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2D/2D Ti_(3)C_(2) MXene/HTiNbO_(5) nanosheets Schottky heterojunction for boosting photothermal-assisted solar-driven photodegradation of tetracycline hydrochloride

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Journal of Materials science & technology 2024年第13期180卷 193-206页

作者： Wen Xiao Huan Yu Chenghao Xu Zhongyi Pu Xiangyu Cheng Fang Yu Chao Liu Qinfang Zhang Zhigang Zou School of Materials Science and Engineering Yancheng Institute of TechnologyYancheng 224051China Jiangsu Provincial Key Laboratory of Eco-Environmental Materials Yancheng Institute of TechnologyYancheng 224051China Eco-Materials and Renewable Energy Research Centre(ERERC) Nanjing UniversityNanjing 210093China

Developing high-efficiency photocatalysts for tetracycline hydrochloride(TCH)degradation is of great sig-nificance to ecosystems and human *** this work,a two-step process of exfoliation and re-stacking was performed to prepare re-stacked HTiNbO_(5) nanosheets(R-HTNS)and then coupled with Ti_(3)C_(2) MXene to construct Ti_(3)C_(2) MXene/R-HTNS(MX/RTS)with a 2D/2D Schottky *** 2D/2D het-erostructures between Ti_(3)C_(2) MXene and R-HTNS can produce an internal electric field and provide max-imum interface area for efficient charge transfer across the intimate *** photocatalytic perfor-mance of samples was evaluated by TCH degradation under simulated *** MX/RTS composites,with an optimal sample of 3-MX/RTS,show enhanced photocatalytic activity for TCH degradation com-pared with *** characterization results reveal that the introduction of Ti_(3)C_(2) MXene can signif-icantly increase specific surface area for providing more reactive sites and broaden the light absorption ***,the incident light energy is absorbed by the Ti_(3)C_(2) MXene component in MX/RTS compos-ites to generate photothermal energy(heat),which facilitates the charge carrier separation and surface reaction ***,the enhanced TCH photodegradation activity for MX/RTS composites is due to the introduction of Ti_(3)C_(2) MXene,which possesses the synergistic effect of the increased specific surface area,improved light-harvesting capacity,2D/2D Schottky heterojunction,and photothermal energy ***,the TCH photodegradation behavior is deliberated with a detailed discussion on various co-existing *** TCH photodegradation,the active radical species are determined for 3-MX/***-cording to the characterization results,the possible TCH photodegradation pathway and mechanism over 3-MX/RTS are *** work may offer a novel insight for constructing MXene-based heterostruc-tured photocatalysts with high efficiency.

关键词： HTiNbO_(5) Ti_(3)C_(2)MXene Schottky heterojunction Photodegradation Phototherma

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Acidic electroreduction CO_(2)to formic acid via interfacial modification of Bi nanoparticles at industrial-level current

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Nano Research 2024年第7期17卷 5817-5825页

作者： Tian Dong Hongdong Li Zhenhui Wang Yanling Geng Rui Chang Xiaofeng Tian Jianping Lai Shouhua Feng Lei Wang Key Laboratory of Eco-Chemical Engineering International Science and Technology Cooperation Base of Eco-Chemical Engineering and Green ManufacturingCollege of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042China Shandong Engineering Research Center for Marine Environment Corrosion and Safety Protection College of Environment and Safety EngineeringQingdao University of Science and TechnologyQingdao 266042China

Electrocatalytic CO_(2)reduction reaction(CO_(2)RR)in acidic media is a promising approach to overcome the unavoidable formation of carbonates in alkaline or neutral ***,the proton-rich environment near the catalyst surface favors hydrogen evolution reactions(HER),leading to lower energy efficiency of the desired products,especially in industrial-level current ***,quaternary ammonium cationic surfactant(cetyltrimethylammonium bromide(CTAB))was introduced into acidic electrolyte to modulate the interfacial microenvironment,which greatly enhanced CO_(2)electroreduction to formic acid(HCOOH)at the Bi/C nanoparticles *** a Bi/C nanoparticles electrode with CTAB added,constant production of formic acid was enabled with a cathodic energy efficiency of>40%and maximum FE_(HCOOH)(FE=Faradaic efficiency)of 86.2%at−400 mA·cm^(−2)over 24 *** with in-situ attenuated total reflection Fourier transform infrared spectroscopy,the concentration of*OCHO intermediates significantly increased after CTAB modification,confirming that the hydrophobic interface microenvironment formed by dynamic adsorption of positively charged long alkyl chains on Bi/C nanoparticle electrodes inhibited HER and improved the selectivity of CO_(2)RR to HCOOH.

关键词： acidic media CO_(2)electrolysis electrolyte additive hydrophobic interfacial microenvironment industrial-level current

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Reconfiguration and self-healing integrated Janus electrospinning nanofiber membranes for durable seawater desalination

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Nano Research 2023年第1期16卷 489-495页

作者： Huijie Liu Jiatai Gu Ye Liu Lei Yang Liming Wang Jianyong Yu Xiaohong Qin Key Laboratory of Textile Science&Technology of Ministry of Education College of TextilesDonghua UniversityShanghai 201620China State Key Laboratory for Modification of Chemical Fibers and Polymer Materials International Joint Laboratory for Advanced Fiber and Lowdimension MaterialsCollege of Materials Science and EngineeringDonghua UniversityShanghai 201620China Innovation Center for Textile Science and Technology Donghua UniversityShanghai 201620China

Janus electrospinning nanofiber membranes have attracted extensive attention in the fields such as solar-driven interfacial desalination,liquid filtration,and waterproof and breathable ***,the Janus structures suffer from weak interfacial bonding and vulnerability to damage,making the durability and sustainability are highly sought after in real-word ***,we fabricate the simply reconfigurable and entirely self-healing Janus evaporator by electrospinning polypropylene glycol based polyurethane(PPG@PU)and polydimethylsiloxane based polyurethane-CNTs(PDMS@PU-CNTs)with different wettability,which are both designed based on dynamic Diels–Alder(DA)*** interface of the Janus membrane is stitched by the covalent bonds to directly improve the interface adhesion to 22 N·m−1,constructing an integrated evaporator,and thereby achieving a stable desalination rate of 1.34 kg·m−2·h−1 under one *** dissociation of DA networks allows the evaporators for self-healing and reconfiguration abilities,after which the photothermal performance is *** is the first work for the crosslinked self-healing polymer to be directly electrospun,achieving the improved interfacial bond and reconfiguration of entire evaporators,which presented promising new design principles and materials for interfacial solar seawater desalination.

关键词： Janus nanofiber membrane electrospinning interfacial bonding solar steam generation seawater desalination

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MOF-templated tubular Ni_(1−x)Co_(x)S_(2)-CdS heterojunction with intensified direct Z-scheme charge transmission for highly promoted visible-light photocatalysis

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Nano Research 2024年第7期17卷 6281-6293页

作者： Chuan Jiang Yuanxin Qiu Xinxin Xin Yanyan Li Huilin Li Hui Wang Jixiang Xu Haifeng Lin Lei Wang Volodymyr Turkevych Key Laboratory of Eco-chemical Engineering International S&T Cooperation Foundation of Eco-chemical Engineering and Green ManufactureCollege of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042China Shandong Provincial Key Laboratory of Olefin Catalysis and Polymerization Key Laboratory of Rubber-Plastics of Ministry of EducationSchool of Polymer Science and EngineeringQingdao University of Science and TechnologyQingdao 266042China V.Bakul Institute for Superhard Materials National Academy of Sciences of UkraineKyiv 04074Ukraine

Hollow semiconductor nanostructures with direct Z-scheme heterojunction have significant advantages for photocatalytic reactions,and optimizing the interfacial charge transmission of Z-scheme heterojunction is the hinge to achieve excellent solar conversion *** this work,tubular Ni_(1−x)Co_(x)S_(2)-CdS heterostructures with reinforced Z-scheme charge transmission were constructed through an In-metal-organic framework(MOF)templated *** Z-scheme charge transfer mechanism was sufficiently confirmed by combining density functional theory(DFT)calculation,X-ray photoelectron spectroscopy(XPS),surface photovoltage spectroscopy(SPV),and radical testing ***,the use of sodium citrate complexant contributes to the formation of intimate heterointerface,and the Fermi level gap between CdS and NiS_(2)is enlarged through Co doping into NiS_(2),which enhances the built-in electric field and photo-carriers transmission driving force for Ni_(1−x)Co_(x)S_(2)-CdS heterojunction,resulting in an evidently promoted activity toward H2 evolution reaction(HER).Under visible-light(λ>400 nm)irradiation,the Ni_(1−x)Co_(x)S_(2)-CdS composite with 10 mol%Co doping and 80 wt.%CdS(NC_(0.10)S-80%CdS)achieved an outstanding HER rate up to 35.94 mmol·g^(−1)·h^(−1)(corresponding to the apparent quantum efficiency of 34.7%at 420 nm),approximately 76.4 times that of 3 wt.%Pt-loaded CdS and it is much superior to that of most CdS-based photocatalysts ever ***,the good photocatalytic durability of Ni_(1−x)Co_(x)S_(2)-CdS heterostructures was validated by cycling and long-term HER *** work could inspire the development of high-performance Z-scheme heterojunction via optimizing the morphology and interfacial charge transmission.

关键词： tubular heterostructure Z-scheme charge transmission interfacial coupling built-in electric field visible-light photocatalysis

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Bioinspired multi-scale core-spun yarn-based solar evaporator for ultra-efficient and durable high-salinity brine desalination

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Fundamental Research 2025年第3期5卷 1144-1152页

作者： Li, Ailin He, Mantang Zheng, Maorong Liu, Han Liu, Ye Liu, Huijie Yu, Jianyong Wang, Liming Qin, Xiaohong Key Laboratory of Textile Science & Technology Ministry of Education College of Textiles Donghua University Shanghai 201620 China Innovation Center for Textile Science and Technology Donghua University Shanghai 201620 China

Solar-driven interfacial desalination has been considered a promising and green technology for relieving worldwide water shortage because of its zero carbon emission. However, salt accumulation during evaporation results in a significant reduction in solar evaporation performance and sustained service life. High-performance and long-term salt-rejecting solar evaporators are urgently desirable. Inspired by the rapid water transfer driven by leaf transpiration and the capillary pressure in woody plants, we developed electrospun polyacrylonitrile (PAN) @carbon nanotubes (CNTs) nanofiber/cotton core-spun yarn (PCCS yarn) based solar evaporator enabled by the multi-branch microchannels and sub-microchannels for ultra-efficient and durable high-salinity brine desalination. The optimal PCCS yarn-based solar evaporator exhibits a record-high evaporation rate of 3.46 kg m⁻²h⁻¹ under one sun illumination among 2D evaporators. Meanwhile, an excellent and stable brine desalination rate of ∼2.75 kg m⁻²h⁻¹ for 100 h continuous solar irradiation is achieved even in 20wt% NaCl solution. The above results are attributed to the massive micro evaporation surfaces formed between nanofibers, rapid water replenishment in the radius direction, and orientational fast water transport by Laplace pressure along and across the PCCS yarn. In addition, the continuous preparation of the core-spun yarn by the conjugated electrospinning technology and the complete fabric production process in the textile industry make it possible for the practical application of the PCCS yarn-based solar evaporator. This work promotes the development of high-performance, long-term and scalable solar desalination devices. © 2023

关键词： Bioinspired design Core-spun yarn Desalination Electrospinning Solar evaporator

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High-Performance Flexible Magnetic textile Fabricated Using Porous Juncus effusus Fiber for Biomechanical Energy Harvesting

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Engineering 2025年第3期46卷 267-277页

作者： Junyao Gong Chunhua Zhang Liangjun Xia Zhaozixuan Zhou Weihao Long Zhuan Fu Sijie Zhou Hua Ji Lixin Du Weilin Xu State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhan 430200China College of Textile Science and Engineering Zhejiang University of Science and TechnologyHangzhou 310018China College of Textiles Donghua UniversityShanghai 201620China Winner Medical Co. Ltd.Wuhan 430200China Luthai Textile Co. Ltd.Zibo 255100China

Mechanical energy produced by human motion is ubiquitous,continuous,and usually not utilized,making it an attractive target for sustainable electricity-harvesting *** this study,flexible magnetic-Juncus effusus(M-JE)fibers were prepared from plant-extracted three-dimensional porous Juncus effusus(JE)fibers decorated with polyurethane and magnetic *** M-JE fibers were woven into fabrics and used for mechanical energy harvesting through electromagnetic *** M-JE fabric and induction coil,attached to the human wrist and waist,yielded continuous and stable voltage(2 V)and current(3 mA)during *** proposed M-JE fabric energy harvester exhibited good energy harvesting potential and was capable of quickly charging commercial capacitors to power small electronic *** proposed M-JE fabric exhibited good mechanical energy harvesting performance,paving the way for the use of natural plant fibers in energy-harvesting fabrics.

关键词： Juncus effusus Magnetic fabrics Electromagnetic induction Energy harvest Mechanical-electrical energy conversion

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Engineered interface of three-dimensional coralliform NiS/FeS_(2)heterostructures for robust electrocatalytic water cleavage

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Nano Research 2024年第6期17卷 4693-4701页

作者： Xin Yu Jing Mei Yeshuang Du Xiaohong Cheng Xing Wang Qi Wu State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhan 430073China Hubei Key Laboratory of Pollutant Analysis&Reuse Technology College of Chemistry and Chemical EngineeringHubei Normal UniversityHuangshi 435002China Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices Hubei University of Arts and ScienceXiangyang 441053China

Heterojunction structures improve the intrinsic activity of electrocatalysts by enhancing the charge transfer between the catalyst and the *** this paper,the NiS/FeS_(2)heterostructured electrocatalyst is fabricated by a simple sulfidation method using an interface engineering strategy to adjust the surface electron density of the *** expected,NiS/FeS_(2)electrocatalyst exhibits superior activity and durable oxygen evolution reaction(OER)stability,requiring only a low overpotential of 183 mV to achieve a current density of 10 mA·cm^(−2)and can be stable for more than 80 h,superior to NiS,FeS_(2)electrocatalyst individually,and precious RuO_(2).Notably,NiS/FeS_(2)is also a good bifunctional electrocatalyst with good overall water splitting performance,and it only requires a voltage 1.56 V to obtain a current density of 10 mA·cm^(−2)for more than 12 ***,the NiS/FeS_(2)hybridization facilitates the formation of coral-like structures,increasing the electrochemical surface area(ECSA)and enhancing the charge transfer efficiency,thus leading to excellent electrocatalytic *** work proposes a constructive strategy for designing efficient electrocatalysts based on interface engineering,and lays a foundation for designing a new class of electrocatalysts.

关键词： NiS/FeS_(2) interface engineering nanorods bifunctional water splitting

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Spatial conﬁnement of zeolitic imidazolate framework deposits by porous carbon nanospheres for dual-atom catalyst towards high-performance oxygen reduction reaction

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Nano Research 2023年第8期16卷 11464-11472页

作者： Jiayi Zhao Ping Li Kaicai Fan Wenjie Wei Fenghong Lu Huimin Zhao Bin Li Lingbo Zong Lei Wang Key Laboratory of Eco-chemical Engineering College of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042China College of Materials Science and Engineering Qingdao University of Science and TechnologyQingdao 266042China

Dual atom catalysts(DACs),are promising electrocatalysts for oxygen reduction reaction(ORR)on account of the potential dual-atom active sites for the optimized adsorption of catalytic intermediates and the lower reaction energy ***,spatial conﬁnement strategy to fabricate DACs with well-defined Fe,Co dual-atom active site is proposed by implanting zeolitic imidazolate frameworks inside the pores of highly porous carbon nanospheres(Fe/Co-SAs-Nx-PCNSs).The atomically dispersed dual-atom active sites facilitate the adsorption/desorption of ***,the spatial conﬁnement effect protects metal atoms *** from the rich accessible dual-atom active sites and boosted mass transport,we achieve remarkable ORR performance with half-wave potential up to 0.91 and 0.8 V(*** hydrogen electrode(RHE)),and long-term stability up to 10 h in both alkaline and acidic *** remarkably enhanced ORR catalytic property of our as-developed DACs is in the rank of excellence for 1%.The as-developed rechargeable Zn-air battery(ZAB)with Fe/Co-SAs-Nx-PCNSs air cathode delivers ultrahigh power density of 216 mW·cm^(−2),outstanding specific capacity of 813 mAh·g^(−1),and promising cycling operation durability over 160 *** flexible Zn-air battery also exhibits excellent specific capacity,cycling stability,and flexibility *** work opens up a new pathway for the multiscale design of efficient electrocatalysts with atomically dispersed multiple active sites.

关键词： spatial confinement zeolitic imidazolate framework porous carbon nanospheres(PCNSs) dual-atom catalyst oxygen reduction reaction(ORR)

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Environmental characteristics of trace metals in seawater from the Ninety East Ridge in the Indian Ocean

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Journal of Oceanology and Limnology 2024年第4期42卷 1119-1129页

作者： Jingxi LI Di ZHANG Fenghua JIANG Hong CHEN Wei CAO Chengjun SUN Key Laboratory of Marine Eco-Environmental Science and Technology First Institute of OceanographyMinistry of Natural ResourcesQingdao 266061China College of Safety and Environmental Engineering Shandong University of Science and TechnologyQingdao 266590China Laoshan Laboratory of Marine Science and Technology Laboratory of Marine Drugs and Biological ProductsQingdao 266071China

The Ninety East Ridge in the Indian Ocean has complex and unique *** concentrations and distribution characteristics of 10 trace metals(V,Cr,Mn,Fe,Co,Ni,Cu,Cd,Pb,and U)in seawater from the Ninety East Ridge in the Indian Ocean were *** show that the average concentrations of different trace metals in all the collected seawater samples were 1.134μg/L for V,0.158μg/L for Cr,0.489μg/L for Mn,0.427μg/L for Fe,0.011μg/L for Co,0.395μg/L for Ni,0.403μg/L for Cu,0.097μg/L for Cd,0.139μg/L for Pb,and 3.470μg/L for *** in the horizontal and vertical distributions of all measured trace metals were revealed,and the occurrence of high concentrations was *** addition,the significant differences in the concentration distribution of different trace metals in seawater on both sides of the Ninety East Ridge present regional segmentation in the area for various trace metals in deep sea *** study provided basic data for future investigations on the environmental and ecological impact of trace metals in the Indian Ocean and the potential water mass transport mechanism.

关键词： trace metal environmental characteristic Ninety East Ridge seawater Indian Ocean

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Trace ruthenium promoted dual-reconstruction of CoFeP@C/NF for activating overall water splitting performance beyond precious-metals

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Nano Research 2023年第8期16卷 10810-10821页

作者： Jinhong Ren Jie Liu Yunmei Du Shuangshuang Li Mengmeng Wang Bin Li Bo Yang Lei Wang Yanru Liu College of Environment and Safety Engineering Qingdao University of Science and TechnologyQingdao 266042China College of Chemistry and Molecular Engineering Qingdao University of Science and TechnologyKey Laboratory of Eco-chemical EngineeringKey Laboratory of Optic-electric Sensing and Analytical Chemistry of Life ScienceTaishan Scholar Advantage and Characteristic Discipline Team of Eco Chemical Process and TechnologyQingdao 266042China College of Materials Science and Engineering Qingdao University of Science and TechnologyQingdao 266042China

At present,Ru dopants mainly enhance electrocatalytic performance by inducing strain,vacancy,local electron difference,and ***,this work innovatively proposes that trace Ru atoms induce dual-reconstruction of phosphide by regulating the electronic configuration and proportion of Co–P/Co–O species,and ultimately activate superb electrocatalytic ***,Ru-CoFeP@C/nickel foam(NF)is reconstructed to generate hydrophilic Co(OH)_(2)nanosheets during the hydrogen evolution reaction(HER)process,further accelerating the alkaline HER kinetics of *** the as-formed CoOOH during the oxygen evolution reaction(OER)process directly accelerates the oxygen overflow *** expected,the overpotential at 100 mA·cm^(−2)(η100)values of the reconstructed Ru-CoFeP@C/NF are 0.104 and 0.257 V for HER and OER,which are greatly lower than that of Pt/C-NF and RuO_(2)-NF benchmarks,*** work provides guidance for the construction of highperformance catalysts for HER and OER dual *** work provides a new idea for the optimization of catalyst structure and electrocatalytic performance.

关键词： Ru doping dual reconstruction overall water splitting phosphide Ru-CoFeP@C/nickel foam(NF)

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