Hybrid deflagration/auto-ignition flame structures coexist in the combustion of advanced *** exergy destruction caused by different irreversible processes under varied flame regimes is thus important for understanding...
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Hybrid deflagration/auto-ignition flame structures coexist in the combustion of advanced *** exergy destruction caused by different irreversible processes under varied flame regimes is thus important for understanding engine *** this study,the flame propagation modes for the premixed DME/air mixtures are numerically investigated under engine-relevant *** entropy generation and exergy destruction characteristics are compared under different flame *** reveal that as the typical premixed flame transition towards auto-ignition front,the exergy destruction from heat conduction and species mass diffusion gradually vanish and are dominated by chemical *** distributions of temperature and species mole fraction in the flame domain are analyzed to clarify the exergy destruction behaviors caused by heat conduction and mass ***,by dividing the DME oxidation process into four stages,the main reaction channels that contribute to the increase in exergy destruction from chemical reaction have been *** is found that the production and consumption of CH_(2)O and HO_(2) radical dominate the exergy destruction behavior during DME *** this basis,the kinetic mechanism of low-temperature chemistry causing greater exergy destruction is ***,low-temperature chemistry leads to significant exergy destruction due to(a)the large irreversibility of itself and(b)(mainly)the enhancement of H_(2)O_(2)loop reactions by low-temperature reaction *** the reduction of combustion irreversibility is promising to be achieved by reasonably regulating the fuel oxidation path.
Supercritical water gasification driven by solar energy is a promising way for clean utilization of biomass with high moisture content, but direct discharge of liquid residual causes energy waste and decreases energy ...
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Supercritical water gasification driven by solar energy is a promising way for clean utilization of biomass with high moisture content, but direct discharge of liquid residual causes energy waste and decreases energy efficiency. To reduce energy waste, a poly-generation system for hydrogen-rich gas production coupling heat supply and power generation based on supercritical water gasification of biomass driven by concentrated solar energy was established in this paper, which also provided a novel energy storage method to overcome the shortcomings of solar discontinuity. Thermodynamic model of the system was proposed and life cycle assessment(LCA) of the system was conducted. Influence of different parameters(temperature of 600℃ to 800℃, outlet temperature of heat exchanger of 42℃ to 56℃, biomass slurry concentration of 5% to 6.5%) on the gasification performance, energy and exergy efficiency, energy distribution and global warming potential(GWP) was discussed. The results indicated that hydrogen yield increased as gasification temperature increased since free radical reaction was enhanced which gas production reaction was classified into. Molar fraction of hydrogen increased as gasification temperature increased and reached 65.6% at 750℃. Energy and exergy efficiency of the system reached 74.84% and 34.87% at 700℃ and 600℃ respectively and that of gas production was 18.15% at 650℃, which was the highest. Increasing reaction temperature and decreasing biomass slurry concentration were effective ways to decrease GWP. Optimal operating parameter was reaction temperature of 650℃, outlet temperature of heat exchanger of 50℃ and biomass concentration of 5%.
The coarse graining of particle cluster is of great significance to the study of a fluidized bed. The effects of variations in the physical properties of supercritical water on the coarse graining of particle cluster ...
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The coarse graining of particle cluster is of great significance to the study of a fluidized bed. The effects of variations in the physical properties of supercritical water on the coarse graining of particle cluster are investigated in this work. The drag coefficient distributions of the particle cluster are not influenced by the physical properties. However, the physical properties have effects on the values of drag coefficient. The effects of physical properties are weaker in the case of large particle concentrations. Furthermore, the physical properties lead to that the effect of particle cluster wake on the drag of downstream particles being significantly different from that of constant property flow. The variation trend of drag of coarse graining particle is consistent with that of isolated particle. The physical properties lead to significant differences in the values of drag. In this paper, the dominance of the effects of physical properties in a variety of cases is confirmed. Finally, a physical properties effect model is developed accordingly.
Two-dimensional graphene nanopores have shown great promise as ultra-permeable molecular sieves based on their size-sieving effects. We design a nitrogen/hydrogen modified graphene nanopore and conduct a transient non...
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Two-dimensional graphene nanopores have shown great promise as ultra-permeable molecular sieves based on their size-sieving effects. We design a nitrogen/hydrogen modified graphene nanopore and conduct a transient non-equilibrium molecular dynamics simulation on its molecular sieving effects. The distinct time-varying molecular crossing numbers show that this special nanopore can efficiently sieve CO_2 and H_2S molecules from CH_4 molecules with high selectivity. By analyzing the molecular structure and pore functionalization-related molecular orientation and permeable zone in the nanopore, density distribution in the molecular adsorption layer on the graphene surface, as well as other features, the molecular sieving mechanisms of graphene nanopores are revealed. Finally, several implications on the design of highly-efficient graphene nanopores, especially for determining the porosity and chemical functionalization, as gas separation membranes are summarized based on the identified phenomena and mechanisms.
The supercritical water fluidized bed(SCWFB)is a recently introduced reactor for biomass gasification that does not release *** groups of Geldart B-type quartz sands with different particle sizes were fluidized at a s...
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The supercritical water fluidized bed(SCWFB)is a recently introduced reactor for biomass gasification that does not release *** groups of Geldart B-type quartz sands with different particle sizes were fluidized at a system pressure of 20-27 MPa and system temperature of 410-570℃.A series of experiments were performed for determining the drag coefficient and volume fraction of *** effects of the particles’size,superficial velocity,system pressure,and temperature on the drag coefficient and volume fraction are *** addition,a correlation between experimental and computed values is demonstrated for both the drag coefficient and volume fraction in *** relative error of the correlation is within±30%.The results of this study provide significant guidance for the scaling-up design of SCWFBs and for the development of supercritical water gasification technology.
An Eulerian/Lagrangian numerical simulation is performed on mixed sand transport. Volume averaged Navier-Stokes equations are solved to calculate gas motion, and particle motion is calculated using Newton＇s equation,...
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An Eulerian/Lagrangian numerical simulation is performed on mixed sand transport. Volume averaged Navier-Stokes equations are solved to calculate gas motion, and particle motion is calculated using Newton＇s equation, involving a hard sphere model to describe particle-to-particle and particle-to-wall collisions. The influence of wall characteristics, size distribution of sand particles and boundary layer depth on vertical distribution of sand mass flux and particle mean horizontal velocity is analyzed, suggesting that all these three factors affect sand transport at different levels. In all cases, for small size groups, sand mass flux first increases with height and then decreases while for large size groups, it decreases exponen- tially with height and for middle size groups the behavior is in-between. The mean horizontal velocity for all size groups well fits experimental data, that is, increasing logarithmically with height in the middle height region. Wall characteristics greatly affects particle to wall collision and makes the fiat bed similar to a Gobi surface and the rough bed similar to a sandy surface. Particle size distribution largely affects the sand mass flux and the highest heights they can reach especially for larger particles.
Porous particle flow is universal in nature and ***,in previous numerical simulations,porous particles have usually been assumed to be *** is necessary to study the flow and heat-transfer characteristics around porous...
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Porous particle flow is universal in nature and ***,in previous numerical simulations,porous particles have usually been assumed to be *** is necessary to study the flow and heat-transfer characteristics around porous particles because they are greatly different from those of impermeable *** this study,two-dimensional steady flow and heat transfer around and through a porous particle with a constant temperature placed in a cold fluid were numerically *** effects of the Reynolds number(Re)and Darcy number(Da)on the flow and heat-transfer characteristics were investigated in *** investigated ranges of the parameters were 10≤Re≤40 and 10^(−6)≤Da≤10^(−2).It is sophisticated to simulate porous particles with traditional simulation methods because of their complicated ***,the lattice Boltzmann method was used to solve the generalized macroscopic governing equations because of its *** drag coefficient decreased with increasing Re or Da,but the decrease was not prominent in the range 10^(−6)≤Da≤10^(−4).The heat-transfer efficiency of the front surface was much stronger than that of the rear *** heat-transfer efficiency between the particle and the fluid increased with increasing Re or ***,for 10^(−6)≤Da≤10^(−4),the increase was not prominent and the heat-transfer enhancement ratio was slightly larger than ***,the effect of Da became more prominent at larger *** addition,new correlations for the drag coefficient and surface-averaged Nusselt number were obtained based on the simulated results.
Liquid Droplet Radiator (LDR) system is regarded as a quite promising waste heat rejection system for aerospace engineering.A comprehensive review on the state-of-the-art of LDR system was carried *** thermal design c...
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Liquid Droplet Radiator (LDR) system is regarded as a quite promising waste heat rejection system for aerospace engineering.A comprehensive review on the state-of-the-art of LDR system was carried *** thermal design considerations of crucial components such as working fluid,droplet generator and collector,intermediate heat exchanger,circulating pump and return pipe were *** state-of-the-art of existing mathematical models of radiation and evaporation characteristics of droplet layer from literatures were ***,thermal designs of three LDR systems were *** weight and required planform area between the rectangular and triangular LDR systems were respectively compared and the evaporation models for calculating the mass loss were *** on the review,some prospective studies of LDR system were put forward in this paper.
Researches on solids mixing and segregation are of great significance for the operation and design of fluidized bed *** this paper,the local and global mixing and segregation characteristics of binary mixtures were in...
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Researches on solids mixing and segregation are of great significance for the operation and design of fluidized bed *** this paper,the local and global mixing and segregation characteristics of binary mixtures were investigated in a gas–solid fluidized bed by computational fluid dynamics-discrete element method(CFD-DEM)coupled approach.A methodology based on solids mixing entropy was developed to quantitatively calculate the mixing degree and time of the *** mixing curves of global mixing entropy were acquired,and the distribution maps of local mixing entropy and mixing time were also *** comparing different operating conditions,the effects of superficial gas velocity,particle density ratio and size ratio on mixing/segregation behavior were *** showed that for the partial mixing state,the fluidized bed can be divided into three parts along the bed height:complete segregation area,transition area and stable mixing *** areas showed different mixing/segregation *** gas velocity promoted the local and global mixing of binary *** increase in particle density ratio and size ratio enlarged the complete segregation area,reduced the mixing degree and increased the mixing time in the stable mixing area.
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