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Facile fabrication of NiCo-hydroxysulfide nanosheets array for electrocatalytic urea oxidation

Science China(Technological Sciences) 2025年第1期68卷 218-228页

作者： Jing ZOU Chang LIU Kun XIANG Qiong LI Shihao DAI Jizhou JIANG School of Chemistry and Environmental Engineering School of Environmental Ecology and Biological EngineeringKey Laboratory of Green Chemical Engineering Process of Ministry of EducationEngineering Research Center of Phosphorus Resources Development and Utilization of Ministry of EducationNovel Catalytic Materials of Hubei Engineering Research CenterWuhan Institute of TechnologyWuhan 430205China

Urea oxidation reaction(UOR)instead of anodic oxygen evolution reaction(OER)is considered an effective way to reduce energy consumption in electrocatalytic water splitting for hydrogen ***,the slow rate of reaction of UOR,which entails a procedure of transferring six electrons,has hindered its widespread ***,it is crucial to design highly effective electrocatalysts for the implementation of ***,a novel NiCo-hydroxysulfide(NiCo-HOS)electrocatalyst has been reported for UOR,which is obtained by the exchange of sulfur ions in NiCo layered double hydroxide(NiCo-LDH)nanosheets at room *** from the sulfurization process,the composition,electronic structure,and surface properties of electrocatalysts have undergone significant changes and *** sulfurization treatment,the resulting NiCo-HOS showed enhanced chemical resistance to alkaline electrolytes and improved electrical *** a 40 h operation test,it maintained high stability and provided a stable current density of 100 mA cm^(-2)at a relatively low potential of 1.33 V(***)in a solution of 1 mol L^(-1)KOH+0.5 mol L^(-1)***,the anode electrolytic product is analyzed through gas chromatography(GC),and N_2 is detected as the product without the presence of CO,indicating that the urea has undergone complete oxidation.

关键词： urea oxidation reaction NiCo-hydroxysulfide electrocatalyst hydrogen

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Research on the Influencing Factors of Peristalsis Amplitude Based on an in Vitro Bionic Rat Stomach Model

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Journal of Bionic engineering 2024年第5期21卷 2379-2394页

作者： Wentao Liang keyong Zhao Peng Wu Changyong Li Xiaodong Chen Renpan Deng Zhigang Lei School of Chemistry and Chemical Engineering/State Key Laboratory Incubation Base for Green Processing of Chemical Engineering of Xinjiang Bingtuan Shihezi UniversityShihezi832003China School of Chemical and Environmental Engineering and Key Laboratory of Coal-Based Energy and Chemical IndustryXinjiang Institute of EngineeringXinjiang830091China School of Chemical and Environmental Engineering Soochow UniversitySuzhou215123China Fujian Provincial Key Laboratory of Biochemical Technology&Institute of Biomaterials and Tissue Engineering College of Chemical EngineeringHuaqiao UniversityXiamen361021China

The In Vitro Bionic Digestion Model(IVBDM)are used to simulate the digestion process of food or pharmaceuticals in corresponding digestion tracts for obtaining the digestion data,which are expected to replace in vivo experiments with ani-mals in the early stages of functional food or drug development,and thus have broad applications ***,little is known so far about how the factors including the Young's modulus of the model,the level,location and direction of the applied load,affect the peristalsis amplitude of the *** on an In Vitro Bionic Rat Stomach Model(IVBRSM),simulation and experimental analysis were conducted to examine the factors effecting the peristalsis amplitude of the *** is shown that Young's modulus of the model significantly affects the peristalsis amplitude,with lower Young's modulus resulting in larger *** level,location,and direction also influence the peristalsis ***-ally,IVBRSM size and wall thickness play a role,with larger models requiring higher load levels or lower Young's modulus for the same peristalsis *** data correlate well with experimental *** findings contribute to the understanding of the peristalsis state of IVBRSM under different conditions and can guide the design and fabrication of such in vitro bionic digestion models.

关键词： Bionic In vitro digestion models Rat stomach Peristalsis amplitude Young's modulus

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Multivariate statistical and bioinformatic analyses for the seasonal variations of actinobacterial community structures in a drinking water reservoir

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Journal of environmental Sciences 2024年第3期137卷 1-17页

作者： Haihan Zhang Sixuan Pan BenMa Tinglin Huang Dmitry B.Kosolapov Manli Ma Xiang Liu Huan Liu Xiaoyan Liu Shaanxi Key Laboratory of Environmental Engineering Key Laboratory of Northwest Water ResourceEnvironment and EcologyMOEXi’an University of Architecture and TechnologyXi’an 710055China School of Environmental and Municipal Engineering Xi’an University of Architecture and TechnologyXi’an 710055China Papanin Institute for Biology of Inland Waters of Russian Academy of Sciences(IBIW RAS) 109BorokNekouzYaroslavl152742Russia

Actinobacterial community is a conspicuous part of aquatic ecosystems and displays an important role in the case of biogeochemical cycle,but little is known about the seasonal variation of actinobacterial community in reservoir ecological *** this study,the high-throughput techniques were used to investigate the structure of the aquatic actinobacterial community and its inducing water quality parameters in different *** results showed that the highest diversity and abundance of actinobacterial community occurred in winter,with Sporichthya(45.42%)being the most abundant genus and Rhodococcus sp.(29.32%)being the most abundant *** analysis and correlation analysis suggested that in autumn the dynamics of actinobacterial community were infuenced by more factors and Nocardioides ***2R5S2 was the potential keystone species which was negatively correlated with temperature(R=-0.72,P<0.05).Changes in environmental factors could significantly affect the changes in actinobacterial community,and the dynamics of temperature,dissolved oxygen(DO),and turbidity are potential conspicuous factors infuencing seasonal actinobacterial community *** partial least squares path modeling further elucidated that the combined effects of DO and temperature not only in the diversity of actinobacterial community but also in other water qualities,while the physiochemical parameters(path coefficient=1.571,P<0.05)was strong environmental factors in natural mixture *** results strengthen our understanding of the dynamics and structures of actinobacterial community in the drinking water reservoirs and provide scientific guidance for further water quality management and protection in water sources.

关键词： Source water reservoir High-throughput sequencing Correlation analysis Network analysis Partial least squares path modeling

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Promotional effect of cobalt doping on catalytic performance of cryptomelane-type manganese oxide in toluene oxidation

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Journal of environmental Sciences 2023年第4期126卷 263-274页

作者： Ning Dong Mengyue Chen Qing Ye Dan Zhang Hongxing Dai Key Laboratory of Beijing on Regional Air Pollution Control Department of Environmental ScienceSchool of Environmental and Chemical EngineeringFaculty of Environment and LifeBeijing University of TechnologyBeijing 100124China R&D Department of Atmospheric Prevention and Control Technology Guangdong Suncere Technology Co.Ltd.Guangzhou 510220China Beijing Key Laboratory for Green Catalysis and Separation Key Laboratory of Beijing on Regional Air Pollution ControlKey Laboratory of Advanced Functional MaterialsEducation Ministry of Chinaand Laboratory of Catalysis Chemistry and NanoscienceDepartment of Environmental Chemical EngineeringSchool of Environmental and Chemical EngineeringFaculty of Environment and LifeBeijing University of TechnologyBeijing 100124China

The cryptomelane-type manganese oxide (OMS-2)-supported Co (x Co/OMS-2;x=5,10,and15 wt.%) catalysts were prepared via a pre-incorporation *** as-prepared materials were used as catalysts for catalytic oxidation of toluene (2000 ppmV).Physical and chemical properties of the catalysts were measured using the X-ray diffraction (XRD),Fourier transform infrared spectroscopic (FT-IR),scanning electron microscopic (SEM),X-ray photoelectron spectroscopy (XPS),and hydrogen temperature-programmed reduction (H_(2)-TPR)*** all of the catalysts,10Co/OMS-2 performed the best,with the T90%,specific reaction rate at 245℃,and turnover frequency at 245℃ (TOFCo) being 245℃,1.23×10^(-3)moltoluene/(gcat·sec),and 11.58×10^(-3)sec-1for toluene oxidation at a space velocity of 60,000mL/(g·hr),*** excellent catalytic performance of 10Co/OMS-2 were due to more oxygen vacancies,enhanced redox ability and oxygen mobility,and strong synergistic effect between Co species and OMS-2 ***,in the presence of poisoning gases CO_(2),SO_(2)or NH_(3),the activity of 10Co/OMS-2 decreased for the carbonate,sulfate and ammonia species covered the active sites and oxygen vacancies,*** the activation treatment,the catalytic activity was partly *** good low-temperature reducibility of 10Co/OMS-2 could also facilitate the redox process accompanied by the consecutive electron transfer between the adsorbed O_(2)and the cobalt or manganese *** the oxidation process of toluene,the benzoic and aldehydic intermediates werefirst generated,which were further oxidized to the benzoate intermediate that were eventually converted into H_(2)O and CO_(2).

关键词： Cryptomelane-type manganese oxide Cobalt doping Volatile organic compound Toluene oxidation

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Re-Evaluating Challenges and Solutions in Wastewater Surveillance

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engineering 2024年第12期43卷 22-24页

作者： Jing Han Zhou-Hua Cheng Dong-Feng Liu Han-Qing Yu CAS Key Laboratory of Urban Pollutant Conversion Department of Environmental Science and EngineeringUniversity of Science and Technology of ChinaHefei 230026China

The coronavirus disease 2019(COVID-19)pandemic has reshaped our understanding of pathogen *** surveillance has gained widespread acceptance as a practical strategy complementary to clinical reports to achieve accurate... 详细信息

关键词： Wastewater gained shaped

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Synergistic effects in Mn-Co mixed oxide supported on cordierite honeycomb for catalytic deep oxidation of VOCs

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Journal of environmental Sciences 2022年第2期34卷 231-243页

作者： Hongyang Zhao Hui Wang Zhenping Qu Key Laboratory of Industrial Ecology and Environmental Engineering School of Environmental Science and TechnologyDalian University of TechnologyDalian 116024China

A series of Co-Mn mixed oxide catalyst supported on a cordierite monolith was facilely synthesized by ultrasonic *** catalytic performance was evaluated in the combustion of toluene,ethyl acetate and its *** was observed that with incorporating Mn into Co_(3)O_(4),the formation of solid solution with spinel structure could significantly improve the catalytic activity of pure phase Co_(3)O_(4).And the monolithic Co_(0.67)Mn_(0.33)O_(x) catalyst showed the best catalytic performance in the catalytic oxidation of toluene and ethyl acetate which could be completely oxidized at 220 and 180℃ respectively under the reaction velocity(WHSV)about 45,000 m L/(g·hr)and pollutant concentration of 500 ppm *** total conversion temperature of the VOCs mixture was at 230℃(500 ppm V toluene and 500 ppm V ethyl acetate)and determined by the temperature at which the most difficult molecule was *** excellent catalytic performance of monolithic Co_(0.67)Mn_(0.33)O_(x) was attributed to the higher content of Mn^(3+),Co^(3+),surface adsorbed oxygen and better redox *** prepared catalyst showed the good mechanical stability,reaction stability,and good adaptability to different reaction conditions.

关键词： Catalytic oxidation Cobalt Manganese Cordierite Monolithic catalyst

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reliability evaluation of PMS considering coupling effect of functional and physical dependency

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Chinese Journal of Aeronautics 2022年第2期35卷 154-163页

作者： Ying CHEN Qichao MA Rui KANG Science and Technology on Reliability and Environmental Engineering Laboratory Beihang UniversityBeijing 100083China Institute of Electronic Engineering China Academy of Engineering PhysicsMianyang 621999China

Aviation and aerospace system are typical Phased-Mission Systems(PMSs)featured with varying configuration,phased load condition and cross phase failure *** coupling effect of Functional Dependency(FDEP)and Physical Dependency(PDEP)has a unique influence on the failure behavior of *** this article,the coupling effect is analyzed,and the degradation of components is modeled with the positive drift wiener process,in which the drift coefficient is related to environmental conditions and operation ***,failure behavior and system reliability are *** avionics controller is studied as a case,with the degradation time distribution model and simulation algorithm,the coupling effect and dynamical system reliability can be *** show that this modeling method can describe the coupling effects of FDEP and PDEP and their influence on the failure behavior and reliability of the PMS system.

关键词： Functional dependency Phased-mission system Physical dependency reliability evaluation Stochastic degradation process

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Two-dimensional dumbbell silicene as a promising anode material for(Li/Na/K)-ion batteries

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Chinese Physics B 2023年第9期32卷 28-34页

作者：刘曼程子爽张小明李叶枫靳蕾刘丛代学芳刘影王啸天刘国栋 State Key Laboratory of Reliability and Intelligence of Electrical Equipment and School of Materials Science and EngineeringHebei University of TechnologyTianjin 300130China School of Physical Science and Technology Southwest UniversityChongqing 400715China

Rechargeable ion batteries require anode materials with excellent performance,presenting a key challenge for *** paper explores the potential of using two-dimensional dumbbell silicene as an anode material for alkali metal ion batteries through density functional theory(DFT)*** findings demonstrate that alkali metal ions have negative adsorption energies on dumbbell silicene,and the energy barriers for Li/Na/K ion diffusion are as low as0.032 e V/0.055 e V/0.21 e V,indicating that metal ions can easily diffuse across the entire surface of dumbbell ***,the average open circuit voltages of dumbbell silicene as anode for Li-ion,Na-ion,and K-ion batteries are 0.42 V,0.41 V,and 0.60 V,respectively,with corresponding storage capacities of 716 m Ah/g,622 m Ah/g,and 716 m Ah/*** results suggest that dumbbell silicene is an ideal anode material for Li-ion,Na-ion,and K-ion batteries,with high capacity,low open circuit voltage,and high ion diffusion ***,our calculations show that the theoretical capacities obtained using DFT-D2 are higher than those obtained using DFT-D3,providing a valuable reference for subsequent theoretical calculations.

关键词： dumbbell silicene density functional theory anode materials ion batteries

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Achieving high ductility and low in-plane anisotropy in magnesium alloy through a novel texture design strategy

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Journal of Magnesium and Alloys 2024年第7期12卷 2863-2873页

作者： Shi Liu Cheng Wang Hong Ning Zhao-Yuan Meng Kai Guan Hui-Yuan Wang State Key Laboratory of Automotive Simulation and Control Jilin UniversityPR China Key Laboratory of Automobile Materials of Ministry of Education&School of Materials Science and Engineering Nanling CampusJilin UniversityNo.5988 Renmin StreetChangchun130025 PR China State Key Laboratory of Reliability and Intelligence of Electrical Equipment School of Material Science and EngineeringHebei University of TechnologyTianjin300130 PR China

Texture regulation is a prominent method to modify the mechanical properties and anisotropy of magnesium *** this work,the Mg-1Al-0.3Ca-0.5Mn-0.2Gd(wt.%)alloy sheet with TD-tilted and circular texture was fabricated by unidirectional rolling(UR)and multidirectional rolling(MR)method,*** generating a strong in-plane mechanical anisotropy in conventional TD-tilted texture,the novel circular texture sample possessed a weak in-plane yield *** can be rationalized by the similar proportion of soft grains with favorable orientation for basalslip and{10.12}tensile twinning during the uniaxial tension of circular-texture sample along different ***,compared with the TD-tilted texture,the circular texture improved the elongation to failure both along the rolling direction(RD)and transverse direction(TD).By quasi-in-situ EBSD-assisted slip trace analysis,higher activation of basal slip was observed in the circular-texture sample during RD tension,contributing to its excellent *** loading along the TD,the TD-tilted texture promoted the activation of{10.12}tensile twins significantly,thus providing nucleation sites for cracks and deteriorating the *** research may shed new insights into the development of formable and ductile Mg alloy sheets by texture modification.

关键词： Magnesium alloy TD-tilted texture Circular texture In-plane yield anisotropy Ductility

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Enhancing the photocatalytic efficiency by the molecular modification effect derived from pollutant adsorption on highly crystalline BiOBr

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Journal of environmental Sciences 2025年第2期148卷 263-273页

作者： Yang Jin Tongyin Liu Yanpeng Mao Fan Li Chun Hu National Engineering Laboratory for Reducing Emissions from Coal Combustion Engineering Research Center of Environmental Thermal Technology of Ministry of EducationShandong Key Laboratory of Energy Carbon Reduction and Resource UtilizationSchool of Energy and Power EngineeringShandong UniversityJinan 250061China Beijing Enterprises Water Group<China>Investment Limited Beijing 100102China Institute of Environmental Research at Greater Bay Key Laboratory for Water Quality and Conservation of the Pearl River DeltaMinistry of EducationGuangzhou UniversityGuangzhou 510006China Key Laboratory of Drinking Water Science and Technology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China

The adsorption of pollutants can not only promote the direct surface reaction,but also modify the catalyst itself to improve its photoelectric characteristics,which is rarely studied for water treatment with inorganic photocatalyst.A highly crystalline BiOBr(c-BiOBr)was synthesized by a two-step preparation *** to the calcination,the highly crystalline enhanced the interface interaction between pollutant and *** complex of organic pollutant and[Bi_(2)O_(2)]^(2+)could promote the active electron transfer from the adsorbed pollutant to c-BiOBr for the direct pollutant degradation by holes(h^(+)).Moreover,the pollutant adsorption actually modified c-BiOBr and promoted more unpaired electrons,which would coupling with the photoexcitation to promote generate more O_(2)^(•-).The molecular modification effect derived from pollutant adsorption significantly improved the removal of *** work strongly deepens the understanding of the molecularmodification effect from the pollutant adsorption and develops a novel and efficient approach for water treatment.

关键词： Highly crystalline BiOBr Pollutant adsorption Molecular modification Photocatalysis Water treatment

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