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Feasibility analysis of MA transmutation in radial fuel shuffling TWR

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Yuanzineng Kexue Jishu/Atomic Energy Science and Technology 2015年 49卷 58-62页

作者： Zheng, Mei-Yin Tian, Wen-Xi Chu, Xiao Zhang, Da-Lin Su, Guang-Hui Qiu, Sui-Zheng State Key Laboratory of Multiphase Flow in Power Engineering School of Nuclear Science and Technology Xi'an Jiaotong University Xi'an710049 China

TWR can make use of non-enriched fuel and obtain very high burnup without the need of fuel reprocessing. TWR is an effective way of fuel utilization besides the closed fuel cycle. In this paper, the feasibility of MA transmutation in a TWR was analyzed to further excavate the fuel utilization of this type of reactor. MA was homogeneously charged in the self-designed 1 250 MWt board type radial fuel shuffling sodium cooled TWR core, and the MA weight fraction is from 2.0% to 12.0%. A self-developed MCNP-ORIGEN coupled code was applied to perform burnup calculation. The results indicate that the transmutation amount increases linearly with the MA weight fraction, while the transmutation rate parabolically varies with the increase of the MA weight fraction. Neutronic safety parameters, such as the core effective multiplication factor, Doppler feedback coefficient, void worth coefficient and effective delayed neutron fraction, were compared under different MA weight fractions. The results indicate that the core effective multiplication factor and the void worth coefficient increase with the MA weight fraction, while the Doppler feedback coefficient and the effective delayed neutron fraction decrease with the increase of the MA weight fraction. © 2015, Atomic Energy Press. All right reserved.

关键词： Nuclear fuel reprocessing

Supercritical Water Gasification of Phenol with Metal Cations-A Way to Degrade Coal Industrial Wastewater and Metal-Contaminated Wastewater Simultaneously

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SSRN 2022年

作者： Cao, Wen Wang, Shaoqi Ma, Lujing Liu, Shi Jin, Hui Wei, Wenwen Guo, Liejin State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xianning West Road Xi’an710049 China Suzhou Academy of Xi’an Jiaotong University No.99 Ren’ai Road Jiangsu Suzhou215123 China

Phenol is a representative compound in coal industrial wastewater. Metal cations are the main harmful components in the wastewater of the electroplating and dyeing industries. Supercritical water gasification (SCWG) of phenol with metal cations could provide a promising way to degrade coal chemical wastewater and metal-containing wastewater simultaneously. In this study, SCWG of phenol with Mg2+, Mn2+, and Ni2+ was carried out to investigate the effect of metal cations on gasification results. Results showed that gaseous product was mainly composed of H2, CO, CH4 and CO2, and CO2 was the dominant one. Prolonging residence time and increasing the concentration of metal cations significantly increased the gas yield of CO2 and carbon gasification efficiency. Higher concentrations of metal cations facilitated methane-reforming reaction and water-gas shift reaction. Metal cations promoted the generation of 1-Ethoxybutane by the ring-breaking reaction and prevented the polymerization reaction. The order of catalytic effect was ranked as Ni2+>Mn2+>Mg2+. Mg2+, Mn2+ and Ni2+ were finally transformed into the corresponding metal hydroxides and metal oxides which could be recycled for reutilization. NiO could be reduced into metallic Ni, which consumed the H2 but effectively catalyzed SCWG of phenol. © 2022, The Authors. All rights reserved.

关键词： Phenols

Combining Core-Shell Construction with Alloying Effect for High Efficiency Ethanol Electrooxidation: A Case of Core-Shell Au@Fepd Nanoparticles with Sub-Nano Alloy Shells

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SSRN 2020年

作者： Liu, Danye Zeng, Qing Liu, Hui Hu, Chaoquan Chen, Dong Xu, Lin Yang, Jun State Key Laboratory of Multiphase Complex Systems Institute of Process Engineering Chinese Academy of Sciences Beijing100190 China State Key Laboratory of Multiphase Complex Systems Institute of Process Engineering Chinese Academy of Sciences Beijing100190 China State Key Laboratory of Multiphase Complex Systems Institute of Process Engineering Chinese Academy of Sciences Beijing100190 China State Key Laboratory of Multiphase Complex Systems Institute of Process Engineering Chinese Academy of Sciences Beijing100190 China State Key Laboratory of Multiphase Complex Systems Institute of Process Engineering Chinese Academy of Sciences Beijing100190 China School of Chemistry and Materials Science Jiangsu Key Laboratory of New Power Batteries Nanjing Normal University Nanjing210023 China State Key Laboratory of Multiphase Complex Systems Institute of Process Engineering Chinese Academy of Sciences Beijing100190 China

Combining the core-shell construction with an alloying effect is an effective way to optimize the electronic and lattice strain effects generated in core-shell configurations for achieving highly catalytic efficiency for a given electrochemical reaction. To demonstrate this concept, we herein report the use of core-shell Au@FePd nanoparticles with an Au core and a sub-nano FePd alloy shell to promote the electrocatalytic oxidation of ethanol. In these core-shell structures, the Au core modifies the electronic configuration of Pd atoms through differences in electronegativity, while the Fe component in thin shells reduces the lattice expansion of Pd induced by the Au core, both of which endows the Pd shell with an appropriate d-band center, favorable for the electrooxidation of ethanol molecules through C1 pathway. In particular, the as-prepared core-shell Au@FePd nanoparticles at an optimized Fe/Pd ratio of 0.5/1 (Au@FePd-0.5) exhibit a mass activity of 13.3 A mg-1 and a specific activity of 20.2 mA cm-2 for the ethanol electrooxidation in an alkaline medium, which significantly outperform those of a majority of the recent reported Pd-based electrocatalysts. This study highlights the concept of engineering the geometry and surface composition of a nanostructure for designing highly efficient electrocatalysts for a large variety of electrochemical applications. © 2020, The Authors. All rights reserved.

关键词： Shells (structures)

Experimental Study on Thermoelectric Characteristics of Heat Pipe Reactor (Nuster-100) Single Assembly

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SSRN 2022年

作者： Yang, Haiwang Wang, Chenglong Tian, Wenxi Qiu, Suizheng Su, Guanghui H. Department of Nuclear Science and Technology State Key Lab. of Multiphase Flow in Power Engineering Shaanxi Key Lab. of Advanced Nuclear Energy and Technology Xi’an Jiaotong University Shaanxi Xi’an710049 China

The heat pipe cooled reactor has the advantages of miniaturization,modularization and high inherent safety,having broad application prospects in the fields of national defense and military,space exploration and energy supply in remote *** this paper, a heat pipe-thermoelectric generator integrated experimental device similar to the heat pipe cooled reactor (NUSTER-100) Single Assembly is *** heat transfer performance of sodium heat pipe and thermoelectric performance of Half-Heusler thermoelectric generator are *** results show that after the sodium heat pipe is started,the axial temperature difference of the heat pipe is 85°C,the equivalent heat transfer coefficient is 40886W/K·m,which can provide stable heat to the thermoelectric *** performance parameters of thermoelectric generator such as open voltage,output power increase with the hot side temperature *** maximum thermoelectric conversion efficiency of single thermoelectric generator reaches 7.2%,but the efficiency of integrated experimental device is only 3.5%. © 2022, The Authors. All rights reserved.

关键词： Heat pipes

Measurement of saturated liquid density of dimethyl ether

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Kung Cheng Je Wu Li Hsueh Pao/Journal of engineering Thermophysics 2006年第5期27卷 748-750页

作者： Wu, Jiang-Tao Wang, Bin Yuan, Le-Ming Liu, Zhi-Gang State Key Lab of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China

A new vibrating tube densimeter was developed with a precision of better than ±0.5 kg/m3. Using this apparatus, the saturation liquid density of dimethyl ether was measured from 233.15 K to 320.15 K, and the max relative expanded uncertainty was 0.34%(coverage factor k = 2). The experimental data of this work were correlated as a polynomial function of the temperature with the published data of our previous work. The average and maximum relative deviation were 0.13% and 0.37%, respectively.

关键词： Dimethyl ether Saturation liquid density Vibrating tube

High-Entropy (Cocrfemnni)3o4 Catalysts for Propane Catalytic Destruction: Effect of the Precipitation Agent

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SSRN 2023年

作者： Ma, Yue Zhang, Yun Jian, Yanfei Jiang, Zeyu Chai, Shouning Li, Lu Xia, Lianghui He, Chi State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Shaanxi Xi’an710049 China Department of Physics and Information Technology Baoji University of Arts and Sciences Shaanxi Baoji721016 China National Engineering Laboratory for VOCs Pollution Control Material & Technology University of Chinese Academy of Sciences Beijing101408 China

Efficient catalytic destruction of light alkane with ultra-stable and highly symmetric structure is still an intractable issue. High entropy oxides (HEOs) with high chemical disorder and lattice distortion and superior stability have shown great potential in heterogeneous thermocatalysis. Herein, spinel-type HEOs are synthesized via a scalable co-precipitation method with different precipitants (NaOH, Na2CO3, and NaHCO3) and firstly adopted in catalytic destruction of propane. Results demonstrate that the HEO-NaOH possesses the best activity, achieving 90% of propane conversion at 325 °C with an apparent activation energy of 56 kJ·mol-1. Compared with other two HEOs, HEO-NaOH system has larger quantities of surface oxygen vacancies and easily forming several reactive oxygen species (OOH-, O2-, and OH-, etc.), which significantly contribute to the catalytic performance. Moreover, the excellent water resistance of HEOs is verified due to their high conformational entropy and structural stability. Reaction mechanism reveals that OOH- and O2- are the key species in the oxidation of C3H8, which break C-H and C-C bonds in sequence, and are then converted to oxygenated compounds via oxygen oxidation before the final mineralization. The present work provides new insights into the fabrication of efficient catalysts for light alkane destruction as well as other thermocatalytic applications. © 2023, The Authors. All rights reserved.

关键词： Sodium hydroxide

Effects of A‐Site Replacement (Sm, Y, and Pr) on Catalytic Performances of Mullite Catalysts for No Oxidation

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SSRN 2022年

作者： Chen, Lei Zhang, Chen Wu, Tiantian Huang, Boqiang Zhang, Jinping Guan, Guowei Zhang, Zaoxiao Hou, Xiaoke Hu, Chao Lu, Qiang School of Chemical Engineering and Technology Xi'an Jiaotong University Xi'An710049 China School of Chemistry Xi'an Jiaotong University Xi'An710049 China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'An China National Engineering Research Center of New Energy Power Generation North China Electric Power University Beijing China

Mullite is one of the most promising NO-SCO catalyst alternatives to the commercial Pt/Al 2 O 3 , and deciphering its intrinsic properties that affecting the catalytic performance is a great challenge but critical to the development of mullite catalysts. Herein, a series of Mn-based mullite nanofibers with different A‐site cations are synthesized by electrospinning method and used for catalytic NO oxidation. Activity tests show that SmMn 2 O 5 exhibits a better NO conversion rate (77.8%) than these of PrMn 2 O 5 (63.3%) and YMn 2 O 5 (57.5%) under typical experimental conditions ( GHSV=120 000 h -1 , T =325 °C ). To investigate the factors influencing the catalytic activity, various techniques including XRD, N 2 adsorption, SEM, TEM, EDX, XPS, H 2 -TPR and O 2 -TPR are employed, and the results show that abundant surface adsorbed oxygen species and good reducibility contribute greatly to the catalytic performance of SmMn 2 O 5 . DFT calculations revealed that A-site cation played the decisive role in the Fermi level relative to the Mn 3d-band centre, thus affecting the adsorption and dissociation of O 2 molecule. The present synthetic strategy offers a new viable route for the large-scale preparation of metal oxide catalysts with remarkable NO oxidation performance for practical application. © 2022, The Authors. All rights reserved.

关键词： Positive ions

Experimental study on potassium catalyzed gasification of large particle size biomass with CO2

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Journal of the Energy Institute 2023年 111卷

作者： Huang, Xiaole Li, Yuhang Ren, Jiyun Yang, KaiXuan Li, Ruiyu Bai, Yang Deng, Lei Che, Defu State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi'an Jiaotong University Xi'an710049 China Xi'an Thermal Power Research Institue Co. Ltd. Xi'an710032 China Shanghai Power Equipment Research Institute Co. Ltd. Shanghai 200240 China Shunde Institue of Inspection Guangdong Institue of Special Equipment Inspection and Research Foshan528300 China

Candlenut wood with large particle size is selected to investigate the biomass gasification catalyzed by potassium. The sample pore structure, the spatial distribution of potassium, and the effects of potassium salt species on the biomass gasification with CO2 are examined. The results show that the large particle candlenut wood exhibits obvious spatial anisotropy and that the pore structure is mainly distributed along the axial direction. Large particle candlenut wood has a more uniform distribution of potassium salts along the axial direction. Part of the potassium salt releases outward during the gasification, which reduces the potassium salt content in the sample center. The average potassium contents of sample loaded with KCl and biochar of sample loaded with KCl are 9.273% and 7.745%, respectively. The synthesis of polycyclic aromatic hydrocarbons in tar could be inhibited by potassium, which could also catalyze the gasification and methane removal reactions of biochar and facilitate the formation of CO and H2. Compared to raw sample (28.99%), the syngas yields from the gasification of sample loaded with KCl, sample loaded with K2CO3, and sample loaded with K2SO4 are 40.22%, 52.16%, and 41.72%, separately. The catalysis of potassium is closely related to its occupation of the active sites on biochar. The chemical bonds formed by potassium and biochar are repeatedly broken and formed during the gasification, which promotes the decomposition of organic matter. Compared with KCl and K2SO4, K2CO3 has a better catalytic effect. © 2023 Energy Institute

关键词： Biomass

Performance Analysis of Sco2 Tube with High Non-Uniform Heat Flux: Thermal-Fluid-Structural Evaluation and Optimization

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SSRN 2023年

作者： Gao, Shuo Wang, Yanjuan Li, Yi Liu, Qibin Xu, Jinliang The Beijing Key Laboratory of Multiphase Flow and Heat Transfer North China Electric Power University Beijing102206 China Institute of Engineering Thermophysics Chinese Academy of Sciences Beijing100190 China University of Chinese Academy of Sciences Beijing100190 China

Supercritical carbon dioxide (sCO2) has been a promising alternative working medium in coal-fired power plants, high-temperature solar power systems, and fuel cells. In these cases, sCO2 is in a round tube under high temperature and pressure with high non-uniform heat flux (NUH). In this study, a novel structure tube is proposed to match high NUH with thermal resistance by changing tube eccentricity. A three-dimensional (3D) multiphysical coupling model was constructed to compare the novel structure with a conventional tube. The properties of fluid dynamics, thermal stress, and coupled heat transfer were analyzed. The key working parameters were discussed. The maximum temperature of the novel structure was reduced by 13–36 K, and the maximum thermal stress was reduced by approximately 25–33% under all the simulated working conditions when the eccentricity changed from 0 to 0.4. The proposed structure can reduce the maximum temperature and thermal stress effectively under high NUH. Consequently, a novel insight is presented for the design and optimization of sCO2 tube under high NUH. © 2023, The Authors. All rights reserved.

关键词： Heat transfer