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Construction of a Transient Multi-Physics Model of Solid Oxide Fuel Cell Fed by Biomass Syngas Considering the Carbon Deposition and Temperature Effect

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SSRN 2022年

作者： Zhu, Pengfei Yao, Jing Wu, Zhen Huang, Si-Min Abu Mansor, Mohd Radzi Yang, Fusheng Zhang, Zaoxiao School of Chemical Engineering and Technology Xi’an Jiaotong University Xi’an710049 China Guangdong Provincial Key Laboratory of Distributed Energy Systems Guangdong Provincial Engineering Research Center of Distributed Energy Systems Dongguan University of Technology Dongguan523808 China Department of Mechanical and Manufacturing Engineering University Kebangsaan Malaysia Selangor43600 Malaysia State Key Laboratory of Multiphase Flow for Power Engineering Xi’an Jiaotong University Xi’an710049 China

Carbon deposition is a thorny issue for the SOFC fueled by low carbon hydrocarbons such as biomass syngas. Moreover, long-term large temperature gradients would reduce SOFC durability. Regarding these two issues, a two dimensional transient multi-physical model considering carbon deposition and temperature effect is developed for SOFC in this work. Typically due to the carbon deposition, the SOFC anode porosity decreases from 0.5 to 0.26, and the reaction activity decreases from 1.0 to about 0.45 after running 140 day. Accordingly, the current density decreases by 1.6 % at t =42 d and 6% at t =140 d, which indicates the damage of SOFC durability compared to the durability target (1%/1000h) of commercial SOFC. The maximum temperature difference of the cell is predicted to be about 106 o C. It was found that the carbon deposition and large temperature gradient are closely related to the operating parameters. With the increase of operating voltage from 0.4 V to 0.8 V, the porosity and reaction activity respectively increase by 50% and 55%, and the maximum temperature difference is reduced from 150 o C to 16 o C after running 140 day. The increase of the inlet temperature could improve the overall temperature and decrease the porosity. Besides, the reduction in the ratio of CH 4 to H 2 O helps to suppress carbon deposition, thus to improving the performance. © 2022, The Authors. All rights reserved.

关键词： Solid oxide fuel cells (SOFC)

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Evaluation on Hydrothermal Gasification of Styrene-Butadiene Rubber with Oxidants Via Reaxff-Md Simulation

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SSRN 2023年

作者： Nie, Shaoqiang Chen, Meiqian Li, Qinghai Institute of Thermal Engineering School of Mechanical Electronic and Control Engineering Beijing Jiaotong University Beijing100044 China Beijing Key Laboratory of Flow and Heat Transfer of Phase Changing in Micro and Small Scale Beijing100044 China Key Laboratory for Thermal Science and Power Engineering of Ministry of Education Department of Energy and Power Engineering Tsinghua University Beijing100084 China

Styrene-butadiene rubber (SBR) is widely used in tires, which brings great challenge to the disposal and reclaiming of the used tires. The ring-opening reaction pathways of benzene rings in hydrothermal gasification of styrene-butadiene rubber were revealed based on reactive force field molecular dynamics (ReaxFF-MD) simulation. H-abstraction reaction that OH radicals capture H atom from the vinyl group of styrene was critical to degrade styrene monomers. The energy barrier of H2O2 converted to OH radicals was lower than that of O2 and pure water converted to OH radicals. The oxidants that can urge OH radical formed in reaction were beneficial to SBR degradation, which could be assigned to confirm that SBR degradation with H2O2 was better than that with oxygen at the same concentration. The addition of oxidant could be helpful for decreasing the degradation temperature of styrene monomers. At oxygen equivalent ratio (ER) of 0.1, H2 yield at 2500 K lifted after 135 ps and increased by 75% at 500 ps compared with that without oxidants. According to chemical equilibrium analysis, the optimal ER for H2 was 0.4 between 350-600 ºC (real temperatures). The results could provide theoretic support and experiment guidance for adding oxidants in reclaiming waste rubber products. © 2023, The Authors. All rights reserved.

关键词： Oxygen

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Rationally Engineered Reox-Cuso4/Tio2 Catalyst with Superior Nh3-Sco Efficiency and Remarkably Boosted So2 Tolerance: Synergy of Acid Sites and Surface Adsorbed Oxygen

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SSRN 2022年

作者： Yu, Yanke Wei, Desheng Tong, Zhaojian Wang, Jinxiu Chen, Jinsheng He, Chi Department of Environmental Science and Engineering School of Energy and Power Engineering Xi’an Jiaotong University Xi’an710049 China Center for Excellence in Regional Atmospheric Environment Institute of Urban Environment Chinese Academy of Sciences Xiamen361021 China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Shaanxi Xi'An710049 China National Engineering Laboratory for VOCs Pollution Control Material & Technology University of Chinese Academy of Sciences Beijing101408 China

Ammonia (NH3) is a critical component causing environmental problems like haze and water pollution. Selective catalytic oxidation of ammonia (NH3-SCO) to N2 and H2O is a promising method to abate NH3 emission. However, inferior SO2 tolerance is still a tremendous challenge to be conquered for present NH3-SCO catalysts regarding practical applications. Application of materials which was difficult to be sulfated by SO2 should be an effective pathway to solve this problem. Here, a ReOx-CuSO4/TiO2 catalyst which coupled the advantages of ReOx (Rhenium oxides, supplying highly active adsorbed surface oxygen for enhancing NH3-SCO reaction) and CuSO4 (providing Brønsted acid sites for inhibiting the formation of N2O) was rationally fabricated. Results indicated that ReOx-CuSO4/TiO2 catalyst performed excellent catalytic performance in NH3-SCO with almost 100% of NH3 oxidized at 300 °C (N2 selectivity as high as 96%). Crucially, the composite catalyst exhibited incredible activity and stability under harsh reaction conditions toward SO2 (600 ppm) and H2O (4.0 vol.%) owing to the superior inhibition capability for SO2 adsorption. In situ DRIFTS, in situ Raman and in situ XPS demonstrated that the NH3-SCO reaction over ReOx-CuSO4/TiO2 catalyst mainly obeyed a N2H4 reaction mechanism and oxidation-reduction circle between Re7+ and Re6+ played a vital role. In addition, SO2 would not affect this reaction mechanism on ReOx-CuSO4/TiO2 catalyst. The knowledge and understanding reported could provide critical insights for the design and optimization of efficient materials for industrial NH3 oxidative elimination. © 2022, The Authors. All rights reserved.

关键词： Ammonia

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Zif-L(Co) Derived Cobalt Doped In2o3 Hollow Nanofibers with High Surface Activity for Efficient Formaldehyde Gas Sensing

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SSRN 2023年

作者： Zhu, Lei Wang, Jianan Liu, Jianwei Wang, Ze Sun, Shiyi Li, Mingtao Yan, Wei Xi’an Key Laboratory of Solid Waste Resource Regeneration and Recycling State Key Laboratory of Multiphase Flow Engineering Xi’an Jiaotong University Xi’an710049 China School of Physics and Electrical Engineering Weinan Normal University Chaoyang Street Weinan714099 China School of Chemistry and Chemical Engineering Xi’an University of Science & Technology Xi’an710054 China

Gas sensors based on semiconductor metal oxides are identified as a highly promising candidate for toxic gas detection, yet they still suffer from high operating temperature due to low surface activity at low temperature. To address this issue, we present an elaborate design for the homogeneous functionalization of ZIF-L(Co) derived cobalt (Co) catalysts into hollow In2O3 frameworks, aiming to highly activate the redox capacity and catalytic efficacy of the In2O3 sensor to HCHO gas. Benefiting from the Co catalysts doping boosts the catalytic activity and generates abundant oxygen vacancies, the optimized 1 wt% Co-doped In2O3 HNFs sensor exhibits a high response of 40.4 toward 100 ppm HCHO at a moderately low temperature of 180 ℃, which is 4 times higher than that of pristine In2O3 HNFs. Moreover, 1 wt% Co-doped In2O3 HNFs sensor has virtues of high selectivity and excellent long-term stability for HCHO sensing. This study highlights the important influence of Co catalyst on the modulation of surface active sites of metal oxides-based sensors, inspiring the development of cost-effective sensors for indoor hazardous gas monitoring. © 2023, The Authors. All rights reserved.

关键词： Cost effectiveness

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Experimental Study on Fragmentation Characteristics of Molten Stainless Steel Discharged into Liquid Lbe Pool

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SSRN 2024年

作者： Fan, Shuowang Chen, Yutong Zhang, Dalin Deng, Jian Zhang, Xisi Wu, Xiaoli Tian, Wenxi Qiu, Suizheng Su, Guanghui School of Nuclear Science and Technology Shaanxi Key Laboratory of Advanced Nuclear Energy and Technology State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi’an710049 China Shanghai Nuclear Engineering Research and Design Institute Co. Ltd 29 Hongcao Road Shanghai200233 China Nuclear Power Institute of China 328 Changshun Avenue Chengdu610213 China China Institute of Atomic Energy Beijing611731 China

The LFR is a candidate for the Generation-IV nuclear systems, where the process of MFCI differs from that occurred in LWRs and SFRs. In the absence of experimental study and widely applied theoretical models for LFRs, experiments on the interaction between molten SS and liquid LBE are conducted in this study under eight conditions. The morphological characteristics and fragment sizes of the products are analyzed based on the hydrodynamic effect parameter (We) and thermal effect parameter (Tic). Simplified thermal fragmentation models are established, where the innermost layer of the solidified shell is subjected to the maximum tangential compressive stress, while the outermost layer is subjected to the maximum tangential tensile stress. As the shell thickness increases, the total tangential stress of the outermost layer decreases. The fragmentation will occur when the maximum tangential stress on the shell exceeds the shell tensile strength. © 2024, The Authors. All rights reserved.

关键词： Tensile strength

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Investigations on affinity law under gas–liquid conditions in multistage radial and mixed-flow multiphase pumps

International Journal of Fluid Engineering

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International Journal of Fluid engineering 2024年第1期1卷 56-70页

作者： Liang Chang Chenyu Yang Xiaobin Su Xiaoyu Dai Qiang Xu Liejin Guo State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049China

Affinity laws have been widely used in pump design and simulation under high-temperature and corrosive *** applying such laws,it is possible to shorten development cycles and reduce test ***,current applications of affinity laws are still limited to liquid *** this paper,expressions for affinity laws and their applicability are investigated for multistage radial and mixed-flow multiphase pumps under gas–liquid conditions.A high-pressure(30 MPa)gas–liquid experimental platform is constructed,and three-stage and 25-stage radial pumps and a 15-stage mixed-flow pump are investigated,with specific speeds of 107 and *** gas compressibility taken into account,the gas–liquid two-phase flow rate,head,and power,and the corresponding dimensionless hydraulic coefficients,are defined for multiphase *** deterioration of gas–liquid pressurization performance is found to be divided into three processes with different dynamic mechanisms,corresponding to three flow *** inlet gas volume fraction of pump is used to judge dynamic *** the same inlet gas volume fractionsλ_(1)=λ_(2),when the gas–liquid flows in two pumps have the same flow pattern,dynamic similarity will be *** affinity law that is established shows good applicability to the three-stage radial multiphase pump,with goodness of fit R^(2)larger than 0.9 for the two-phaseΨ_(m)–Φ_(m)andΠ_(m)–Φ_(m)performance ***,experimental results indicate that the affinity law also has good applicability to multiphase pumps with different stage numbers and blade structures under gas–liquid conditions.

关键词： flow law radial

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Pattern and Dynamics of Methane/Water Two-Phase flow in Deep-Shale Illite Nanoslits

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SSRN 2024年

作者： Wang, Rui Yang, Xu Li, Gao Zheng, Wenxiu Zou, Zhenhai Sun, Chengzhen State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Shaanxi Xi’an710049 China State Key Laboratory of Oil and Gas Reservoir Geology and Exploration Southwest Petroleum University Sichuan Chengdu610500 China Air and Missile Defense College Air Force Engineering University Shaanxi Xi’an710051 China Wuhan Second Ship Design and Research Institute Wuhan430202 China

Developing deep shale gas is crucial for the sustainable development of unconventional energy sources. Deep shale has a high illite content, and understanding the structure and flow behaviors of methane and water coexisting in deep shale illite nanoslits is essential for methane transport and production in deep shale reservoirs. Here, molecular dynamics simulations were performed to investigate the methane and water flow characteristics in slit-shaped illite nanopores. The effects of water saturation, acceleration, and pore size on two-phase flow are elucidated. The results show that water molecules preferentially adsorb on the surface of the illite channel. As the water saturation increases, the water phase gradually forms a water film, water bridge, and water lock, ultimately creating methane nanobubbles surrounded by the water phase. The existence of the water phase compresses the methane flow space. With increasing water saturation, the peak methane density near the channel wall gradually disappears, and the density distribution curves show parabolic shapes. The methane flow flux decreases with the increase of water saturation, mainly when the water saturation increases from 0% to 40%. In illite slits with pore sizes ranging from 2 to 4 nm, the flow rates of water and methane increase with increased pore size. These results are expected to provide insights into developing deep shale gas reservoirs, such as optimizing hydraulic fracturing design and reliably predicting production performance. © 2024, The Authors. All rights reserved.

关键词： Methane

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Editorial: multiphase flow in energy studies and applications—A special issue for MTCUE-2022

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Physics of Fluids 2023年第7期35卷

作者： Zhu, Li-Tao Xu, Fei Jin, Hui Xiong, Qingang Department of Chemical and Biological Engineering University of British Columbia VancouverBCV6T 1Z3 Canada School of Chemistry and Chemical Engineering Shanghai Jiao Tong University Shanghai200240 China Electronics Business Unit Ansys Inc. AustinTX78746 United States State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China State Key Laboratory of Pulp and Paper Engineering South China University of Technology Guangzhou510641 China

Establishing a clean, low-carbon, and efficient energy system is paramount for the sustainable development of industries and human society. multiphase flows are encountered extensively in various energy applications, including transportation, conversion, and utilization of fossil, renewable, hydrogen, and nuclear energies. These flows encompass a wide range of phenomena, such as fluid flow, heat and mass transfer, combustion, and chemical reactions. However, multiphase flows are highly intricate due to the coexistence of multiple phases, states, and components, as well as the interactions among them that occur across diverse spatiotemporal scales. Consequently, both academia and industry face significant challenges in comprehending and harnessing multiphase flows. Thus, establishing connections between basic research and industrial applications in the field of multiphase flows is fundamental and indispensable for advancements in energy science and technologies. © 2023 Author(s).

关键词： multiphase flow

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Investigations on affinity law under gas-liquid conditions in multistage radial and mixed-flow multiphase pumps

国际流体工程（英文）

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国际流体工程（英文） 2024年第1期1卷 52-66页

作者： Liang Chang Chenyu Yang Xiaobin Su Xiaoyu Dai Qiang Xu Liejin Guo State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong UniversityXi'an 710049China

Affinity laws have been widely used in pump design and simulation under high-temperature and corrosive *** applying such laws,it is possible to shorten development cycles and reduce test ***,current applications of affinity laws are still limited to liquid *** this paper,expressions for affinity laws and their applicability are investigated for multistage radial and mixed-flow multiphase pumps under gas-liquid conditions.A high-pressure(30 MPa)gas-liquid experimental platform is constructed,and three-stage and 25-stage radial pumps and a 15-stage mixed-flow pump are investigated,with specific speeds of 107 and *** gas compressibility taken into account,the gas-liquid two-phase flow rate,head,and power,and the corresponding dimensionless hydraulic coefficients,are defined for multiphase *** deterioration of gas-liquid pressurization performance is found to be divided into three processes with different dynamic mechanisms,corresponding to three flow *** inlet gas volume fraction of pump is used to judge dynamic *** the same inlet gas volume fractions λ1=λ2,when the gas-liquid flows in two pumps have the same flow pattern,dynamic similarity will be *** affinity law that is established shows good applicability to the three-stage radial multiphase pump,with goodness of fit R2 larger than 0.9 for the two-phaseΨm-Φm andΠm-Φm performance ***,experimental results indicate that the affinity law also has good applicability to multiphase pumps with different stage numbers and blade structures under gas-liquid conditions.

关键词： conditions radial affinity gas-liquid investigations mixed-flow multiphase multistage pumps under

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Study of the intensified heat transfer of longitudinally ridged internal-finned tubes

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Reneng Dongli Gongcheng/Journal of engineering for Thermal Energy and power 2006年第3期21卷 283-286页

作者： Wu, Feng Lin, Mei Tian, Lin Wang, Qiu-Wang State Key Laboratory of Power Engineering Multiphase Flows Xi'an Jiaotong University Xi'an 710049 China

Through experiments and numerical simulation methods a study has been conducted of the characteristics of convection heat exchange of ridged internal-finned tubes and a comparison of the above characteristics with the flow and heat transfer characteristics of straight internal-finned tubes is performed. The experimental results indicate that the heat exchange characteristics of ridged internal-finned tubes are better than those of straight internal-finned tubes in terms of intensified heat transfer performance, but at the same time there is a corresponding increase in flow resistance. Through the adoption of a turbulent flow model capable of realizing k-ε equation, the flow and heat transfer process of ridged internal-finned tubes have been simulated. The calculation results are in good agreement with the experimental ones. The calculation results indicate that the periodical ridges inside the finned tubes have changed the distribution of the inner-flow fields and temperature ones. Relative to the straight internal-finned tubes, a secondary vortex flow has emerged, which is conducive to an intensified heat exchange and plays a definite destructive role to the flow boundary layer. Meanwhile, by increasing the turbulent kinetic energy of the flow field, the temperature gradient in the neighborhood of the heat exchange wall surfaces has been enhanced, contributing to an intensification of heat transfer.

关键词： Forced convection Heat transfer characteristics Intensified heat transfer Ridged internal-finned tube Secondary vortex flow

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