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Electrochemical dissolution, reduction, and nucleation mechanisms of molybdenum in NaCl-KCl molten salt systems

Journal of Materials Science and Technology 2025年 238卷 45-54页

作者： Lv, Hongzhan Zhang, Liwen Xi, Xiaoli Nie, Zuoren Collaborative Innovation Center of Capital Resource-Recycling Material Technology Beijing University of Technology Beijing100124 China Key Laboratory of Advanced Functional Materials Ministry of Education Faculty of Materials and Manufacturing Beijing University of Technology Beijing100124 China National Engineering Laboratory for Industrial Big-data Application Technology Beijing University of Technology Beijing100124 China

This study investigates the anodic dissolution and electrochemical behavior of molybdenum in a NaCl-KCl molten salt system at 1023 K. The anodic dissolution process was systematically analyzed, revealing a sequential oxidation pathway of molybdenum into high-valence ions (Mo6+, Mo5+, Mo4+) under varying electrolysis potentials. Electrochemical Impedance Spectroscopy (EIS) demonstrated that the dissolution is governed by both charge transfer and diffusion mechanisms, with reduced impedance at higher potentials facilitating molybdenum dissolution. The reduction behavior of dissolved molybdenum ions was further explored using cyclic voltammetry (CV) and square wave voltammetry (SWV), confirming a multi-step reduction process controlled by diffusion and high reversibility. Nucleation studies using chronoamperometry established that molybdenum deposition follows an instantaneous nucleation mechanism. Morphological analysis of cathodic deposits revealed that current density significantly influences particle size, transitioning from nano-sized spherical particles to larger equiaxed crystals with increasing current density. These findings provide a comprehensive understanding of molybdenum's electrochemical properties in molten salts, offering valuable insights for optimizing electrolysis processes and advancing molybdenum-based material production. © 2025

关键词： Cyclic voltammetry

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Efficient Homomorphic Approximation of Max Pooling for Privacy-Preserving Deep Learning 6th

Efficient Homomorphic Approximation of Max Pooling for Pri...

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6th International Conference on Machine Learning for Cyber Security, ML4CS 2024

作者： Zhang, Peng Qiu, Dongyan Duan, Ao Liu, Hongwei The Guangdong Key Laboratory of Intelligent Information Processing College of Electronics and Information Engineering Shenzhen University Guangdong Shenzhen518060 China College of Big Data and Internet Shenzhen Technology University Guangdong Shenzhen518118 China

ISBN: (纸本)9789819645657

Privacy-Preserving Deep Learning (PPDL) using Fully Homomorphic Encryption (FHE) addresses potential data privacy exposure risks associated with deploying deep learning models in untrusted cloud environments. FHE-based PPDL enables users to encrypt their data locally, allowing cloud service providers to perform computations directly on the encrypted data without ever accessing it. However, FHE faces challenges in efficiently handling nonlinear computations, which are essential to deep learning frameworks, particularly in implementing activation functions and max pooling layers. To address this challenge, we improve the homomorphic max pooling approximation scheme HMaxPool, and propose an efficient homomorphic max pooling algorithm, denoted as HMaxPool+. Specifically, we first redefine the approximation of the maximum function, and then design sub-algorithm to address the potential output expansion issue. The experimental results validate that both the homomorphic max pooling algorithm itself and the corresponding homomorphic SqueezeNet neural network demonstrate enhancements in computational efficiency and accuracy. © The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. 2025.

关键词： Differential privacy

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First-principles investigation of adhesion strength and interfacial bonding in Mg/X(X=Ti,Zr,Hf,V,Nd,Cr,Mo,Mn,and Fe)interface

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Journal of Magnesium and Alloys 2025年第1期13卷 83-89页

作者： Longke Bao Zhifu Yao Yuhui Zhang Cuiping Wang Kaihong Zheng Rongpei Shi Xingjun Liu Fusheng Pan State Key Laboratory of Advanced Welding and Joining Harbin Institute of TechnologyShenzhen 518055China College of Materials Science and Engineering and Institute of Materials Genome and Big DataHarbin Institute of TechnologyShenzhen 518055China Institute of New Materials Guangdong Academy of SciencesGuangzhou 510650China College of Materials Science and Engineering Xiamen UniversityXiamen 361005China College of Materials Science and Engineering Chongqing UniversityChongqing 400045China

Magnesium alloys have gained extensive applications across various industries,including aerospace,transportation,and civil construction,owing to their excellent combinations of high specific strength and stiffness[1].However,their lim-ited strength due to the lack of effective strengthening phases has hindered their broader industrial applications[2].Never-theless,it has been challenging to achieve significant strength-ening due to the restricted solubility of alloying elements in magnesium[3].Thus,more and more efforts have been made to explore the concept of secondary phase-reinforced magne-sium alloys[2,4,5],where the secondary phase acts as re-inforcing agents within the magnesium matrix,resembling a composite material.

关键词： adhesion strength interfacial bonding aluminum alloys industrial applications solubility strengthening phases alloying elements Mg X interfaces

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T³Planner: Multi-Phase Planning Across Structure-Constrained Optical, IP, and Routing Topologies

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IEEE Journal on Selected Areas in Communications 2025年第5期43卷 1823-1839页

作者： Yijun Hao Shusen Yang Fang Li Yifan Zhang Cong Zhao Xuebin Ren Peng Zhao Chenren Xu Shibo Wang National Engineering Laboratory for Big Data Analytics Xi’an Jiaotong University Xi’an China National Engineering Laboratory for Big Data Analytics and the Ministry of Education Key Laboratory for Intelligent Networks and Network Security Xi’an Jiaotong University Xi’an China School of Computer Science Peking University Beijing China Department of Computer Science and Engineering The Chinese University of Hong Kong Hong Kong China National Engineering Laboratory for Big Data Analytics XiÃan Jiaotong University XiÃan China

Network topology planning is an essential multi-phase process to build and jointly optimize the multi-layer network topologies in wide-area networks (WANs). Most existing practices target single-phase/layer planning, and are incapable of satisfying all rigorous topological structure constraints (e.g., dual-homing rings) defined by network standards and operators, especially in large-scale networks. These significantly limit their usability and performance in production networks. We consider a general topology planning problem with typical structure constraints over three essential phases (greenfield, reconfiguration, and site expansion) and topological layers (optical, IP, and routing topologies). We present, T3Planner, a novel practical solver to this problem in production. Specifically, we develop a structure-driven encoder based on graph neural network (GNN) for concise structure encoding, and design a new learning framework with optical-centric layer compression/reconstruction and rule-aided reinforcement learning (RL) for fast convergence and high performance. Extensive experiments on nine real topologies demonstrate that T3Planner scales to large optical networks with hundreds of sites, saves 46.6% cost, and supports $3.12\times $ more demand when compared to related existing approaches.

关键词： Topology Network topology Planning IP networks Optical fiber networks Routing Optical fibers Optical feedback Production Graph neural networks

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Controlled-source electromagnetic noise attenuation via a deep convolutional neural network and high-quality sounding curve screening mechanism

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Geophysics 2025年第3期90卷 WA125-WA140页

作者： Liu, Yecheng Li, Diquan Li, Jin Zhang, Xian Central South University Monitoring Ministry of Education Key Laboratory of Metallogenic Prediction of Nonferrous Metals and Geological Environment Changsha China Hunan Provincial Key Laboratory of Non-ferrous Resources and Geological Hazard Detection Changsha China Central South University School of Geoscience and Info-physics Changsha China Hunan Normal University College of Information Science and Engineering Hunan Provincial Key Laboratory of Intelligent Computing and Language Information Processing Changsha China Hunan University of Finance and Economics School of Information Technology and Management Hunan Provincial Key Laboratory of Finance & Economics Big Data Science and Technology Changsha China

Strong noise is one of the biggest challenges in controlled-source electromagnetic (CSEM) exploration, which severely affects the quality of the recorded signal. We develop a novel and effective CSEM noise attenuation method that integrates a deep convolutional neural network (DCNN) with a high-quality sounding curve screening mechanism. This method first uses a DCNN to learn the large-scale noise characteristics of CSEM measured data and build a DCNN denoising model for attenuating the noise. Because some impulse noise remains after DCNN denoising, the high-quality sounding curve screening mechanism is innovatively applied to optimize the DCNN denoised data. The core of this method is the smoothness value (SV), which quantitatively evaluates the smoothness of the sounding curve (apparent resistivity curve). In effect, the mechanism segments the overall DCNN denoised data and calculates the corresponding sounding curve and its SV for each segment. The highest-quality sounding curve can be screened out by comparing the SVs of all curves as well as obtaining the highest-quality data segment present in the overall DCNN denoised data. Finally, our method is validated with synthetic and field data, demonstrating its feasibility and effectiveness in attenuating large-scale CSEM noise. The quality of CSEM data, which is heavily affected by noise, is significantly improved after processing by our method. © 2025 Society of Exploration Geophysicists. All rights reserved.

关键词： Deep neural networks

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Wind turbine detection based on high spatial resolution four-band reflectance images 6

Wind turbine detection based on high spatial resolution four...

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6th International Conference on Geoscience and Remote Sensing Mapping, GRSM 2024

作者： Deng, Fengying Qiao, Baojun Li, Kaitao Zhao, Limin Chen, Xingfeng Li, Jiaguo Liu, Jun Sun, Yuan Henan Key Laboratory of Big Data Analysis and Processing Henan University Kaifeng China Aerospace Information Research Institute Chinese Academy of Science Beijing China School of Space Information Space Engineering University Beijing China

ISBN: (纸本)9781510688018

Wind turbine detection is essential for the power industry and regulatory agencies to efficiently and accurately determine their number and spatial distribution. Under complex underlying surface conditions, the detection accuracy of conventional methods is low, especially when dealing with multi-scale wind turbine targets. In addition, the underutilization of the near-infrared (NIR) band limits the capability of optical remote sensing sensors in wind turbine detection. To address the above problems, this paper proposes a wind turbine detection algorithm YOLOv8m-BD based on high spatial resolution four-band reflectance images using YOLOv8m as the baseline model. Firstly, the four-band image is input through channel adaptation modification. Next, the CSPDarknet53 to 2-stage FPN (C2f) module is enhanced by introducing deformable convolution (DCN) to expand the receptive field. Finally, the effectiveness of our design was validated through extensive experiments on a self-built wind turbine dataset. Compared to the YOLOv8m baseline model that only inputs RGB three bands, the improved YOLOv8m-BD achieves an accuracy of 96.4% and a false alarm rate of 2.0%, an increase of 3.4% in accuracy and a decrease of 2.5% in false alarm rate. © 2025 SPIE.

关键词： Proximity sensors

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Calibration of Car-Following Behavior Based on Monocular Camera 11th

Calibration of Car-Following Behavior Based on Monocular Cam...

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11th International Conference on Traffic and Transportation Studies, ICTTS 2024

作者： Liu, Yufei Wei, Chong MOT Key Laboratory of Transport Industry of Big Data Application Technologies for Comprehensive Transport School of Traffic and Transportation Beijing Jiaotong University Beijing100044 China School of Mechanical and Electrical Engineering Hainan University Haikou China

ISBN: (纸本)9789819796434

In the past, most of the research on car-following models in China focused on physical statistics, with relatively little collection and analysis of car-following data. Therefore, it is essential to establish a car-following model suitable for analyzing the car-following characteristics of Chinese drivers based on real driving data. This paper utilizes a vehicle-mounted monocular camera to capture traffic flow images on the highway and uses the YOLOv5 algorithm to detect vehicles. Through the homography transformation between the image plane in the front view and the spatial plane in the top view, the pixel coordinates are converted to 3D spatial coordinates. Then, the ranging model is established, and its effectiveness is verified using the length of the lane dividing lines. The factor analysis is used to determine the main influencing factors of car-following behavior. The appropriate linear car-following models are selected and its parameters are calibrated using multiple linear regression methods. This paper realizes the collection and subsequent processing of car-following behavior data under natural driving conditions, and transforms generalized car-following models into specific research theories for application in practical situations. This method of collecting car-following driving data has strong practicality and can provide effective data support for studying car-following models that accurately reflect the operation conditions of road traffic. © Beijing Paike Culture Commu. Co., Ltd. 2025.

关键词： Behavioral research

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An intelligent solar flare prediction model based on X-ray flux curves using Long Short-Term Memory

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Astronomical Techniques and Instruments 2025年第2期2卷 65-72页

作者： Yan Gao Li Zhang Long Xu College of Big Data and Information Engineering Guizhou UniversityGuiyang 550025China State Key Laboratory of Public Big Data Guizhou UniversityGuiyang 550025China Faculty of Electrical Engineering and Computer Science Ningbo UniversityNingbo 315211China

Solar flares are violent solar outbursts which have a great influence on the space environment surrounding Earth,potentially causing disruption of the ionosphere and interference with the geomagnetic field,thus causing magnetic ***,it is very important to accurately predict the time period of solar *** paper proposes a flare prediction model,based on physical images of active solar *** employ X-ray flux curves recorded directly by the Geostationary Operational Environmental Satellite,used as input data for the model,allowing us to largely avoid the influence of accidental errors,effectively improving the model prediction efficiency.A model based on the X-ray flux curve can predict whether there will be a flare event within 24 *** reverse can also be verified by the peak of the X-ray flux curve to see if a flare has occurred within the past 24 *** True Positive Rate and False Positive Rate of the prediction model,based on physical images of active regions are 0.6070 and 0.2410 respectively,and the accuracy and True Skill Statistics are 0.7590 and *** model can effectively improve prediction efficiency compared with models based on the physical parameters of active regions or magnetic field records,providing a simple method for solar flare prediction.

关键词： Neural Network Long Short-Term Memory Solar flare prediction X-ray flux curve

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DMC-Watermark: A backdoor richer watermark for dual identity verification by dynamic mask covering

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Applied Intelligence 2025年第8期55卷 1-15页

作者： Zhu, Yujia Wang, Ruoxi Xia, Daoxun School of Big Data and Computer Science Guizhou Normal University Guiyang China Guizhou Key Laboratory of Advanced Computing Guizhou Normal University Guiyang China Engineering Laboratory for Applied Technology of Big Data in Education Guizhou Normal University Guiyang China

With the increasing use of neural networks, the importance of copyright protection for these models has gained significant attention. Backdoor watermarking is one of the key methods for protecting copyright. However, on the one hand, most existing backdoor watermarks are triggered by visual images, making them easily detectable, and therefore vulnerable to various attacks. On the other hand, it is difficult for these methods to carry information related to the creator’s identity which can easily lead to fraudulent claims of ownership. These factors contribute to the vulnerability and limitations of backdoor watermarking. In this paper, we propose DMC-Watermark, a backdoor richer watermarking method that uses dynamic mask-covered image structures as triggers. Leveraging the semantic preservation of image structure in transformation attacks, we select image structure as triggers. Furthermore, we convert the author-related information into an array of color information and apply it as a mask to the extracted image structures, allowing it to serve as a second layer of verification during the validation phase to resist fraudulent claims of ownership. The final trigger pattern, embedded with author-related image structures, is applied to the selected images in the trigger set, generating a final trigger set that is trained together with clean samples to produce a protected model. The experiments show that the proposed DMC-Watermark performs well in terms of fidelity, invisibility, undetectability, functionality, dual verification and robustness on three different datasets and four representative DNNs, and it has wide applicability and excellent results in high-resolution images. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2025.

关键词： Image watermarking

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Joint Double Auction-Based Channel Selection in Wireless Monitoring Networks

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IEEE Transactions on Network and Service Management 2025年

作者： Xia, Na Chen, Lei Li, Meng Yin, Yutao Zhang, Ke Ministry of Education School of Computer Science and Information Engineering Hefei University of Technology Key Laboratory of Knowledge Engineering with Big Data China State Grid Electric Power Research Institute Co. Ltd Hefei230088 China

In wireless networks, utilizing sniffers for fault analysis, traffic traceback, and resource optimization is a crucial task. However, existing centralized algorithms cannot be applied to high-density wireless networks. Therefore, distributed optimization of channel selection to maximize the monitoring rate of sensors in Wireless Monitoring Networks (WMNs) is a challenge. This paper proposes a joint double auction-based distributed channel selection algorithm (J2A-CS) to maximize overall quality of monitoring (QoM). First, sniffers are redundantly deployed in WMNs, and an initial channel allocation strategy is formulated. Subsequently, sniffers collectively act as buyers and sellers at different stages. Finally, buyers bid asynchronously, and sellers settle synchronously to maximize the seller's marginal revenue and update the channel selection scheme. As a distributed channel selection algorithm, J2A-CS addresses the highest overall QoM issue in WMNs, demonstrating high scalability and fault tolerance. Simulation results show that J2A-CS significantly improves QoM compared to existing distributed algorithms and outperforms centralized algorithms in high-density scenarios. © 2004-2012 IEEE.

关键词： Sales

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