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Energy saving analysis for CO_(2)–O_(2)mixed injection technology in converter steelmaking

Journal of Iron and Steel Research International 2024年第5期31卷 1095-1103页

作者： Bao-chen Han Chun-liang Gao Ya-qiang Li Dan Liu Guang-sheng Wei Rong Zhu Hebei Key Laboratory of Material Near-Net Forming Technology School of Material Science and EngineeringHebei University of Science and TechnologyShijiazhuang050018HebeiChina Department of Automotive Engineering Hebei Vocational University of Technology and EngineeringXingtai054000HebeiChina School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing100083China

Energy-saving in China's iron and steel industry still relies on the development and improvement of short-term energy saving ***,a special converter smelting technology incorporating energy saving was *** evaluate the energy-saving potential of the CO_(2)–O_(2)mixed injection(COMI)technology,collected production data were used to develop an improved techno-economic *** reveal that the technology can save energy through auxiliary material consumption,sensible heat of solid by-product,iron loss reduction,and energy *** application of COMI technology in an enterprise is cost effective,involving the energy saving potential of 0.206 GJ/t,the cost of conserved energy of−48.83 yuan/GJ,and a simple payback period of 0.35 year for a 60-million-yuan *** analysis shows that the investment cost and discount rate primarily influence the cost of conserved energy of the *** the discount rate increased,the cost of conserved energy also gradually ***,the COMI technology is an energy-saving technology with good development prospects.

关键词： Converter steelmaking COMI technology Energy saving Techno-economic model Investment cost

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Numerical simulation of microstructure and microporosity morphology in directional solidification of aluminum-copper alloys:Effect of copper content and withdrawal rate

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China Foundry 2025年第1期22卷 33-44页

作者： Wei Yuan Hai-dong Zhao Xu Shen Chun Zou Yuan Liu Qing-yan Xu National Engineering Research Center of Near-Net-Shape Forming for Metallic Materials South China University of TechnologyGuangzhou 510640China Key Laboratory for Advanced Materials Processing Technology(Ministry of Education) Tsinghua UniversityBeijing 100084China

Microporosity formed in the solidification process of Al alloys is detrimental to the alloy properties.A two-dimensional cellular automaton(CA)model was developed to simulate the microstructure and microporosity formation in Al-Cu alloys,considering variations in Cu content and solidification *** results indicate that the Cu content primarily influences the growth of *** validate the model,directional solidification experiments were conducted on Al-Cu alloys with varing Cu contents and withdrawal *** experimental results of dendrites and microporosity characteristics agree well with the predictions from the developed model,thus confirming the validity of the *** alloy’s liquidus temperature,dendrite morphology,and hydrogen saturation solubility arising from different Cu contents have significant effects on microporosity *** withdrawal rate primarily affects the nucleation of hydrogen microporosity by altering cooling rates and dendritic growth rates,resulting in different microporosity characteristics.

关键词： microporosity dendrites cellular automaton Al-Cu alloys directional solidification

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Synergetic deformation mechanisms in an Mg-Zn-Y-Zr alloy with intragranular LPSO structures

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Journal of Magnesium and Alloys 2023年第5期11卷 1754-1768页

作者： Z.Z.Peng X.H.Shao Z.M.Liang D.L.Wang L.W.Wang X.L.Ma Hebei Key Laboratory of Material Near-Net Forming Technology School of Materials Science and EngineeringHebei University of Science and TechnologyShijiazhuang 050018China Shenyang National Laboratory for Materials Science Institute of Metal ResearchChinese Academy of Sciences72 Whenua RoadShenyang 110016China

Deformation kink is one of the important strengthening mechanisms of the long-period-stacking-ordered(LPSO)phase containing magnesium(Mg)alloys,while the deformation twin is generally *** optimize the mechanical properties of LPSO containing Mg alloy by simultaneously exciting kink and twin,we successfully prepared the Mg-Zn-Y-Zr alloy featuring intragranular LPSO phase and free grain boundary LPSO phase by *** unraveled the corresponding strengthening and toughening mechanisms through transmission electron microscopy characterization and theoretical *** high strength and good plasticity of the homogenized alloy benefit from the synergistic deformation mechanism of multiple kinking and twining in the *** the activation of kinking and twinning depends on the thicknesses of LPSO lamellae and their relative *** results may shed light on optimizing the design of Mg alloys regulating the microstructure of LPSO phases.

关键词： Mg alloy LPSO distribution Kink Twin Transmission electron microscopy

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In situ regulating intimately connected heterostructure by decomposition of solid solution oxides toward high-efficient water oxidation

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Rare Metals 2024年第4期43卷 1557-1569页

作者： Shao-Fei Zhang Xiao-Lu Yin Jin Wang Jian-Li Kang Tian-Tian Li Jin-Feng Sun Yong-Qiang Meng Jian-Jiang Wang Dian-Long Wang Kai-Qiang Qin Hebei Key Laboratory of Flexible Functional Materials/Hebei Key Laboratory of Material Near-Net Forming Technology School of Materials Science and EngineeringHebei University of Science and TechnologyShijiazhuang050018China Key Laboratory of Advanced Ceramics and Machining Technology/Ministry of Education School of Materials Science and EngineeringTianjin UniversityTianjin300072China Electrochemical Engine Center Department of Mechanical EngineeringPennsylvania State UniversityUniversity ParkPA16802USA

Heterogeneous interfaces produced by interdomain interactions on a nanoscale performs a crucial role in boosting the properties of an electrocatalyst toward oxygen evolution reaction(OER)***,a series of dual-phase electrodes with intimately connected heterointerfaces are prepared by in situ decomposing solid solution oxide of Ni_(x)Co_(y)Fe_(100-x-y)O,which grew on Ni foam massively via an ultrafast combustion ***,with high-reaction kinetics caused by the reduction treatment at 450℃,the less electronegative Fe and Co are more oxyphilic than Ni,which facilitated their co-exsolution and formation of CoFe_2O_4/NiO oxide with enriched oxygen *** from the nanoporous framework,heterojunction structure,and oxygen defects,the self-supporting electrodes present rapid charge/mass transmission and provide abundant active sites for *** optimized sample(R-SNCF4.5)shows low overpotentials of 226 and 324 mV at 10 and100 mA·cm^(-2),a small Tafel slope(46.7 mV·dec^(-1)),and excellent *** assembled R-SNCF4.5//Pt/C/NF electrolyzer demonstrates continuous electrolysis over 50 h at a current density of 10 mA·cm^(-2),under 1.51 *** functional theory(DFT)calculations verify that the strong electronic modulation plays a critical part in the CoFe_2O_4/NiO hybrid by lowering the energy barriers for the ratedetermining steps,and Fe sites are the most active OER sites.

关键词： Rapid combustion Decomposition of solid solution oxide Dual-phase heterostructure Oxygen evolution reaction Theoretical calculation

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Effect of MgO, Ti2O3, and Al2O3 Inclusions on the Formation of Manganese-Depleted Zones Through First-Principles Calculation 152nd

Effect of MgO, Ti2O3, and Al2O3 Inclusions on the Formation ...

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152nd Annual Meeting and Exhibition of The Minerals, Metals and materials Society, TMS 2023

作者： Liu, Er-kang Wang, Qi Ma, Chen-yu Guo, Zhi-hong Zheng, Ya-xu Zhu, Li-guang Hebei Key Laboratory of Materials Near-Net Forming Technology School of Material Science and Engineering Hebei University of Science and Technology Shijiazhuang050018 China

ISBN: (纸本)9783031225239

Using inclusions with a certain composite, which act as heterogeneous nucleation sites for intragranular acicular ferrite (IAF), has been acknowledged as an effective way for grain refinement. In this study, we investigated the strength of interaction between Mn solute atoms and different oxide inclusions (such as MgO, Ti2O3, and Al2O3) experimentally and using first-principles calculations, to identify the ability that oxides that can lead to the formation of local Mn-depleted zones (MDZ) promoting the nucleation of intragranular ferrite. The calculated results show that Ti2O3 are easy, MgO are moderately easy, and Al2O3 are invalid to form Mn-doped inclusions. Furthermore, the experimental results confirm that a wide MDZ appear at Ti2O3–steel interface, which effectively induces the nucleation of ferrite. © 2023, The Minerals, Metals & materials Society.

关键词： Magnesia

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Improvement of impact properties of Al-Si-Mg alloy via solution treatment and joint modification with Sr and La

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Rare Metals 2024年第7期43卷 3301-3313页

作者： Xiong-Ling Zheng Shao-Xiang Li Jia-Le Ma Qing-Yan Xu Hai-Dong Zhao Zhi-Qiang Han Key Laboratory for Advanced Materials Processing Technology Ministry of EducationSchool of Materials Science and EngineeringTsinghua UniversityBeijing 100084China National Engineering Research Center of Near-Net Shape Forming for Metallic Materials South China University of TechnologyGuangzhou 510641China

An effort to obtain superior impact properties for Al-7Si-0.35 Mg alloy is presented,where modification with 0.02 wt% Sr and 0.1 wt% La as well as solution treatment was jointly *** samples were solution treated at 535℃ for 15 min to 12 *** microstructure,fracture mechanism,and their correlation with the impact properties of the alloy were studied in detail mainly through optical microscopy(OM),scanning electron microscopy(SEM) and oscillography impact *** results show that the addition of Sr and La refined the eutectic Si particles significantly from~ 2.05 μm(modified with Sr alone) to~ 0.75 μm in as-cast microstructure,leading to a very homogeneous distribution of spheroidized Si particles in the alloy solution treated at 535℃ for 8 *** alloy exhibits excellent impact toughness up to 75 J·cm^(-2),which is much higher than the maximum impact toughness of the alloys modified by Sr alone(~ 46 J·cm^(-2)).The major reason for this remarkable increase in the impact property is the dramatic increase in crack initiation *** dispersoid-free zones(DFZs)near the eutectic regions mainly consist of the ductile Al-matrix,which exhibits excellent *** ductile Al-matrix of the DFZs hinders the crack propagation,resulting in a significant increase in crack propagation energy.

关键词： Aluminum alloys Modification Solution treatment Microstructure Impact properties Fracture mechanism

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Disrupting variant selection memory effect in laser powder bed fusion to improve strength-ductility synergy of Ti-6Al-4V alloys

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Journal of materials Science and technology 2025年 219卷 19-32页

作者： Yang, C. Liu, B. Pan, L.L. Yang, Y. Zhou, Y. Cai, W.S. Liu, Le-hua National Engineering Research Center of Near-net-shape Forming for Metallic Materials Guangdong Provincial Key Laboratory for Processing and Forming of Advanced Metallic Materials South China University of Technology Guangzhou 510640 China Shenzhen Leadwell Technology Co. Ltd. Shenzhen Guangdong 518000 China

Texture formation is frequently observed in parts produced by Laser Powder Bed Fusion (L-PBF), which can induce anisotropy and may potentially degrade plasticity. In this study, we introduce a laser remelting strategy to mitigate these adverse effects. By employing experimental observations and numerical simulations, we established the relationship between melt pool thermal history, variant selection, and mechanical properties. Our results indicate that the strengthening of texture can be prevented by disrupting the variant selection memory effect when there is a difference in scanning speeds between the printing and remelting lasers. The achieved random variant orientation is attributed to the altered cooling rates and temperature gradient directions during solidification across different layers. The optimized Ti-6Al-4V alloy demonstrates high strength (1211.5 ± 13.3 MPa) and significant elongation (12.3 % ± 0.8 %), exhibiting a superior strength-ductility synergy compared to samples produced by direct printing or laser remelting with consistent parameters, as well as most reported L-PBF processed Ti-6Al-4V alloys. Our findings provide new insights into phase transformation kinetics in L-PBF of Ti-6Al-4V alloys and facilitate the optimization of this process for manufacturing high-performance components. © 2024

关键词： Titanium alloys

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Laser Powder Bed Fusion of Beta-Type Titanium Alloys for Biomedical Application:A Review

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Acta Metallurgica Sinica(English Letters) 2024年第1期37卷 17-28页

作者： Xuan Luo Chao Yang Dongdong Li Lai-Chang Zhang State Key Laboratory of Materials Processing and Die&Mould Technology Huazhong University of Science and TechnologyWuhan430074China National Engineering Research Center of Near-Net-Shape Forming for Metallic Materials Guangdong Provincial Key Laboratory for Processing and Forming of Advanced Metallic MaterialsSouth China University of TechnologyGuangzhou510640China Centre for Advanced Materials and Manufacturing School of EngineeringEdith Cowan University270 Joondalup DriveJoondalupPerthWA6027Australia

Additive manufacturing ofβ-type titanium alloy is expected to replace Ti-6Al-4V alloy in the field of orthopedic implantation because of their low elastic modulus,excellent corrosion resistance,and *** briefly introducing the laser powder bed fusion(LPBF)process and physical phenomena,this paper reviews the recent progresses in LPBF-edβ-type Ti *** strategies to strengthening and tougheningβ-type Ti alloys are critically *** is followed by the processing routes employed to achieve to low modulus for orthopedic applications,especially a new methodology for tailoring crystallographic orientation called multi-track coupled directional *** effect of processing and compositions on performance metrics ofβ-type Ti alloys included corrosion behavior,and biocompatibility is *** the end,challenges in additive manufacturing ofβ-type Ti alloys in future are highlighted,with the aim to ensue clinical application of LPBF-edβ-type Ti alloys.

关键词： β-type Ti alloys Laser powder bed fusion Mechanical properties Elastic modulus Biocompatibility

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Microstructure evolution and enhanced fatigue behavior in the Mg-10Li-5Zn-0.5Er alloys micro-alloyed with Yb

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Journal of Magnesium and Alloys 2024年第8期12卷 3159-3172页

作者： Guanglan Liao Guohua Wu Wencai Liu Jiawei Sun Lv Xiao Song Pang Peijun Chen National Engineering Research Center of Light Alloy Net Forming and State Key Laboratory of Metal Matrix Composite School of Materials Science and EngineeringShanghai Jiao Tong UniversityShanghai 200240China Shanghai Spaceflight Precision Machinery Institute Shanghai 201600China Shanghai Engineering Technology Research Center of Near-Net-Shape Forming for Metallic Materials Shanghai 201600China Luoyang Shengya Magnesium Alloy Technology Co. LtdLuoyang 471921China

In this paper,(0.2-1 wt%)Yb was added to improve the tensile properties and high-cycle fatigue behavior of the as-cast and as-extruded Mg-10Li-5Zn-0.5Er *** is found that Yb mainly affects the mechanical properties of the alloy by changing the grain size,type and morphology of the second *** mainly exists in the formation of Mg_(2)Yb and Mg-Zn-Yb phases in the metallographic *** the addition of Yb,the grains are refined and these Yb-containing phases replace the large-sized MgLiZn phase to be enriched at the grain *** the addition of excess Yb reduces the number of small-sized MgLiZn phases in the grain,thus reducing the alloys’mechanical *** extrusion,the small-sized MgLiZn phase is refined and the number increases,which effectively improves the tensile and fatigue strength of the *** fatigue strength is mainly affected by the number and morphology of the second phase,positively correlated with the *** in grain size and number and size of second phases,the extruded alloy with 0.2Yb added exhibits excellent mechanical properties with the yield strength,ultimate tensile strength and elongation of 292 MPa,303 MPa and 11.7%,and an fatigue strength of 130 MPa.

关键词： Mg-Li alloy Yb Microstructure Fatigue property Hot extrusion

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Microstructural evolution and superelastic properties of ultrafine-graine d NiTi-base d shape memory alloy via sintering of amorphous ribbon precursor

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Journal of materials Science & technology 2023年第7期138卷 80-92页

作者： W.S.Cai H.Z.Lu H.Z.Li Z.Liu H.B.Ke W.H.Wang C.Yang National Engineering Research Center of Near-net-shape Forming for Metallic Materials Guangdong Provincial Key Laboratory for Processing and Forming of Advanced Metallic MaterialsSouth China University of TechnologyGuangzhou 510640China Songshan Lake Materials Laboratory Dongguan 523808China Institute of Physics Chinese Academy of SciencesBeijing 100190China

NiTi-based shape memory alloys(SMAs)are considered as cutting-edge intelligent functional ***,it remains a great challenge to obtain ultrafine-grained(UFGed)bulk materials with mm-scale size as well as outstanding superelastic ***,UFGed bulk Ti_(35)Zr_(15)Ni_(35)Cu_(15)NiTi-based SMA is successfully prepared via spark plasma sintering of amorphous ribbon precursor at different sintering temperatures,and microstructural evolution and superelastic properties are symmetrically *** is found that its grain size ranges from UFG to micro-grain with increased sintering temperature regard-less of the predominant B2 matrix in all bulk ***,the orientation relationships between B2 matrix and nano-scale fcc(Ti,Zr)_(2)Ni precipitate evolve from coherent to ***,the UFGed samples exhibit perfect superelasticity with the high recoverable strain of∼5.8%,the stable recov-ery rate above 99%,and the great critical stress inducing martensitic transformation higher than 1 GPa,far superior to the corresponding ones of suction-cast micro-grained TiZrNiCu ***,the perfect superelasticity is attributed to the good resistance to dislocation slip or grain boundary slip by residual nano-scale amorphous phase or secondary phase of coherent and semi-coherent fcc(Ti,Zr)_(2)Ni *** addition,the gentle superelastic plateau is associated to the favorable transfer stress and the strong ability to accommodate dislocation movement,which is generated by the coherent interface between nano-scale fcc(Ti,Zr)_(2)Ni and UFGed B2 *** results suggest that spark plasma sintering of amorphous alloy precursor is a feasible route to obtaining excellent superelasticity in NiTi-based SMAs.

关键词： Shape memory alloy Amorphous alloy Microstructure Superelasticity

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