检索结果-内蒙古大学图书馆

Merging polymers of intrinsic microporosity and porous carbon-based zinc oxide composites in novel mixed matrix membranes for efficient gas separation

引用

Green Energy & environment 2025年第1期10卷 203-213页

作者： Muning Chen Jiemei Zhou Jing Ma Weigang Zheng Guanying Dong Xin Li Zhihong Tian Yatao Zhang Jing Wang Yong Wang School of Chemical Engineering Zhengzhou UniversityZhengzhou450001HenanChina State Key Laboratory of Materials-Oriented Chemical Engineering and College of Chemical Engineering Nanjing Tech UniversityNanjing211816JiangsuChina Singapore Membrane Technology Centre Nanyang Environment and Water Research InstituteNanyang Technological UniversitySingapore637141Singapore Engineering Research Center for Nanomaterials Henan UniversityKaifeng475004HenanChina State Key Laboratory of Coking Coal Resources Green Exploitation Zhengzhou UniversityZhengzhou 450001China School of Energy and Environment Southeast UniversityNanjing210096JiangsuChina

Mixed matrix membranes(MMMs)have demonstrated significant promise in energy-intensive gas separations by amalgamating the unique properties of fillers with the facile processability of ***,achieving a simultaneous enhancement of permeability and selectivity remains a formidable challenge,due to the difficulty of achieving an optimal match between polymers and *** this study,we incorporate a porous carbon-based zinc oxide composite(C@ZnO)into high-permeability polymers of intrinsic microporosity(PIMs)to fabricate *** dipole–dipole interaction between C@ZnO and PIMs ensures their exceptional compatibility,mitigating the formation of non-selective voids in the resulting ***,C@ZnO with abundant interconnected pores can provide additional low-resistance pathways for gas transport in *** a result,the CO_(2) permeability of the optimized C@ZnO/PIM-1 MMMs is elevated to 13,215 barrer,while the CO_(2)/N_(2) and CO_(2)/CH_(4) selectivity reached 21.5 and 14.4,respectively,substantially surpassing the 2008 Robeson upper ***,molecular simulation results further corroborate that the augmented membrane gas selectivity is attributed to the superior CO_(2) affinity of C@*** summary,we believe that this work not only expands the application of MMMs for gas separation but also heralds a paradigm shift in the application of porous carbon materials.

关键词： Mixed matrix membranes Polymers of intrinsic microporosity CO_(2)separation Porous carbon materials

来源：评论

学校读者我要写书评

暂无评论

Adsorption of typical gasoline vapor emitted from service stations by commercial activated carbon:static/dynamic adsorption and kinetics simulation

引用

Frontiers of environmental Science & engineering 2025年第3期19卷 87-98页

作者： Wei Hu Quanming Liang Dan Lu Beibei Li Biqi Ren Qingye Luan Jia Liu Wenjun Liang Yuhu Huang National Engineering Research Center of Urban Environmental Pollution Control Beijing Key Laboratory of Urban Atmospheric Volatile Organic Compounds Control Technology and ApplicationsBeijing Municipal Research Institute of Eco-Environmental ProtectionBeijing 100037China Key Laboratory of Beijing on Regional Air Pollution Control Faculty of Environment and LifeBeijing University of TechnologyBeijing 100124China Institute of Urban Safety and Environmental Science Beijing Academy of Science and TechnologyBeijing 100054China

Gasoline vapor emissions from service stations significantly affect urban *** the research on the mechanisms and effectiveness of gasoline vapor removal is limited,this study innovatively investigates the static and dynamic adsorption of xylene—a typical gasoline vapor and one of the most active secondary organic aerosol(SOA)species—by commercial activated carbon(AC).The results showed that the saturation static adsorption capacity(Q_(e))of 12 ACs varied from 0.9 to 870.7 mg/g,which correlated with the specific surface area(SSA)and pore *** them,11#and 12#ACs were identified as the most effective adsorbents for typical gasoline vapor *** maximum dynamic Q_(e) increased from 301.5 to 414.3 mg/g when the initial xylene concentration rose from 918 to 2008 mg/m^(3) for 11#AC,and from 201.4 to 406.2 mg/g when the initial xylene concentration increased from 589 to 2120 mg/m^(3) for 12#*** findings implied a direct correlation between higher initial xylene concentrations and greater dynamic Q_(e) values,with static Q_(e) values surpassing dynamic *** adsorption kinetics simulation were analyzed by the pseudo-first-order(PFO)and pseudo-second-order(PSO)*** kinetics results demonstrated that the PFO was more effective in characterizing the adsorption of xylene onto ACs(R2>0.989),indicating that the adsorption of typical gasoline vapor by ACs primarily involves physical *** findings of static/dynamic adsorption and kinetics provide valuable guidance for practical applications of gasoline vapor removal in service stations.

关键词： Activated carbon Gasoline vapor Xylene Dynamic adsorption Breakthrough curve

来源：评论

学校读者我要写书评

暂无评论

Itinerant-electron dynamics suppressing Jahn-Teller distortions: Enabling high-rate and stable sodium-ion storage

引用

Journal of Energy Chemistry 2025年 107卷 780-791页

作者： Yao, Shuyun Yang, Zhiyu Wang, Shiyu Liu, Yuanming Ji, Yingjie Ji, Kang Zhang, Feike Fu, Weijie Wu, Ningning Xie, Jiangzhou Yan, Yi-Ming State Key Lab of Organic-Inorganic Composites Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical Technology Beijing100029 China State Key Laboratory of Reliability and Intelligence of Electrical Equipment Hebei University of Technology Tianjin300401 China School of Mechanical and Manufacturing Engineering University of New South Wales SydneyNSW2052 Australia

Jahn-Teller distortion (JTD) remains a fundamental bottleneck for transition metal oxides (TMOs) in electrochemical energy storage, where the eg-orbital single-electron occupancy induces irreversible octahedral collapse and rapid capacity fading. Here, we pioneer an itinerant-electron-mediated dynamic suppression strategy that fundamentally reshapes the JTD evolution pathway through π-d orbital hybridization engineering. By constructing reduced graphene oxide/TMO heterointerfaces (rGO/MOx, M = Fe/Ni/Mn), localized 3d electrons are transformed into delocalized itinerant states, which (1) eliminate eg-band degeneracy via orbital repopulation and (2) establish an electron density buffer layer to neutralize lattice strain. This electronic regulation enables ultrafast Na+ diffusion kinetics (508.3 F g−1 at 1 A g−1 → 304.6 F g−1 at 20 A g−1) and near-zero lattice deformation (91.07% capacitance retention after 20,000 cycles). Synchrotron-based X-ray absorption spectroscopy and density functional theory calculations reveal that itinerant electron dynamics actively decouple the Mn3+ d4 electronic configuration from JTD triggering, leading to a dramatic suppression of octahedral distortion compared to the conventional MnO2. The proposed electron delocalization-to-lattice stabilization paradigm opens a universal route to design distortion-resistant electrodes for high-power energy storage systems. © 2025 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences

关键词： Manganese oxide

来源：评论

学校读者我要写书评

暂无评论

Asymbiotic Nitrogen Fixation in the Phyllosphere of Urban Green Spaces

引用

Current Microbiology 2025年第6期82卷 1-13页

作者： Li, Jian-Feng Yang, Le-Yang Zhang, Zhao Huang, Xin-Rong Li, Hu Li, Shun Yang, Xiao-Ru College of Environment and Safety Engineering Fuzhou University Fuzhou 350116 China State Key Laboratory for Ecological Security of Regions and Cities Institute of Urban Environment Chinese Academy of Sciences Xiamen 361021 China State Key Laboratory of Microbial Technology Shandong University Qingdao 266237 China

Biological nitrogen fixation (BNF) is an important source of nitrogen in ecosystems. Compared to symbiotic nitrogen-fixing microorganisms, free-living diazotrophic bacteria have a broader distribution and greater diversity, demonstrating greater potential for application. Leaf surfaces constitute one of the largest microbial reservoirs on Earth, harboring a variety of free-living diazotrophic bacteria, contributing significantly to plant N acquisition and growth. The distribution patterns, abundance, diversity, and the environmental variables affecting the asymbiotic nitrogen fixation (ANF) rates of free-living diazotrophic bacteria of non-leguminous plants in urban green spaces were investigated using high-throughput sequencing of nifH gene amplicons and the acetylene reduction method. Both green space type and plant species significantly impact ANF rates and nifH gene abundance in the phyllosphere, with green space type having a more pronounced effect. Leaf metal elements iron (Fe), molybdenum (Mo), and the free-living diazotrophic bacteria of the genus Skermanella collectively influence the ANF rates in the phyllosphere of urban green spaces. Linear regression analysis revealed that metal elements Fe, Mo, and potassium (K) in the leaves were significantly positive correlated with the diversity of the free-living diazotrophic bacteria and the abundance of the N-fixing gene nifH. The alpha diversity and symbiotic network structure of the free-living diazotrophic bacterial community in the phyllosphere indicated a significant negative correlation between human disturbance and environmental perturbation and the biodiversity and network complexity of these bacteria. This study provides a crucial foundation for understanding the nitrogen-fixing functions of microbes in urban ecosystems and their contributions to the nitrogen cycle. © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2025.

关键词：

来源：评论

学校读者我要写书评

暂无评论

Very high cycle fatigue resistance improvement of Mg-Gd-Zn-Zr alloy by introducing curved long-period stacking ordered lamellae

引用

Journal of Magnesium and Alloys 2025年第3期13卷 1218-1231页

作者： Min Zhan Xinglin Yang Shoucheng Shi Yao Chen Lang Li Bing Xue Yongbo Li Wanshuang Yi Qingyuan Wang Chao He Key Laboratory of Deep Earth Science and Engineering Ministry of EducationCollege of Architecture and EnvironmentSichuan UniversityChengdu 610065China Failure Mechanics&Engineering Disaster Prevention and Mitigation Key Laboratory of Sichuan ProvinceSichuan UniversityChengdu 610065China Science and Technology Research Center China Yangtze Power Corp(CYPC)Yichang Hubei 443002China Hubei Technology Innovation Center for Smart Hydropower Wuhan Hubei 430000China School of Architecture and Civil Engineering Chengdu UniversityChengdu 610106China

Magnesium alloys with long-period stacking ordered(LPSO)structures are known for their impressive static mechanical strength,but the consistent occurrence of slip-cracking along the LPSO lamellae,which do not effectively impede the movement of basal dislocations,has prompted concerns about their very high cycle fatigue(VHCF)*** this study,an extruded Mg-Gd-Zn-Zr alloy was developed,showcasing exceptional VHCF resistance due to its bimodal structure comprisingﬁne grains and coarse grains consisting of curved LPSO *** investigation on the crack initiation mechanism revealed that slip-induced cracking predominantly occurs inﬁne-grained regions rather than in the interior of coarse *** extrusion process aligns the basal planes of most coarse grains parallel to the axial direction,and the presence of curved LPSO lamellae acts as barriers to the movement of basal dislocations,thereby effectively increasing the threshold for slip-cracking along the basal ***,fatigue damage manifests in the form of slip bands and micro-cracks within the interior ofﬁne grains,ultimately resulting in fatigue crack initiation,propagation andﬁnal fracture.

关键词： Very high cycle fatigue Mg-Gd-Zn-Zr alloy Crack initiation Curved LPSO lamellae Micro-cracks

来源：评论

学校读者我要写书评

暂无评论

Review on the abiotic degradation of biodegradable plastic poly(butylene adipate-terephthalate):Mechanisms and main factors of the degradation

引用

Chinese Chemical Letters 2025年第1期36卷 158-164页

作者： Haibo Ye Qianyu Li Juan Li Didi Li Zhimin Ao Guangdong-Hong Kong-Macao Joint Laboratory for Contaminants Exposure and Health Guangzhou Key Laboratory Environmental Catalysis and Pollution ControlInstitute of Environmental Health and Pollution ControlGuangzhou 510006China Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control Key Laboratory for City Cluster Environmental Safety and Green Development of the Ministry of EducationSchool of Environmental Science and EngineeringGuangdong University of TechnologyGuangzhou 510006China Advanced Interdisciplinary Institute of Environment and Ecology Beijing Normal UniversityZhuhai 519087China School of Environment Beijing Normal UniversityBeijing 100875China

Poly(butylene adipate-terephthalate)(PBAT),as one of the most common and promising biodegradable plastics,has been widely used in agriculture,packaging,and other industries due to its strong biodegradability *** is well known that PBAT suffers a series of natural weathering,mechanical wear,hydrolysis,photochemical transformation,and other abiotic degradation processes before being ***,it is particularly important to understand the role of abiotic degradation in the life cycle of *** the abiotic degradation of PBAT has not been systematically summarized,this review aims to summarize the mechanisms and main factors of the three major abiotic degradation pathways(hydrolysis,photochemical transformation,and thermochemical degradation)of *** was found that all of them preferentially destroy the chemical bonds with higher energy(especially C-O and C=O)of PBAT,which eventually leads to the shortening of the polymer chain and then leads to reduction in molecular *** main factors affecting these abiotic degradations are closely related to the energy or PBAT *** findings provide important theoretical and practical guidance for identifying effective methods for PBAT waste management and proposing advanced schemes to regulate the degradation rate of PBAT.

关键词： Biodegradable plastics PBAT Abiotic degradation Degradation mechanism

来源：评论

学校读者我要写书评

暂无评论

Deep learning-based software engineering: progress,challenges, and opportunities

引用

Science China(Information Sciences) 2025年第1期68卷 57-144页

作者： Xiangping CHEN Xing HU Yuan HUANG He JIANG Weixing JI Yanjie JIANG Yanyan JIANG Bo LIU Hui LIU Xiaochen LI Xiaoli LIAN Guozhu MENG Xin PENG Hailong SUN Lin SHI Bo WANG Chong WANG Jiayi WANG Tiantian WANG Jifeng XUAN Xin XIA Yibiao YANG Yixin YANG Li ZHANG Yuming ZHOU Lu ZHANG School of Journalism and Communication Sun Yat-sen University School of Software Technology Zhejiang University School of Software Engineering Sun Yat-sen University School of Software Dalian University of Technology School of Computer Science and Technology Beijing Institute of Technology Key Laboratory of High Confidence Software Technologies (Peking University) Ministry of EducationSchool of Computer Science Peking University State Key Laboratory for Novel Software Technology Nanjing University School of Computer Science and Engineering Beihang University Institute of Information Engineering Chinese Academy of Sciences School of Computer Science Fudan University State Key Laboratory of Complex & Critical Software Environment (CCSE) School of Software Beihang University School of Computer and Information Technology Beijing Jiaotong University School of Computer Science and Technology Harbin Institute of Technology School of Computer Science Wuhan University Huawei Technologies

Researchers have recently achieved significant advances in deep learning techniques, which in turn has substantially advanced other research disciplines, such as natural language processing, image processing, speech recognition, and software engineering. Various deep learning techniques have been successfully employed to facilitate software engineering tasks, including code generation, software refactoring, and fault localization. Many studies have also been presented in top conferences and journals, demonstrating the applications of deep learning techniques in resolving various software engineering tasks. However,although several surveys have provided overall pictures of the application of deep learning techniques in software engineering,they focus more on learning techniques, that is, what kind of deep learning techniques are employed and how deep models are trained or fine-tuned for software engineering tasks. We still lack surveys explaining the advances of subareas in software engineering driven by deep learning techniques, as well as challenges and opportunities in each subarea. To this end, in this study, we present the first task-oriented survey on deep learning-based software engineering. It covers twelve major software engineering subareas significantly impacted by deep learning techniques. Such subareas spread out through the whole lifecycle of software development and maintenance, including requirements engineering, software development, testing, maintenance, and developer collaboration. As we believe that deep learning may provide an opportunity to revolutionize the whole discipline of software engineering, providing one survey covering as many subareas as possible in software engineering can help future research push forward the frontier of deep learning-based software engineering more systematically. For each of the selected subareas,we highlight the major advances achieved by applying deep learning techniques with pointers to the available datasets i

关键词： deep learning software engineering software benchmark software artifact representation survey

来源：评论

学校读者我要写书评

暂无评论

Ethanol steam reforming for hydrogen production over alkali metals modified kaolin-supported Ni catalysts

引用

International Journal of Hydrogen Energy 2025年 129卷 113-129页

作者： Wang, Yishuang Sun, Xiaoxiao Liang, Defang Li, Chang Xin, Haosheng Wang, Jun Chen, Mingqiang School of Chemical and Blasting Engineering Analysis and Testing Center Anhui University of Science and Technology Huainan232001 China State Key Laboratory for Safe Mining of Deep Coal Resources and Environment Protection Huainan232000 China

Herein, alkali metals (Na, K, Mg and Ca) modified kaolin-supported Ni catalysts display bright prospect for ethanol steam reforming (ESR). It finds that alkali metals lower the proportion of acid sites, optimize the reduction of nickel species and create the interaction of nickel components with alkali metals. These features inhibit ethanol dehydration, Ni metal sintering and carbon deposits during ESR. Amongst, Ni–K/KL presents the highest ethanol conversion (97.5%) and H2 yield (76.3%) at 600 °C and almost no deactivation during 50 h of ESR. It demonstrates Ni–K/KL alters the reaction path by suppressing acetaldehyde intermediates in comparison with Ni/KL. Subsequently, the K-modified metallic Ni sites fleetly rupture intermediate C–C bonds and activate CO. Additionally, the Ni–O–K interface sites achieve H2O activation to produce abundant OH∗. Eventually, the synergetic interplay of Ni0 with Ni–O–K improves the water-gas shift reaction and CHx steam reforming to produce more hydrogen. © 2025 Hydrogen Energy Publications LLC

关键词： Steam

来源：评论

学校读者我要写书评

暂无评论

A theoretical and experimental study of deformation mechanism dictated by disclination-dislocation coupling in Mg alloys at different temperatures

引用

材料科学技术（英文版） 2025年第5期208卷 176-188页

作者： Chunfeng Du Yipeng Gao Yizhen Li Quan Li Min Zha Cheng Wang Hailong Jia Hui-Yuan Wang Key Laboratory of Automobile Materials of Ministry of Education&School of Materials Science and Engineering Nanling CampusJilin UniversityChangchun 130025China Key Laboratory of Automobile Materials of Ministry of Education&School of Materials Science and Engineering Nanling CampusJilin UniversityChangchun 130025China International Center of Future Science Jilin UniversityChangchun 130012China International Center of Future Science Jilin UniversityChangchun 130012China State Key Lab of Superhard Materials and Key Laboratory of Material Simulation Methods&Software of Ministry of Education College of PhysicsJilin UniversityChangchun 130012China Key Laboratory of Automobile Materials of Ministry of Education&School of Materials Science and Engineering Nanling CampusJilin UniversityChangchun 130025China International Center of Future Science Jilin UniversityChangchun 130012China State Key Laboratory of Reliability and Intelligence of Electrical Equipment School of Material Science and EngineeringHebei University of TechnologyTianjin 300130China

Dislocations and disclinations are fundamental topological defects within crystals,which determine the mechanical properties of metals and *** their important roles in multiple physical mecha-nisms,e.g.,dynamic recovery and grain boundary mediated plasticity,the intrinsic coupling and corre-lation between disclinations and dislocations,and their impacts on the deformation behavior of metallic materials still remain obscure,partially due to the lack of a theoretical tool to capture the rotational na-ture of *** using a Lie-algebra-based theoretical framework,we obtain a general equation to quantify the intrinsic coupling of disclinations and *** quasi in-situ electron backscat-ter diffraction characterizations and disclination/dislocation density analyses in Mg alloys,the generation,coevolution and reactions of disclinations and dislocations during dynamic recovery and superplastic de-formation have been quantitatively *** has been demonstrated that the obtained governing equa-tion can capture multiple physical processes associated with mechanical deformation of metals,e.g.,grain rotation and grain boundary migration,at both room temperature and high *** establishing the disclination-dislocation coupling equation within a Lie algebra description,our work provides new insights for exploring the coevolution and reaction of disclinations/dislocations,with profound implica-tions for elucidating the microstructure-property relationship and underlying deformation mechanisms in metallic materials.

关键词： Magnesium alloys Dislocations Grain boundaries Plastic deformation Grain rotation Disclination-dislocation coupling

来源：评论

学校读者我要写书评

暂无评论

Deciphering environmental factors influencing phytoplankton community structure in a polluted urban river

引用

Journal of environmental Sciences 2025年第2期148卷 375-386页

作者： Xiaxia Li Kai Chen Chao Wang Tianyu Zhuo Hongtao Li Yong Wu Xiaohui Lei Ming Li Bin Chen Beibei Chai School of Water Conservancy and Hydroelectric Power Hebei University of EngineeringHandan 056038China Collaborative Innovation Center for Intelligent Regulation and Comprehensive Management of Water Resources School of Water Conservancy and HydroelectricHebei University of EngineeringHandan 056038China Hebei Key Laboratory of Intelligent Water Conservancy Hebei University of EngineeringHandan 056038China Tianjin Water Group Binhai Water Co. Ltd.Tianjin 300308China State Key Laboratory of Simulation and Regulation of Water Cycle in River Basin China Institute of Water Resources and Hydropower ResearchBeijing 100038China School of Architecture and Civil Engineering Xi’an University of Science and TechnologyXi’an 710054China Chengdu University of Technology Chengdu 610059China College of Natural Resources and Environment Northwest A&F UniversityYangling 712100China State Key Joint Laboratory of Environment Simulation and Pollution Control School of EnvironmentBeijing Normal UniversityBeijing 100875China

Tuojiang River Basin is a first-class tributary of the upper reaches of the Yangtze River—which is the longest river in *** phytoplankton are sensitive indicators of trophic changes inwater bodies,characterizing phytoplankton communities and their growth influencing factors in polluted urban rivers can provide new ideas for pollution ***,we used direct microscopic count and environmental DNA(eDNA)metabarcoding methods to investigate phytoplankton community structure in Tuojiang River Basin(Chengdu,Sichuan Province,China).The association between phytoplankton community structure and water environmental factors was evaluated by Mantel *** environmental monitoring data were used to pinpoint major factors that influenced phytoplankton growth based on structural equation *** the phylum level,the dominant phytoplankton taxa identified by the conventional microscopic method mainly belonged to Bacillariophyta,Chlorophyta,and Cyanophyta,in contrast with Chlorophyta,Dinophyceae,and Bacillariophyta identified by eDNA ***α-diversity analysis,eDNA metabarcoding detected greater species diversity and achieved higher precision than the microscopic *** growth was largely limited by phosphorus based on the nitrogen-to-phosphorus ratios>16:1 in all water *** analysis and structural equation modeling also confirmed that the nitrogen-to-phosphorus ratio was the principal factor influencing phytoplankton *** results could be useful for implementing comprehensive management of the river basin *** is recommended to control the discharge of point-and surface-source pollutants and the concentration of dissolved oxygen in areas with excessive nutrients(e.g.,Jianyang-Ziyang).Algae monitoring techniques and removal strategies should be improved in 201 Hospital,Hongrihe Bridge and Colmar Town areas.

关键词： environmental DNA Microscopic count Phytoplankton growth Structural equation modeling Tuojiang River Basin

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：