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Estimation of thermodynamic properties of the ternary molten salt system, LiF-NaF-BeF2, by the modified Peng-Robinson equation

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中国高等学校学术文摘·能源与动力工程 2007年第2期1卷 174-180页

作者： ZHANG Dalin QIU Suizheng SU Guanghui JIA Dounan School of Energy and Power Engineering State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China

The molten salt reactor (MSR), which is one of the generation IV reactors, can meet the demand of transmutation and breeding. The thermodynamic properties of the molten salt system like LiF-NaF-BeF2 influence the design and construction of the fuel salt and coolant in the MSR for the new generation. In this paper, the equation of state of the ternary system 15%LiF-58%NaF-27%BeF2, over the temperature range from 873.15 to 1 073.15 K at one atmosphere pressure, is described using a modified Peng-Robinson (PR) equation. The densities of the ternary system and its components are estimated by this equation directly, and compared with the experimental data. Based on the equation of state, the other thermodynamic properties such as the enthalpy, entropyand heat capacity at constant pressure are estimated by the residual function method and the fugacity coefficient method respectively. The densities calculated by PR equation are highly in agr eement with the experimental data, and the enthalpy, entropy and heat capacity evaluated by the two different methods are consistent with each other. It can be concluded that the modified PR equation can be applied to evaluate the density of the molten salt system, and it is recommended that it be used as the basis to estimate the enthalpy, entropy and heat capacity of the molten salt system.

关键词： thermodynamic properties molten salt LiF-NaF-BeF2 Peng-Robinson equation

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Two-dimensional self-adapting fast Fourier transform algorithm for nanoparticle sizing by ultrafast image-based dynamic light scattering

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Particuology 2018年第6期16卷 74-84页

作者： Dechuan Zhang Xiaoshu Cai Wu Zhou Institute of Particle and Two-Phase Flow Measurement University of Shanghai for Sdence and TechnologyShanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering (University of Shanghai for Sdence and Technology)Shanghai 200093China

In nanoparticle sizing using the ultrafast image-based dynamic light scattering (UIDLS)method,larger impurities and dark noise from the complementary metal-oxide-semiconductor (CMOS)detector affect measurement *** solve this problem,a two-dimensional self-adapting fast Fourier transform (2D-SAFFT)algorithm is proposed for *** light scattering images of nanoparticles are processed using 2D fast Fourier transforms,and a high-frequency threshold and a low-frequency threshold are then set using the self-adapting algorithm to eliminate the effects of the dark noise of the CMOS detector and the *** signals caused by the dark noise of the CMOS detector and the impurities are cut off using the high-frequency threshold and the low-frequency *** signals without the high- and low-frequency components are then processed again using an inverse Fourier transform to obtain new images without the dark noise and impurities *** mean diameters of the measured nanoparticles can be obtained from images obtained using *** standard latex nanoparticles (46,100, 203,508,994nm)and commercial nanoparticles (antimony-doped tin oxide,indium tin oxide,TWEEN- 80,nano-Fe,and nano-Al2O3)were measured using this new *** show that 2D-SAFFT can effectively eliminate the effects of dark noise from the CMOS detector and the impurities.

关键词： Dynamic light scattering Nanoparticle size Fast Fourier transform algorithm Spectrum segmentation

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Effect of ignition timing and hydrogen fraction on combustion and emission characteristics of natural gas direct-injection engine

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中国高等学校学术文摘·能源与动力工程 2008年第2期2卷 194-201页

作者： Jinhua WANG Zuohua HUANG Bing LIU Ke ZENG Jinrong YU Deming JIANG State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power EngineeringXi'an Jiaotong UniversityXi'an 710049China

An experimental study on the combustion and emission characteristics of a direct-injection spark-ignited engine fueled with natural gas/hydrogen blends under various ignition timings was *** results show that ignition timing has a significant influence on engine performance,combustion and *** interval between the end of fuel injection and ignition timing is a very important parameter for direct-injection natural gas *** turbulent flow in the combustion chamber generated by the fuel jet remains high and relative strong mixture stratification is introduced when decreasing the angle interval between the end of fuel injection and ignition timing giving fast burning rates and high thermal *** maximum cylinder gas pressure,maximum mean gas temperature,maximum rate of pressure rise and maximum heat release rate increase with the advancing of ignition ***,these parameters do not vary much with hydrogen addition under specific ignition timing indicating that a small hydrogen fraction addition of less than 20% in the present experiment has little influence on combustion parameters under specific ignition *** exhaust HC emission decreases while the exhaust CO2 concentration increases with the advancing of ignition *** the lean combustion condition,the exhaust CO does not vary much with ignition *** the same ignition timing,the exhaust HC decreases with hydrogen addition while the exhaust CO and CO2 do not vary much with hydrogen *** exhaust NOx increases with the advancing of' ignition timing and the behavior tends to be more obvious at large ignition advance *** brake mean effective pressure and the effective thermal efficiency of natural gas/hydrogen mixture combustion increase compared with those of natural gas combustion when the hydrogen fraction is over 10%.

关键词： natural gas hydrogen ignition timing combustion emissions direct-injection

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Liutex identification on hairpin vortex structures in a channel based on msfle and moving-PIV

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Journal of Hydrodynamics 2021年第6期33卷 1119-1128页

作者： Xin-ran Tang Xiang-rui Dong Xiao-shu Cai Wu Zhou School of Energy and Power Engineering University of Shanghai for Science and TechnologyShanghai 200093China Key Laboratory of Multiphase Flow and Heat Transfer in Shanghai Power Engineering University of Shanghai for Science and TechnologyShanghai 200093China

The spatiotemporal evolution of hairpin vortex structures in a fully developed turbulent boundary layer is investigated qualitatively and quantitatively by using two image *** this paper,the moving single-frame and long-exposure(MSFLE)image method is used to intuitively track the evolution process of a hairpin vortex,while the moving particle image velocimetry(moving-PIV)method is applied for obtaining a moving velocity field for quantitative *** to the structural characteristics of the hairpin vortex,an inclined light sheet with an appropriate inclination of 53°is arranged to capture the complete hairpin vortex structure at Re_(θ)=97–*** addition,the core size and the rotational strength of a hairpin vortex are further defined and quantified by the Liutex vector *** evolution process of a complete hairpin vortex structure observed by MSFLE shows that the shear along the normal direction leads to an increasing strength of the hairpin vortex,accompanied by a lifting vortex head and a distance decrease between two vortex legs during the dissipation *** combining moving-PIV with the Liutex identification,the spatiotemporal evolution of four typical regions of a hairpin vortex projecting into a 53°cross-section is *** results show that the process from the generation to the dissipation of a single hairpin vortex can be well characterized and recorded by the Liutex based on the core size and rotational intensity,and the evolution process is consistent with the MSFLE *** to the statistics of vortex core size and rotation intensity along time,the evolution of the hairpin vortex necks and legs can be described as a process of enhancement followed by *** the vortex head,its evolution maintains longer attributed to its far-from-wall position,which consists of an absolute enhancement process(stage 1)with an increasing rotation strength and a constant core size,and an absolute dissipation(stage 2)with a dec

关键词： Turbulent boundary layer hairpin vortex moving single-frame and long-exposure moving particle image velocimetry(PIV) Liutex vortex identification method

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Development of Liquid Slug Length in Gas-Liquid Slug flow along Horizontal Pipeline: Experiment and Simulation

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Chinese Journal of Chemical engineering 2006年第5期14卷 626-633页

作者：王鑫郭烈锦张西民 State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University

The liquid slug length distribution is crucial for designing the downstream processing system with mul-tiphase pipeline. Experiments were conducted in a 133m long horizontal test loop. The measurements were per-formed by conductivity probes to determine the liquid slug length distribution. The data covered both the slug and plug flow regimes. From experimental results, the mean liquid slug lengths were relatively insensitive to gas and liquid flow rates in the higher mixture velocity range. But in the lower mixture velocity range, the mean liquid slug length decreased and then increased with mixture velocity. It shows that the development length of slug flow was longer than x/D=1157. A slug tracking model was adapted to study the evolution of liquid slug length distribution in a horizontal pipeline. In the present model, the wake effect of elongated bubble and the pressure drop due to accel-eration are taken into account and random slug lengths are introduced at the entrance. The results of the model are compared with the measured slug length distributions of slug flow regime. It shows that the predicted mean and maximum slug lengths are in agreement with the experimental data at x/D=1157 and the form of the slug length distributions is also predicted well by the model.

关键词： two-phase flow slug flow liquid slug length slug tracking

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A MODEL FOR LIQUID SLUG LENGTH DISTRIBUTION IN VERTICAL GAS-LIQUID SLUG flow

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Journal of Hydrodynamics 2009年第4期21卷 491-498页

作者： XIA Guo-dong CUI Zhen-zhen LIU Qing ZHOU Fang-de HU Ming-sheng College of Environmental and Energy Engineering Beijing University of Technology Beijing 100124 China State Key Laboratory of Multiphase Flow in Power Engineering Xi＇an Jiaotong University Xi＇an 710049 China

The slug length and the trailing Taylor bubble velocity in an upward vertical slug flow were measured by using the optical probes and the EKTAPRO 1000 high speed motion analyzer. The correlation between the trailing bubble velocity and the length of liquid slug ahead of that bubble is derived from the experimental data. Based on this correlation as well as the bubble overtaking mechanism, a model for the slug length distribution at any designated locations along the pipe is proposed. The predicted results are in agreement with the experimental data.

关键词： gas-liquid two-phase flow slug flow Taylor bubble liquid slug

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Photochemical Systems for Solar‑to‑Fuel Production

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Electrochemical Energy Reviews 2022年第3期5卷 137-177页

作者： Ya Liu Feng Wang Zihao Jiao Shengjie Bai Haoran Qiu Liejin Guo International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong UniversityXi’an 710049ShaanxiChina

The photochemical system,which utilizes only solar energy and H_(2)O/CO_(2) to produce hydrogen/carbon-based fuels,is considered a promising approach to reduce CO_(2) emissions and achieve the goal of carbon *** date,numerous photochemical systems have been developed to obtain a viable solar-to-fuel production system with sufficient energy ***,more effort is still needed to meet the requirements of industrial *** this review,we systematically discuss a typical photochemical system for solar-to-fuel production,from classical theories and fundamental mechanisms to raw material selection,reaction condition optimization,and unit device/system advancement,from the viewpoint of ordered energy ***-of-the-art photochemical systems,including photocatalytic,photovoltaic-electrochemical,photoelectrochemical,solar thermochemical,and other emerging systems,are *** highlight the existing bottlenecks and discuss the developing trend of this ***,optimization strategies and new opportunities are proposed to enhance photochemical systems with higher energy efficiency.

关键词： Solar energy Photochemical Hydrogen Carbon-based fuels

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Study on Thermo-Conductive Plastic Finned TubeRadiators

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Journal of Thermal Science 1997年第1期6卷 21-26页

作者： Yang Jiehui Cheng Lixin(Chemical engineering School, State key laboratory of multiphase flow in power engineering, Xi’anJiaotong University, Xi’an 710049, China) Chemical Engineering School State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an China

This paper discusses thermo-conductive plastic finned tube radiators used in water saving type powerstations. First, the development of thermo-conductive plastics is introduced. Second, in order todetermine the rational geometric dimensions of thermo-conductive plastic finned tubes, an objectivefunction which takes the minimum volume of the consumed material for making finned tubes as an ob-ject is introduced. On the basis of the function, the economy comparison between thermaxonductiveplastic finned tubes and metal finned tubes is conducted.

关键词： air-cooling radiator thermo-conductive plastic finned tube optimum geometric parameters economy comparison

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Chlorine anchored pyrrole-based conjugated porous polymers for ultrahigh capacity and selective Hg(II) capture

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Separation and Purification Technology 2025年

作者： Bianyan He Jiarui Zhang Yubing Wang Mingtao Li Wei Yan Department of Environmental Science and Engineering Xi’an Key Laboratory of Solid Waste Recycling and Resource Recovery Xi’an Jiaotong University Xi’an 710049 PR China State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Xi’an 710049 PR China

In this study, chlorine anchored pyrrole-based conjugated porous polymers (CPPs) with distinct pore properties were synthesized using the Knoevenagel reaction and the double chain condensation method. The partially crosslinked and partially oxidized structures of the materials exhibit a unique microstructure integrating interconnected nets and molecular hooks. This architecture utilizes pore channels for physical interception of Hg(II), while synergistic chemical immobilization at N, O, and Cl active sites enables multifunctional enhancement of Hg(II) capture efficiency. Among these materials, the maximum adsorption capacity reached 1183 mg·g −1 , demonstrating ultrahigh selectivity. Moreover, the adsorbents maintained > 90 % removal efficiency over 10 adsorption–desorption cycles, confirming excellent reusability. Mechanistic studies revealed that Hg(II) adsorption primarily whin material pores through hydrogen bonding and coordination interactions, and their synergistic interactions. This work highlights the efficiency of the double chain condensation design strategy in advancing conjugated porous polymers for the removal of heavy metals, particularly Hg(II), from wastewater.

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Resource utilization of solid waste carbide slag:a brief review of application technologies in various scenes

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Waste Disposal and Sustainable Energy 2022年第1期4卷 1-16页

作者： Hongxia Wang Wanyi Xu Maimoona Sharif Guangxu Cheng Zaoxiao Zhang State Key Laboratory of Multiphase Flow in Power Engineering School of Chemical Engineering and TechnologyXi’an Jiaotong UniversityXi’an 710049ShaanxiChina

China is the largest producer and consumer of calcium carbide in the *** calcium carbide industry is an indispensable industry to support the basic life of *** huge production capacity of calcium carbide is accompanied by a large number of solid waste carbide *** to the immature treatment technology of carbide slag,a large number of carbide slag are stacked on-site,resulting in land occupation,air-drying,easy take-off ash,and pollution of the environment and water *** China,calcium carbide is mainly used to produce acetylene and further utilized,80%of which is used to produce polyvinyl chloride(PVC).A large amount of carbide slag is not used,while only a small part is used in the traditional building materials industry,flue gas desulfurization,sewage treatment,etc.,however,the economic benefits are ***,converting the solid waste carbide slag produced by the calcium carbide industry into high value-added CaCO3,CaCl2,CaSO4 whiskers,*** become a potential way to expand the development field of the calcium carbide industry and is environmentally *** paper focuses on summarizing the traditional and emerging high value-added utiliza-tion technologies of carbide slag,and then introduces the application research of carbide slag in carbon emission ***,the defects of these technologies are summarized and further research directions are *** study provides basic guidance for the diversified development of efficient resource utilization of carbide *** abstract Diversified development of calcium carbide industry,resource utilization of solid waste carbide slag and its application of carbon emission reduction have been fully reviewed.

关键词： Calcium carbide Carbide slag Application research High added value Carbon emission reduction

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