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Atomically Dispersed Janus Nickel Sites on Red Phosphorus for Photocatalytic Overall Water Splitting

Angewandte Chemie 2022年第29期134卷

作者： Menglong Wang Shuai Xu Prof. Zhaohui Zhou Prof. Chung-Li Dong Dr. Xu Guo Jeng-Lung Chen Dr. Yu-Cheng Huang Prof. Shaohua Shen Prof. Yubin Chen Prof. Liejin Guo Prof. Clemens Burda International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Shaanxi 710049 China Chemical Engineering and Technology School of Water and Environment Key Laboratory of Subsurface Hydrology and Ecological Effects in Arid Region Ministry of Education Chang'an University Xi'an 710064 China Department of Physics Tamkang University New Taipei City 25137 Taiwan National Synchrotron Radiation Research Center Hsinchu 30076 Taiwan Department of Chemistry Case Western Reserve University Cleveland OH 44106 USA

Single-atom nickel catalysts hold great promise for photocatalytic water splitting due to their plentiful active sites and cost-effectiveness. Herein, we adopt a reactive-group guided strategy to prepare atomically dispersed nickel catalysts on red phosphorus. The hydrothermal treatment of red phosphorus leads to the formation of P−H and P−OH groups, which behave as the reactive functionalities to generate the dual structure of single-atom P−Ni and P−O−Ni catalytic sites. The produced single-atom sites provide two different functions: P−Ni for water reduction and P−O−Ni for water oxidation. Benefitting from this specific Janus structure, Ni-red phosphorus shows an elevated hydrogen evolution rate compared to Ni nanoparticle-modified red phosphorus under visible-light irradiation. The hydrogen evolution rate was additionally enhanced with increased reaction temperature, reaching 91.51 μmol h −1 at 70 °C, corresponding to an apparent quantum efficiency of 8.9 % at 420 nm excitation wavelength.

关键词： Nickel Photocatalysis Red Phosphorus Single-Atom Catalysts Water Splitting

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Preparation and Properties of Rice Hull Ash as the catalysis supporter in the fluidized-bed reactor

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IOP Conference Series: Earth and Environmental Science 2021年第1期766卷

作者： Zhaohui Teng Shan Huang Heng Xu Na Li Qulan Zhou College of energy Chengdu University of Tecnoogy Chengdu 610059 China National Key Laboratory of Nuclear Reactor System Design Technology Nuclear Power Institute of China Chengdu 610200 China shenzhen ILNG energy technology CO. LTD Shenzhen 518061 China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China

This research focuses on the preparation and properties of rice hull ash(RHA). We prepared RHA from combustion of rice husk in the fluidized-bed reactor. The temperature field of the furnace was steady and bellow 850°C to keep SiO2 amorphous. XRD, BET and SEM were applied in the characterization tests to investigate the effect of flow rate(u), the higher primary-secondary wind ratio(i) and relative height of bed material. The optimal combustion condition for preparing RHA was discussed. RHA obtained from rice hull contains abundant amorphous SiO2 (>90%) and the characterization results of RHA show its potential to be a good catalyst supporter.

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Corrigendum to: “One-pot synthesis of amorphous/crystalline SnO 2 /BaSO 4 composite sensitized with Eosin Y for enhanced photocatalytic H 2 production” [J. Environ. Chem. Eng. 12 (2024) 112770/JECE112770]

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Journal of Environmental Chemical engineering 2024年第5期12卷

作者： Cheng Cheng Jinfeng Zhang Haiping Jia Xutao Ding Gongyue Dong Feng Chen Yuchao Hu Jinwen Shi School of Chemical Engineering and Technology International Research Center for Renewable Energy (IRCRE) State Key Laboratory of Multiphase Flow in Power Engineering (MFPE) Xi’an Jiaotong University (XJTU) 28 West Xianning Road Xi’an 710049 China Shaanxi Key Laboratory of Advanced Stimulation Technology for Oil & Gas Reservoirs Xi’an Shiyou University Xi’an 710065 China Shaanxi Gas Group Fuping Energy Technology Co. Ltd 2 Kaiyuan Road Xi'an 710016 China Integrated Energy Institute Sichuan Digital Economy Industry Development Research Institute 88 Jiefang Road Chengdu 610036 China West Pipeline Company PipeChina 666 Beijing Middle Road Urumqi 830013 China School of Materials and Energy University of Electronic Science and Technology of China Chengdu 611731 China

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Experimental and numerical investigation of flow dynamics and thermal behavior of supercritical n-decane in jet-regeneration composite cooling technology for scramjet engines

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International Journal of Thermal Sciences 2025年 217卷

作者： Yong Li Qirun Zhou Yingchun Zhang Jiajie Zhang Suxia Ma Gongnan Xie Bengt Sunden College of Electrical and Power Engineering Taiyuan University of Technology Taiyuan Shanxi 030024 PR China Key Laboratory of Cleaner Intelligent Control on Coal & Electricity Ministry of Education Taiyuan Shanxi 030024 PR China School of Energy and Power Engineering North University of China Taiyuan Shanxi 030051 PR China School of Marine Science and Technology Northwestern Polytechnical University P.O. Box 24 Xi'an Shaanxi 710072 PR China Professor Emeritus of Lund University BS Heat Transfer and Fluid Flow SE 26253 Angelholm Sweden

Traditional regenerative cooling methods fall short of meeting the thermal dissipation demands when the scramjet is flying at higher Mach numbers. In this paper, jet cooling is employed for the thermal management of scramjets, leveraging its exceptional thermal dissipation capabilities in environments with intense heat flux. Liquid crystal thermography technology was utilized to experimentally study the thermal exchange behaviors of the ambient air under varying conditions including different numbers of jet holes, diverse combinations of jet and mainstream flow, and varied flow rates. Experimental findings conclusively demonstrate that the synergistic interaction between the jet flow and the mainstream significantly enhances the heat dissipation capacity of the jet. Taking the case of four jet nozzles as an illustration, when the aggregate flow rate reaches 150 L/min, the wall average Nu exhibits a 31 % increase compared to the scenario where only the jet flow is present. The heat dissipation capacity of an array of jets interacting with the mainstream flow is approximately six times higher than that of the mainstream alone. In the numerical simulation, the supercritical fluid flow mechanics and thermal exchange behaviors of jets under operating conditions of scramjet were thoroughly analyzed. The mutual effect between the jet and mainstream flow demonstrated a robust heat dissipation capability. Notably, the maximum Nu for the synergistic mutual effect between the jet and mainstream is seven times larger than that of the mainstream alone. In conclusion, both experimental and numerical results indicate that the heat dissipation capacity is superior under the combined action of the jet and mainstream.

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A simple green approach to synthesis of sub-100 nm carbon spheres as template for TiO_2 hollow nanospheres with enhanced photocatalytic activities

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Science China Materials 2018年第6期61卷 869-877页

作者： Yubo Tan1 Maochang Liu1 Daixing Wei1 Heming Tang2 Xinjian Feng2 Shaohua Shen1 International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University College of Chemistry Chemical Engineering and Materials Science Soochow University

Carbon spheres（CSs） have attracted great attention given their wide applications in bio-diagnostics, photonic band-gap crystals and drug delivery, etc. The morphology and size of CSs greatly affect their performances and applications. Herein, we report a green and catalyst-free hydrothermal carbonization（HTC） method to synthesize CSs with glucose as carbon precursor. The diameter of CSs can be tuned within a wide range from 450 to 40 nm by controlling the glucose concentration, reaction time and *** the obtained CSs as template, hollow TiO2 nanospheres（HTNSs） with controllable diameters are prepared via a sol-gel method. As photocatalysts for hydrogen generation, the photoactivity of the HTNSs shows strong dependence upon size,and is much higher than that of solid TiO2. With particle size decreasing, the photoactivity of the obtained HTNSs gradually increases. Without any co-catalyst, the highest photocatalytic hydrogen generation activity is obtained with HTNSs of 40 nm in diameter, which exceeds that of solid TiO2 and commercial P25 by 64 times and 3 times, respectively.

关键词： carbon nanospheres hydrothermal carbonization hollow titanium dioxide nanospheres photocatalytic hydrogen production

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Numerical Study on flow Field in a Diameter-Varying Spray Tower for Amine-Based CO2 Absorption

SSRN

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SSRN 2019年

作者： Wu, Xiaomei Yu, Yunsong Zhang, Zaoxiao Wang, Geoff Rudolph, Victor School of Chemical Engineering and Technology Xi’an Jiaotong University No.28 Xianning West Road Xi’an710049 China State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China

关键词： Greenhouse gases

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Performance of CO_2 absorption in a diameter-varying spray tower

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Chinese Journal of Chemical engineering 2017年第8期25卷 1109-1114页

作者： Xiaomei Wu Yunsong Yu Zhen Qin Zaoxiao Zhang School of Chemical Engineering and Technology Xi'an Jiaotong University State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University

The application of spray towers for CO2 capture is a development trend in recent years. However, most of the previous jobs were conducted in a cylindrical tower by using a single spray nozzle, whose configuration and performance is not good enough for industrial application. To solve this problem, the present work proposed a diameter-varying spray tower and a new spray mode of dual-nozzle opposed impinging spray to enhance the heat and mass transfer of CO2 absorption process. Experiments were performed to investigate the mass transfer performance （in terms of the CO2 removal rate （η） and the overall mass transfer coefficient （KGae）） of the improved spray tower under various operating conditions. Experimental results showed that the liquid to gas ratio and mole ratio of MEA to C02 are major factors, which affect the absorption performance and the maximums of η and KGae that are 94.0% and 0.574 kmol. m^-3·h^-1·kPa^-1, respectively, under the experimental conditions. Furthermore, new correlations to predict the mass transfer coefficient of the proposed spray tower are developed in various CO2 concentrations with a Pearson Correlation Coefficient over 90%.

关键词： Carbon dioxide Absorption Diameter-varying spray tower Mass transfer

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Rapid Prediction Models for Oil Temperature and Surrounding Environment Temperature Fields in Buried Hot Crude Oil Pipelines

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Journal of Pipeline Systems engineering and Practice 2025年第3期16卷

作者： Yan, Feng Xu, Jingyan Li, Qifu Zhou, Chaoqun Ji, Mingyang Gong, Junhua Xiang, Yue Chen, Yujie Han, Dongxu Wang, Peng Dept. of Storage and Transportation Technology Research PipeChina Research Institute of Science and Technology 4 Dongting 1st Rd. Binhai New Area Tianjin300450 China Project Management Center of Production and Operation Dept Northeast Company of PipeChina Hunnan District Liaoning Province Shenyang110000 China Dept. of Production and Operation Changqing Oil and Gas Transportation Branch of Northwest Company of PipeChina Xingqing District Yinchuan Ningxia750004 China School of Mechanical Engineering Beijing Institute of Petrochemical Technology Beijing102617 China State Key Laboratory of Multiphase Flow in Power Engineering Xi'An Jiaotong Univ Xi'an710049 China Dept. of Digital Twin for Energy and Power Systems Sichuan Energy Internet Research Institute Tsinghua Univ Sichuan610213 China

Wax-rich or high-viscosity crude oil requires heating for long-distance transportation in buried pipelines. Monitoring the temperature distributions and variations of both oil and surrounding environment is crucial to ensuring safety and economic efficiency. This study proposes two models for rapidly predicting the steady-state oil temperature and surrounding environment temperature fields based on the Fourier neural operator (FNO) network and U-shaped network (UNet), respectively. These models leverage numerical results as training data, incorporating boundary conditions and environment grid coordinates at the pipeline cross section as inputs to predict the temperature distributions of both oil and the surrounding environment along the buried pipeline. With optimized hyperparameters, the models achieve accurate and efficient predictions. The FNO and UNet models had average RMS errors (RMSEs) in environment temperature field prediction of 2.68×10-3 and 5.49×10-3 at the pipeline cross section, respectively. For oil temperature predictions, the FNO model had an average relative error of 1.49×10-4, compared with 2.55×10-4 for the UNet model, with average absolute error values of 5.32×10-3 and 7.24×10-3, respectively. Moreover, both models exhibited strong generalization, with an average RMSE in the environment temperature field prediction of less than 3.5×10-2 and an average relative error in oil temperature predictions of less than 2.1×10-3 across different data sets. Comparatively, the FNO and UNet model had slightly higher prediction accuracy than the UNet model. In terms of computational efficiency for a 100-km pipeline, these models offer improvements of at least 116.25× over the numerical simulation method, with a maximum improvement of 1,775.03× as the number of simultaneously predicted pipeline cross sections increases. © 2025 American Society of Civil Engineers.

关键词： flowlines

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Current Density Regulating Lithium Metal Directional Deposition for Long Cycle Life Lithium Metal Batteries

SSRN

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SSRN 2020年

作者： Mao, Heng Yu, Wei Cai, Zhuanyun Liu, Guixian Liu, Limin Wen, Rui Su, Yaqiong Xi, Kai Li, Benqiang Da, Xinyu Kou, Huari Yan, Wei Ding, Shujiang Xi'an Key Laboratory of Sustainable Energy Materials Chemistry School of Chemistry Xi’an Jiaotong University & Shaanxi Quantong Joint Research Institute of New Energy Vehicles Power Xi’an Jiaotong University Xi’an710049 China State Key Laboratory of Physical Chemistry of Solid Surfaces Department of Chemistry College of Chemistry and Chemical Engineering Xiamen University Xiamen361005 China Key Laboratory of Molecular Nanostructure and Nanotechnology Beijing National Laboratory for Molecular Sciences CAS Research/Education Center for Excellence in Molecular Sciences Institute of Chemistry Chinese Academy of Sciences Beijing100190 China Cambridge Graphene Centre Department of Engineering University of Cambridge CambridgeCB3 0FA United Kingdom Department of Mechanical Engineering University of Michigan-Dearborn DearbornMI48128 United States Department of Environmental Science and Engineering State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China

Uncontrolled dendrite formation in the high energy density of lithium metal batteries (LMBs) may pose serious safety risks. Numerous works have been reported to protect separator. However, these methods still couldn’t inhibit the dendrite upward growth to protect the separator, effectively. Here, we introduce a novel “orientated-growth” strategy that makes the depositional interface transfer to the anode/current collector interface from the anode/separator interface. We placed a layer of cellulose/graphene carbon composite aerogel (CCA) between the current collector and the anode (CCA-Li). This layer works as the charge organizer;it induces a higher current density distribution and makes Li prefer to deposit in the bottom CCA layer of CCA-Li electrode. Both in-situ and ex-situ images of the electrode demonstrate the anode part of the cell has been flipped;with the new deposited particles facing the current collector and smooth surface facing the separator. Electrochemical characterization of the electrode in half and full cells showed outstanding cyclic stability and rate capability, with the CCA-Li/LPF full cell able to maintain 94% of its initial capacity after 1000 cycles. We believe that the innovative strategy would promote the leapfrog development for LMBs. © 2020, The Authors. All rights reserved.

关键词： Electric current collectors

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Quantitative Statistical Evaluation of Micro Residual Oil after Polymer Flooding Based on X-ray Micro Computed-Tomography Scanning

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Energy & Fuels 2020年第9期34卷 10762-10772页

作者： Yongfei Yang Liu Tao Stefan Iglauer S. Hossein Hejazi Jun Yao Wenjie Zhang Kai Zhang Key Laboratory of Unconventional Oil & Gas Development China University of Petroleum (East China) Ministry of Education Qingdao 266580 People’s Republic of China Research Center of Multiphase Flow in Porous Media School of Petroleum Engineering China University of Petroleum (East China) Qingdao 266580 People’s Republic of China Petroleum Engineering School of Engineering Edith Cowan University Joondalup 6027 Western Australia Australia Porous Media Laboratory Department of Chemical and Petroleum Engineering University of Calgary Calgary Alberta Canada T2N 1N4

Polymer flooding is an important tertiary recovery method. However, even after its application, more than 50% of the oil remains in the formation layers. It is thus important for efficient resource use that both residual oil distribution and the mechanisms associated with polymer flooding are better understood. In the work described in this paper, a series of in situ X-ray tomography experiments were carried out, and different displacement stages were imaged. Then, rock, water, oil, and polymer were identified in the imagery and quantified, while interchanges among the different types of residual oil, and their associated microscopic polymer displacement mechanisms, were discussed. We also studied the impact of permeability on polymer flooding efficiency, and our results showed that polymer flooding could mobilize residual oil that was not accessible via water flooding. Mechanistically, the polymer flood caused the big continuous residual oil clusters to split, dispersing them into smaller clusters. The polymer also changed fluid flow pathways, thus increasing sweep efficiency, while its viscoelasticity was helpful for recovering singlet and film residual types of oil. We found that the polymer could only drive oil locally, and that a large amount of residual oil remained in the middle of the core. We also noted that polymer flooding was more effective for higher permeability samples, which showed that, after polymer flooding, the recovery rate for the samples with permeabilities of 3989, 1543, and 814 millidarcys (mD) were enhanced by 10.13, 6.30, and 4.34%, respectively. Higher permeability samples remained as network-type and multiple-type residual oils after polymer flooding, while samples with lower permeability showed multiple-type and singlet-type residual oils. Thus, our results and conclusions showed that different enhanced oil recovery methods could be applied for further development.

关键词： Saturation Lipids Cluster chemistry Permeability Polymers

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