials with multiple components(Co_(3)O_(4),Mn_(3)O_(4),CoMn_(2)O_(4)and CoFe_(2)O_(4)are as examples),where phase formation is within 15 *** the Joule-heating shock,a crack-break process of microcosmic phase transformation is observed by in-situ transmission electron *** half-wave potential values of Co_(3)O_(4)-JH,Mn_(3)O_(4)-JH,CoMn_(2)O_(4)-JH and CoFe_(2)O_(4)-JH in the electrocatalytic oxygen reduction reaction were 0.77,0.78,0.79 and 0.76,*** suggests that the Joule heating is a fast and efficient method for the preparation of spinel oxide electrocatalysts.

关键词： Ultrafast synthesis Spinel oxides Joule-heating In-situ TEM Oxygen reduction

来源：评论

学校读者我要写书评

暂无评论

Unveiling the twinning and dynamic recrystallization behavior and the resultant texture evolution in the extruded Mg-Bi binary alloys during hot compression

引用

Journal of materials science & Technology 2022年第10期105卷 274-285页

作者： Yu-qin Zhang Wei-li Cheng Hui Yu Hong-xia Wang Xiao-feng Niu Li-fei Wang Hang Li School of Materials Science and Engineering Taiyuan University of TechnologyTaiyuan 030024China Key Laboratory of Interface Science and Engineering in Advanced Materials Ministry of Education Taiyuan University of TechnologyTaiyuan 030024China School of Materials Science and Engineering Hebei University of TechnologyTianjin 300132China

The twinning behavior, dynamic recrystallization(DRX) mechanism and the resultant texture evolution of the extruded Mg-xBi(x=0.5 wt.%, 2.0 wt.%) alloys were systematically investigated during hot compression at the strain rate of 10 s^(-1) and temperature of 200℃. The results indicate that the types and intensities of the texture are greatly dependent on the twining behavior and DRX mechanism. At the initial stage, the evolution of texture is mainly domination by the formation and variation of {1012} extension twins, which is benefcial to the compression direction(CD)-tilted basal texture. With an increase in the strain, the texture evolution is more greatly regulated by the DRX mechanism. Besides, the pyramidal slip and basal slip are activated during the compression process, resulting in the Schmid factors(SF) of pyramidal slip remain at ~0.4 and the average SFs for basal slip increase from 0.2 to0.34 as the strain increase. These fndings provide a new insight into controlling the texture of wrought Mg-Bi-based alloys during hot deformation processing.

关键词： Wrought Mg-Bi alloys Hot deformation Twinning Dynamic recrystallization Dislocation slip Texture

来源：评论

学校读者我要写书评

暂无评论

Enhanced room temperature CO2 photoreduction on gas-solid interfaces using nanocrystals integrated with ZIF-8 wrapping design

引用

材料科学技术（英文版） 2025年第6期209卷 55-63页

作者： Xiaoxiong Hou Zhuangzhuang Ma Zhilei Zhang Xiaotong Gao Hongqiang Wang Lichao Jia Key Laboratory of Applied Surface and Colloid Chemistry Shaanxi Key Laboratory for Advanced Energy DevicesShaanxi Engineering Lab for Advanced Energy TechnologySchool of Materials Science and EngineeringNational Ministry of EducationShaanxi Normal UniversityXi'an 710119China Beijing National Laboratory for Molecular Sciences Key Laboratory of Organic SolidsInstitute of ChemistryChinese Academy of SciencesBeijing 100190China University of the Chinese Academy of Sciences Beijing 100049China State Key Laboratory of Solidification Processing Center for Nano Energy MaterialsSchool of Materials Science and EngineeringNorthwestern Polytechnical University and Shaanxi Joint Laboratory of GrapheneXi'an 710072China

Composites derived from metal-organic frameworks(MOFs)show promise as catalysts for the photocat-alytic reduction of ***,their potential is hindered by constraints such as limited light absorp-tion and sluggish electron transfer and separation,impacting the overall efficiency of the photocatalytic *** this study,TiO2 nanocrystals,modified with Ptx+,underwent laser etching were encapsulated within the traditional MOF-ZIF-8 *** enhanced the adsorption capabilities for CO2 reactants and solar light,while also facilitating directed electron transfer and the separation of photogenerated *** finely-tuned catalyst demonstrates impressive CH4 selectivity at 9.5％,with yields of 250.24 μmol g-1 h-1 for CO and 25.43 μmol g-1 h-1 for CH4,utilizing water as a hole trap and H+*** study demonstrates the viability of achieving characteristics related to the separation of photogen-erated charges in TiO2 nanocrystals through laser etching and MOF composite *** offers novel perspectives for designing MOF-based catalysts with enhanced performance in artificial photosynthesis.

关键词： CO2 photoreduction Nanocrystals TiO2 ZIF-8 Wrapping structure

来源：评论

学校读者我要写书评

暂无评论

Coordination-environment regulation of atomic Co-Mn dual-sites for efficient oxygen reduction reaction

引用

Nano Research 2024年第8期17卷 6841-6848页

作者： Caiting Sun Yarong Liu Zunhang Lv Rui Liu Changli Wang Liuhua Li Jinming Wang Yu Zhang Wenxiu Yang Bo Wang Key Laboratory of Cluster Science(Ministry of Education) Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion MaterialsAdvanced Technology Research Institute(Jinan)Advanced Research Institute of Multidisciplinary ScienceSchool of Chemistry and Chemical EngineeringBeijing Institute of TechnologyBeijing 100081China Beijing Institute of Technology Library Beijing Institute of TechnologyBeijing 100081China

Precisely designing atomic metal-nitrogen-carbon(M-N-C)catalysts with asymmetric diatomic configurations and studying their structure–activity relationships for oxygen reduction reaction(ORR)are important for zinc-air batteries(ZABs).Herein,a dualatomic-site catalyst(DASC)with CoN_(3)S-MnN_(2)S_(2) configuration was prepared for the cathodes of *** with Co-N-C(Mn-free)and CoMn-N-C(S-free doping),CoMn-N/S-C exhibits excellent half-wave potential(0.883 V)and turnover frequency(1.54 e·s^(−1)·site^(−1)),surpassing most of the reported state-of-the-art Pt-free ORR *** CoMn-N/S-C-based ZABs achieve extremely high specific capacity(959 mAh·g^(−1))and good stability(350 h@5 mA·cm^(−2)).Density functional theory(DFT)calculation shows that the introduction of Mn and S can break the electron configuration symmetry of the original Co 3d orbital,lower the dband center of the Co site,and optimize the desorption behavior of*OH intermediate,thereby increasing the ORR activity.

关键词： metal organic frameworks oxygen reduction reaction dual-atom catalyst coordination-environment regulation zinc-air batteries

来源：评论

学校读者我要写书评

暂无评论

High thermoelectric performance of flexible Ag/Ag_(2)Se composite film on nylon for low-grade energy harvesting

引用

Journal of materials science & Technology 2024年第12期179卷 79-85页

作者： Ying Liu Jiajia Li Zixing Wang Ping Wei Wenyu Zhao Lidong Chen Kefeng Cai Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education Shanghai Key Laboratory of Development and Application for Metal-Functional MaterialsSchool of Materials Science&EngineeringTongji UniversityShanghai 201804China State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of CeramicsChinese Academy of SciencesShanghai 200050China University of Chinese Academy of Sciences Beijing 100049China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

In this work,Ag/Ag_(2)Se composite films with excellent thermoelectric(TE)properties and flexibility are prepared based on a simple one-pot *** adjusting the nominal ratios of Ag/Se,an optimal Ag/Ag_(2)Se composite film shows a large power factor of~2275 μW m^(-1) K^(-2) at 300 *** an outstand-ing TE performance of the composite film is due to the unique microstructure and the synergistic effect between the Ag and Ag_(2)***,the composite film also shows outstanding flexibility(~91.8%of the initial electrical conductivity is maintained,and the S is unchanged after 1500 bending cycles with a bending radius of 4 mm).Furthermore,a 4-leg flexible TE generator assembled with the optimal film produces a voltage of 14.06 mV and 4.96 μW at a temperature difference of 30.4 *** work provides a new inspiration for the preparation of flexible Ag_(2)Se-based films with excellent TE performance near room temperature.

关键词： Thermoelectric Ag/Ag_(2)Se Flexible Film Power generator

来源：评论

学校读者我要写书评

暂无评论

Achieving large near-linear elasticity,low modulus,and high strength in a metastable β-Ti alloy by mild cold rolling

引用

Journal of materials science & Technology 2024年第22期189卷 1-12页

作者： Yu Fu Wenlong Xiao Jian Rong Lei Ren Huabei Peng Yuhua Wen Xinqing Zhao Chaoli Ma Key Laboratory of Aerospace Advanced Materials and Performance of Ministry of Education School of Materials Science and EngineeringBeihang UniversityBeijing 100191China Scholl of Mechanical Engineering Sichuan UniversityChengdu 610065China Tianmushan Laboratory Hangzhou 310023China Key Laboratory of Mechanics in Fluid Solid Coupling Systems Institute of MechanicsChinese Academy of SciencesBeijing 100190China

Simultaneously achieving high elasticity,low modulus,and high strength in Ti alloy has been a long-standing *** this study,cold rolling was conducted to modulate the martensitic transformation of the Ti-15Nb-5Zr-4Sn-1Fe alloy to address this *** 10%cold rolling process was primarily accommodated by a novel stress-induced sequential β-to-α″-to-α′martensitic transformation accompanied by the disappearance of ω phase,which was sufficient to induce adequate martensite and defects to suppress the initial rapid stress-induced martensitic transformation,without destroying the equiaxed shape of prio rβ ***,the novel sequential phase transformation led to a substantial decrease in Young’s modulus by 50.5%while increasing the strength,resulting in an excellent combination of large near-linear elasticity of 2.34%,low modulus of 45 GPa,and high strength of 1093 *** obtained large near-linear elasticity was mainly contributed by the concurrent low modulus and high strength obeying Hooke’s *** findings provide valuable insights into the attainment of concurrent high elasticity and low modulus in Ti alloys by regulating the stress-induced sequential martensitic transformation.

关键词： Titanium alloys Martensitic transformation Young’s modulus Elasticity Mechanical properties

来源：评论

学校读者我要写书评

暂无评论

Photoinduced interface activation strategy for enhancing photocatalytic hydrogen production performance of plasmonic nano Bi/Ni based metalorganic framework

引用

science China materials 2024年第10期67卷 3151-3159页

作者： Baichao Zhang Xuchuan Cao Chao Suo Jing Cui Xiaochuan Duan Shaohui Guo Xian-Ming Zhang Key Laboratory of Interface Science and Engineering in Advanced Materials Ministry of EducationCollege of ChemistryCollege of Chemical Engineering and TechnologyTaiyuan University of TechnologyTaiyuan 030024China

Utilizing plasmonic non-noble metal nanoparticles(NPs)for photocatalytic hydrogen evolution reaction is a significant step toward green energy ***,optimizing the interface between non-noble metal NPs and semiconducting materials in metal-semiconductor composites remains challenging owing to the inevitable surface oxide layers of non-noble metal NPs because the surface oxide layers of non-noble metal NPs can suppress the transfer of photoinduced carriers,leading to poor photocatalytic ***,we propose a photoinduced interface activation strategy to reduce the number of oxide layers based on a dynamic charge-transfer mechanism under illumination conditions,with Bi NPs and a Ni-based metal-organic framework(MOF)selected as model *** light illumination,the photoinduced charges and plasmonic hot electrons heavily pooled at the interface between the Bi NPs and Ni-MOF,resulting in the reduction of the oxide layer on the surface of Bi,thus attenuating its hindering effect on charge *** phenomenon led to a dynamically enhanced carrier concentration in the Bi/Ni-MOF composite,with an outstanding photocatalytic hydrogen evolution rate of 5822μmol g^(−1)h^(−1)achieved with the *** results of this study indicate that our strategy provides a new method for optimizing plasmonic non-noble metal Bi NPs with oxide layers.

关键词： plasmonic non-noble metal interface activation metal-organic framework charge transfer photocatalytic hydrogen

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：