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SSRN 2022年

作者： Jin, Xiaoling Zhang, Kai Jiang, Jiahao Zhu, Zhengrong Deng, Lei Che, Defu State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Xi’an710049 China Kunming Institute of Physics Kunming650223 China

This study aims to investigate the effects of biomass species, modification treatment, experimental time and atmosphere on the catalytic conversion of toluene (model tar compound) by the biochar from gasification of oak, wheat straw and Enteromorpha. The gas and liquid phase products are detected by GC and GC-MS, respectively. The physical and chemical characteristics of biochar samples are analyzed by SEM-EDS, XRD and XPS. The results show that the activity of oak char modified by KMnO 4 (Mn-OC) is higher than that of other biochar samples. The KMnO 4 modification improves the pore structure, increases oxygen-containing groups and enhances the activity of biochar. The relatively high toluene conversion rate (53.96%) and low carbon deposition rate (3.41%) of Mn-OC indicates that KMnO 4 is more suitable for the modification of oak char. H 2 and aromatic hydrocarbons (especially biphenyl and their derivatives) are the main components of gas and liquid products, respectively. The proportion of H 2 in the total volume of H 2 , CO, CH 4 and CO 2 of Mn-OC reaches 56.94%. The addition of water vapor is helpful to the formation of oxygen-containing groups, more uniform distribution of inorganic salt particles and the improvement of biochar surface structure. Thus, adding moderate water vapor is beneficial to promote the catalytic activity of biochar. The toluene conversion rate and the total volume fraction of four main gases decrease with the increase of experimental time. They reduce significantly when the experimental time is longer than 120 min, from 44.51% (120 min) to 24.86% (180 min), which might be due to the damage of pore structure and the consumption of oxygen-containing functional groups. © 2022, The Authors. All rights reserved.

关键词： Toluene

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An Investigation on the Formation and flow Characteristics of Nature Gas Hydrates at Different Loop Inclination Angles

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SSRN 2022年

作者： Liu, Ni Wang, Cheng Meng, Fei Yang, Liang Liu, Daoping School of Energy and Power Engineering The University of Shanghai for Science and Technology Shanghai200093 China Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering Shanghai200093 China

One of the major issues in flow assurance includes pipeline plugging due to gas hydrate formation and deposition,which makes it imperative to look for appropriate hydrate control strategies. In this study, a high-pressure visual flow loop was used to analyze the influence of different inclination angles (0°–4°) on the formation, flow, morphology evolution, deposition process, and mechanism of hydrates. The macro-parametric data, including pressure, temperature, velocity, hydrate induction time and hydrate volume fraction, were compared and analyzed. Results showed that the hydration reaction rate of downslope section is slightly faster than that of upslope section in inclined section. Although the amount of hydrate finally formed is the same, the hydrate in the downslope section is more dense. While the loop inclination angle had little effect on the amount of hydrate formation, with the increase of inclination angle, the induction time tends to decrease and the hydration reaction time will be longer overall. At 1° inclination angle, the induction time was the shortest and the hydration reaction time was the longest. The deposition process of the horizontal pipe is divided into four stages, in which large hydrate particles in the liquid phase are evenly distributed throughout the pipeline, forming a hydrate moving bed. The hydrate deposition process of the inclined pipe is also divided into four stages. Among them, the large hydrate particles in the liquid phase are concentrated on the upper wall of the pipeline, which causes the density of the upper part of the pipeline to be much higher than that of the lower part, forming a hydrate-fixed *** results of this study can deliver theoretical support to ensure the safe transportation of gas hydrate slurries. © 2022, The Authors. All rights reserved.

关键词： Gas hydrates

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Numerical simulation of condensation of supercritical water gasification products in a supersonic nozzle

International Journal of Fluid Engineering

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International Journal of Fluid engineering 2024年第4期1卷 76-88页

作者： Hongtu Wu Miso Jurcevic Henrik Ström Muhammad Shahzad Khurram Hui Jin State Key Laboratory of Multiphase Flow in Power Engineering(SKLMF) Xi’an Jiaotong University28 Xianning West RoadXi’an 710049ShaanxiChina LTEF—Laboratory for Thermodynamics and Energy Efficiency Faculty of Electrical EngineeringMechanical Engineering and Naval Architecture(FESB)University of SplitRudjera Boskovica 3221000 SplitCroatia Chalmers University of Technology GöteborgSweden COMSATS LahorePakistan

The clean and efficient separation of supercritical water gasification products(SCWGP)has emerged as a significant challenge in supercritical water gasification *** paper proposes the use of a supersonic nozzle for the condensation and separation of H2and CO_(2)from SCWGP,leveraging the high-pressure characteristics of these *** establishing a flow model and a condensation model for the supersonic nozzle,the effects of inlet pressure and inlet temperature on the condensation process are *** analysis reveals that the latent heat released during condensation causes an abnormal distribution of pressure and temperature within the *** the inlet pressure of the nozzle is increased from 7.0 to 9.0 MPa,the liquid phase mass fraction at the outlet rises from 5.3×10^(-3)to ***,when the inlet temperature is lowered from 300.0 to 290.0 K,the liquid phase mass fraction at the outlet also rises from 5.3×10^(-3)to *** increase in inlet pressure leads to the condensation location shifting toward the throat by~8.5×10^(-3)m·MPa^(-1),while the impact of inlet temperature is approximately-2.3×10^(-3)m·K^(-1).The nucleation rate in the nozzle is always concentrated in a small region.

关键词： condensation separation outlet

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Experimental Study on Supported MnO2-Based Catalysts for No Oxidation

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SSRN 2022年

作者： Wang, Denghui Li, Hui Wu, Feng Hui, Shien State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University No. 28 Xianning West Rd. Xi’an710049 China

The selective catalytic oxidation (SCO) of NO in the flue gas to easily soluble NO2 has received extensive attention. In this paper, a single-phase supported MnO2/Al2O3 catalyst and Ce-doped MnCe/Al catalyst system were used for the NO-SCO experiment with MnO2 as the main active component. Combined with XRD, BET, XPS, SEM, O2-TPD, and H2-TPR characterization methods, the physicochemical state of the catalyst surface was analyzed. Furthermore, the effect of loading and Ce doping on active oxygen species and the important factors related to catalyst activity was revealed. The MnO2 catalyst obtained the best activity at 300 °C, corresponding to a NO conversion rate of 79.4%. After MnO2 was loaded on the γ-Al2O3, the activity of the Mn/Al catalysts was not as good as that of the MnO2 catalyst, and the temperature window of Mn/Al shifted to the high-temperature region with the increase of the loading ratio. The relative content of adsorbed oxygen Oα of Mn/Al catalysts was lower than that of MnO2, resulting in poor activity. Ce-doped Mn0.23Ce0.023/Al catalysts exhibited good low-temperature activity. The introduction of the Ce element enhanced the dispersion of Mn species on the catalyst surface, the relative content of surface adsorbed oxygen Oα increased, and the low-temperature activity and mobility of surface oxygen species were enhanced. The Mn0.23Ce0.023/Al catalyst was endowed with both a high specific surface area and good pore structure, as well as a large oxygen storage capacity and excellent surface oxygen species. © 2022, The Authors. All rights reserved.

关键词： Manganese oxide

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Prediction of Pressure Drop in Heavy Oil-Water Ring Two-Phase flow Based on Modified Two-Fluid Model

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SSRN 2024年

作者： Fu, Jiqiang Du, Mingjun Jing, Jiaqiang Sun, Jie Liu, Huichao Chen, Yongjiu State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China China Petroleum Engineering & Construction Corp North Company Heibei Renqiu062552 China School of Oil & Natural Gas Engineering Southwest Petroleum University Sichuan Chengdu610500 China

Accurate prediction of pressure drop of the heavy oil-water ring flow in pipeline is of great significance for establishing an optimal drag reduction model and ensuring safe production. The effects of different factors on the flow pattern and pressure drop of heavy oil-water annular two-phase flow were systematically analyzed, and a standard two-fluid pressure drop prediction model for annular flow was established. By modifying the shear stress equation of oil-water interface and introducing the wave-flow theory to modify the shear stress equation of water wall, a pressure drop prediction model for the generalized concentric water ring was obtained to calculate the periodic fluctuations of oil phase. Furthermore, by introducing the comprehensive Reynolds number expression of eccentric water ring, the pressure drop prediction model for the generalized eccentric water ring was obtained to calculate the periodic fluctuations of oil phase. The results show that the pressure drop prediction accuracy of the concentric water ring for ultra-heavy oil is improved by 80 % by using the modified pressure drop prediction model. The comprehensive Reynolds number expression of eccentric water ring can effectively reflect the influence of eccentric effect on shear stress of water wall and the calculation error is less than 20 % by predicting the pressure drop of the generalized eccentric water ring with different density differences. © 2024, The Authors. All rights reserved.

关键词： Two phase flow

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Multi-Objective Optimization and Configurations Comparison of Closed-Air Brayton Cycle

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SSRN 2023年

作者： Qian, Yiran Gu, Zhenzhen Song, Meihui Yang, Yi Zhao, Quanbin Chen, Weixiong Yan, Junjie State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an710049 China China Institute of Atomic Energy P.O. Box 275-32 Beijing102413 China

Microreactor power system has characteristics of efficient, compact and high environmental adaptability. In this study, closed-air Brayton cycle (CABC) is proposed as the microreactor thermoelectric conversion system, and thermodynamic model of CABC with different configurations are established. The cycle parameters and component’s structure are designed using system-component combined design method. To obtained the optimal system design scheme, the Genetic Algorithm (GA) and the Non-dominated Sorting Genetic Algorithm II (NSGA-II) are separately applied for single-objective optimization and multi-objective optimization. According to multi-objective optimization results, the IRRC has the highest cycle efficiency of 35.4% and the ratio of power to mass of 59.1 kW·t-1 , respectively, and the RRC has the highest power density of 179.6 kW·m-3 . Similar performance with IRRC and simpler structure make the RRC the optimal configuration of CABC. Compared with single-objective optimization, the design results of multi-objective optimization are more balanced in terms of three performance indicators, meaning that the optimized design scheme has a better comprehensive performance. © 2023, The Authors. All rights reserved.

关键词： Multiobjective optimization

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Corrosion Effect Analysis on Thermal-Hydraulics of Lbe/Water Spiral Tube Steam Generator Under Oxygen-Controlled Environment

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SSRN 2023年

作者： Lu, Dingsheng Yang, Yupeng Wang, Chenglong Zhang, Dalin Qiao, Pengrui Tian, Wenxi Qiu, Suizheng Su, Guanghui H. School of Nuclear Science and Technology Shanxi Key Laboratory of Advanced Nuclear Energy and Technology Xi'an Jiaotong University Xi'An710049 China China Institute of Atomic Energy Beijing102413 China State Key Laboratory of Multiphase Flow in Power Engineering China

In order to explore the flow and heat transfer characteristics of spiral tube steam generators under Lead-Bismuth Eutectic (LBE) corrosion, the accelerated removal effect of LBE corrosion flow was perfected, and a bidirectional coupling model of LBE corrosion and flow heat transfer was established. Computational fluid dynamics (CFD) method was used to simulate the corrosion and flow heat transfer of helical tube steam generator under saturated oxygen concentration and oxygen-controlled environment. The results indicate that the corrosion of liquid LBE forms an oxidation layer, which hinders the heat transfer in the spiral tube steam generator. This leads to a significant increase in the wall friction coefficient and a decrease in the surface Nusselt number. However, it does not have a significant effect on the water side evaporation process of the spiral tube steam generator. The implementation of an oxygen-controlled environment can effectively reduce the influence of LBE corrosion on the flow heat transfer of the spiral tube steam generator. Especially under high temperature conditions, it can reduce the near wall temperature of LBE change by up to 57.5% and the outlet temperature change by up to 61.5%. The oxygen-controlled environment results in prolonged local hypoxia time, with a more pronounced effect at higher temperatures. © 2023, The Authors. All rights reserved.

关键词： Oxygen

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Thermodynamics analyses on a novel CHP system integrated with multi-grade thermal energy storage

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Journal of Energy Storage 2025年 106卷

作者： Liu, Rongtang Zhang, Kezhen Qin, Yuanzhi Wan, Kaidi Xu, Can Liu, Ming Ningbo Institute of Technology Beihang University Ningbo315800 China Xi'an Thermal Power Research Institute Co. Ltd. Xi'an710054 China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an710049 China Dongfang Boiler Co. Ltd. of Dongfang Electric Group Chengdu611731 China

The high penetration level of intermittent renewable power necessitates the crucial requirement for combined heat and power systems to possess both high efficiency and flexibility. However, the heat-controlled operation modes of traditional combined heat and power systems impose limitations on their efficiency and flexibility. Therefore, it is of great significance to develop a heat-power decoupling technology that exhibits exceptional efficiency and flexibility. A novel combined heat and power system integrated with multi-grade thermal energy storage is proposed in this study. Thermodynamic analysis models of all operational conditions are developed, and the comprehensive characteristics of efficiency and operational flexibility for the proposed system are assessed by taking a 330 MW system as an example. Results show that the proposed system can decrease/increase 16.05 MW/30.96 MW power loads comparing with the reference system during the charging/discharging periods under the design condition. Energy efficiency of the proposed system can reach 49.40 %, which is improved by 1.66 percentage points. Exergy analysis reveals the exergy destruction order for the proposed system, and shows that the combustion and heat transfer in the boiler are the major process of exergy dissipation. Moreover, operation strategies of the proposed system during charging-discharging cycle are explored and formulated under off-design condition, suggesting that thermodynamic performances of the novel system under various conditions even extreme conditions exhibits exceptional properties. The maximum heat load of the proposed system can be improved by 46.78 % comparing with the reference system, and the maximum improvement of power load capacity during charging-discharging cycle is 14.58 percentage points. This study provides a promising approach for multi-grade thermal energy storage to improve the comprehensive characteristics of combined heat and power systems. © 2024

关键词： Charge storage

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Thermal-Mechanical Influence Aspects and Evaluation of Helical Cruciform Single Rod in Fluoride-Salt-Cooled High-Temperature Advanced Reactor

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SSRN 2024年

作者： Chen, Yiwen Zhang, Dalin Jiang, Dianqiang Li, Wei Wu, Xiaoli Tian, Wenxi Qiu, Suizheng Su, Guanghui Lu, Qi State Key Laboratory of Multiphase Flow in Power Engineering Shaanxi Key Laboratory of Advanced Nuclear Energy and Technology School of Nuclear Science and Technology Xi’an Jiaotong University Xi’an710049 China State Key Laboratory for Strength and Vibration of Mechanical Structures Xi’an Jiaotong University Xi’an710049 China Science Technology on Reactor System Design Technology Laboratory Nuclear Power Institute of China Chengdu610213 China China

Helical cruciform fuels are novel in nuclear reactors, potential to increase reactor’s power density. However, the geometry is complicated so influence of it on the fuel performance is not identified yet. In this paper, impact of power density, cross-section parameters, and twist pitch on thermal and mechanical characteristics of fuel used in Fluoride-Salt-cooled high-Temperature Advanced Reactor is discussed based on fluid-thermal-mechanical coupling. For thermal features, twist pitch is key while others have few effects. Increase in twist pitch leads to temperature uniformity and rise owing to weaker mixing effects. Fuel center temperature at middle plane of 300mm-pitch rod is 829.58℃, 54.66℃ higher than that of 100mm-pitch rod. Difference of maximum and minimum temperature at 45° cross section of 500mm-pitch rod is 153.62℃, while the figure is only 74.00℃ of 300mm-pitch rod. Besides, axial temperature of cladding outer surface increases wavelike due to complex geometry. For mechanical features, not geometry sizes but temperature affects stress distribution. Maximum Von-Mises stress appears at the elbow, where maximum temperature exists, 116.8MPa under normal conditions, lower than tensile strength of the material. After identifying the influence of these factors, five dimensionless parameters are proposed to evaluate and rate fuel performance based on Technique for Order Preference by Similarity to an Ideal Solution. As a result, an optimization comes up, scoring 0.310, twice more than the original design, owing to the thermal uniformity and mechanical safety. This study provides a reference for identifying and evaluating the performance of helical structure. © 2024, The Authors. All rights reserved.

关键词： Geometry

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Numerical Study on the Local Heat Transfer Characteristic of Supercritical Co2 in Semicircular/Circular Channel Under Cooling Condition

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SSRN 2022年

作者： Zhong, Shao-Geng Ren, Yan Wu, Weidong Yang, Ying-Ying Yang, Qi-Guo School of Energy and Power Engineering University of Shanghai for Science and Technology Shanghai200093 China Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering Shanghai200093 China

A mathematic-physical model was established to explore the local heat transfer characteristics of supercritical CO2 in semicircular and circular channels under cooling condition, which was applied in the field of supercritical CO2 Brayton cycle. The numerical method was validated by the experimental data with the average error of 3.79%, meeting the accuracy requirement. And the operation pressure, cooling heat flux, inlet velocity and hydraulic diameter were 8~9 MPa, 10~14 kW·m-2, 1.2~5 m·s-1 and 1~2 mm, respectively. The results showed that the local heat transfer coefficient of supercritical CO2 would increase at first and then decrease along the flow direction regardless of the semicircular channel and circular channel, and the peak value gradually decreased with increasing operation pressure and disappeared when the inlet velocity exceeded 3 m·s-1. Meanwhile, the heat transfer performance of the semicircular channel was weaker than that of the circular channel due to the influence of the corner area and the buoyant effect, and the latter played a dominant role. For the horizontal flow, the buoyant effect was increased, while the heat transfer was decreased with increasing hydraulic diameter of the semicircular channel. Besides, the influence of different flow directions on the heat transfer performance of the semicircular channel (about 6.2%) was greater than that of the circular channel (about 0.48%, and could be ignored). Finally, the heat transfer correlation of the supercritical CO2 cooling process in the horizontal semicircular channel was modified by considering the influence of the dimensionless buoyancy effect and hydraulic diameter, and the prediction errors of 90% correlation calculation results were within ±14% after the modification. These results will provide some theoretical guidance on the design and optimization of the cooler for the supercritical CO2 Brayton cycle system. © 2022, The Authors. All rights reserved.

关键词： Heat flux

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