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Study on the characteristics of flowing organization in DMFC. Part I: Model development of cell with conventional symmetrical plates

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Taiyangneng Xuebao/Acta Energiae Solaris Sinica 2008年第9期29卷 1155-1160页

作者： Yin, Benhao He, Yaling Li, Xianglin Miao, Zheng State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China

A two-dimensional, steady-state model of a direct methanol fuel cell (DMFC) with liquid methanol feed was developed. The electrode kinetics, multi-component transport and methanol crossover phenomenon were all considered. The effect of channels disposal density, the influence of backing layer, catalyst layer and polymer electrolyte membrane thickness on mass transfer and cell performance was investigated. The results showed that: with the increase of channels disposal density and the increase of catalyst layer thickness, the equality of reaction rate and cell performance will elevated. The sizes of catalyst layer and membrane effect farthest, the correspondingly optimized work can increase the average current density about 131.0% and 17.8%. There are moderate optimal thickness sizes of backing layer and membrane, and the sizes should be chosen after thinking about the sizes of flow field plate and MEA.

关键词： Methanol

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Accuracy analysis of moving particle semi-implicit method

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Kung Cheng Je Wu Li Hsueh Pao/Journal of engineering Thermophysics 2011年第SUPPL. 1期32卷 146-149页

作者： Duan, Guang-Tao Chen, Bin State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China

The viscous and pressure gradient terms, which can be solved by Green Function method theoretically, are calculated separately in MPS method. Through the analysis of kernel function, an accuracy condition of viscous term is proposed and the reasonable match between spatial and time step will increase the accuracy and stability of MPS method. Poiseuille flow is simulated and the accuracy condition is validated. In the analysis of the source term of Pressure Poisson equation, the particle number density (PND), which is very sensitive to the relative configuration of particles, yields the deviation of velocity profile from the theoretical solution. It is the fluctuation in PND that causes the spurious fluctuation of pressure.

关键词： Poisson equation

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Development of a Two-Phase flow Solver with Drift-Flux Model Based on Openfoam: Validation Against Single/Two-Phase and Boiling flow

SSRN

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SSRN 2024年

作者： Wu, Wenqiang Zhang, Dalin Huang, Tao Du, Peng Zhou, Lei Wang, Bo Deng, Jian Qiu, Zhifang Tian, Wenxi Qiu, Suizheng Su, Guanghui State Key Laboratory of Multiphase Flow in Power Engineering Shaanxi Key Laboratory of Advanced Nuclear Energy and Technology School of Nuclear Science and Technology Xi’an Jiaotong University Shaanxi Xi’an710049 China Nuclear Power Institute of China 328 Changshun Avenue Chengdu610213 China

Based on the open-source platform OpenFOAM, this paper implements a two-phase flow solver for drift flux models with realistic closure relations. The solver inherits the numerical method from the OpenFOAM framework, adopts the PIMPLE algorithm, and follows its discrete and matrix-solving criteria, focusing on developing a two-phase flow model and constitutive models. The drift velocity model is based on Ishii and his collaborators’ work. The remaining models, such as wall friction, wall heat transfer, interfacial heat and mass transfer, are taken from TRACE Theory Manual. To fulfill the condition of conjugate heat transfer between fluid and solid, a virtual solid heat transfer function is developed under the premise of a single-domain solver. Extensive and successful validation has been conducted involving single-phase, two-phase, and boiling flow heat transfer phenomena by comparing with experimental data or typical system codes, and the two-phase flow solver's success has been demonstrated in several aspects. © 2024, The Authors. All rights reserved.

关键词： Two phase flow

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Inuence of Nozzle Type on Spray Characteristics and Surface Heat Transfer in Cryogen Spray Cooling

引用

Kung Cheng Je Wu Li Hsueh Pao/Journal of engineering Thermophysics 2017年第12期38卷 2646-2650页

作者： Wang, Rui Yang, Tao Zhou, Zhi-Fu Chen, Bin Wang, Guo-Xiang State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China

Cryogen spray cooling has been applied to protect epidermis from thermal damage in laser dermatology. However, present clinical application suffers insufficient cooling capacity and non-uniform surface cooling. In present paper, the comparison research of nozzle type is conducted to investigate its influence on spray characteristics and surface heat transfer in cryogen spray cooling. The results show that the substitution of expansion-chambered nozzle or two-phase nozzle may improve therapy outcomes for their high cooling efficiency and precise cooling control. © 2017, Science Press. All right reserved.

关键词： Cooling

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Measurement of diffusion coefficient using Michelson interferometry

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Yi Qi Yi Biao Xue Bao/Chinese Journal of Scientific Instrument 2008年第SUPPL. 2期29卷 488-492页

作者： Guo, Ying He, Maogang Zhang, Ying Zhong, Qiu State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China

In this paper, an experimental system for the measurement of mass diffusion coefficient using Michelson laser holographic Interferometry was designed and constructed. The experimental system include: the subsystem of Michelson interferometer, the diffusion cell for the mass diffusion of liquid-liquid, the subsystem of thermostatic water bath, the subsystem of image collecting and image processing. The mass diffusion coefficients of 0.33 molL-1 KCI solution with water at the temperature of 289.15 K were measured, and the result shows that the average of relative deviations is 1.30% compared with the literature values, and it verified the accuracy and reliability of the system. The mass diffusion coefficients of 0.1 molL-1 saccharose with water at 5 different temperature were measured, and the result shows that the biggest relative deviations is within 5% which verified the reliability of the system further.

关键词： Michelson interferometers

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Preparation of CdS photocatalyst and its performance of hydrogen production

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Wuhan Ligong Daxue Xuebao/Journal of Wuhan University of Technology 2006年第SUPPL. 2期28卷 164-168页

作者： Zhang, Xiang-Hui Jing, Deng-Wei Xing, Chan-Juan Guo, Lie-Jin State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China

Cadmium sulfide photocatalyst was prepared by hydrothermal methods with one-step and two-step methods, respectively. Platinum was loaded on the surface of prepared photocatalysts and its optimal loading amount was examined. All the prepared photocatalysts were characterized by XRD, UV-Vis, XRF, SEM and TEM and their pohtocatalytic activity was evaluated by H2 evolution from water under visible light. It was found that the photocatalyst prepared by two-step showed markedly improved hydrogen production activity.

关键词： CdS Hydrogen production Photocatalyst

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Mild Combustion of a Premixed Nh3/Air Jet Flame in Hot Coflow Versus its Ch4/Air Counterpart

SSRN

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SSRN 2023年

作者： Li, Pengfei Wang, Guochang Liu, Xiangtao Shi, Guodong Cai, Xiao Liu, Zhaohui Mi, Jianchun State Key Laboratory of Coal Combustion School of Energy and Power Engineering Huazhong University of Science and Technology Wuhan430074 China College of Engineering Peking University Beijing100871 China State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China Dalian Maritime University China

MILD combustion is very suitable for solving the problems of unstable flame and high NOx emission (ENOx ) for ammonia fuel, but the related studies are rare. This work numerically investigates the MILD combustion characteristics of a premixed NH3/air jet flame in hot coflow (JHC) under different jet equivalence ratio (ΦJ), coflow temperature (TC) and oxygen level (XO2,C). For comparison, the similar CH4/air MILD-JHC flames are also calculated. Results show that the NH3 flame generally has lower temperature rise and heat release as well as larger reaction zone than CH4. This may suggest that the former flame can develop to the MILD regime more easily. ENOx is two orders higher from the NH3 than CH4 flame at all TC and XO2,C for ΦJ 1, ENOx of the NH3 flame quickly drops to near zero, but ENH3 and EH2 are very high (~1000 ppm) and the combustion efficiency is low. Moreover, ENOx increases quickly (slowly) with XO2,C (TC) while ENH3 and EH2 are quite low at TC ≥ 1300 K and XO2,C ≥ 1% for the NH3 flame. ENOx mainly comes from NO but N2O is also important at low ΦJ and TC. Therefore, considering all ENOx , ENH3, EH2 and the burning efficiency, the optimal conditions for NH3 MILD combustion are ΦJ =1, TC ≥ 1500 K and XO2,C =1%-3%. In addition, compared to the conventional flame, the NH3 MILD combustion can reduce ENOx by 1-2 orders. © 2023, The Authors. All rights reserved.

关键词： Ammonia

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Experimental study on the contribution of included/excluded minerals to particulate formation during coal char combustion

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Fuel 2023年第1期346卷

作者： Shang, Yimin Liu, Siqi Niu, Yanqing Zhu, Guangqing Cheng, Zening Hui, Shi'en State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi'an Jiaotong University Shaanxi710049 China China Nuclear Power Technology Research Institute Shenzhen518031 China Zhundong Energy Research Institute Xinjiang Tianchi Energy Co. Ltd. Xinjiang831100 China

The contributions of included and excluded minerals to particulate matter formation are quantified in this work. By devolatilization of three typical Chinese coals, three coal chars with low (LA), moderate (MA), and high ash (HA) content (with both included and excluded minerals) were prepared, from which three float coal chars with low (LA−), moderate (MA−), and high ash (HA−) content (without excluded minerals) were separated by density differentiation method. The coal chars before and after separation were burned in a drop-tube furnace at 1600 K, the results of three float coal chars can directly reveal the contribution of included minerals, and the comparison of two kinds of chars with and without excluded minerals would reveal the excluded mineral contribution to ash distribution. The size distributions of the combustion-generated ash particle were obtained from the combination of ELPI+ and laser particle-size analyzer. The fractions of included/excluded minerals were obtained from SEM images. The results from the combustion of the float chars indicate the physical transformation of included minerals, while the results from original coal chars involve the transformation of both included and excluded minerals. Results indicate that the distribution of ash particles from included minerals for HA− char possesses a single peak, while the ash distributions of MA− and LA− char show a bi-modal shape. The excluded minerals in LA and MA chars mainly contribute to the ash emissions with sizes larger than 80 μm. The contribution from excluded minerals reach 86% to the ash particles of 205 μm for HA char, 54% for MA char and 51% for LA char. The number fractions of included minerals continuously decrease with a transformation into excluded minerals during char dynamic combustion. © 2023 Elsevier Ltd

关键词： Minerals

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Light doping of tungsten into copper-platinum nanoalloys for boosting their electrocatalytic performance in methanol oxidation

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Nano Research Energy 2022年第2期1卷 194-200页

作者： Danye Liu Qing Zeng Chaoquan Hu Dong Chen Hui Liu Yongsheng Han Lin Xu Qingbo Zhang Jun Yang State Key Laboratory of Multiphase Complex Systems Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China Nanjing IPE Institute of Green Manufacturing Industry Nanjing 211100China School of Chemistry and Materials Science Jiangsu Key Laboratory of New Power BatteriesJiangsu Collaborative Innovation Centre of Biomedical Functional MaterialsNanjing Normal UniversityNanjing 210023China Department of Bioengineering Rice UniversityHoustonTexas 77005USA

Coupling the bi-functional mechanism with compressive lattice strain might be an effective way to boost the electrocatalysis of platinum(Pt)-based nanoparticles for methanol oxidation reaction(MOR).This strategy weakens the chemisorption of poisoning CO-like intermediates generated during MOR on the active Pt sites by lowering their d-band *** this context,we herein report the synthesis of ternary copper-tungsten-platinum(CuWPt)nanoalloys with light doping of W element by simply co-reducing their precursors at elevated *** this ternary alloy system,the presence of only small amount of W element not only weakens the chemisorption of CO-like intermediates by lowering the Pt d-band center through compressive lattice strain,but also cleans the active Pt sites by“hydrogen spillover effect”,endowing the as-prepared CuWPt nanoalloys at an appropriate Cu/W/Pt ratio with good activity for *** specific,the ternary CuWPt alloy nanoparticles at a Cu/W/Pt molar ratio of 21/4/75 show a specific activity of 2.5 mA·cm^(−2)and a mass activity of 2.11 A·mg^(−1)with a better durability,outperforming those ternary CuWPt alloy nanoparticles at other Cu/W/Pt ratios,binary CuPt alloys and commercial Pt/C catalyst as well as a large number of reported Pt-based *** addition,a single direct methanol fuel cell(DMFC)assembled using ternary CuWPt nanoalloys as anodic catalysts shows a power density of 24.3 mW·cm^(−2)and an open-circle voltage of 0.6 V,also much higher than those of the single DMFC assembled from commercial Pt/C catalysts.

关键词： lattice strain d-band center electrocatalysis hydrogen spillover methanol oxidation reaction

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Clogging failure in microfilter for blood cell separation and Its novel improvements tao dong

Clogging failure in microfilter for blood cell separation an...

引用

2009 16th IEEE International Symposium on the Physical and Failure Analysis of Integrated Circuits, IPFA 2009

作者： Yang, Zhaochu Egeland, Eirik Bentzen Karlsen, Frank Jakobsen, Henrik Norwegian Center of Expertise on Micro- and Nanotechnology Vestfold University College I.M.S.T./R.I. Norway State Key Lab. of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an China NorChipTM A.S. Industriveien 8 N-3490 Klokkarstra Norway

ISBN: (纸本)9781424439102

Clogging failure is common for microfilter utilizing the flat membrane structure. To reduce clogging failure in microfilters, the turbine blade-like micropillar is introduced in microfilter design. Two improved cross-flow microfilter designs employing the blade-like micropillar barrier are presented, one with varied cross-section channels, and the other with Archimedes' spiral channels. Analogy experimental-data based simulations show that the two aforementioned novel microfilters have good filtrating efficiency and fantastic anti-clogging characteristics. and the commercial value of the turbine blade-like barriers is affirmed by the industry Partners. © 2009 IEEE.

关键词： Turbomachine blades

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